FR3133544B1 - Matériau catalytique à base d’un élément du groupe VIB et d’un élément du groupe IVB pour la production d’hydrogène par électrolyse de l’eau - Google Patents

Matériau catalytique à base d’un élément du groupe VIB et d’un élément du groupe IVB pour la production d’hydrogène par électrolyse de l’eau Download PDF

Info

Publication number
FR3133544B1
FR3133544B1 FR2202406A FR2202406A FR3133544B1 FR 3133544 B1 FR3133544 B1 FR 3133544B1 FR 2202406 A FR2202406 A FR 2202406A FR 2202406 A FR2202406 A FR 2202406A FR 3133544 B1 FR3133544 B1 FR 3133544B1
Authority
FR
France
Prior art keywords
group
catalytic material
hydrogen
production
material based
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
FR2202406A
Other languages
English (en)
Other versions
FR3133544A1 (fr
Inventor
Audrey Bonduelle
Mona Marie Obadia
Quentin Cacciuttolo
Stephan Steinmann
Nawras Abidi
Laetitia Dubau
Eric Sibert
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Grenoble Inp Inst Polytechnique De Grenoble
Centre National de la Recherche Scientifique CNRS
IFP Energies Nouvelles IFPEN
Institut Polytechnique de Grenoble
Ecole Normale Superieure de Lyon
Universite Grenoble Alpes
Universite Savoie Mont Blanc
Universite Claude Bernard Lyon 1
Original Assignee
Grenoble Inp Inst Polytechnique De Grenoble
Centre National de la Recherche Scientifique CNRS
IFP Energies Nouvelles IFPEN
Institut Polytechnique de Grenoble
Ecole Normale Superieure de Lyon
Universite Grenoble Alpes
Universite Savoie Mont Blanc
Universite Claude Bernard Lyon 1
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Grenoble Inp Inst Polytechnique De Grenoble, Centre National de la Recherche Scientifique CNRS, IFP Energies Nouvelles IFPEN, Institut Polytechnique de Grenoble, Ecole Normale Superieure de Lyon, Universite Grenoble Alpes, Universite Savoie Mont Blanc, Universite Claude Bernard Lyon 1 filed Critical Grenoble Inp Inst Polytechnique De Grenoble
Priority to FR2202406A priority Critical patent/FR3133544B1/fr
Priority to EP23708826.5A priority patent/EP4493317B1/fr
Priority to US18/847,907 priority patent/US20250207277A1/en
Priority to PCT/EP2023/055823 priority patent/WO2023174768A1/fr
Priority to CN202380028346.XA priority patent/CN118900937A/zh
Publication of FR3133544A1 publication Critical patent/FR3133544A1/fr
Application granted granted Critical
Publication of FR3133544B1 publication Critical patent/FR3133544B1/fr
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B11/00—Electrodes; Manufacture thereof not otherwise provided for
    • C25B11/04—Electrodes; Manufacture thereof not otherwise provided for characterised by the material
    • C25B11/051—Electrodes formed of electrocatalysts on a substrate or carrier
    • C25B11/073—Electrodes formed of electrocatalysts on a substrate or carrier characterised by the electrocatalyst material
    • C25B11/091—Electrodes formed of electrocatalysts on a substrate or carrier characterised by the electrocatalyst material consisting of at least one catalytic element and at least one catalytic compound; consisting of two or more catalytic elements or catalytic compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/066—Zirconium or hafnium; Oxides or hydroxides thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/18—Carbon
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/883—Molybdenum and nickel
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/02—Sulfur, selenium or tellurium; Compounds thereof
    • B01J27/04—Sulfides
    • B01J27/047—Sulfides with chromium, molybdenum, tungsten or polonium
    • B01J27/051—Molybdenum
    • B01J27/0515—Molybdenum with iron group metals or platinum group metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/186—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J27/188—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with chromium, molybdenum, tungsten or polonium
    • B01J27/19—Molybdenum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08—Heat treatment
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08—Heat treatment
    • B01J37/10—Heat treatment in the presence of water, e.g. steam
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/20—Sulfiding
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/28—Phosphorising
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B1/00—Electrolytic production of inorganic compounds or non-metals
    • C25B1/01—Products
    • C25B1/02—Hydrogen or oxygen
    • C25B1/04—Hydrogen or oxygen by electrolysis of water
