FR3050740B1 - Electrode metal / chalcogenure metallique a haute surface specifique - Google Patents

Electrode metal / chalcogenure metallique a haute surface specifique Download PDF

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Publication number
FR3050740B1
FR3050740B1 FR1653753A FR1653753A FR3050740B1 FR 3050740 B1 FR3050740 B1 FR 3050740B1 FR 1653753 A FR1653753 A FR 1653753A FR 1653753 A FR1653753 A FR 1653753A FR 3050740 B1 FR3050740 B1 FR 3050740B1
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FR
France
Prior art keywords
metal
electrode
specific surface
deposit
high specific
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
FR1653753A
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English (en)
Other versions
FR3050740A1 (fr
Inventor
Marc Fontecave
Victor Mougel
Ngoc Huan Tran
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Centre National de la Recherche Scientifique CNRS
Sorbonne Universite
Universite Paris Sciences et Lettres
Original Assignee
Centre National de la Recherche Scientifique CNRS
Universite Pierre et Marie Curie
Universite Paris Sciences et Lettres
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to FR1653753A priority Critical patent/FR3050740B1/fr
Application filed by Centre National de la Recherche Scientifique CNRS, Universite Pierre et Marie Curie, Universite Paris Sciences et Lettres filed Critical Centre National de la Recherche Scientifique CNRS
Priority to EP17714480.5A priority patent/EP3449042B1/fr
Priority to CN201780030120.8A priority patent/CN109415825B/zh
Priority to AU2017258442A priority patent/AU2017258442A1/en
Priority to JP2018556434A priority patent/JP2019518869A/ja
Priority to CA3022198A priority patent/CA3022198A1/fr
Priority to PCT/EP2017/057756 priority patent/WO2017186454A1/fr
Priority to KR1020187033459A priority patent/KR20190031197A/ko
Priority to US16/096,740 priority patent/US11661662B2/en
Publication of FR3050740A1 publication Critical patent/FR3050740A1/fr
Application granted granted Critical
Publication of FR3050740B1 publication Critical patent/FR3050740B1/fr
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

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Classifications

    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25BELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B11/00Electrodes; Manufacture thereof not otherwise provided for
    • C25B11/04Electrodes; Manufacture thereof not otherwise provided for characterised by the material
    • C25B11/051Electrodes formed of electrocatalysts on a substrate or carrier
    • C25B11/073Electrodes formed of electrocatalysts on a substrate or carrier characterised by the electrocatalyst material
    • C25B11/075Electrodes formed of electrocatalysts on a substrate or carrier characterised by the electrocatalyst material consisting of a single catalytic element or catalytic compound
    • C25B11/077Electrodes formed of electrocatalysts on a substrate or carrier characterised by the electrocatalyst material consisting of a single catalytic element or catalytic compound the compound being a non-noble metal oxide
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25BELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B1/00Electrolytic production of inorganic compounds or non-metals
    • C25B1/01Products
    • C25B1/02Hydrogen or oxygen
    • C25B1/04Hydrogen or oxygen by electrolysis of water
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25BELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B11/00Electrodes; Manufacture thereof not otherwise provided for
    • C25B11/04Electrodes; Manufacture thereof not otherwise provided for characterised by the material
    • C25B11/051Electrodes formed of electrocatalysts on a substrate or carrier
    • C25B11/073Electrodes formed of electrocatalysts on a substrate or carrier characterised by the electrocatalyst material
    • C25B11/075Electrodes formed of electrocatalysts on a substrate or carrier characterised by the electrocatalyst material consisting of a single catalytic element or catalytic compound
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25BELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B11/00Electrodes; Manufacture thereof not otherwise provided for
    • C25B11/04Electrodes; Manufacture thereof not otherwise provided for characterised by the material
    • C25B11/051Electrodes formed of electrocatalysts on a substrate or carrier
    • C25B11/073Electrodes formed of electrocatalysts on a substrate or carrier characterised by the electrocatalyst material
    • C25B11/091Electrodes formed of electrocatalysts on a substrate or carrier characterised by the electrocatalyst material consisting of at least one catalytic element and at least one catalytic compound; consisting of two or more catalytic elements or catalytic compounds
    • C25B11/093Electrodes formed of electrocatalysts on a substrate or carrier characterised by the electrocatalyst material consisting of at least one catalytic element and at least one catalytic compound; consisting of two or more catalytic elements or catalytic compounds at least one noble metal or noble metal oxide and at least one non-noble metal oxide
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D3/00Electroplating: Baths therefor
    • C25D3/02Electroplating: Baths therefor from solutions
    • C25D3/38Electroplating: Baths therefor from solutions of copper
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D5/00Electroplating characterised by the process; Pretreatment or after-treatment of workpieces
    • C25D5/48After-treatment of electroplated surfaces
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D7/00Electroplating characterised by the article coated
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/86Inert electrodes with catalytic activity, e.g. for fuel cells
    • H01M4/88Processes of manufacture
    • H01M4/8825Methods for deposition of the catalytic active composition
    • H01M4/8853Electrodeposition
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/86Inert electrodes with catalytic activity, e.g. for fuel cells
    • H01M4/90Selection of catalytic material
    • H01M4/9016Oxides, hydroxides or oxygenated metallic salts
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/86Inert electrodes with catalytic activity, e.g. for fuel cells
    • H01M4/90Selection of catalytic material
    • H01M4/9041Metals or alloys
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30Hydrogen technology
    • Y02E60/36Hydrogen production from non-carbon containing sources, e.g. by water electrolysis
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30Hydrogen technology
    • Y02E60/50Fuel cells

