FR3026412B1 - Traitement de surface de substrats metalliques - Google Patents

Traitement de surface de substrats metalliques Download PDF

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Publication number
FR3026412B1
FR3026412B1 FR1459158A FR1459158A FR3026412B1 FR 3026412 B1 FR3026412 B1 FR 3026412B1 FR 1459158 A FR1459158 A FR 1459158A FR 1459158 A FR1459158 A FR 1459158A FR 3026412 B1 FR3026412 B1 FR 3026412B1
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FR
France
Prior art keywords
metal substrate
metal substrates
organophosphorus compound
metal
surface treatment
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
FR1459158A
Other languages
English (en)
Other versions
FR3026412A1 (fr
Inventor
Fabrice LALLEMAND
Xavier ROIZARD
Jean-Marie MELOT
Aurelien Buteri
Melanie Borgeot
Romain EVRARD
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Universite de Franche-Comte
Aperam SA
Original Assignee
Universite de Franche-Comte
Aperam SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to FR1459158A priority Critical patent/FR3026412B1/fr
Application filed by Universite de Franche-Comte, Aperam SA filed Critical Universite de Franche-Comte
Priority to PL15770520.3T priority patent/PL3198054T3/pl
Priority to MA039690A priority patent/MA39690A/fr
Priority to ES15770520T priority patent/ES2952509T3/es
Priority to US15/514,809 priority patent/US10196744B2/en
Priority to PCT/EP2015/072172 priority patent/WO2016046401A1/fr
Priority to CN201580052122.8A priority patent/CN107109657B/zh
Priority to EP15770520.3A priority patent/EP3198054B1/fr
Priority to CA2962057A priority patent/CA2962057C/fr
Publication of FR3026412A1 publication Critical patent/FR3026412A1/fr
Application granted granted Critical
Publication of FR3026412B1 publication Critical patent/FR3026412B1/fr
Active legal-status Critical Current
Anticipated expiration legal-status Critical

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
    • C23C22/02—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using non-aqueous solutions
    • C23C22/03—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using non-aqueous solutions containing phosphorus compounds
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
    • C23C22/05—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
    • C23C22/06—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6
    • C23C22/07—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing phosphates
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M105/00—Lubricating compositions characterised by the base-material being a non-macromolecular organic compound
    • C10M105/74—Lubricating compositions characterised by the base-material being a non-macromolecular organic compound containing phosphorus
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M137/00—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing phosphorus
    • C10M137/12—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing phosphorus having a phosphorus-to-carbon bond
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
    • C23C22/05—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
    • C23C22/06—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23F—NON-MECHANICAL REMOVAL OF METALLIC MATERIAL FROM SURFACE; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL; MULTI-STEP PROCESSES FOR SURFACE TREATMENT OF METALLIC MATERIAL INVOLVING AT LEAST ONE PROCESS PROVIDED FOR IN CLASS C23 AND AT LEAST ONE PROCESS COVERED BY SUBCLASS C21D OR C22F OR CLASS C25
    • C23F11/00—Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent
    • C23F11/08—Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent in other liquids
    • C23F11/10—Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent in other liquids using organic inhibitors
    • C23F11/167—Phosphorus-containing compounds
    • C23F11/1676—Phosphonic acids
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/06—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having phosphorus-to-carbon bonds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/06—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having phosphorus-to-carbon bonds
    • C10M2223/0603—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having phosphorus-to-carbon bonds used as base material
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/06—Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/12—Inhibition of corrosion, e.g. anti-rust agents or anti-corrosives
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/20—Metal working
    • C10N2040/24—Metal working without essential removal of material, e.g. forming, gorging, drawing, pressing, stamping, rolling or extruding; Punching metal
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/20—Metal working
    • C10N2040/244—Metal working of specific metals
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/20—Metal working
    • C10N2040/244—Metal working of specific metals
    • C10N2040/245—Soft metals, e.g. aluminum
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/20—Metal working
    • C10N2040/244—Metal working of specific metals
    • C10N2040/246—Iron or steel
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/20—Metal working
    • C10N2040/244—Metal working of specific metals
    • C10N2040/247—Stainless steel
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2050/00—Form in which the lubricant is applied to the material being lubricated
    • C10N2050/023—Multi-layer lubricant coatings

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Metallurgy (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Treatment Of Metals (AREA)
  • Other Surface Treatments For Metallic Materials (AREA)
  • Chemically Coating (AREA)
  • Preventing Corrosion Or Incrustation Of Metals (AREA)
  • Lubricants (AREA)
  • Manufacturing Of Printed Wiring (AREA)

Abstract

La présente invention vise principalement un procédé de traitement de surface de substrats métalliques, comprenant les étapes de : (i) fourniture d'un substrat métallique comportant des groupes hydroxyles en surface ; (ii) mise en contact du substrat métallique avec une solution d'au moins un composé organophosphoré de sorte à permettre la réaction desdits groupes hydroxyles en surface du substrat métallique avec ledit composé organophosphoré pour former une couche monomoléculaire sur la surface et une seconde couche de molécules organophosphorées physisorbées partiellement cristallisées, le substrat traité obtenu étant revêtu de composé organophosphoré sous forme monomoléculaire et sous forme physisorbée cristallisée. Elle vise par ailleurs un substrat métallique traité susceptible d'être obtenu par ce procédé, la solution correspondante et son utilisation pour le traitement de substrats métalliques en vue d'améliorer leurs propriétés tribologiques lors de leur mise en forme, notamment à l'emboutissage, ainsi que leur résistance à la corrosion.
FR1459158A 2014-09-26 2014-09-26 Traitement de surface de substrats metalliques Active FR3026412B1 (fr)

