GB1034042A - Polyoxyalkylene quaternary ammonium compounds as dyeing auxiliaries - Google Patents

Polyoxyalkylene quaternary ammonium compounds as dyeing auxiliaries

Info

Publication number
GB1034042A
GB1034042A GB3562862A GB3562862A GB1034042A GB 1034042 A GB1034042 A GB 1034042A GB 3562862 A GB3562862 A GB 3562862A GB 3562862 A GB3562862 A GB 3562862A GB 1034042 A GB1034042 A GB 1034042A
Authority
GB
United Kingdom
Prior art keywords
moles
oxide
propylene oxide
ammonium compounds
oleylamine
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB3562862A
Inventor
Jakob Bindler
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Novartis AG
Original Assignee
JR Geigy AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by JR Geigy AG filed Critical JR Geigy AG
Priority to GB3562862A priority Critical patent/GB1034042A/en
Publication of GB1034042A publication Critical patent/GB1034042A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/40Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
    • C08G59/50Amines

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Coloring (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

Quaternary ammonium compounds are prepared by reacting (A) an addition product of 1 mole of a primary alkyl or alkenyl amine of 12-22 carbon atoms and 1-2 moles of styrene oxide followed by 10-30 moles of ethylene oxide with (B) 1 mole of a reactive ester of a strong acid and a C1-4 alkanol. Up to 2 moles of propylene oxide may also be present in the addition product. The reaction may take place at 60-120 DEG C. Amines specified are dodecylamine, tetradecylamine, hexadecylamine, docosylamine, octadecenylamine, octodecylamine, stearylamine or olcylamine. Esters specified are dimethyl sulphate, diethyl sulphate, methyl or ethyl chlorides, bromides or iodides and the methyl esters of benzene, toluene, halobenzene and nitrobenzene sulphonic acids.ALSO:Quarternary ammonium compounds suitable as dyeing auxiliaries are prepared by the addition of 1-2 moles of styrene oxide followed by 0-2 moles of propylene oxide and then 10-30 moles of ethylene oxide to 1 mole of a C12-22 alkyl or alkenyl primary amine and treating the product with an ester of a C1-4 alkanol and a strong acid 0.5-2% of the compound may be added to an acid bath of an anionic dyestuff, e.g. a sulphonated dioxazine dyestuff, used in the dyeing of wool to produce a deepening and levelling of shade. In example (1) a compound produced by adding styrene oxide, propylene oxide and ethylene oxide to oleylamine and treating the product with dimethyl sulphate is added to wool dyeing solution comprising Sirius Light Blue FF2GL (the sodium salt of 2, 6-bis-phenylamino-9, 10-dichlorotriphenodioxazine-di-sulphonic acid) in ag. acetic acid. In other examples the oleylamine is replaced by stearyl amine and the dye is Remstral (Registered Trade Mark) Blue FF2GL(2), the oleylamine is replaced by dodecylamine (3) and the propylene oxide is omitted (4).
GB3562862A 1962-09-19 1962-09-19 Polyoxyalkylene quaternary ammonium compounds as dyeing auxiliaries Expired GB1034042A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
GB3562862A GB1034042A (en) 1962-09-19 1962-09-19 Polyoxyalkylene quaternary ammonium compounds as dyeing auxiliaries

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB3562862A GB1034042A (en) 1962-09-19 1962-09-19 Polyoxyalkylene quaternary ammonium compounds as dyeing auxiliaries

Publications (1)

Publication Number Publication Date
GB1034042A true GB1034042A (en) 1966-06-29

Family

ID=10379830

Family Applications (1)

Application Number Title Priority Date Filing Date
GB3562862A Expired GB1034042A (en) 1962-09-19 1962-09-19 Polyoxyalkylene quaternary ammonium compounds as dyeing auxiliaries

Country Status (1)

Country Link
GB (1) GB1034042A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3972855A (en) * 1971-11-19 1976-08-03 Modokemi Aktiebolag Quaternary ammonium compounds and treatment of plastic and other materials therewith
US4104175A (en) * 1973-12-10 1978-08-01 Modokemi Aktiebolag Aqueous solutions of quaternary ammonium compounds
EP0053389A1 (en) * 1980-12-01 1982-06-09 Toho Chemical Industry Co., Ltd. Process for preparing cationic surface active agents

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3972855A (en) * 1971-11-19 1976-08-03 Modokemi Aktiebolag Quaternary ammonium compounds and treatment of plastic and other materials therewith
US4104175A (en) * 1973-12-10 1978-08-01 Modokemi Aktiebolag Aqueous solutions of quaternary ammonium compounds
EP0053389A1 (en) * 1980-12-01 1982-06-09 Toho Chemical Industry Co., Ltd. Process for preparing cationic surface active agents

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