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Metallurgy (AREA)
  • General Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Manufacturing & Machinery (AREA)
  • Electrodes For Compound Or Non-Metal Manufacture (AREA)
  • Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
  • Electrolytic Production Of Metals (AREA)
  • Inert Electrodes (AREA)

Abstract

La présente invention concerne une électrode comprenant un support électroconducteur dont au moins une partie de la surface est recouverte par un dépôt d'un métal choisi dans le groupe constitué par le cuivre, le fer, le nickel, le zinc, le cobalt, le manganèse, le titane et un mélange de ceux-ci, la surface dudit dépôt étant sous une forme oxydée, sulfurée, sélénée et/ou tellurée et le dépôt ayant une surface spécifique supérieure à 1 m2/g ; un procédé de préparation d'une telle électrode ; un dispositif électrochimique comprenant une telle électrode ; et un procédé d'oxydation de l'eau en dioxygène impliquant une telle électrode.
FR1653753A 2016-04-27 2016-04-27 Electrode metal / chalcogenure metallique a haute surface specifique Expired - Fee Related FR3050740B1 (fr)

Priority Applications (9)

Application Number Priority Date Filing Date Title
FR1653753A FR3050740B1 (fr) 2016-04-27 2016-04-27 Electrode metal / chalcogenure metallique a haute surface specifique
CN201780030120.8A CN109415825B (zh) 2016-04-27 2017-03-31 具有高比表面积的金属/金属硫属元素化物电极
AU2017258442A AU2017258442A1 (en) 2016-04-27 2017-03-31 Metal / metal chalcogenide electrode with high specific surface area
JP2018556434A JP2019518869A (ja) 2016-04-27 2017-03-31 高い比表面積を有する金属/金属カルコゲナイド電極
EP17714480.5A EP3449042B1 (fr) 2016-04-27 2017-03-31 Electrode metal / chalcogenure metallique a haute surface specifique
CA3022198A CA3022198A1 (fr) 2016-04-27 2017-03-31 Electrode metal / chalcogenure metallique a haute surface specifique
PCT/EP2017/057756 WO2017186454A1 (fr) 2016-04-27 2017-03-31 Electrode metal / chalcogenure metallique a haute surface specifique
KR1020187033459A KR20190031197A (ko) 2016-04-27 2017-03-31 고 비표면적을 갖는 금속/금속 칼코게나이드 전극
US16/096,740 US11661662B2 (en) 2016-04-27 2017-03-31 Metal/metal chalcogenide electrode with high specific surface area

