FR3061182B1 - Poudre de particules spheriques de polyamide reticulable, procede de preparation et utilisation avec la technique de frittage par laser selectif - Google Patents

Poudre de particules spheriques de polyamide reticulable, procede de preparation et utilisation avec la technique de frittage par laser selectif Download PDF

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Publication number
FR3061182B1
FR3061182B1 FR1663160A FR1663160A FR3061182B1 FR 3061182 B1 FR3061182 B1 FR 3061182B1 FR 1663160 A FR1663160 A FR 1663160A FR 1663160 A FR1663160 A FR 1663160A FR 3061182 B1 FR3061182 B1 FR 3061182B1
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France
Prior art keywords
particle powder
laser sintering
selective laser
preparation
crosslinkable polyamide
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FR1663160A
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English (en)
French (fr)
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FR3061182A1 (fr
Inventor
Jerome Gimenez
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Setup Performance SAS
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Setup Performance SAS
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Publication date
Priority to FR1663160A priority Critical patent/FR3061182B1/fr
Application filed by Setup Performance SAS filed Critical Setup Performance SAS
Priority to CN201780079481.1A priority patent/CN110099945B/zh
Priority to CN202210362837.5A priority patent/CN114773592A/zh
Priority to EP17832528.8A priority patent/EP3559086B1/fr
Priority to ES17832528T priority patent/ES2926150T3/es
Priority to US16/472,318 priority patent/US11236242B2/en
Priority to PCT/FR2017/053776 priority patent/WO2018115767A1/fr
Priority to KR1020197020791A priority patent/KR102534351B1/ko
Priority to JP2019534672A priority patent/JP7106233B2/ja
Publication of FR3061182A1 publication Critical patent/FR3061182A1/fr
Application granted granted Critical
Publication of FR3061182B1 publication Critical patent/FR3061182B1/fr
Priority to US17/555,889 priority patent/US11891528B2/en
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G69/00Macromolecular compounds obtained by reactions forming a carboxylic amide link in the main chain of the macromolecule
    • C08G69/48Polymers modified by chemical after-treatment
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00Inks
    • C09D11/02Printing inks
    • C09D11/10Printing inks based on artificial resins
    • C09D11/101Inks specially adapted for printing processes involving curing by wave energy or particle radiation, e.g. with UV-curing following the printing
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29BPREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
    • B29B9/00Making granules
    • B29B9/12Making granules characterised by structure or composition
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B33ADDITIVE MANUFACTURING TECHNOLOGY
    • B33YADDITIVE MANUFACTURING, i.e. MANUFACTURING OF THREE-DIMENSIONAL [3-D] OBJECTS BY ADDITIVE DEPOSITION, ADDITIVE AGGLOMERATION OR ADDITIVE LAYERING, e.g. BY 3-D PRINTING, STEREOLITHOGRAPHY OR SELECTIVE LASER SINTERING
    • B33Y70/00Materials specially adapted for additive manufacturing
    • B33Y70/10Composites of different types of material, e.g. mixtures of ceramics and polymers or mixtures of metals and biomaterials
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J3/00Processes of treating or compounding macromolecular substances
    • C08J3/20Compounding polymers with additives, e.g. colouring
    • C08J3/203Solid polymers with solid and/or liquid additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J3/00Processes of treating or compounding macromolecular substances
    • C08J3/24Crosslinking, e.g. vulcanising, of macromolecules
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/12Bonding of a preformed macromolecular material to the same or other solid material such as metal, glass, leather, e.g. using adhesives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L77/00Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
    • C08L77/02Polyamides derived from omega-amino carboxylic acids or from lactams thereof
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L77/00Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
    • C08L77/06Polyamides derived from polyamines and polycarboxylic acids
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00Inks
    • C09D11/02Printing inks
    • C09D11/10Printing inks based on artificial resins
    • C09D11/102Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C64/00Additive manufacturing, i.e. manufacturing of three-dimensional [3D] objects by additive deposition, additive agglomeration or additive layering, e.g. by 3D printing, stereolithography or selective laser sintering
    • B29C64/10Processes of additive manufacturing
    • B29C64/141Processes of additive manufacturing using only solid materials
    • B29C64/153Processes of additive manufacturing using only solid materials using layers of powder being selectively joined, e.g. by selective laser sintering or melting
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29KINDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2077/00Use of PA, i.e. polyamides, e.g. polyesteramides or derivatives thereof, as moulding material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29KINDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2105/00Condition, form or state of moulded material or of the material to be shaped
    • B29K2105/24Condition, form or state of moulded material or of the material to be shaped crosslinked or vulcanised
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B33ADDITIVE MANUFACTURING TECHNOLOGY
    • B33YADDITIVE MANUFACTURING, i.e. MANUFACTURING OF THREE-DIMENSIONAL [3-D] OBJECTS BY ADDITIVE DEPOSITION, ADDITIVE AGGLOMERATION OR ADDITIVE LAYERING, e.g. BY 3-D PRINTING, STEREOLITHOGRAPHY OR SELECTIVE LASER SINTERING
    • B33Y10/00Processes of additive manufacturing
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2377/00Characterised by the use of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Derivatives of such polymers
    • C08J2377/02Polyamides derived from omega-amino carboxylic acids or from lactams thereof
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2377/00Characterised by the use of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Derivatives of such polymers
    • C08J2377/06Polyamides derived from polyamines and polycarboxylic acids
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/54Silicon-containing compounds
    • C08K5/541Silicon-containing compounds containing oxygen
    • C08K5/5415Silicon-containing compounds containing oxygen containing at least one Si—O bond
    • C08K5/5419Silicon-containing compounds containing oxygen containing at least one Si—O bond containing at least one Si—C bond
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/14Polymer mixtures characterised by other features containing polymeric additives characterised by shape
    • C08L2205/18Spheres