Priority Applications (9)

Application Number Priority Date Filing Date Title
FR1459158A FR3026412B1 (fr) 2014-09-26 2014-09-26 Traitement de surface de substrats metalliques
MA039690A MA39690A (fr) 2014-09-26 2015-09-25 Traitement de surface de substrats métalliques
ES15770520T ES2952509T3 (es) 2014-09-26 2015-09-25 Tratamiento de superficie de sustratos metálicos
US15/514,809 US10196744B2 (en) 2014-09-26 2015-09-25 Surface treatment of metal substrates
PL15770520.3T PL3198054T3 (pl) 2014-09-26 2015-09-25 Obróbka powierzchniowa podłoży metalowych
PCT/EP2015/072172 WO2016046401A1 (fr) 2014-09-26 2015-09-25 Traitement de surface de substrats métalliques
CN201580052122.8A CN107109657B (zh) 2014-09-26 2015-09-25 金属基材的表面处理
EP15770520.3A EP3198054B1 (fr) 2014-09-26 2015-09-25 Traitement de surface de substrats métalliques
CA2962057A CA2962057C (fr) 2014-09-26 2015-09-25 Traitement de surface de substrats metalliques

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR1459158 2014-09-26
FR1459158A FR3026412B1 (fr) 2014-09-26 2014-09-26 Traitement de surface de substrats metalliques

Publications (2)

Publication Number Publication Date
FR3026412A1 FR3026412A1 (fr) 2016-04-01
FR3026412B1 true FR3026412B1 (fr) 2019-03-29

Family

ID=52474005

Family Applications (1)

Application Number Title Priority Date Filing Date
FR1459158A Active FR3026412B1 (fr) 2014-09-26 2014-09-26 Traitement de surface de substrats metalliques

Country Status (9)

Country Link
US (1) US10196744B2 (fr)
EP (1) EP3198054B1 (fr)
CN (1) CN107109657B (fr)
CA (1) CA2962057C (fr)
ES (1) ES2952509T3 (fr)
FR (1) FR3026412B1 (fr)
MA (1) MA39690A (fr)
PL (1) PL3198054T3 (fr)
WO (1) WO2016046401A1 (fr)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2020067509A1 (fr) * 2018-09-27 2020-04-02 Toto株式会社 Élément d'installation sanitaire
US20230250536A1 (en) * 2020-07-10 2023-08-10 Biological Dynamics, Inc. Modification of metallic surfaces with phosphonic acids

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4048374A (en) * 1973-09-01 1977-09-13 Dynamit Nobel Aktiengesellschaft Functional organophosphonic acid esters as preservative adhesion promoting agents and coating for metals
US5103550A (en) * 1989-12-26 1992-04-14 Aluminum Company Of America Method of making a food or beverage container
WO1997018905A1 (fr) * 1995-11-20 1997-05-29 Berg Technology, Inc. Procede permettant de conferer une protection anticorrosion
AR009499A1 (es) * 1996-08-30 2000-04-26 Monsanto Technology Llc Composicion y metodos para maquinado de metales y alimentacion de una composicion lubricante, superficie de metal lubricada y articulomanufacturado
CA2336186A1 (fr) * 1998-06-19 1999-12-23 Raymond J. Colbert Procede d'inhibition de taches a la surface de produits en aluminium
WO2007080138A1 (fr) * 2006-01-09 2007-07-19 Basf Se Procede de traitement de surfaces
US9365931B2 (en) * 2006-12-01 2016-06-14 Kobe Steel, Ltd. Aluminum alloy with high seawater corrosion resistance and plate-fin heat exchanger
WO2009000820A2 (fr) * 2007-06-28 2008-12-31 Siemens Aktiengesellschaft Additif anticorrosion pour liquides
TWI394863B (zh) * 2007-12-27 2013-05-01 Kansai Paint Co Ltd 金屬表面處理用組成物及從該金屬表面處理用組成物獲得之具有金屬表面處理層的表面處理金屬材
US8178004B2 (en) * 2008-06-27 2012-05-15 Aculon, Inc. Compositions for providing hydrophobic layers to metallic substrates

Also Published As

Publication number Publication date
MA39690A (fr) 2016-03-31
ES2952509T3 (es) 2023-10-31
CN107109657B (zh) 2019-08-30
CA2962057A1 (fr) 2016-03-31
US10196744B2 (en) 2019-02-05
WO2016046401A1 (fr) 2016-03-31
US20180119287A1 (en) 2018-05-03
CN107109657A (zh) 2017-08-29
CA2962057C (fr) 2021-04-20
EP3198054C0 (fr) 2023-06-07
EP3198054B1 (fr) 2023-06-07
FR3026412A1 (fr) 2016-04-01
EP3198054A1 (fr) 2017-08-02
PL3198054T3 (pl) 2024-01-08

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