FR2994090A1 - Composition used to dye human keratin fibers e.g. hair, includes coloring agent, amphoteric or zwitterionic surfactants, nonionic and anionic surfactants, fatty substances, cationic polymer, and oxidizing agent different from oxygen in air - Google Patents

Abstract

Composition comprises at least one coloring agent, at least one amphoteric or zwitterionic surfactant, at least one nonionic surfactant, at least one anionic surfactant, at least one fatty substances, at least one cationic polymer, and at least one oxidizing agent different from oxygen in the air. An independent claim is included for multi-compartment device comprising a first compartment containing the oxidizing agent different from oxygen in the air and the coloring agent, and a second compartment containing an oxidizing composition, where one and/or other composition comprises at least two compartments comprising the fatty substances, the cationic polymer, the amphoteric or zwitterionic surfactants, the nonionic surfactant, the anionic surfactant and the two compartments are mixed prior to use to obtain the composition.

Description

The present invention relates to a dye composition comprising at least one dyeing composition comprising at least one dyeing composition comprising at least one dyeing composition comprising at least one dyeing composition comprising at least one dyeing composition comprising at least one dyeing composition comprising at least one dyeing composition comprising at least one dyeing composition comprising at least one dyeing composition and at least one dyeing agent. direct dye, at least one amphoteric or zwitterionic surfactant, at least one nonionic surfactant and at least one anionic surfactant, at least one fatty substance, at least one cationic polymer and at least one oxidizing agent different from the oxygen in the air as well as a coloring process using said composition. It also relates to a suitable multi-compartment device. Among the methods for staining human keratinous fibers, such as the hair, mention may be made of oxidation or permanent staining. More particularly, this mode of staining uses one or more oxidation dyes, usually one or more oxidation bases possibly associated with one or more couplers. In general, the oxidation bases are chosen from ortho- or para-phenylenediamines, ortho- or para-aminophenols as well as heterocyclic compounds. These oxidation bases are colorless or weakly colored compounds which, combined with oxidizing products, allow access to colored species. Very often, the shades obtained with these oxidation bases are varied by combining them with one or more couplers, the latter being chosen in particular from aromatic meta-diamines, meta-aminophenols, meta-diphenols and certain heterocyclic compounds, such as indole compounds. The variety of molecules involved in the oxidation bases and couplers allows a rich palette of colors to be obtained.

The permanent coloring processes therefore consist in using with the dyeing composition containing the oxidation dyes an aqueous composition comprising at least one oxidizing agent such as hydrogen peroxide, under alkaline pH conditions in the vast majority of cases. The alkaline agent conventionally used is ammonia or may be chosen from other alkaline agents, such as alkanolamines. Recently, coloring formulations having higher levels of fat have been developed than compositions previously on the market. These formulations provide numerous advantages, in particular in that they make it possible to reduce the ammonia content, thus bringing about a very clear improvement in user comfort (less unpleasant odor and less risk of tingling), without observing a decrease. tinctorial performances, even increasing them.

However, such formulations are complex to implement, precisely because of this high content of fat and often lead to a deterioration of the qualities of use such as ease of application and rinsability. The object of the present invention is therefore to improve the qualities of use of the dye compositions, in particular in the form of a cream, comprising high levels of fat, without reducing the dyeing performance of such compositions. This and other objects are achieved by the present invention which is therefore directed to a human keratin fiber staining composition, such as hair, comprising: (a) at least one direct dye; (b) at least one amphoteric or zwitterionic surfactant; (c) at least one nonionic surfactant; (d) at least one anionic surfactant; (e) at least one fatty substance; (F) at least one cationic polymer; (g) at least one oxidizing agent different from the oxygen of the air. It also relates to a method for staining human keratin fibers in which said composition is applied. The invention likewise relates to a multi-compartment device comprising a compartment containing a composition devoid of an oxidizing agent other than oxygen from air comprising at least one oxidation dye precursor; a compartment containing an oxidizing composition; one and / or the other of the compositions of the two compartments comprising at least one fatty substance, at least one cationic polymer, at least one amphoteric or zwitterionic surfactant, at least one nonionic surfactant, at least one anionic surfactant; the two compartments being mixed before use to obtain a ready-to-use composition as defined above. The composition of the invention makes it possible to obtain good dyeing properties such as the power of color, resistance to external agents (shampoos, perspiration, light) and homogeneity, which are particularly effective. It also has a texture suitable for the application. Indeed, the composition according to the invention is easy to apply to the fibers. It rinses easily after the break time.

Other characteristics and advantages of the invention will emerge more clearly on reading the description and examples which follow. In what follows, and unless otherwise indicated, the boundaries of a domain of values are included in this field.

The term "at least one" associated with an ingredient in the composition means "one or more". The human keratinous fibers treated by the process according to the invention are preferably the hair.

Dyestuffs As indicated above, the dyeing composition according to the invention comprises at least one direct dye. By "direct dye" is meant natural and / or synthetic dyes, different from oxidation dyes. These are dyes that will diffuse superficially on the fiber and color the fibers by themselves. They may be ionic or nonionic, preferably cationic or nonionic. These direct dyes are, for example, chosen from neutral, acidic or cationic nitro-benzene direct dyes, neutral azo, acid or cationic direct dyes, tetraazapentamethine dyes, neutral or acidic or cationic quinone dyes, in particular neutral anthraquinone dyes and direct azine dyes. , triarylmethane direct dyes, azomethine direct dyes and natural direct dyes. As examples of suitable direct dyes, mention may be made of azo direct dyes; (poly) methine dyes such as cyanines, hemicyanins, and styryl dyes; carbonyls; azinic; nitro (hetero) aryl; tri- (hetero) aryl methanes; porphyrins; phthalocyanines and natural direct dyes, alone or in mixtures. Preferentially, the direct dye (s) contain at least one quaternized cationic chromophore or at least one chromophore carrying a quaternized or quaternizable cationic group. According to a particular embodiment of the invention, the direct dyes comprise at least one quaternized cationic chromophore. As direct dye present in the composition according to the invention, mention may be made of acridine dyes; acridones; anthranthrones; anthrapyrimidines; anthraquinones; azines; (poly) azo, hydrazono or hydrazones, especially arylhydrazones; azomethines; benzanthrones; benzimidazoles; benzimidazolones; benzindoles; benzoxazoles; benzopyrans; benzothiazoles; benzoquinones; bisazines; bis isoindolines; carboxanilides; coumarins; cyanines such as azacarbocyanines, diazacarbocyanines, diazahemicyanines, hemicyanines, or tetraazacarbocyanines; diazi nes; diketopyrrolopyrroles; dioxazines; diphenylamines; diphenylmethanes; dithiazines; flavonoids such as flavanthrones and flavones; fluorines; formazans; indamines; indanthrones; indigoides and pseudoindigoids; indophenols; indoanilines; isoindolines; isoindolinones; isoviolanthrones; lactones; (poly) methines such as dimethines of stilbene or styryl types; naphthalimides; naphthanilides; naphtholactams; naphthoquinones; nitro, especially nitro (hetero) aromatic; oxadiazoles; oxazines; perilones; perinones; perylenes; phenazines; phenoxazine; phenothiazines; phthalocyanine; polyenes / carotenoids; porphyrins; pyranthrones; pyrazolanthrones; pyrazolones; pyrimidinoanthrones; pyronines; quinacridones; quinolines; quinophthalones; squaranes; tetrazoliums; thiazines, thioindigo; thiopyronines; triarylmethanes, or xanthenes.

For cationic azo dyes, mention may be made especially of those derived from the cationic dyes described in the Kirk Othmer encyclopedia Encyclopedia of Chemical Technology, "Dyes, Azo", J. Wley & sons, updated on 19/04/2010. Among the azo dyes that may be used according to the invention, mention may be made of the cationic azo dyes described in patent applications WO 95/15144, WO 95/01772 and EP-714954. According to a preferred embodiment of the invention, the direct dye (s) are chosen from cationic dyes called "basic dyes". Amongst the azo dyes described in the Color Index 25 International 3rd Edition, and in particular the following compounds: Basic Red 22, Basic Red 76, Basic Yellow 57, Basic Brown 16, Basic Brown 17. Among the cationic quinone dyes mentioned in the above-mentioned Color Index International are suitable, among them the following dyestuffs: Basic Blue 22, Basic Blue 99, Among the suitable azine dyes are those listed in the Color Index International and for example, the following dyes: Basic Blue 17, Basic Red 2. Among the cationic triarylmethane dyes that can be used according to the invention, mention may be made, in addition to those listed in the Color Index, of the following dyes: Basic Green 1, Basic Violet 3, Basic Violet 14, Basic Blue 7, Basic Blue 26. The cationic dyes described in US 5888252, EP 1133975, WO 03/029359, EP 860636, WO 95/01772, WO may also be mentioned. 95/15144, EP 714954.

