GB1045050A - Process for the manufacture of unsaturated carboxylic acid esters - Google Patents

Process for the manufacture of unsaturated carboxylic acid esters

Info

Publication number
GB1045050A
GB1045050A GB11287/64A GB1128764A GB1045050A GB 1045050 A GB1045050 A GB 1045050A GB 11287/64 A GB11287/64 A GB 11287/64A GB 1128764 A GB1128764 A GB 1128764A GB 1045050 A GB1045050 A GB 1045050A
Authority
GB
United Kingdom
Prior art keywords
carbon monoxide
alcohol
chloride
manufacture
carboxylic acid
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB11287/64A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Toray Industries Inc
Original Assignee
Toyo Rayon Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Toyo Rayon Co Ltd filed Critical Toyo Rayon Co Ltd
Publication of GB1045050A publication Critical patent/GB1045050A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
    • C07C69/52—Esters of acyclic unsaturated carboxylic acids having the esterified carboxyl group bound to an acyclic carbon atom
    • C07C69/533—Monocarboxylic acid esters having only one carbon-to-carbon double bond
    • C07C69/54—Acrylic acid esters; Methacrylic acid esters
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C17/00—Preparation of halogenated hydrocarbons
    • C07C17/093—Preparation of halogenated hydrocarbons by replacement by halogens
    • C07C17/10—Preparation of halogenated hydrocarbons by replacement by halogens of hydrogen atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/36—Preparation of carboxylic acid esters by reaction with carbon monoxide or formates
    • C07C67/37—Preparation of carboxylic acid esters by reaction with carbon monoxide or formates by reaction of ethers with carbon monoxide
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
    • C07C2601/16—Systems containing only non-condensed rings with a six-membered ring the ring being unsaturated

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)

Abstract

In a process for the manufacture of b , g -unsaturated carboxylic acid esters, three components consisting of (1) an allylic compound which has a structure of <FORM:1045050/C2/1> (where Hal. is halogen) or <FORM:1045050/C2/2> (2) carbon monoxide and (3) an alcohol, or consisting of (1) an allylic compound having the structure <FORM:1045050/C2/3> (where X is a halogen atom or an -OY group, where Y is a hydrogen atom, an alkyl radical, an aryl radical or an organic acid residue), (2) carbon monoxide and (3) a cyclic ether, are caused to react in the presence of a catalyst essentially consisting of a noble metal of Group VII-VIII in the Periodic Table, e.g. palladium, rhodium, rhenium or a compound comprising the noble metals, e.g. oxide, halide, nitrates or complex salt. Many examples are given including using allyl chloride, methallyl chloride, tetrahydrofuran, propylene oxide, bromocyclohexene, allyl ethyl ether, acetic ester of 3-pentene-2-ol, crotyl alcohol, 1-chloro-n-octene-2-chloride and carbon monoxide and alcohol in the presence of compounds of palladium, rhodium and rhenium.
GB11287/64A 1963-03-22 1964-03-17 Process for the manufacture of unsaturated carboxylic acid esters Expired GB1045050A (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
JP1340763 1963-03-22
JP1700463 1963-04-03
JP3773063 1963-07-29

Publications (1)

Publication Number Publication Date
GB1045050A true GB1045050A (en) 1966-10-05

Family

ID=27280236

Family Applications (1)

Application Number Title Priority Date Filing Date
GB11287/64A Expired GB1045050A (en) 1963-03-22 1964-03-17 Process for the manufacture of unsaturated carboxylic acid esters

Country Status (2)

Country Link
DE (1) DE1493238A1 (en)
GB (1) GB1045050A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0081152A1 (en) * 1981-12-04 1983-06-15 Hoechst Aktiengesellschaft Process for preparing acetic-anhydride and/or acetic-acid and/or ethylidene diacetate

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0081152A1 (en) * 1981-12-04 1983-06-15 Hoechst Aktiengesellschaft Process for preparing acetic-anhydride and/or acetic-acid and/or ethylidene diacetate

Also Published As

Publication number Publication date
DE1493238A1 (en) 1969-06-04

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