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Health & Medical Sciences (AREA)
  • Manufacturing & Machinery (AREA)
  • Wood Science & Technology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Mechanical Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Optics & Photonics (AREA)
  • Civil Engineering (AREA)
  • Ceramic Engineering (AREA)
  • Composite Materials (AREA)
  • Structural Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Processes Of Treating Macromolecular Substances (AREA)
  • Polyamides (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Treatments Of Macromolecular Shaped Articles (AREA)
FR1663160A 2016-12-22 2016-12-22 Poudre de particules spheriques de polyamide reticulable, procede de preparation et utilisation avec la technique de frittage par laser selectif Active FR3061182B1 (fr)

Priority Applications (10)

Application Number Priority Date Filing Date Title
FR1663160A FR3061182B1 (fr) 2016-12-22 2016-12-22 Poudre de particules spheriques de polyamide reticulable, procede de preparation et utilisation avec la technique de frittage par laser selectif
JP2019534672A JP7106233B2 (ja) 2016-12-22 2017-12-21 球状で架橋可能なポリアミド粒子の粉末、製造方法及び選択的レーザー焼結技術における使用方法
EP17832528.8A EP3559086B1 (fr) 2016-12-22 2017-12-21 Poudre de particules spheriques de polyamide reticulable, procede de preparation et utilisation avec la technique de frittage par laser selectif
ES17832528T ES2926150T3 (es) 2016-12-22 2017-12-21 Polvo de partículas esféricas de poliamida reticulable, procedimiento de preparación y uso con la técnica de sinterización selectiva por láser
US16/472,318 US11236242B2 (en) 2016-12-22 2017-12-21 Powder of spherical crosslinkable polyamide particles, preparation process and use with the selective laser sintering technique
PCT/FR2017/053776 WO2018115767A1 (fr) 2016-12-22 2017-12-21 Poudre de particules spheriques de polyamide reticulable, procede de preparation et utilisation avec la technique de frittage par laser selectif
CN201780079481.1A CN110099945B (zh) 2016-12-22 2017-12-21 可交联性聚酰胺球形粒子的粉末、其制备方法和采用选择性激光烧结技术的用途
CN202210362837.5A CN114773592A (zh) 2016-12-22 2017-12-21 可交联性聚酰胺球形粒子的粉末、其制备方法和采用选择性激光烧结技术的用途
KR1020197020791A KR102534351B1 (ko) 2016-12-22 2017-12-21 구형 가교결합성 폴리아미드 입자 분말, 제조 방법 및 선택적 레이저 소결 기술을 사용한 용도
US17/555,889 US11891528B2 (en) 2016-12-22 2021-12-20 Powder of spherical crosslinkable polyamide particles, preparation process and use with the selective laser sintering technique

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR1663160A FR3061182B1 (fr) 2016-12-22 2016-12-22 Poudre de particules spheriques de polyamide reticulable, procede de preparation et utilisation avec la technique de frittage par laser selectif
FR1663160 2016-12-22

Publications (2)

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FR3061182A1 FR3061182A1 (fr) 2018-06-29
FR3061182B1 true FR3061182B1 (fr) 2019-05-31

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FR1663160A Active FR3061182B1 (fr) 2016-12-22 2016-12-22 Poudre de particules spheriques de polyamide reticulable, procede de preparation et utilisation avec la technique de frittage par laser selectif

Country Status (8)

Country Link
US (2) US11236242B2 (ko)
EP (1) EP3559086B1 (ko)
JP (1) JP7106233B2 (ko)
KR (1) KR102534351B1 (ko)
CN (2) CN114773592A (ko)
ES (1) ES2926150T3 (ko)
FR (1) FR3061182B1 (ko)
WO (1) WO2018115767A1 (ko)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP3594272A1 (de) * 2018-07-10 2020-01-15 Basf Se Verfahren zur kontinuierlichen herstellung eines polyamidpulvers
FR3085254A1 (fr) 2018-08-28 2020-03-06 Jlz Sacs personnalisables
WO2020043754A1 (fr) 2018-08-28 2020-03-05 Jlz Sacs personnalisables
JP7338316B2 (ja) * 2018-08-31 2023-09-05 株式会社リコー 樹脂粉末、及び立体造形物の製造方法
US11833750B2 (en) * 2018-09-22 2023-12-05 Hewlett-Packard Development Company, L.P. Three-dimensional printing
US11458677B2 (en) * 2019-12-26 2022-10-04 Industrial Technology Research Institute Selective laser sintering composition and selective laser sintering 3D printing method employing the same