There are also those listed in the encyclopedia "The chemistry of synthetic dye" by K. VENKATARAMAN, 1952, Academic press vol 1 to 7, in the encyclopedia "Kirk Othmer" "Chemical technology", chapter "dyes and Dye intermediate ", 1993, VViley and Sounds, and in various chapters of the encyclopedia" ULLMANN's ENCYCLOPEDIA of Industrial Chemistry "7th edition, VViley and Sounds. Preferably, the cationic direct dyes are chosen from those derived from azo-type dyes, and hydrazono. According to a particular embodiment, the direct dyes are cationic azo, as described in EP 850636, FR 2788433, EP 920856, WO 9948465, FR 2757385, EP 850637, EP 918053, WO 9744004, FR 2570946, FR 2285851, DE 2538363. , FR 2189006, FR 1560664, FR 1540423, FR 1567219, FR 1516943, FR 1221122, DE 4220388, DE 4137005, WO 0166646, US 5708151, WO 9501772, WO 515144, GB 1195386, US 3524842, US 5879413, EP 1062940, EP 1133976, GB 738585, DE 2527638, FR 2275462, GB 1974-27645, Acta Histochem. (1978), 61 (1), 48-52; Tsitologiya (1968), 10 (3), 403-5; Zh. Obshch. Khim. (1970), 40 (1), 195-202; Ann. Chim. (Rome) (1975), 65 (5-6), 305-14; Journal of the Chinese Chemical Society (Taipei) (1998), 45 (1), 209-211; Rev. Roum. Chim. (1988), 33 (4), 377-83; Text. Res. J. (1984), 54 (2), 105-7; Chim. Ind. (Milan) (1974), 56 (9), 600-3; Khim. Tekhnol. (1979), 22 (5), 548-53; Ger. Monatsh. Chem. (1975), 106 (3), 643-8; MRL Bull. Res. Dev. (1992), 6 (2), 21-7; Lihua Jianyan, Huaxue Fence (1993), 29 (4), 233-4; Dyes Pigm. (1992), 19 (1), 69-79; Dyes Pigm. (1989), 11 (3), 163-72. Preferably, the cationic direct dye (s) comprise a quaternary ammonium group, more preferably the cationic charge is endocyclic. These cationic radicals are, for example, a cationic radical: - with an exocyclic (di / tri) (C 1 -C 8) alkylammonium charge, or - with an endocyclic charge such as comprising a cationic heteroaryl group chosen from: acridinium, benzimidazolium, benzobistriazolium, benzopyrazolium, benzopyridazinium, benzoquinolium, benzothiazolium, benzotriazolium, benzoxazolium, bi-pyridinium bis-tetrazolium dihydrothiazolium, imidazopyridinium, imidazolium, indolium, isoquinolium, naphthoimidazolium, naphthooxazolium, naphthopyrazolium, oxadiazolium, oxazolium, oxazolopyridinium, oxonium, phenazinium, phénooxazolium, pyrazinium, pyrazolium, pyrazoyltriazolium, pyridinium, pyridinoimidazolium, pyrrolium, pyrylium, quinolium, tetrazolium, thiadiazolium, thiazolium, thiazolopyridinium, thiazoylimidazolium, thiopyrylium, triazolium or xanthylium.

Mention may be made of the hydrazono cationic dyes of formula (II) and (1111), the azo compounds of formulas (IV) and (V) below: Het + -C (Ra) = NN (Rb) -Ar, Q-Het + -N (Ra) -N = C (Rb) -Ar, Q- (II) (III) Het + -N = N-Ar, Q-Ar + -N = N-Ar ", Q- (IV) (V) formulas ( II) to (V) in which: - Het + represents a cationic heteroaryl radical, preferably with an endocyclic cationic charge such as imidazolium, indolium, or pyridinium, optionally substituted, preferably with at least one (CiC8) alkyl group such as methyl; represents an aryl radical, such as phenyl or naphthyl, with an exocyclic cationic charge, preferably an ammonium, especially a tri (C1C8) alkylammonium ammonium such as trimethylammonium, - Ar represents an aryl group, in particular phenyl, which is optionally substituted, preferably with one or more electron-donor groups. such as i) (C1-C8) optionally substituted alkyl, ii) (C1-C8) optionally substituted alkoxy, iii) (di ) (C1-C8) (alkyl) amino optionally substituted on the one or more alkyl groups by a hydroxyl group, iv) aryl (C1C8) alkylamino, v) N- (C1-C8) alkyl-N-aryl (C1-C8) optionally substituted alkylamino or Ar represents a julolidine group; Ar "represents an optionally substituted (hetero) aryl group such as phenyl or pyrazolyl, optionally substituted, preferably with one or more (C1-C8) alkyl, hydroxyl, (di) (C1-C8) (alkyl) amino, C8) groups; alkoxy or phenyl; - Ra and Rb, identical or different, representing a hydrogen atom or a group (C1-C8) alkyl optionally substituted, preferably with a hydroxyl group; - or the substituent Ra with a substituent of Hee and / or Rb with a substituent of Ar together with the atoms which carry them a (hetero) cycloalkyl, especially Ra and Rb, representing a hydrogen atom or a (C1-C4) alkyl group optionally substituted by a hydroxyl group; represents an organic or inorganic anionic counterion such as a halide or an alkyl sulphate.

In particular, mention may be made of the direct dyes with azo and hydrazono endocyclic cationic charge of formula (II) to (V) as defined above. More particularly, the cationic direct dyes of formula (II) to (V) with endocyclic cationic charges described in patent applications WO 95/15144, WO 95/01772 and EP-714954. Preferably, the following direct dyes: ## STR1 ## in which formulas (II-1) and (IV-1) in which: R 1 represents a (C 1 -C 4) alkyl group such than methyl; - R2 and R3, identical or different, represent a hydrogen atom or a group (C1-C4) alkyl such as methyl; and - R4 represents a hydrogen atom or an electron-donor group such as (C1-C8) alkyl optionally substituted, (C1-C8) alkoxy optionally substituted, (di) (C1-C8) (alkyl) amino optionally substituted on or the alkyl groups with a hydroxyl group; in particular, R 4 is a hydrogen atom, Z is a CH group or a nitrogen atom, preferentially CH 2 -CO 2 is an anionic counterion as defined above, especially a halide such as chloride or an alkyl sulphate such as methyl sulphate or mesytyl; .

In particular, the dyes of formula (II-1) and (IV-1) are chosen from Basic Red 51, Basic Yellow 87 and Basic Orange 31 or their derivatives: ## STR2 ## H3C Basic Red 51 Basic Orange 31 Basic Yellow 87 with anionic counter ion as defined above, especially halide such as chloride or an alkylsulfate such as methylsulfate or mesytyl. According to one particular embodiment of the invention, the direct dyes are fluorescent, in other words they contain at least one fluorescent chromophore as defined above. As fluorescent dyes, mention may be made of the radicals derived from acridine dyes, acridones, benzanthrones, benzimidazoles, benzimidazolones, benzindoles, benzoxazoles, benzopyrans, benzothiazoles, coumarines, difluoro {2 - [(2H-pyrrol-2-ylidene-kN) methy1] -1H-pyrrolato-kN} bores (BODIPYO), diketopyrrolopyrroles, fluorindines, (poly) methines (especially cyanines and styryls / hemicyanines), naphthalimides, naphthhanilides, naphthylamine (such as dansyls), oxadiazoles, oxazines, perilones, perinones, perylenes, polyenes / carotenoids, squaranes, stilbenes, xanthenes.

The fluorescent dyes described in documents EP 1133975, WO 03/029359, EP 860636, WO 95/01772, WO 95/15144, EP 714954 and those listed in K's encyclopedia VENKATARAMAN, 1952, Academic press vol 1 to 7, in the encyclopedia "Kirk Othmer" "Chemical technology", chapter "dyes and intermediate Dye", 1993, Wley and sons, and in various chapters of the encyclopedia "ULLMANN's ENCYCLOPEDIA of Industrial Chemistry "7th Edition, VViley and Sounds, in The Handbook - A Guide to Fluorescent Probes and Labeling Technologies, 10th ed Molecular Probes / Invitrogen - Oregon 2005 distributed over the Internet or in previous print editions.