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B1/00—Electrolytic production of inorganic compounds or non-metals
    • C25B1/01—Products
    • C25B1/27—Ammonia
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B11/00—Electrodes; Manufacture thereof not otherwise provided for
    • C25B11/04—Electrodes; Manufacture thereof not otherwise provided for characterised by the material
    • C25B11/051—Electrodes formed of electrocatalysts on a substrate or carrier
    • C25B11/054—Electrodes comprising electrocatalysts supported on a carrier
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B11/00—Electrodes; Manufacture thereof not otherwise provided for
    • C25B11/04—Electrodes; Manufacture thereof not otherwise provided for characterised by the material
    • C25B11/051—Electrodes formed of electrocatalysts on a substrate or carrier
    • C25B11/055—Electrodes formed of electrocatalysts on a substrate or carrier characterised by the substrate or carrier material
    • C25B11/057—Electrodes formed of electrocatalysts on a substrate or carrier characterised by the substrate or carrier material consisting of a single element or compound
    • C25B11/061—Metal or alloy
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B11/00—Electrodes; Manufacture thereof not otherwise provided for
    • C25B11/04—Electrodes; Manufacture thereof not otherwise provided for characterised by the material
    • C25B11/051—Electrodes formed of electrocatalysts on a substrate or carrier
    • C25B11/055—Electrodes formed of electrocatalysts on a substrate or carrier characterised by the substrate or carrier material
    • C25B11/057—Electrodes formed of electrocatalysts on a substrate or carrier characterised by the substrate or carrier material consisting of a single element or compound
    • C25B11/061—Metal or alloy
    • C25B11/063—Valve metal, e.g. titanium
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B11/00—Electrodes; Manufacture thereof not otherwise provided for
    • C25B11/04—Electrodes; Manufacture thereof not otherwise provided for characterised by the material
    • C25B11/051—Electrodes formed of electrocatalysts on a substrate or carrier
    • C25B11/055—Electrodes formed of electrocatalysts on a substrate or carrier characterised by the substrate or carrier material
    • C25B11/057—Electrodes formed of electrocatalysts on a substrate or carrier characterised by the substrate or carrier material consisting of a single element or compound
    • C25B11/065—Carbon
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B11/00—Electrodes; Manufacture thereof not otherwise provided for
    • C25B11/04—Electrodes; Manufacture thereof not otherwise provided for characterised by the material
    • C25B11/051—Electrodes formed of electrocatalysts on a substrate or carrier
    • C25B11/055—Electrodes formed of electrocatalysts on a substrate or carrier characterised by the substrate or carrier material
    • C25B11/057—Electrodes formed of electrocatalysts on a substrate or carrier characterised by the substrate or carrier material consisting of a single element or compound
    • C25B11/067—Inorganic compound e.g. ITO, silica or titania
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B11/00—Electrodes; Manufacture thereof not otherwise provided for
    • C25B11/04—Electrodes; Manufacture thereof not otherwise provided for characterised by the material
    • C25B11/051—Electrodes formed of electrocatalysts on a substrate or carrier
    • C25B11/073—Electrodes formed of electrocatalysts on a substrate or carrier characterised by the electrocatalyst material
    • C25B11/075—Electrodes formed of electrocatalysts on a substrate or carrier characterised by the electrocatalyst material consisting of a single catalytic element or catalytic compound
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B3/00—Electrolytic production of organic compounds
    • C25B3/01—Products
    • C25B3/07—Oxygen containing compounds
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B3/00—Electrolytic production of organic compounds
    • C25B3/20—Processes
    • C25B3/25—Reduction
    • C25B3/26—Reduction of carbon dioxide
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
    • H01M4/90—Selection of catalytic material
    • H01M4/9075—Catalytic material supported on carriers, e.g. powder carriers
    • H01M4/9083—Catalytic material supported on carriers, e.g. powder carriers on carbon or graphite
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/36—Hydrogen production from non-carbon containing sources, e.g. by water electrolysis