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR1653753A FR3050740B1 (fr) 2016-04-27 2016-04-27 Electrode metal / chalcogenure metallique a haute surface specifique

Publications (2)

Publication Number Publication Date
FR3050740A1 FR3050740A1 (fr) 2017-11-03
FR3050740B1 true FR3050740B1 (fr) 2021-01-29

Family

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Family Applications (1)

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FR1653753A Expired - Fee Related FR3050740B1 (fr) 2016-04-27 2016-04-27 Electrode metal / chalcogenure metallique a haute surface specifique

Country Status (9)

Country Link
US (1) US11661662B2 (fr)
EP (1) EP3449042B1 (fr)
JP (1) JP2019518869A (fr)
KR (1) KR20190031197A (fr)
CN (1) CN109415825B (fr)
AU (1) AU2017258442A1 (fr)
CA (1) CA3022198A1 (fr)
FR (1) FR3050740B1 (fr)
WO (1) WO2017186454A1 (fr)

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* Cited by examiner, † Cited by third party
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EP3656892B1 (fr) * 2018-11-21 2023-06-07 Paris Sciences et Lettres Procédé de réduction de co2 en hydrocarbures
JP7291377B2 (ja) * 2019-05-21 2023-06-15 国立大学法人 新潟大学 触媒の製造方法および金属酸化物の製造方法
TWI738190B (zh) 2020-01-21 2021-09-01 國立清華大學 非酵素型感測器、非酵素型感測元件及其製造方法
KR102311750B1 (ko) * 2020-02-13 2021-10-13 한국과학기술연구원 물분해 수소발생용 광전극 및 그 제조 방법
US10975482B1 (en) * 2020-02-27 2021-04-13 Haiming Li Self-derivative iron-containing nickel anode for water electrolysis
WO2022064414A1 (fr) * 2020-09-25 2022-03-31 Eni S.P.A. Électrodes contenant du cuivre et des oxydes de cuivre et leur procédé de préparation
CN113488630A (zh) * 2021-07-27 2021-10-08 广西师范大学 一种表面包覆和体相参杂富锂正极材料的制备方法
KR20240118762A (ko) * 2021-10-22 2024-08-05 오스트레일리언 내셔널 유니버시티 기판 상에 촉매를 제조하는 방법
JPWO2023181627A1 (fr) * 2022-03-22 2023-09-28
KR102783121B1 (ko) * 2022-09-08 2025-03-19 한국과학기술연구원 산소 발생 반응용 코발트 폼 전극의 제조방법
GB2630010A (en) * 2023-01-05 2024-11-20 Oxford Nanosystems Ltd Improved electrodes
KR102901643B1 (ko) * 2023-10-27 2025-12-19 한국과학기술원 금속공기 배터리의 고에너지 밀도 및 사이클 안정성을 위한 캐스케이드 혐기성 및 호기성 배터리 모드를 통해 효율적인 산소 환원 및 발생을 허용하는 이중 기능성 톱니 모양의 질소 도핑된 구리 황화물 산화물 전극

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Also Published As

Publication number Publication date
AU2017258442A1 (en) 2018-12-06
EP3449042C0 (fr) 2024-10-23
EP3449042A1 (fr) 2019-03-06
US20190119822A1 (en) 2019-04-25
FR3050740A1 (fr) 2017-11-03
JP2019518869A (ja) 2019-07-04
WO2017186454A1 (fr) 2017-11-02
US11661662B2 (en) 2023-05-30
CN109415825A (zh) 2019-03-01
KR20190031197A (ko) 2019-03-25
EP3449042B1 (fr) 2024-10-23
CA3022198A1 (fr) 2017-11-02
CN109415825B (zh) 2021-04-13

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