According to a preferred variant of the invention, the fluorescent dye (s) are cationic and comprise at least one quaternary ammonium radical such as those of the following formula (V): W + - [C (R 1) = C (Rd)], - Ar, Q- (V) formula (V) in which: - W + represents a heterocyclic or cationic heteroaryl group, particularly comprising a quaternary ammonium optionally substituted with one or more (C1-C8) alkyl groups optionally substituted in particular by one or more groups hydroxyls; - Ar representing an aryl group such as phenyl or naphthyl, optionally substituted preferably with i) one or more halogen atoms, such as chlorine, fluorine; ii) one or more (ClC8) alkyl, preferably C1-C4, groups such as methyl; iii) one or more hydroxyl groups; iv) one or more (C1-C8) alkoxy groups such as methoxy; v) one or more hydroxyl groups (C1-C8) alkyl such as hydroxyethyl, vi) one or more amino groups or (di) (CiC8) alkylamino, preferably with the alkyl moiety C1-C4 optionally substituted with one or more hydroxyl such as (di) hydroxyethylamino, vii) with one or more acylamino groups; viii) one or more heterocycloalkyl groups such as 5- or 6-membered piperazinyl, piperidinyl or heteroaryl such as pyrrolidinyl, pyridinyl and imidazolinyl; - m 'represents an integer inclusive between 1 and 4, particularly m is 1 or 2; more preferably 1; Rd, which are identical or different, represent a hydrogen atom or an optionally substituted (Ci-C8) alkyl group, preferentially at 0104, or else R, contiguous with V \ / * and / or Rd contiguous with Ar, form with the atoms which carry them a (hetero) cycloalkyl, especially R, is contiguous with V 1 / and form a (hetero) cycloalkyl such as cyclohexyl; C2- is an organic or inorganic anionic counterion as defined above. Among the natural direct dyes that may be used according to the invention, lawsone, juglone, alizarin, purpurine, carminic acid, kermesic acid, purpurogalline, protocatechaldehyde, indigo, isatin , curcumin, spinulosin, apigenidine, hamein, braziline, orceins. It is also possible to use the extracts or decoctions containing these natural dyes, and in particular poultices or extracts made from henna.

The direct dye (s) more particularly represent from 0.001 to 10% by weight of the total weight of the composition, and preferably from 0.005 to 5% by weight. Additional dyes The dyeing composition according to the invention may optionally comprise at least one additional dye, chosen in particular from oxidation dye precursors, for example bases and couplers. By way of example, the oxidation bases are chosen from para-phenylenediamines, bis-phenylalkylenediamines, para-aminophenols, ortho-aminophenols, heterocyclic bases and their addition salts. Among the para-phenylenediamines, there may be mentioned, for example, para-phenylenediamine, paratoluylenediamine, 2-chloro-para-phenylenediamine, 2,3-dimethyl-para-phenylenediamine, 2,6-dimethyl-para-phenylenediamine, 2,6-diethyl paraphenylenediamine, 2,5-dimethyl paraphenylenediamine, N, N-dimethyl paraphenylenediamine, N, N-diethyl paraphenylenediamine, N, Ndipropyl paraphenylenediamine, 4-amino N, N-diethyl-3-methylaniline, N, N-bis ((3 hydroxy-para-phenylenediamine, 4-N, N-bis - ((3-hydroxyethyl) amino-2-methylaniline, 4-N, N-bis - ((3-hydroxyethyl) amino 2-chloroaniline, hydroxyethyl paraphenylenediamine, 2-fluoro-para-phenylenediamine, 2-isopropyl-para-phenylenediamine, N - ((3-hydroxypropyl) para-phenylenediamine, 2-hydroxymethyl-para-phenylenediamine, N, N-dimethyl-3-methyl-para-phenylenediamine, N, N- (ethyl , 3-hydroxyethyl) paraphenylenediamine, N- (13, γ-dihydroxypropyl) by aphenylenediamine, N- (4'-aminophenyl) paraphenylenediamine, N-phenyl paraphenylenediamine, 2 (3-hydroxyethyloxy) paraphenylenediamine, 2 (3-acetylaminoethyloxy) paraphenylenediamine, N - ((3-methoxyethyl) paraphenylenediamine, 4 aminophenylpyrrolidine, 2-thienyl paraphenylenediamine, hydroxyethylamino 5-amino toluene, 3-hydroxy-1- (4'-aminophenyl) pyrrolidine and their addition salts with an acid. Of the paraphenylenediamines mentioned above, paraphenylenediamine, paratoluylenediamine, 2-isopropyl paraphenylenediamine, 213-hydroxyethyl paraphenylenediamine, 2 (3-hydroxyethyloxy) paraphenylenediamine, 2,6-dimethyl paraphenylenediamine, 2,6-diethyl paraphenylenediamine, 2,3-dimethyl paraphenylenediamine, N, N-bis- ((3-hydroxyethyl) paraphenylenediamine, 2-chloro-para-phenylenediamine, 2 (3-acetylaminoethyloxy) para-phenylenediamine, and their acid addition salts are particularly Among the bis-phenylalkylenediamines, N, N'-bis-((3-hydroxyethyl) N, N'-bis (4'-aminophenyl) -1,3-diamino propanol may be mentioned as an example. N, N'-bis - ([3-hydroxyethyl) N, N'-bis- (4'-aminophenyl) ethylenediamine, N, N'-bis- (4-aminophenyl) tetramethylenediamine, N, N ' bis ((3-hydroxyethyl) N, N'-bis- (4-aminophenyl) tetramethylenediamine, N, N'-bis- (4-methylaminophenyl) tetramate thylenediamine, N, N'-bis- (ethyl) N, N'-bis- (4'-amino, 3'-methylphenyl) ethylenediamine, 1,8-bis (2,5-diamino phenoxy) -3 , 6-dioxaoctane, and their addition salts.

Examples of para-aminophenols include para-aminophenol, 4-amino-3-methylphenol, 4-amino-3-fluoro phenol, 4-amino-3-chlorophenol, 4- amino 3-hydroxymethyl phenol, 4-amino-2-methylphenol, 4-amino-2-hydroxymethylphenol, 4-amino-2-methoxymethylphenol, 4-amino-2-aminomethylphenol, 4-amino-2- hydroxyethyl aminomethyl) phenol, 4-amino-2-fluoro phenol, and their addition salts with an acid. Among the ortho-aminophenols, mention may be made, for example, of 2-amino phenol, 2-amino-5-methylphenol, 2-amino-6-methylphenol and 5-acetamido-2-aminophenol, and their addition salts.

Among the heterocyclic bases that may be mentioned by way of example are pyridine derivatives, pyrimidine derivatives and pyrazole derivatives. Among the pyridine derivatives, mention may be made of the compounds described for example in patents GB 1 026 978 and GB 1 153 196, such as 2,5-diamino pyridine, 2- (4-methoxyphenyl) amino-3-amino pyridine, 3,4-diamino pyridine, and their addition salts. Other pyridinic oxidation bases useful in the present invention are the 3-amino pyrazolo [1,5-a] pyridines oxidation bases or their addition salts described for example in the patent application FR 2801308. By way of example, mention may be made of pyrazolo [1,5-a] pyridin-3-ylamine; 2-acetylamino pyrazolo [1,5-a] pyridin-3-ylamine; 2-morpholin-4-yl-pyrazolo [1,5-a] pyridin-3-ylamine; 3-amino-pyrazolo [1,5-a] pyridin-2-carboxylic acid; 2-methoxy-pyrazolo [1,5-a] pyridin-3-ylamino; (3-amino-pyrazolo [1,5-a] pyridin-7-yl) -methanol; 2- (3-aminopyrazolo [1,5-a] pyridin-5-yl) ethanol; 2- (3-Amino-pyrazolo [1,5-a] pyridin-7-yl) -ethanol; (3-Amino-pyrazolo [1,5-a] pyridin-2-yl) -methanol; 3,6-diaminopyrazolo [1,5-a] pyridine; 3,4-diamino-pyrazolo [1,5-a] pyridine; pyrazolo [1,5-a] pyridine-3,7-diamine; 7-morpholin-4-yl-pyrazolo [1,5-a] pyridin-3-ylamine; pyrazolo [1,5-a] pyridine-3,5-diamine; 5-morpholin-4-yl-pyrazolo [1,5-a] pyridin-3-ylamine; 2 - [(3-amino-pyrazolo [1,5-a] pyridin-5-yl) - (2-hydroxyethyl) amino] ethanol; 2 - [(3-amino-pyrazolo [1,5-a] pyridin-7-yl) - (2-hydroxyethyl) amino] ethanol; 3-amino-pyrazolo [1,5-a] pyridin-5-ol; 3-amino-pyrazolo [1,5-a] pyridin-4-ol; 3-amino-pyrazolo [1,5-a] pyridin-6-ol; 3-amino-pyrazolo [1,5-a] pyridin-7-ol; as well as their addition salts. Among the pyrimidine derivatives, mention may be made of the compounds described, for example, in DE 2359399; JP 88-169571; JP 05-63124; EP 0770375 or patent application WO 96/15765 such as 2,4,5,6-tetraaminopyrimidine, 4-hydroxy 2,5,6-triaminopyrimidine, 2-hydroxy 4,5,6-triaminopyrimidine, , 4-dihydroxy-5,6-diaminopyrimidine, 2,5,6-triaminopyrimidine and their addition salts and tautomeric forms, when tautomeric equilibrium exists.

