FR3112030B1 - Utilisation d’éléments électrochimiques secondaires au lithium contenant un mélange d'un oxyde lithié de nickel et d'un phosphate lithié de manganèse et de fer pour des applications automobiles - Google Patents
Utilisation d’éléments électrochimiques secondaires au lithium contenant un mélange d'un oxyde lithié de nickel et d'un phosphate lithié de manganèse et de fer pour des applications automobiles Download PDFInfo
- Publication number
- FR3112030B1 FR3112030B1 FR2006764A FR2006764A FR3112030B1 FR 3112030 B1 FR3112030 B1 FR 3112030B1 FR 2006764 A FR2006764 A FR 2006764A FR 2006764 A FR2006764 A FR 2006764A FR 3112030 B1 FR3112030 B1 FR 3112030B1
- Authority
- FR
- France
- Prior art keywords
- lithiated
- iron phosphate
- mixture
- nickel oxide
- lithium secondary
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000000203 mixture Substances 0.000 title abstract 4
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 title abstract 2
- 229910052744 lithium Inorganic materials 0.000 title abstract 2
- AWKHTBXFNVGFRX-UHFFFAOYSA-K iron(2+);manganese(2+);phosphate Chemical compound [Mn+2].[Fe+2].[O-]P([O-])([O-])=O AWKHTBXFNVGFRX-UHFFFAOYSA-K 0.000 title 1
- 229910000480 nickel oxide Inorganic materials 0.000 title 1
- GNRSAWUEBMWBQH-UHFFFAOYSA-N oxonickel Chemical compound [Ni]=O GNRSAWUEBMWBQH-UHFFFAOYSA-N 0.000 title 1
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 abstract 1
- 230000002159 abnormal effect Effects 0.000 abstract 1
- 239000011149 active material Substances 0.000 abstract 1
- 229910000398 iron phosphate Inorganic materials 0.000 abstract 1
- WBJZTOZJJYAKHQ-UHFFFAOYSA-K iron(3+) phosphate Chemical compound [Fe+3].[O-]P([O-])([O-])=O WBJZTOZJJYAKHQ-UHFFFAOYSA-K 0.000 abstract 1
- DVATZODUVBMYHN-UHFFFAOYSA-K lithium;iron(2+);manganese(2+);phosphate Chemical compound [Li+].[Mn+2].[Fe+2].[O-]P([O-])([O-])=O DVATZODUVBMYHN-UHFFFAOYSA-K 0.000 abstract 1
- URIIGZKXFBNRAU-UHFFFAOYSA-N lithium;oxonickel Chemical compound [Li].[Ni]=O URIIGZKXFBNRAU-UHFFFAOYSA-N 0.000 abstract 1
- 229910052748 manganese Inorganic materials 0.000 abstract 1
- 239000011572 manganese Substances 0.000 abstract 1
Classifications
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/362—Composites
- H01M4/364—Composites as mixtures
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/052—Li-accumulators
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/052—Li-accumulators
- H01M10/0525—Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/42—Methods or arrangements for servicing or maintenance of secondary cells or secondary half-cells
- H01M10/4235—Safety or regulating additives or arrangements in electrodes, separators or electrolyte
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/42—Methods or arrangements for servicing or maintenance of secondary cells or secondary half-cells
- H01M10/48—Accumulators combined with arrangements for measuring, testing or indicating the condition of cells, e.g. the level or density of the electrolyte
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
- H01M4/136—Electrodes based on inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
- H01M4/50—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese
- H01M4/505—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese of mixed oxides or hydroxides containing manganese for inserting or intercalating light metals, e.g. LiMn2O4 or LiMn2OxFy
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
- H01M4/52—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron
- H01M4/525—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron of mixed oxides or hydroxides containing iron, cobalt or nickel for inserting or intercalating light metals, e.g. LiNiO2, LiCoO2 or LiCoOxFy