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • Metallurgy (AREA)
  • Inorganic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • General Chemical & Material Sciences (AREA)
  • Catalysts (AREA)
  • Electrodes For Compound Or Non-Metal Manufacture (AREA)
  • Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)

Abstract

Matériau catalytique comprenant au moins un métal du groupe VIB au moins en partie sous forme sulfurée, au moins un métal du groupe IVB au moins en partie sous forme sulfurée, et un support électro-conducteur dans lequel ledit métal du groupe VIB est choisi parmi le molybdène et/ou le tungstène, ledit métal du groupe IVB est choisi parmi le titane, le zirconium et/ou l’hafnium.
FR2202406A 2022-03-18 2022-03-18 Matériau catalytique à base d’un élément du groupe VIB et d’un élément du groupe IVB pour la production d’hydrogène par électrolyse de l’eau Active FR3133544B1 (fr)

Priority Applications (5)

Application Number Priority Date Filing Date Title
FR2202406A FR3133544B1 (fr) 2022-03-18 2022-03-18 Matériau catalytique à base d’un élément du groupe VIB et d’un élément du groupe IVB pour la production d’hydrogène par électrolyse de l’eau
EP23708826.5A EP4493317B1 (fr) 2022-03-18 2023-03-08 Matériau catalytique à base d'un élément du groupe vib et d'un élément du groupe ivb pour la production d'hydrogène par électrolyse de l'eau
US18/847,907 US20250207277A1 (en) 2022-03-18 2023-03-08 Catalytic material based on a group vib element and a group ivb element for the production of hydrogen by electrolysis of water
PCT/EP2023/055823 WO2023174768A1 (fr) 2022-03-18 2023-03-08 Matériau catalytique à base d'un élément du groupe vib et d'un élément du groupe ivb pour la production d'hydrogène par électrolyse de l'eau
CN202380028346.XA CN118900937A (zh) 2022-03-18 2023-03-08 用于通过电解水制氢的基于第vib族元素和第ivb族元素的催化材料

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR2202406A FR3133544B1 (fr) 2022-03-18 2022-03-18 Matériau catalytique à base d’un élément du groupe VIB et d’un élément du groupe IVB pour la production d’hydrogène par électrolyse de l’eau
FR2202406 2022-03-18

Publications (2)

Publication Number Publication Date
FR3133544A1 FR3133544A1 (fr) 2023-09-22
FR3133544B1 true FR3133544B1 (fr) 2024-03-08

Family

ID=82482723

Family Applications (1)

Application Number Title Priority Date Filing Date
FR2202406A Active FR3133544B1 (fr) 2022-03-18 2022-03-18 Matériau catalytique à base d’un élément du groupe VIB et d’un élément du groupe IVB pour la production d’hydrogène par électrolyse de l’eau

Country Status (5)

Country Link
US (1) US20250207277A1 (fr)
EP (1) EP4493317B1 (fr)
CN (1) CN118900937A (fr)
FR (1) FR3133544B1 (fr)
WO (1) WO2023174768A1 (fr)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN117660806B (zh) * 2023-12-08 2025-11-25 成都工业学院 乙醇溶剂调控的可变组分Mo-Ni合金、制备方法及其应用