Among the pyrazole derivatives, there may be mentioned for example the compounds described in DE 3843892, DE 4133957 and patent applications WO 94/08969, WO 94/08970, FR-A-2 733 749 and DE 195 43 988 as the 4 , 5-diamino-1-methyl pyrazole, 4,5-diamino-1 - ((3-hydroxyethyl) pyrazole, 3,4-diamino pyrazole, 4,5-diamino-1- (4'-chlorobenzyl) pyrazole, 4,5-diamino 1,3-dimethyl pyrazole, 4,5-diamino-3-methyl-1-phenyl pyrazole, 4,5-diamino-1-methyl-3-phenylpyrazole, 4-amino-1,3-dimethyl -hydrazino pyrazole, 1-benzyl 4,5-diamino-3-methyl pyrazole, 4,5-diamino-3-tert-butyl-1-methyl pyrazole, 4,5-diamino-1-tert-butyl-3-methyl pyrazole, 4,5-diamino 1 - ((3-hydroxyethyl) 3-methyl pyrazole, 4,5-diamino-1-ethyl-3-methyl-pyrazole, 4,5-diamino-1-ethyl-3- (4'-methoxyphenyl) pyrazole, 4,5-diamino-1-ethyl-3-hydroxymethyl pyrazole, 4,5-diamino-3-hydroxymethyl-1-methyl pyrazole, 4,5-diamino-3-hydroxymethyl-1-isopropyl pyrazole, 4,5-d iamino 3-methyl 1-isopropyl pyrazole, 4-amino-5- (2'-aminoethyl) amino 1,3-dimethyl pyrazole, 3,4,5-triamino pyrazole, 1-methyl-3,4,5-triamino pyrazole, 3,5-diamino-1-methyl-4-methylamino pyrazole, 3,5-diamino 4 - ((3-hydroxyethyl) amino-1-methyl pyrazole, and their addition salts. 4-5-Diamino-1 - ((3-methoxyethyl) pyrazole may also be used, preferably a 4,5-diaminopyrazole and even more preferably 4,5-diamino-1 - ((3-hydroxyethyl) Pyrazole derivatives and / or one of its salts Pyrazole derivatives which may also be mentioned are diamino N, Ndihydropyrazolopyrazolones and in particular those described in Application FR-A2 886 136, such as the following compounds and their addition salts 2,3-diamino-6,7-dihydro-1H, 5H-pyrazolo [1,2-a] pyrazol-1-one, 2-amino-3-ethylamino-6,7-dihydro-1H, 5H-pyrazolo [1,2-a] pyrazol-1-one, 2-aminomo-3-isopropylamino-6,7-dihydro-1H, 5H-pyrazolo [1,2-a] pyrazol-1-one, 2-amino 3- (pyrrolidin-1-yl) -6,7-dihydro-1H, 5H-pyrazolo [1,2-a] pyrazol-1-one, 4,5-diamino-1,2-dimethyl-1, 2-yl; dihydro-pyrazol-3-one, 4,5-diamino-1,2-diethyl-1,2-dihydro-pyrazol-3-one, 4,5-diamino-1,2-di- (2-hydroxyethyl) 1,2-dihydro-pyrazol-3-one, 2-amino-3- (2-hydroxyethyl) amino-6,7-dihydro-1H, 5H-pyrazolo [1,2-a] pyrazol-1-one, 2-amino-3- di-methylamino-6,7-dihydro-1H, 5H-pyrazolo [1,2-a] pyrazol-1-one, 2,3-diamino-5,6,7,8-tetrahydro-1H, 6H-pyridazino [1] 2-a] pyrazol-1-one, 4-aminodo-1,2-diethyl-5- (pyrrolidin-1-yl) -1,2-dihydro-pyrazol-3-one, 4-amino-5- (3-Dimethylamino-pyrrolidin-1-yl) -1,2-diethyl-1,2-dihydro-pyrazol-3-one, 2,3-diamino-6-hydroxy-6,7-dihydro-1H, 5H- pyrazolo [1,2-a] pyrazol-1-one. It is preferred to use 2,3-diamino-6,7-dihydro-1H, 5H-pyrazolo [1,2-a] pyrazol-1-one and / or a salt thereof. As heterocyclic bases, 4,5-diamino-1 - ((3-hydroxyethyl) pyrazole and / or 2,3-diamino-6,7-dihydro-1H, 5H-pyrazolo [1,2-a] are preferably used. ] pyrazol-1-one and / or a salt thereof.

Among the couplers that may be used in the composition according to the invention, there may be mentioned in particular meta-phenylenediamines, meta-aminophenols, meta-diphenols, naphthalenic couplers, heterocyclic couplers such as, for example, indole derivatives, derivatives indolinics, sesamol and its derivatives, pyridine derivatives, pyrazolotriazole derivatives, pyrazolones, indazoles, benzimidazoles, benzothiazoles, benzoxazoles, 1,3-benzodioxoles, quinolines, and the addition salts thereof with an acid.

These couplers are more particularly chosen from 2,4-diamino-1 - ((3-hydroxyethyloxy) -benzene, 2-methyl-5-aminophenol, 5-N - ((3-hydroxyethyl) amino-2-methyl- phenol, 3-amino-phenol, 1,3-dihydroxybenzene, 1,3-dihydroxy-2-methyl-benzene, 4-chloro-1,3-dihydroxybenzene, 2-amino-4- ([3-hydroxyethylamino) -1-methoxybenzene, 1,3-diamino-benzene, 1,3-bis (2,4-diaminophenoxy) -propane, sesamol, 1-amino-2-methoxy 4,5-methylenedioxybenzene, α-naphthol, 6-hydroxyindole, 4-hydroxyindole, 4-hydroxy-N -methylindole, 6-hydroxyindoline, 2,6-dihydroxy- 4-methyl-pyridine, 1-H-3-methyl-pyrazol-5-one, 1-phenyl-3-methyl-pyrazol-5-one, 2-amino-3-hydroxypyridine, dimethylpyrazolo [3,2-c] -1,2,4-triazole, 2,6-dimethylpyrazolo- [1,5-b] -1,2,4-triazole, their addition salts with a acid, and mixtures thereof The addition salts of the oxidation bases and the couplers are chosen in particular from the salts with an acid such as hydrochlorides, hydrobromides, sulphates, citrates, succinates, tartrates, lactates, tosylates, benzenesulfonates, phosphates and acetates. The oxidation base (s), if they are present, are generally employed each in an amount of between 0.0001 to 10% by weight relative to the total weight of the composition of the invention, and preferably from 0.005 to 5% by weight. % by weight relative to the total weight of the composition. The coupler (s), if present, are each in general from 0.0001 to 10% by weight relative to the total weight of the composition, and preferably from 0.005 to 5% by weight relative to the weight. total of the composition of the invention. Preferably, the composition according to the invention comprises at least one additional dye chosen from oxidation bases and couplers, or mixtures thereof. Amphoteric or Zwitterionic Surfactants The dyeing composition according to the invention further comprises at least one amphoteric or zwitterionic surfactant.

In particular, the amphoteric or zwitterionic surfactant (s), preferably non-silicone, that may be used in the present invention may be in particular derivatives of secondary or tertiary aliphatic amines, optionally quaternized, in which the aliphatic group is a linear or branched chain comprising from 8 to 22 carbon atoms, said amine derivatives containing at least one anionic group such as, for example, a carboxylate, sulfonate, sulfate, phosphate or phosphonate group.