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
- H01M4/5825—Oxygenated metallic salts or polyanionic structures, e.g. borates, phosphates, silicates, olivines
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/50—Current conducting connections for cells or batteries
- H01M50/572—Means for preventing undesired use or discharge
- H01M50/574—Devices or arrangements for the interruption of current
- H01M50/578—Devices or arrangements for the interruption of current in response to pressure
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/50—Current conducting connections for cells or batteries
- H01M50/572—Means for preventing undesired use or discharge
- H01M50/574—Devices or arrangements for the interruption of current
- H01M50/581—Devices or arrangements for the interruption of current in response to temperature
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M2004/021—Physical characteristics, e.g. porosity, surface area
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M2004/026—Electrodes composed of, or comprising, active material characterised by the polarity
- H01M2004/028—Positive electrodes
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M2200/00—Safety devices for primary or secondary batteries
- H01M2200/10—Temperature sensitive devices
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M2200/00—Safety devices for primary or secondary batteries
- H01M2200/20—Pressure-sensitive devices
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M2220/00—Batteries for particular applications
- H01M2220/20—Batteries in motive systems, e.g. vehicle, ship, plane
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
Abstract
L’utilisation d'un mélange d'un oxyde lithié de nickel et d'un phosphate lithié de manganèse et de fer comme composition de matériaux actifs dans la cathode d'un élément électrochimique secondaire au lithium pour des applications automobiles, telles que des véhicules hybrides et électriques. Ce mélange permet de diminuer la porosité d'une cathode à base de phosphate lithié de manganèse et de fer. Il permet également d'améliorer la détectabilité d'un dégagement gazeux dans l’élément en cas de fonctionnement anormal de l’élément. Il permet d'abaisser l'impédance de l’élément, pour un faible état de charge, généralement inférieur à 30 %, et de réduire l'augmentation d'impédance de l’élément pendant la durée de vie de l’élément.
Priority Applications (7)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR2006764A FR3112030B1 (fr) | 2020-06-26 | 2020-06-26 | Utilisation d’éléments électrochimiques secondaires au lithium contenant un mélange d'un oxyde lithié de nickel et d'un phosphate lithié de manganèse et de fer pour des applications automobiles |
CN202180045476.5A CN115777153A (zh) | 2020-06-26 | 2021-06-23 | 包含锂镍氧化物和磷酸锰铁锂的混合物的锂二次电化学电池在汽车应用中的用途 |
PCT/EP2021/067124 WO2021259991A2 (fr) | 2020-06-26 | 2021-06-23 | Utilisation de piles électrochimiques au lithium rechargeables contenant un mélange d'un oxyde de lithium-nickel et un de lithium-fer-manganèse phosphate pour des applications automobiles |
EP23180570.6A EP4239700A3 (fr) | 2020-06-26 | 2021-06-23 | Utilisation de piles électrochimiques secondaires au lithium contenant un mélange d'oxyde de lithium-nickel et de phosphate de lithium-manganèse-fer pour des applications automobiles |
EP23180572.2A EP4239701A3 (fr) | 2020-06-26 | 2021-06-23 | Utilisation de piles électrochimiques secondaires au lithium contenant un mélange d'oxyde de lithium-nickel et de phosphate de lithium-manganèse-fer pour des applications automobiles |