Family Cites Families (28)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102849798B (zh) 2012-08-29 2014-02-26 北京化工大学 一种二硫化钼纳米片薄膜材料及其制备方法
FR3007427B1 (fr) 2013-06-20 2016-07-01 Ifp Energies Now Couche active a base de particules metalliques sur support conducteur poreux, methode de fabrication et utilisation en tant que cathode pour l'electroreduction de dioxyde de carbone.
CN105655140B (zh) 2016-03-07 2018-04-10 浙江理工大学 一种片状二硫化钼/硫化镍—石墨烯复合材料的制备方法
CN107574454B (zh) 2017-09-19 2019-04-05 河北工业大学 一种用于电化学析氢的掺钨二氧化钒纳米棒/二硫化钼复合材料及其制备方法
CN107904620B (zh) 2017-10-23 2020-01-10 温州大学 一种三维石墨烯/碳纳米管基二硫化钼/硫化钴复合材料电催化剂及其制备方法和应用
CN107881529B (zh) 2017-10-27 2019-08-27 江苏大学 一种复合析氢电催化材料及制备方法
CN108517534B (zh) 2018-03-09 2020-06-23 三峡大学 一种cvd方法制备多功能的镍掺杂二硫化钼原位电极
CN108441879B (zh) 2018-03-21 2019-08-30 吉林大学 纳米多孔镍-二硫化钼/石墨烯复合材料的制备方法及应用
CN108654647B (zh) 2018-04-28 2020-10-02 安徽大学 一种金纳米颗粒/二硫化钼复合物的制备方法及其作为析氢反应催化剂的应用
CN110479311A (zh) 2018-05-14 2019-11-22 中国科学院大连化学物理研究所 一种杂原子掺杂多孔二硫化钼包裹石墨烯的制备方法
CN109097790B (zh) 2018-06-19 2020-04-21 重庆大学 体相析氢电极的制备方法及电解水制氢反应器
CN109046409A (zh) 2018-09-11 2018-12-21 浙江理工大学 一种磷化钴-二硫化钼纳米片@碳纳米管的制备方法
CN109161919A (zh) 2018-09-11 2019-01-08 浙江理工大学 一种类石墨相氮化碳-二硫化钼二元复合物的制备方法
FR3089134B1 (fr) 2018-11-30 2020-11-13 Ifp Energies Now Procédé de préparation d’un matériau catalytique d’électrode pour des réactions de réduction électrochimique préparé par électroréduction.
FR3089133B1 (fr) 2018-11-30 2024-04-19 Ifp Energies Now Procédé de préparation d’une couche active d’électrode pour des réactions de réduction électrochimique
CN109796044B (zh) 2019-03-22 2021-07-06 南京晓庄学院 二硫化钼、钴修饰的二硫化钼、负载Pd的纳米片及其合成方法和应用
CN109939699B (zh) 2019-04-16 2022-04-05 湘潭大学 一种钼掺杂二硫化钒微米花材料及其制备方法和应用
CN111847513A (zh) 2019-04-28 2020-10-30 中国科学院大连化学物理研究所 一种多原子共掺杂二硫化钼及其制备方法与应用
CN110252345B (zh) 2019-05-10 2021-07-20 吉林大学 具有手风琴结构的石墨烯-二硫化钼/二氧化钛复合材料的制备方法及其应用
CN110026210B (zh) 2019-05-27 2020-06-26 南京工业大学 一种二硫化钼复合材料双功能电催化剂的制备方法与应用
CN110327946B (zh) 2019-08-09 2022-02-08 哈尔滨师范大学 一种二硫化钼/硒化镍复合材料及其制备方法和应用
US11413611B2 (en) 2019-12-09 2022-08-16 King Fahd University Of Petroleum And Minerals Molybdenum sulfide nanosheets decorated with iron phosphide for hydrogen gas evolution
CN111229260B (zh) 2020-03-02 2021-07-20 齐鲁工业大学 用于可见光下分解水制氢的硫化镉纳米颗粒/二硫化钼纳米带异质结构催化剂及其制备方法
CN111992227B (zh) 2020-08-28 2024-03-15 山东安润氢储新能源科技有限公司 一种镍钴-二硫化钼中空纳米复合材料及其合成方法与电催化析氢应用
CN113061928B (zh) 2021-03-24 2022-05-20 三峡大学 二硫化钼纳米片@硫化钴纳米颗粒阵列电极的制备方法
CN113755827A (zh) 2021-08-23 2021-12-07 上海纳米技术及应用国家工程研究中心有限公司 以钛网为基底的超薄二硫化钼晶体纳米复合材料的制备方法及产品和应用
CN113668008B (zh) 2021-08-25 2023-01-17 常州大学 一种二硫化钼/钴碳纳米管电催化剂及其制备方法和应用
CN113846347B (zh) 2021-09-11 2023-03-28 武汉科技大学 一种碳/二硫化钼-富氮氮化钼复合材料及其制备与电催化析氢应用