Mention may in particular be made of (C8-C20) alkyl betaines, (C8-C20) alkyl (?) Sulfobetaines, (C8-C20) alkylamido (C3-C8) alkyl betaines and (08-020) alkylamidylamines. (C6-C8) sulphobetaines. Among the derivatives of secondary or tertiary aliphatic amines, which can optionally be quaternized, which can be used, as defined above, there may also be mentioned the compounds of the following structures (B1) and (B2): Ra-C (O) -NH- CH2-CH2-N + (Rb) (Rc) -CH2C (O) O-, W, X- (B1) Formula wherein: Ra represents a C1-C30 alkyl or alkenyl group derived from a RaCOOH acid, preferably present in hydrolysed coconut oil, a heptyl, nonyl or undecyl group; Rb represents a beta-hydroxyethyl group; and - R, represents a carboxymethyl group; W represents a cationic counterion derived from an alkaline, alkaline earth metal, such as sodium, an ammonium ion or an ion derived from an organic amine, and X represents an organic or inorganic anionic counterion, such as that selected from halides, acetates, phosphates, nitrates, (C1C4) alkyl sulfates, (C1-C4) alkyl or (C1-C4) alkylarylsulfonates, in particular methylsulfate and ethylsulfate; or else W and X- are absent; Ra-C (O) -NH-CH 2 -CH 2 -N (B) (B ') (B2) Formula wherein: B is -CH 2 -CH 2 -O-X'; B 'represents the group - (CH2) zY', with z = 1 or 2; X 'represents the group -CH2-C (O) OH, -CH2-C (O) OZ', -CH2-CH2-C (O) OH, -CH2-CH2-C (O) OZ ', or a hydrogen atom; Y 'represents the group -C (O) OH, -C (O) OZ', -CH2-CH (OH) -SO3H or the group -CH2-CH (OH) -SO3-Z '; Z 'represents a cationic counterion derived from an alkaline or alkaline earth metal, such as sodium, an ammonium ion or an ion derived from an organic amine; Ra, represents a C10-C30 alkyl or alkenyl group of a Ra-C (O) OH acid, preferably present in coconut oil or in hydrolysed linseed oil, an alkyl group, in particular at 017 and its iso form, an unsaturated C17 group. These compounds are classified in the CTFA dictionary, 5th edition, 1993, under the names cocoamphodiacétate disodium, lauroamphodiacétate disodium, caprylamphodiacétate disodium, capryloamphodiacétate disodium, cocoamphodipropionate disodium, lauroamphodipropionate disodium, caprylamphodipropionate disodium, capryloamphodipropionate disodium, acid lauroamphodipropionic, cocoamphodipropionic acid. By way of example, mention may be made of cocoamphodiacetate marketed by Rhodia under the trade name MIRANOL® C2M concentrate. It is also possible to use compounds of formula (B'2); Ra-NH-CH (Y ") - (CH2) nC (O) -NH- (CH2) n -N (Rd) (Re) (B'2) Formula wherein: ^ Y" represents the group -C (O) OH, -C (O) OZ-, -CH2-CH (OH) -SO3H or the group -CH2-CH (OH) -SO3-Z-; Rd and Re, independently of one another, represent a C 1 -C 6 alkyl or hydroxyalkyl radical; represents a cationic counterion derived from an alkali metal or alkaline earth metal, such as sodium, an ammonium ion or an ion; derived from an organic amine; R e represents a C 10 -C 30 alkyl or alkenyl group of a Ra-C (O) OH acid, preferably present in coconut oil or in hydrolysed linseed oil. and n ', independently of one another, denotes an integer ranging from 1 to 3 Among the compounds of formula (B'2) there may be mentioned the compound classified in the CTFA dictionary under the name sodium diethylaminopropyl cocoaspartamide and marketed by the company CHIMEX under the name CHIMEXANE HB These compounds can be used alone or in mixtures.

Among the amphoteric or zwitterionic surfactants mentioned above, use is preferably made of alkyl (C 8 -C 20) betaines such as cocobetaine, (C 8 -C 20) alkylamido (C 3 -C 8) alkylbetaines, such as cocamidopropylbetaine, and their mixtures, the compounds of formula (B'2) such as the sodium salt of diethylaminopropyl laurylamino succinamate (INCI name: sodium diethylaminopropyl cocoaspartamide). More preferably, the amphoteric or zwitterionic surfactant (s) is (are) chosen from cocamidopropylbetaine and cocobetaine, the sodium salt of diethylaminopropyl laurylamino succinamate, or mixtures thereof.

According to an advantageous embodiment of the invention, the content of amphoteric surfactant (s) or zwitterionic (s) varies from 0.1 to 30% by weight, preferably from 0.5 to 20% by weight, and more preferably from 1 to 10% by weight, based on the total weight of the composition.

Nonionic surfactants The composition according to the invention further comprises at least one second surfactant chosen from nonionic surfactants.

Examples of nonionic surfactants useful in the dye composition used according to the invention are described, for example, in "Handbook of Surfactants" by M. R. PORTER, Blackie & Son editions (Glasgow and London), 1991, pp. 116-178.

By way of examples of additional nonionic surfactants, mention may be made of oxyalkylenated or glycerolated nonionic surfactants, in particular the following surfactants, alone or in mixtures: oxyalkylenated (C 8 -C 24) alkyl phenols; saturated or unsaturated, linear or branched, oxyalkylenated or glycerolated C 8 -C 30 alcohols; saturated or unsaturated, linear or branched, oxyalkylenated fatty acid amides of C 8 -C 30; saturated or unsaturated, linear or branched, C 8 -C 30 acid esters of polyethylene glycols; saturated or unsaturated, linear or branched, C8-C30 fatty acid esters, and preferably oxyethylenated esters of sorbitol; esters of sucrose fatty acids, alkyl (C 8 -C 30) polyglycosides, C 6 -C 30 alkenyl polyglycosides, optionally oxyalkylenated (0 to 10 oxyalkylenated units) and comprising 1 to 15 glucose units, esters of alkyl (C8-C30) glycosides, - oxyethylenated vegetable oils, saturated or not; condensates of ethylene oxide and / or propylene oxide, among others, alone or in mixtures; derivatives of N-alkyl (C 8 -C 30) glucamine and N-acyl (C 8 -C 30) -methylglucamine; aldobionamides; amine oxides; Oxyethylenated and / or oxypropylenated silicones. The oxyalkylenated units are more particularly oxyethylenated units, oxypropylene, or their combination, preferably oxyethylenated. The number of moles of ethylene oxide and / or propylene oxide is preferably from 1 to 100, more preferably from 2 to 50; the number of moles of glycerol ranges from 1 to 30.

Advantageously, the nonionic surfactants do not comprise oxypropylene units. As an example of glycerolated nonionic surfactants, the C 8 -C 40 alcohols, mono- or poly-glycerolated, comprising from 1 to 30 moles of glycerol, preferably from 1 to 10 moles of glycerol, are preferably used. By way of example of compounds of this type, mention may be made of lauryl alcohol containing 4 moles of glycerol (INCI name: POLYGLYCERYL-4 LAURYL ETHER), lauric alcohol containing 1.5 moles of glycerol, and alcohol. oleic acid with 4 moles of glycerol (INCI name: POLYGLYCERYL-4 OLEYL ETHER), oleic alcohol with 2 moles of glycerol (INCI name: POLYGLYCERYL-2 OLEYL ETHER), cetearyl alcohol with 2 moles of glycerol, alcohol 6 moles of glycerol, oleocetyl alcohol with 6 moles of glycerol, and octadecanol with 6 moles of glycerol. Among the glycerolated alcohols, it is more particularly preferred to use the alcohol C8 / 010 to one mole of glycerol, the C10 / 012 alcohol to 1 mole of glycerol and the alcohol in O12 to 1.5 moles of glycerol. According to a preferred embodiment of the invention, the nonionic surfactant or surfactants are chosen from: - C 8 -C 30 alcohols, oxyethylenated comprising from 1 to 100 moles of ethylene oxide, preferably from 2 to 50 more preferably from 2 to 30 moles of ethylene oxide; saturated or unsaturated oxyethylenated vegetable oils comprising from 1 to 100 moles of ethylene oxide, preferably from 2 to 50; alkyl (C 8 -C 30) polyglycosides, optionally oxyalkylenated (0 to 10 OE) and comprising 1 to 15 glucose units; - Alcohols C8-040, mono- or poly-glycerol, comprising from 1 to 30 moles of glycerol, preferably from 1 to 10 moles of glycerol; saturated or unsaturated, linear or branched, oxyalkylenated C8-030 fatty acid amides; - their mixtures. Advantageously, the content of nonionic surfactant (s) varies from 0.1 to 30% by weight, preferably from 1 to 20% by weight, and more preferably from 1 to 10% by weight, relative to total weight of the composition. Anionic surfactants The composition according to the invention further comprises at least a third category of surfactants chosen from anionic surfactants. The term "anionic surfactant" is understood to mean a surfactant comprising as ionic or ionizable groups only anionic groups. These anionic groups are preferably chosen from -C (O) OH, -C (O) O-, -SO3H, -S (O) 20-, -OS (O) 20H, -SO (O) 20- , -P (O) OH2, -P (O) 20-, -P (O) O2, -P (OH) 2, = P (O) OH, -P (OH) O-, = P (O) 0-, = POH, = PO-, the anionic parts comprising a cationic counterion such as an alkali metal, an alkaline earth metal, or an ammonium. As examples of additional anionic surfactants that can be used in the dyeing composition according to the invention, mention may be made of alkyl sulphates, alkyl ether sulphates, alkyl klyamido ether sulphates, alkylaryl polyether sulphates, monoglyceride sulphates, alkyl sulphonates and alkyl amide sulphonates. alkylarylsulfonates, alpha-olefin-sulfonates, paraffin-sulfonates, alkylsulfosuccinates, alkylethersulfosuccinates, alkylamide-sulfosuccinates, alkylsulfoacetates, acylsarcosinates, acylglutamates, alkylsulfosuccinamates, acylisethionates and N-acyltaurates salts of alkyl monoesters and of polyglycoside-polycarboxylic acids, acyllactylates, salts of D-galactoside-uronic acids, salts of alkyl ether-carboxylic acids, salts of alkyl aryl ether-carboxylic acids , alkyl amidoethercarboxylic acid salts, and the corresponding non-salified forms of all these compounds, alkyl and acyl groups of all these compounds having from 6 to 40 carbon atoms and the aryl group denoting a phenyl group.

