FR3089134B1 - Procédé de préparation d’un matériau catalytique d’électrode pour des réactions de réduction électrochimique préparé par électroréduction. - Google Patents

Procédé de préparation d’un matériau catalytique d’électrode pour des réactions de réduction électrochimique préparé par électroréduction. Download PDF

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Publication number
FR3089134B1
FR3089134B1 FR1872181A FR1872181A FR3089134B1 FR 3089134 B1 FR3089134 B1 FR 3089134B1 FR 1872181 A FR1872181 A FR 1872181A FR 1872181 A FR1872181 A FR 1872181A FR 3089134 B1 FR3089134 B1 FR 3089134B1
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France
Prior art keywords
catalytic material
precursor
reduction reactions
electrochemical reduction
electroreduction
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FR1872181A
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English (en)
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FR3089134A1 (fr
Inventor
Audrey Bonduelle-Skrzypczak
Sofiane Belaid
David Pasquier
Emmanuelle Trela-Baudot
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IFP Energies Nouvelles IFPEN
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IFP Energies Nouvelles IFPEN
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Priority to FR1872181A priority Critical patent/FR3089134B1/fr
Priority to EP19806186.3A priority patent/EP3887572A1/fr
Priority to PCT/EP2019/081705 priority patent/WO2020109062A1/fr
Priority to US17/295,775 priority patent/US20220018033A1/en
Publication of FR3089134A1 publication Critical patent/FR3089134A1/fr
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    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B11/00—Electrodes; Manufacture thereof not otherwise provided for
    • C25B11/04—Electrodes; Manufacture thereof not otherwise provided for characterised by the material
    • C25B11/051—Electrodes formed of electrocatalysts on a substrate or carrier
    • C25B11/073—Electrodes formed of electrocatalysts on a substrate or carrier characterised by the electrocatalyst material
    • C25B11/091—Electrodes formed of electrocatalysts on a substrate or carrier characterised by the electrocatalyst material consisting of at least one catalytic element and at least one catalytic compound; consisting of two or more catalytic elements or catalytic compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B1/00—Electrolytic production of inorganic compounds or non-metals
    • C25B1/01—Products
    • C25B1/02—Hydrogen or oxygen
    • C25B1/04—Hydrogen or oxygen by electrolysis of water
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B1/00—Electrolytic production of inorganic compounds or non-metals
    • C25B1/01—Products
    • C25B1/27—Ammonia
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B11/00—Electrodes; Manufacture thereof not otherwise provided for
    • C25B11/04—Electrodes; Manufacture thereof not otherwise provided for characterised by the material
    • C25B11/051—Electrodes formed of electrocatalysts on a substrate or carrier
    • C25B11/055—Electrodes formed of electrocatalysts on a substrate or carrier characterised by the substrate or carrier material
    • C25B11/057—Electrodes formed of electrocatalysts on a substrate or carrier characterised by the substrate or carrier material consisting of a single element or compound
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B11/00—Electrodes; Manufacture thereof not otherwise provided for
    • C25B11/04—Electrodes; Manufacture thereof not otherwise provided for characterised by the material
    • C25B11/051—Electrodes formed of electrocatalysts on a substrate or carrier
    • C25B11/055—Electrodes formed of electrocatalysts on a substrate or carrier characterised by the substrate or carrier material
    • C25B11/057—Electrodes formed of electrocatalysts on a substrate or carrier characterised by the substrate or carrier material consisting of a single element or compound
    • C25B11/065—Carbon
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B11/00—Electrodes; Manufacture thereof not otherwise provided for
    • C25B11/04—Electrodes; Manufacture thereof not otherwise provided for characterised by the material
    • C25B11/051—Electrodes formed of electrocatalysts on a substrate or carrier
    • C25B11/073—Electrodes formed of electrocatalysts on a substrate or carrier characterised by the electrocatalyst material
    • C25B11/075—Electrodes formed of electrocatalysts on a substrate or carrier characterised by the electrocatalyst material consisting of a single catalytic element or catalytic compound
    • C25B11/077—Electrodes formed of electrocatalysts on a substrate or carrier characterised by the electrocatalyst material consisting of a single catalytic element or catalytic compound the compound being a non-noble metal oxide
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B13/00—Diaphragms; Spacing elements
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B3/00—Electrolytic production of organic compounds
    • C25B3/01—Products
    • C25B3/07—Oxygen containing compounds
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B9/00—Cells or assemblies of cells; Constructional parts of cells; Assemblies of constructional parts, e.g. electrode-diaphragm assemblies; Process-related cell features
    • C25B9/17—Cells comprising dimensionally-stable non-movable electrodes; Assemblies of constructional parts thereof
    • C25B9/19—Cells comprising dimensionally-stable non-movable electrodes; Assemblies of constructional parts thereof with diaphragms
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
    • H01M4/90—Selection of catalytic material
    • H01M4/9041—Metals or alloys
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
    • H01M4/90—Selection of catalytic material
    • H01M4/9075—Catalytic material supported on carriers, e.g. powder carriers
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
    • H01M4/98—Raney-type electrodes
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/06—Combination of fuel cells with means for production of reactants or for treatment of residues
    • H01M8/0606—Combination of fuel cells with means for production of reactants or for treatment of residues with means for production of gaseous reactants
    • H01M8/0656—Combination of fuel cells with means for production of reactants or for treatment of residues with means for production of gaseous reactants by electrochemical means
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/36—Hydrogen production from non-carbon containing sources, e.g. by water electrolysis
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/50—Fuel cells
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/10—Process efficiency
    • Y02P20/133—Renewable energy sources, e.g. sunlight

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Electrochemistry (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Metallurgy (AREA)
  • General Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Sustainable Energy (AREA)
  • Sustainable Development (AREA)
  • Manufacturing & Machinery (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Catalysts (AREA)
  • Inert Electrodes (AREA)