Also Published As

Publication number Publication date
CN118900937A (zh) 2024-11-05
US20250207277A1 (en) 2025-06-26
EP4493317A1 (fr) 2025-01-22
FR3133544A1 (fr) 2023-09-22
EP4493317B1 (fr) 2026-02-25
WO2023174768A1 (fr) 2023-09-21
EP4493317C0 (fr) 2026-02-25

Similar Documents

Publication Publication Date Title
FR3133544B1 (fr) Matériau catalytique à base d’un élément du groupe VIB et d’un élément du groupe IVB pour la production d’hydrogène par électrolyse de l’eau
Snead et al. Refractory alloys: vanadium, niobium, molybdenum, tungsten
FR3117381B1 (fr) Procédé de production d’un catalyseur comprenant au moins un métal du groupe VIB, au moins un métal du groupe VIIIB et un support à base d’oxyde(s)
BR112021024096A2 (pt) Instrumento para cirurgia com plasma e processo para geração de plasma
EP1275995A3 (fr) Système optique avec plusieurs éléments optiques
FR3089134B1 (fr) Procédé de préparation d’un matériau catalytique d’électrode pour des réactions de réduction électrochimique préparé par électroréduction.
FR3065722B1 (fr) Vitrage colore et son procede d'obtention
DE60332413D1 (de) Oxidations- und ermüdungsbeständige metallische Beschichtung
FR3089133B1 (fr) Procédé de préparation d’une couche active d’électrode pour des réactions de réduction électrochimique
FR3140708B1 (fr) Substrat comportant des nanofils
FR3073753B1 (fr) Catalyseur a base d'un compose furanique et son utilisation dans un procede d'hydrotraitement et/ou d'hydrocraquage
FR2388401A1 (fr) Disque perfectionne pour structure d'anode de tube a rayons x
FR3096169B1 (fr) Tête de logement pour un instrument, comprenant une pièce mobile
JPH0337027B2 (fr)
FR3091534B1 (fr) Procede d’ hydrocraquage en deux etapes pour la production de naphta comprenant une etape d’hydrogenation mise en œuvre en aval de la deuxieme etape d’hydrocraquage
WO2016005027A1 (fr) Dispositif amélioré pour soutenir des éléments préformés pour produire des superstructures uniques pour prothèses dentaires et système de soutien de ce dispositif sur la machine de traitement desdits éléments préformés
JPH01250614A (ja) ガスベアリング要素
FR3122593B1 (fr) Procédé de façonnage d'un produit semi-fini destiné à un élément de contact électrique, produit semi-fini destiné à un élément de contact électrique
GB1051009A (fr)
FR3109897B1 (fr) Catalyseur d’hydrogénation sélective comprenant un support spécifique en partie sous forme aluminate
ATE533870T1 (de) Nitridierter mo-legierungswerkstoff mit hoher korrosionsbeständigkeit, hoher festigkeit und hoher zähigkeit und herstellungsverfahren dafür
FR3091709B1 (fr) Superalliage à base de nickel à tenue mécanique élevée à haute température
BR112022023593A2 (pt) Peça de desgaste hierárquica e método para fabricar uma peça de desgaste
FR3105319B1 (fr) Bague pour élément de liaison, élément de liaison et procédé de fabrication correspondant
FR3150239B1 (fr) Ensemble comprenant un segment d’arret axial et un outil de deverrouillage dudit segment d’arret axial et procede de deverrouillage d’un segment d’arret axial domaine technique de l’invention

Legal Events

Date Code Title Description
PLFP Fee payment

Year of fee payment: 2

PLSC Publication of the preliminary search report

Effective date: 20230922

PLFP Fee payment

Year of fee payment: 3

PLFP Fee payment

Year of fee payment: 4

PLFP Fee payment

Year of fee payment: 5