These compounds may be oxyethylenated and then preferably comprise from 1 to 50 ethylene oxide units. The salts of C 6 -C 24 alkyl monoesters and of polyglycoside polycarboxylic acids may be chosen from alkyl polyglycoside citrates at 06024, C 6 -C 24 alkyl polyglycoside tartrates and alkyl polyglycoside sulphosuccinates. C6-024. When the agent or the anionic surfactants are in the salt form, they may be chosen from alkali metal salts such as the sodium or potassium salt and preferably sodium salt, ammonium salts, amine salts and in particular aminoalcohols or alkaline earth metal salts such as magnesium salts. By way of example of aminoalcohol salts, mention may be made in particular of the salts of mono-, di- and triethanolamine, the salts of mono-, di- or triisopropanolamine and the salts of 2-amino-2-methyl-1-one. propanol, 2-amino-2-methyl-1,3-propanediol and tris (hydroxymethyl) amino methane. The alkali metal or alkaline earth metal salts and in particular the sodium or magnesium salts are preferably used.

Among the additional anionic surfactants mentioned, it is preferred to use (C 6 -C 24) alkyl sulphates, alkyl (C 6 -C 24) ether sulphates comprising from 2 to 50 ethylene oxide units, especially in the form of alkali metal salts, ammonium, aminoalcohols, and alkaline earth metals, or a mixture of these compounds. In particular, it is preferred to use (C 12 -C 20) alkyl sulphates, C 12 -C 20 alkyl ether sulphates comprising from 2 to 20 ethylene oxide units, in particular in the form of alkali metal salts, ammonium salts, aminoalcohol , and alkaline earth metals, or a mixture of these compounds. More preferably, it is preferred to use sodium lauryl ether sulfate with 2.2 moles of ethylene oxide. The content of anionic or anionic surfactant (s) varies from 0.1 to 30% by weight, preferably from 1 to 20% by weight, and more preferably from 1 to 10% by weight. relative to the total weight of the composition. Preferably, the surfactant (s) amphoteric (s) / anionic surfactant (s) weight ratio advantageously varies from 0.1 to 10, more particularly from 0.5 to 5, preferably from 1 to 3. Advantageously, the surfactant (s) anionic (s) / nonionic surfactant (s) weight ratio advantageously varies from 0.01 to 5, more particularly from 0.05 to 1, preferably from 0.1 to 0.5. It should be noted that, preferably, the surfactant (s) / nonionic surfactant (s) / amphoteric (s) or zwitterionic surfactant (s) ratio advantageously varies from 0.1 to 10, more particularly from 0.5 to 5, preferably from 1 to 5. Fatty bodies As has been mentioned, the composition of the invention comprises at least one fatty substance. By "fatty substance" is meant an organic compound which is insoluble in water at ordinary temperature (25 ° C.) and at atmospheric pressure (760 mmHg) (solubility of less than 5% and preferably of 1%, even more preferentially at 0.1%). They have in their structure at least one hydrocarbon chain containing at least 6 carbon atoms or a chain of at least two siloxane groups. In addition, the fatty substances are generally soluble in organic solvents under the same conditions of temperature and pressure, such as, for example, chloroform, dichloromethane, carbon tetrachloride, ethanol, benzene, toluene, tetrahydrofuran ( THF), petrolatum oil or decamethylcyclopentasiloxane. The fatty substances of the invention do not contain salified carboxylic acid groups.

In addition, the fatty substances of the invention are not (poly) oxyalkylenated nor (poly) glycerolated ethers. By "oil" is meant a "fat" which is liquid at room temperature (25 ° C), and at atmospheric pressure (760 mm Hg). The term "non-silicone oil" means an oil containing no silicon atom (Si) and a "silicone oil" an oil containing at least one silicon atom. More particularly, the fatty substances are chosen from C 6 hydrocarbons. 016, hydrocarbons having more than 16 carbon atoms, non-silicone oils of animal origin, vegetable oils of the triglyceride type, synthetic triglycerides, fluorinated oils, fatty alcohols, fatty acid esters and / or fatty alcohol different from triglycerides and vegetable waxes, non-silicone waxes, silicones, and mixtures thereof. It is recalled that the alcohols, esters and fatty acids more particularly have at least one hydrocarbon group, linear or branched, saturated or unsaturated, comprising 6 to 30, more preferably 8 to 30 carbon atoms, optionally substituted, in particular by one or several hydroxyl groups (in particular 1 to 4). If unsaturated, these compounds may comprise one to three carbon-carbon double bonds, conjugated or otherwise. Regarding the C 6 -C 16 hydrocarbons, the latter are linear, branched, optionally cyclic and preferably alkanes. By way of example, mention may be made of hexane, dodecane and isoparaffins, such as isohexadecane and isodecane. As hydrocarbon oils of animal origin, mention may be made of perhydrosqualene.

Triglyceride oils of vegetable or synthetic origin are preferably chosen from liquid triglycerides of fatty acids containing from 6 to 30 carbon atoms, for example triglycerides of heptanoic or octanoic acids or, for example, sunflower oil or corn oil. , soya, squash, grape seed, sesame, hazelnut, apricot, macadamia, arara, sunflower, castor oil, avocado, triglycerides of caprylic / capric acids such as those sold by Stearineries Dubois or those sold under the names Miglyol® 810, 812 and 818 by the company Dynamit Nobel, jojoba oil, shea butter oil; The linear or branched hydrocarbons, of mineral or synthetic origin, of more than 16 carbon atoms, are preferably chosen from paraffin oils, petroleum jelly, liquid petroleum jelly, polydecenes, hydrogenated polyisobutene such as Parleam® .

As regards the C 6 -C 16 alkanes, the latter are linear, branched, and possibly cyclic. By way of example, mention may be made of hexane, dodecane and isoparaffins, such as isohexadecane and isodecane. As oils of animal, vegetable, mineral or synthetic origin, which can be used in the composition of the invention, mention may be made, for example, of: the fluorinated oils may be chosen from perfluoromethylcyclopentane and perfluoro-1,3-dimethylcyclohexane, sold under the names "FLUTEC® PC1" and "FLUTEC® PC3" by BNFL Fluorochemicals; perfluoro-1,2-dimethylcyclobutane; perfluoroalkanes such as dodecafluoropentane and tetradecafluorohexane, sold under the names "PF 5050®" and "PF 5060®" by the company 3M, or bromoperfluorooctyl sold under the name "Foralkyl®" by the company Atochem; nonafluoro-methoxybutane and nonafluoroethoxyisobutane; perfluoromorpholine derivatives, such as 4-trifluoromethyl perfluoromorpholine sold under the name "PF 5052®" by the company 3M. The fatty alcohols that are suitable for carrying out the invention are more particularly chosen from linear or branched saturated or unsaturated alcohols containing from 6 to 30 carbon atoms, preferably from 8 to 30 carbon atoms. For example, cetyl alcohol, stearyl alcohol and their mixture (cetylstearyl alcohol), octyldodecanol, 2-butyloctanol, 2-hexyldecanol, 2-undecylpentadecanol, oleic alcohol or linoleic alcohol may be mentioned; . With regard to fatty acid esters and / or fatty alcohols, advantageously different from the triglycerides mentioned previously; mention may in particular be made of linear or branched C 1 -C 26 saturated or unsaturated aliphatic mono or poly acid esters and linear or branched C 1 -C 26 saturated or unsaturated aliphatic mono or polyalcohols, the total number of carbon of the esters being greater or equal to 6, more preferably greater than or equal to 10. Among the monoesters, mention may be made of dihydroabietyl behenate; octyldodecyl behenate; isoketyl behenate; cetyl lactate; C12-C15 alkyl lactate; isostearyl lactate; lauryl lactate; linoleyl lactate; oleyl lactate; (iso) stearyl octanoate; isocetyl octanoate; octyl octanoate; cetyl octanoate; decyl oleate; isocetyl isostearate; isocetyl laurate; isocetyl stearate; isodecyl octanoate; isodecyl oleate; isononyl isononanoate; isostearyl palmitate; methyl ricinoleate acetyl; myristyl stearate; octyl isononanoate; 2-ethylhexyl isononate; octyl palmitate; octyl pelargonate; octyl stearate; octyldodecyl erucate; oleyl erucate; ethyl palmitates and isopropyl palmitate, ethyl-2-hexyl palmitate, 2-octyldecyl palmitate, alkyl myristates such as isopropyl, butyl, cetyl, 2-octyldodecyl myristate; , styryl, hexyl stearate, butyl stearate, isobutyl stearate; dioctyl malate, hexyl laurate, 2-hexyldecyl laurate.