US18/002,596 US20230231129A1 (en) | 2020-06-26 | 2021-06-23 | Use of lithium secondary electrochemical cells containing a blend of a lithium nickel oxide and a lithium manganese iron phosphate for automotive applications |
EP21737000.6A EP4173062A2 (fr) | 2020-06-26 | 2021-06-23 | Utilisation de piles électrochimiques au lithium rechargeables contenant un mélange d'un oxyde de lithium-nickel et un de lithium-fer-manganèse phosphate pour des applications automobiles |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR2006764A FR3112030B1 (fr) | 2020-06-26 | 2020-06-26 | Utilisation d’éléments électrochimiques secondaires au lithium contenant un mélange d'un oxyde lithié de nickel et d'un phosphate lithié de manganèse et de fer pour des applications automobiles |
FR2006764 | 2020-06-26 |
Publications (2)
Publication Number | Publication Date |
---|---|
FR3112030A1 FR3112030A1 (fr) | 2021-12-31 |
FR3112030B1 true FR3112030B1 (fr) | 2022-12-16 |
Family
ID=75108353
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
FR2006764A Active FR3112030B1 (fr) | 2020-06-26 | 2020-06-26 | Utilisation d’éléments électrochimiques secondaires au lithium contenant un mélange d'un oxyde lithié de nickel et d'un phosphate lithié de manganèse et de fer pour des applications automobiles |
Country Status (5)
Country | Link |
---|---|
US (1) | US20230231129A1 (fr) |
EP (3) | EP4173062A2 (fr) |
CN (1) | CN115777153A (fr) |
FR (1) | FR3112030B1 (fr) |
WO (1) | WO2021259991A2 (fr) |
Family Cites Families (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP5381024B2 (ja) * | 2008-11-06 | 2014-01-08 | 株式会社Gsユアサ | リチウム二次電池用正極及びリチウム二次電池 |
JP5672113B2 (ja) * | 2010-03-31 | 2015-02-18 | 株式会社Gsユアサ | 非水電解質二次電池 |
WO2012147929A1 (fr) * | 2011-04-28 | 2012-11-01 | 日本電気株式会社 | Pile secondaire au lithium |
EP2737565B1 (fr) * | 2011-07-25 | 2019-09-25 | A123 Systems LLC | Matières mélangées pour cathodes |
US9991566B2 (en) * | 2011-11-03 | 2018-06-05 | Johnson Controls Technology Company | Cathode active material for overcharge protection in secondary lithium batteries |
CN104205428B (zh) * | 2012-02-29 | 2017-03-22 | 日立化成株式会社 | 锂离子电池 |
WO2015006058A1 (fr) * | 2013-07-09 | 2015-01-15 | Dow Global Technologies Llc | Matériau actif positif mélangé comprenant un oxyde métallique de lithium et un phosphate métallique de lithium |
JP6079696B2 (ja) * | 2014-05-19 | 2017-02-15 | トヨタ自動車株式会社 | 非水電解液二次電池 |
JP6596826B2 (ja) * | 2015-01-15 | 2019-10-30 | 株式会社デンソー | 電極及び非水電解質二次電池 |
FR3036538B1 (fr) * | 2015-05-19 | 2017-05-19 | Accumulateurs Fixes | Electrode positive pour generateur electrochimique au lithium |
JP6674631B2 (ja) * | 2016-06-23 | 2020-04-01 | トヨタ自動車株式会社 | リチウムイオン二次電池 |
-
2020
- 2020-06-26 FR FR2006764A patent/FR3112030B1/fr active Active
-
2021
- 2021-06-23 CN CN202180045476.5A patent/CN115777153A/zh active Pending
- 2021-06-23 EP EP21737000.6A patent/EP4173062A2/fr active Pending
- 2021-06-23 WO PCT/EP2021/067124 patent/WO2021259991A2/fr unknown
- 2021-06-23 EP EP23180570.6A patent/EP4239700A3/fr active Pending
- 2021-06-23 US US18/002,596 patent/US20230231129A1/en active Pending
- 2021-06-23 EP EP23180572.2A patent/EP4239701A3/fr active Pending
Also Published As
Publication number | Publication date |
---|---|
EP4173062A2 (fr) | 2023-05-03 |
US20230231129A1 (en) | 2023-07-20 |
WO2021259991A3 (fr) | 2022-04-14 |
CN115777153A (zh) | 2023-03-10 |
WO2021259991A2 (fr) | 2021-12-30 |
EP4239701A2 (fr) | 2023-09-06 |
EP4239701A3 (fr) | 2024-01-17 |
EP4239700A3 (fr) | 2024-01-17 |
EP4239700A2 (fr) | 2023-09-06 |
FR3112030A1 (fr) | 2021-12-31 |
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