Abstract

Procédé de préparation d’un matériau catalytique d’une électrode pour des réactions de réduction électrochimique, ledit matériau comprenant au moins une phase active à base d’un métal du groupe VIB et un support électro-conducteur, lequel procédé comprend: a) une étape d’électrolyse d’au moins une solution aqueuse et/ou organique comprenant au moins un précurseur de la phase active comprenant au moins un métal du groupe VIB pour obtenir une solution comprenant au moins un précurseur comprenant au moins un métal du groupe VIB partiellement réduit ; b) une étape d’imprégnation dudit support avec ladite solution obtenue à l’étape a) pour obtenir un précurseur de matériau catalytique ; c) une étape de séchage dudit précurseur obtenu à l’étape b) à une température inférieure à 250°C, sans calcination ultérieure ; d) une étape de sulfuration du précurseur de matériau catalytique obtenu à l’étape c) à une température comprise entre 100°C et 600°C.
FR1872181A 2018-11-30 2018-11-30 Procédé de préparation d’un matériau catalytique d’électrode pour des réactions de réduction électrochimique préparé par électroréduction. Active FR3089134B1 (fr)

Priority Applications (4)

Application Number Priority Date Filing Date Title
FR1872181A FR3089134B1 (fr) 2018-11-30 2018-11-30 Procédé de préparation d’un matériau catalytique d’électrode pour des réactions de réduction électrochimique préparé par électroréduction.
EP19806186.3A EP3887572A1 (fr) 2018-11-30 2019-11-19 Procede de preparation d'un materiau catalytique d'electrode pour des reactions de reduction electrochimique prepare par electroreduction
PCT/EP2019/081705 WO2020109062A1 (fr) 2018-11-30 2019-11-19 Procede de preparation d'un materiau catalytique d'electrode pour des reactions de reduction electrochimique prepare par electroreduction
US17/295,775 US20220018033A1 (en) 2018-11-30 2019-11-19 Method for preparing a catalytic material of an electrode for electrochemical reduction reactions prepared by electroreduction

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR1872181A FR3089134B1 (fr) 2018-11-30 2018-11-30 Procédé de préparation d’un matériau catalytique d’électrode pour des réactions de réduction électrochimique préparé par électroréduction.

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FR3089134A1 FR3089134A1 (fr) 2020-06-05
FR3089134B1 true FR3089134B1 (fr) 2020-11-13

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FR1872181A Active FR3089134B1 (fr) 2018-11-30 2018-11-30 Procédé de préparation d’un matériau catalytique d’électrode pour des réactions de réduction électrochimique préparé par électroréduction.

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US (1) US20220018033A1 (fr)
EP (1) EP3887572A1 (fr)
FR (1) FR3089134B1 (fr)
WO (1) WO2020109062A1 (fr)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113755879B (zh) * 2021-09-06 2023-03-14 无锡隆基氢能科技有限公司 一种δ相氮化钨电极材料及其制备方法和应用
FR3133544B1 (fr) 2022-03-18 2024-03-08 Ifp Energies Now Matériau catalytique à base d’un élément du groupe VIB et d’un élément du groupe IVB pour la production d’hydrogène par électrolyse de l’eau
CN114908375A (zh) * 2022-05-25 2022-08-16 中国科学技术大学 电催化co2还原中具有稳定活性位点的铜催化剂及其制备方法与应用

Family Cites Families (11)

* Cited by examiner, † Cited by third party
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US2547380A (en) 1945-10-01 1951-04-03 Union Oil Co Catalyst for hydrocarbon conversion
BR112012014687B1 (pt) * 2009-12-16 2018-05-08 Ifp Energies Now catalisador utilizável em hidrotratamento, compreendendo metais dos grupos viii e vib e preparo com o ácido acético e succinato de dialquila c1-c4
JP5802085B2 (ja) * 2011-08-31 2015-10-28 株式会社バンテック アルカリ水電解用電極の製造方法
FR2984763B1 (fr) * 2011-12-22 2013-12-20 IFP Energies Nouvelles Procede de preparation d'un catalyseur utilisable en hydroconversion comprenant au moins une zeolithe nu-86
FR3004968B1 (fr) * 2013-04-30 2016-02-05 IFP Energies Nouvelles Procede de preparation d'un catalyseur a base de tungstene utilisable en hydrotraitement ou en hydrocraquage
FR3004967B1 (fr) * 2013-04-30 2016-12-30 Ifp Energies Now Procede de preparation d'un catalyseur a base de molybdene utilisable en hydrotraitement ou en hydrocraquage
FR3007427B1 (fr) 2013-06-20 2016-07-01 Ifp Energies Now Couche active a base de particules metalliques sur support conducteur poreux, methode de fabrication et utilisation en tant que cathode pour l'electroreduction de dioxyde de carbone.
CN106917105B (zh) * 2017-01-13 2019-05-31 太原理工大学 一种水分解用自支撑过渡金属硫化物泡沫电极的制备方法
WO2019016852A1 (fr) * 2017-07-18 2019-01-24 国立大学法人弘前大学 Procédé de production de catalyseur d'électrode et procédé de production d'hydrogène
KR101894964B1 (ko) * 2017-08-08 2018-09-05 한국과학기술원 그래핀 액정섬유-전이금속계 촉매 섬유복합체 및 이의 제조방법
CN108855146B (zh) * 2018-06-27 2020-05-05 北京师范大学 NiFeMoS复合体及其制备方法

Also Published As

Publication number Publication date
WO2020109062A1 (fr) 2020-06-04
FR3089134A1 (fr) 2020-06-05
US20220018033A1 (en) 2022-01-20
EP3887572A1 (fr) 2021-10-06

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