Still within the scope of this variant, it is also possible to use esters of C 4 -C 22 di or tricarboxylic acids and of C 1 -C 22 alcohols and esters of mono di or tricarboxylic acids and of di, tri, alcohols. tetra or pentahydroxy in 02-026. These include: diethyl sebacate; diisopropyl sebacate; diisopropyl adipate; di-propyl adipate; dioctyl adipate; diisostearyl adipate; dioctyl maleate; glyceryl undecylenate; octyldodecyl stearoyl stearate; pentaerythrityl monoricinoleate; pentaerythrityl tetraisononanoate; pentaerythrityl tetrapelargonate; pentaerythrityl tetraisostearate; pentaerythrityl tetraoctanoate; propylene glycol dicaprylate; propylene glycol dicaprate, tridecyl erucate; triisopropyl citrate; triisotearyl citrate; glyceryl trilactate; glyceryl trioctanoate; trioctyldodecyl citrate; trioleyl citrate, propylene glycol dioctanoate; neopentyl glycol diheptanoate; diethylene glycol diisanonate; and polyethylene glycol distearates. Among the esters mentioned above, it is preferred to use ethyl, isopropyl, myristyl, cetyl, stearyl palmitates, ethyl-2-hexyl palmitate, 2-octyldecyl palmitate, myristates of alkyls such as isopropyl, butyl, cetyl, 2-octyldodecyl myristate, hexyl stearate, butyl stearate, isobutyl stearate; dioctyl malate, hexyl laurate, 2-hexyldecyl laurate and isononyl isononanate, cetyl octanoate.

The composition may also comprise, as fatty ester, esters and diesters of C 6 -C 30, preferably C 12 -C 22, fatty acid sugars. It is recalled that "sugar" is understood to mean oxygenated hydrocarbon compounds which have several alcohol functions, with or without an aldehyde or ketone function, and which contain at least 4 carbon atoms. These sugars can be monosaccharides, oligosaccharides or polysaccharides. Suitable sugars include, for example, sucrose (or sucrose), glucose, galactose, ribose, fucose, maltose, fructose, mannose, arabinose, xylose, lactose, and their derivatives. especially alkyls, such as methyl derivatives such as methylglucose. The esters of sugars and of fatty acids may be chosen in particular from the group comprising the esters or mixtures of esters of sugars described previously and of linear or branched, saturated C 6 -C 30, preferably C 12 -C 22, fatty acids. or unsaturated. If unsaturated, these compounds may comprise one to three carbon-carbon double bonds, conjugated or otherwise. The esters according to this variant may also be chosen from mono-, di-, tri- and tetraesters, polyesters and mixtures thereof.

These esters may be for example oleate, laurate, palmitate, myristate, behenate, cocoate, stearate, linoleate, linolenate, caprate, arachidonates, or mixtures thereof, such as in particular the mixed oleo-palmitate, oleostearate and palmitostearate esters. More particularly, the mono- and di-esters are used, and especially the mono- or dioleate, stearate, behenate, oleopalmitate, linoleate, linolenate, oleostearate, sucrose, glucose or methylglucose. By way of example, mention may be made of the product sold under the name Glucate® DO by the company Amerchol, which is a methylglucose dioleate. Mention may also be made, by way of examples, of esters or mixtures of esters of fatty acid sugar: the products sold under the names F160, F140, F110, F90, F70, SL40 by the company Crodesta, respectively denoting sucrose palmito-stearates of 73% monoester and 27% di- and tri-ester, 61% monoester and 39% di-, tri- and tetraester, 52% monoester and 48% monoester; % di-, tri- and tetraester, 45% monoester and 55% di-, tri- and tetraester, 39% monoester and 61% di-, tri-, and tetra. -ester, and sucrose mono-laurate; the products sold under the name Ryoto Sugar Esters, for example referenced B370 and corresponding to sucrose behenate formed from 20% monoester and 80% di-triester-polyester; the sucrose mono-dipalmito-stearate marketed by Goldschmidt under the name Tegosoft® PSE. The non-silicone wax or waxes are chosen in particular from carnauba wax, candelilla wax, and alfa wax, paraffin wax, ozokerite, vegetable waxes such as olive wax or rice wax. hydrogenated jojoba wax or the absolute waxes of flowers such as the essential wax of blackcurrant sold by the company BERTIN (France), animal waxes such as beeswax, or modified beeswax (cerabellina) ; other waxes or waxy raw materials that can be used according to the invention are, in particular, marine waxes, such as the one sold by SOPHIM under the reference M82, and polyethylene or polyolefin waxes in general. The silicones that can be used in the dyeing composition of the present invention are volatile or non-volatile, cyclic, linear or branched silicones, modified or not with organic groups, having a viscosity of 5 × 10 -6 to 2.5 m 2 / s at 25 ° C. C and preferably 1.10-5 to 1m2 / s. The silicones that can be used in accordance with the invention can be in the form of oils, waxes, resins or gums. Preferably, the silicone is chosen from polydialkylsiloxanes, especially polydimethylsiloxanes (PDMS), and organomodified polysiloxanes comprising at least one functional group chosen from amino groups and alkoxy groups. Organopolysiloxanes are further defined in Walter Noll's "Chemistry and Technology of Silicones" (1968), Academie Press. They can be volatile or nonvolatile. When they are volatile, the silicones are more particularly chosen from those having a boiling point of between 60 ° C. and 260 ° C., and even more particularly from: (i) cyclic polydialkylsiloxanes containing from 3 to 7, preferably from 4 to 5 silicon atoms. It is, for example, octamethylcyclotetrasiloxane sold in particular under the name VOLATILE SILICONE® 7207 by UNION CARBIDE or SILBONE® 70045 V2 by RHODIA, decamethylcyclopentasiloxane sold under the name VOLATILE SILICONE® 7158 by UNION CARBIDE, and SILBIONE ® 70045 V5 by RHODIA, as well as their mixtures.

Mention may also be made of cyclocopolymers of the dimethylsiloxane / methylalkylsiloxane type, such as the VOLATILE® SILICONE FZ 3109 marketed by UNION CARBIDE, of formula: ## STR5 ## Examples of these are cyclic polydialkylsiloxane mixtures with organic compounds derived from silicon, such as the mixture of octamethylcyclotetrasiloxane and tetramethylsilylpentaerythritol (50/50) and the mixture. octamethylcyclotetrasiloxane and oxy-1,1 '- (hexa-2,2,2', 2 ', 3,3'-trimethylsilyloxy) bis-neopentane (ii) linear volatile polydialkylsiloxanes having 2 to 9 carbon atoms; silicon and having a viscosity less than or equal to 5.10-6 m 2 / s at 25 ° C. It is, for example, decamethyltetrasiloxane marketed in particular under the name "SH 200" by Toray Silicone, silicones entering this class. are also described in the article published in Cosmetics and Toiletries, Vol. 91, Jan. 76, p. 27-32 - TODD & BYERS "Volatile Silicone fluids for cosmetics". Non-volatile polydialkylsiloxanes, polydialkylsiloxane gums and resins, polyorganosiloxanes modified with the above organofunctional groups and mixtures thereof are preferably used. These silicones are more particularly chosen from polydialkylsiloxanes, among which may be mentioned mainly polydimethylsiloxanes with trimethylsilyl end groups. The viscosity of the silicones is measured at 25 ° C. according to ASTM 445 Appendix C.