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US4225650A (en) 1975-10-22 1980-09-30 Exxon Research & Engineering Co. Crosslinkable polymer powder and laminate
CH660744A5 (de) 1982-11-05 1987-06-15 Inventa Ag Verfahren zur herstellung hochviskoser bzw. thermisch formstabiler, mindestens teilvernetzter polyamide.
JPS62240355A (ja) * 1986-04-11 1987-10-21 Agency Of Ind Science & Technol シラン変性ポリアミド樹脂の安定化方法
US5648450A (en) 1992-11-23 1997-07-15 Dtm Corporation Sinterable semi-crystalline powder and near-fully dense article formed therein
US5527877A (en) 1992-11-23 1996-06-18 Dtm Corporation Sinterable semi-crystalline powder and near-fully dense article formed therewith
FR2721035B1 (fr) 1994-06-08 1997-05-23 Atochem Elf Sa Polyamides à performances thermomécaniques améliorées, leur procédé de préparation et leur utilisation après réticulation.
DE19708946A1 (de) 1997-03-05 1998-09-10 Huels Chemische Werke Ag Herstellung von Polyamid-Fällpulvern mit enger Korngrößenverteilung und niedriger Porosität
DE19747309B4 (de) 1997-10-27 2007-11-15 Degussa Gmbh Verwendung eines Polyamids 12 für selektives Laser-Sintern
FR2776295B1 (fr) 1998-03-18 2000-06-23 Trl Polyamide thermofusible et reticulable, l'un de ses procedes d'obtention et colle le comprenant
US6399714B1 (en) * 2000-09-27 2002-06-04 Michigan Biotechnology Institute Crosslinked polyamide
JP4419013B2 (ja) 2003-09-22 2010-02-24 大阪府 機能性ポリアミド微粒子及びその製造方法
FR2881431B1 (fr) 2005-01-28 2008-12-05 Arkema Sa Greffage d'une poudre de polyamide par irradiation gamma.
FR2877948B1 (fr) 2004-11-12 2007-01-05 Arkema Sa Procede de synthese de poudres de polyamide
FR2899591B1 (fr) 2006-04-10 2008-05-23 Rhodia Recherches & Tech Procede de preparation de particules a base de polymere thermoplastique et poudre ainsi obtenue
JP5214313B2 (ja) 2007-06-07 2013-06-19 群栄化学工業株式会社 選択的レーザー焼結用複合材料粉末
FR2968664B1 (fr) * 2010-12-10 2014-02-14 Rhodia Operations Realisation d'article par fusion selective de couches de poudre de polymere
EP2716692A1 (de) * 2012-10-08 2014-04-09 WKP Products SA Verbundwerkstoffe zur Nutzung in Spritzguss-Verfahren
FR3005660B1 (fr) * 2013-05-17 2015-04-24 Arkema France Procede de reticulation en surface de particules de polymere
KR101790241B1 (ko) * 2014-08-04 2017-10-26 주식회사 엘지화학 고흡수성 수지 및 이의 제조 방법
CN104910614B (zh) * 2015-06-23 2017-06-27 青岛科技大学 一种3d打印用低翘曲尼龙粉末复合材料及其制备方法
CN105238041B (zh) * 2015-10-22 2019-09-06 深圳光韵达光电科技股份有限公司 一种用于选择性激光烧结的尼龙粉末材料及其制备方法
CN105542200B (zh) * 2015-12-18 2017-11-24 福建瑞森新材料股份有限公司 一种规则球形尼龙粉末的制备方法
CN105754333B (zh) * 2016-03-03 2019-01-18 湖南华曙高科技有限责任公司 一种选择性激光烧结用尼龙粉末及其制备方法

Also Published As

Publication number Publication date
CN110099945B (zh) 2022-06-17
ES2926150T8 (es) 2023-02-14
ES2926150T3 (es) 2022-10-24
EP3559086B1 (fr) 2022-06-15
KR102534351B1 (ko) 2023-05-22
US20220112386A1 (en) 2022-04-14
US11891528B2 (en) 2024-02-06
FR3061182A1 (fr) 2018-06-29
JP7106233B2 (ja) 2022-07-26
US11236242B2 (en) 2022-02-01
CN114773592A (zh) 2022-07-22
KR20190099460A (ko) 2019-08-27
US20190375952A1 (en) 2019-12-12
WO2018115767A1 (fr) 2018-06-28
EP3559086A1 (fr) 2019-10-30
JP2020514457A (ja) 2020-05-21
CN110099945A (zh) 2019-08-06

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