Among these polydialkylsiloxanes, mention may be made, without limitation, of the following commercial products: SILBIONE® oils of the 47 and 70 047 series or the MIRASIL® oils marketed by RHODIA, such as, for example, the 70 047 V 500 000 oil; the oils of the MIRASIL® series marketed by RHODIA; the oils of the 200 series of Dow Corning, such as DC200 having a viscosity of 60,000 mm 2 / s; - VISCASIL® oils from GENERAL ELECTRIC and some oils from SF series (SF 96, SF 18) from GENERAL ELECTRIC. Mention may also be made of polydimethylsiloxanes with dimethylsilanol end groups known under the name of dimethiconol (CTFA), such as the oils of the 48 series from the company RHODIA. In this class of polydialkylsiloxanes, mention may also be made of the products sold under the names "ABIL WAX® 9800 and 9801" by GOLDSCHMIDT, which are polydialkyl (C1-C20) siloxanes.

The silicone gums that can be used in accordance with the invention are in particular polydialkylsiloxanes, preferably polydimethylsiloxanes having high average molecular weights of between 200,000 and 1,000,000 used alone or in a mixture in a solvent. This solvent may be chosen from volatile silicones, polydimethylsiloxane (PDMS) oils, polyphenylmethylsiloxane (PPMS) oils, isoparaffins, polyisobutylenes, methylene chloride, pentane, dodecane, tridecane or their mixtures. More particularly useful products according to the invention are mixtures such as: - mixtures formed from a hydroxyl end-of-the-chain polydimethylsiloxane, or dimethiconol (CTFA) and a cyclic polydimethylsiloxane also called cyclomethicone (CTFA) such that the product Q2 1401 marketed by the company Dow Corning; mixtures of a polydimethylsiloxane gum and a cyclic silicone such as the product SF 1214 Silicone Fluid from the company General Electric, this product is an SF 30 gum corresponding to a dimethicone, having a number average molecular weight of 500,000 solubilized in oil SF 1202 Silicone Fluid corresponding to decamethylcyclopentasiloxane; mixtures of two PDMSs of different viscosities, and more particularly of a PDMS gum and a PDMS oil, such as the product SF 1236 from the company General Electric. The product SF 1236 is the mixture of an SE 30 gum defined above having a viscosity of 20 m 2 / s and an SF 96 oil with a viscosity of 5 × 10 -6 m 2 / s. This product preferably comprises 15% of SE gum and 85% of an SF 96 oil. The organopolysiloxane resins used in accordance with the invention are crosslinked siloxane systems containing the units: R 2 SiO 2/2, R 3 SiO 1/2, R 5 TiO 3 / 2 and SiO412 wherein R represents an alkyl having 1 to 16 carbon atoms.

Among these products, those that are particularly preferred are those in which R denotes a C1-C4 lower alkyl group, more particularly methyl. Among these resins may be mentioned the product sold under the name "Dow Corning 593" or those sold under the names "Silicone Fluid SS 4230 and SS 4267" by the company General Electric and which are silicones of dimethyl / trimethyl siloxane structure. Mention may also be made of the trimethylsiloxysilicate type resins sold in particular under the names X22-4914, X21-5034 and X215037 by the company Shin-Etsu. The organomodified silicones that may be used in accordance with the invention are silicones as defined above and comprising in their structure one or more organofunctional groups attached via a hydrocarbon-based group. In addition to the silicones described above, the organomodified silicones may be polydiaryl siloxanes, in particular polydiphenylsiloxanes, and polyalkyl-arylsiloxanes functionalized with the organofunctional groups mentioned previously.

The polyalkylarylsiloxanes are especially chosen from polydimethyl / methylphenylsiloxanes, linear and / or branched polydimethyl / diphenylsiloxanes with a viscosity ranging from 1 × 10 -5 to 5 × 10 -2 m 2 / s at 25 ° C. Among these polyalkylarylsiloxanes include by way of example the products sold under the following names: SILBIONE® oils of the 70 641 series from RHODIA; . RHODORSIL® 70 633 and 763 RHODIA series of oils; . DOW CORNING 556 COSMETIC GRAD FLUID oil from DOW CORNING; . silicones of the PK series from BAYER, such as the product PK20; . silicones of the PN and PH series of BAYER, such as the PN1000 and PH1000 products; . certain oils of the SF series of GENERAL ELECTRIC such as SF 1023, SF 1154, SF 1250, SF 1265. Among the organomodified silicones, mention may be made of polyorganosiloxanes comprising: substituted or unsubstituted amino groups, such as the products sold under the name GP 4 Silicone Fluid and GP 7100 by the company Genesee or the products sold under the names Q2 8220 and Dow Corning 929 or 939 by Dow Corning. The substituted amino groups are, in particular, C1-C4 aminoalkyl groups; alkoxylated groups, such as the product sold under the name "Silicone Copolymer ER F-755" by SWS Silicones and Abil Wax® 2428, 2434 and 2440 by the company GOLDSCHMIDT. More particularly, the fatty substances are chosen from liquid or pasty compounds at room temperature (25 ° C.) and at atmospheric pressure. Preferably, the fatty substance is a liquid compound at a temperature of 25 ° C. and at atmospheric pressure. The fatty substances are advantageously chosen from C 6 -C 16 alkanes, non-silicone oils of vegetable, mineral or synthetic origin, fatty alcohols, fatty acid esters and / or fatty alcohol esters, non-silicone waxes and silicones, or mixtures thereof. Preferably, the fatty substance is chosen from liquid petrolatum, C6-C16 alkanes, polydecenes, liquid esters of fatty acid and / or fatty alcohol, liquid fatty alcohols or mixtures thereof.

The composition according to the invention more particularly comprises at least 10% by weight of fatty substances, advantageously at least 15% by weight, still more advantageously at least 20% by weight, preferably at least 25% by weight, even more particularly at least 30% by weight and up to 70% by weight relative to the total weight of the composition. Cationic Polymer As indicated above, the composition comprises at least one cationic polymer. It is recalled that within the meaning of the present invention, the expression "cationic polymer" denotes any polymer containing cationic groups and / or ionizable groups in cationic groups.

Preferably, the cationic polymer present in the composition according to the invention is a linear, random, grafted or block homopolymer or copolymer, and comprises at least one cationic and / or ionizable group in a cationic group chosen from primary amine groups, secondary, tertiary and / or quaternary elements forming part of the main chain of the polymer or being carried by a lateral substituent directly connected thereto. Preferably, the cationic charge density of the cationic polymers according to the invention is greater than 1 meq / g, still more particularly greater than or equal to 4 meq / g. This charge density is determined by the Kjeldahl method. It can also be calculated from the chemical nature of the polymer. The cationic polymers used generally have a number-average molecular weight of between about 500 and 5 × 10 6, and preferably between 103 and 3 × 10 6. Among the cationic polymers, mention may be made more particularly of the polyamine, polyaminoamide and quaternary polyammonium type polymers. These are known products and are described in particular in patents FR 2505348 or FR 2542997. Among the cationic polymers that can be used in the context of the invention, mention may be made of the following polymers, alone or as a mixture: (1) Homopolymers or copolymers derivatives of acrylic or methacrylic esters or amides and comprising at least one of the following units of formulas (I), (II), (III) or (IV): R3 R3 R3 R3 -CH2 O = O (I) ANR (R 2 -CH 2 O = O (II) A _.N + Ra R 6 R, -CH 2 O = NH (III) A N + R 4 R 6, -CH 2 O = (IV) NH AN 1 R 2 in which: R 3, identical or different denote a hydrogen atom or a radical CH3; A, which may be identical or different, represent a linear or branched C 1 -C 6, preferably C 2 -C 3, alkyl or a C 1 -C 4 hydroxyalkyl group; R 4 R5, R6, which may be identical or different, represent a C1-C18 alkyl group or a benzyl radical, and preferably a C1-C6 alkyl group; R1 and R2, which may be identical or different, represent hydrogen or a C106 alkyl group, and preferably methyl or ethyl; X denotes an anion derived from a mineral or organic acid such as a methosulphate anion or a halide such as chloride or bromide. The polymers of family (1) may also contain one or more units derived from comonomers which may be chosen from the family of acrylamides, methacrylamides, diacetones acrylamides, acrylamides and methacrylamides substituted on nitrogen by lower alkyls (C1-C4). , acrylic or methacrylic acids or their esters, vinyllactams such as vinylpyrrolidone or vinylcaprolactam, vinyl esters. Thus, among these polymers of family (1), mention may be made of: copolymers of acrylamide and of dimethylaminoethyl methacrylate quaternized with dimethyl sulphate or with a dimethyl holognide, such as that sold under the name Hercofloc by the company Hercules, the copolymers of acrylamide and methacryloyloxyethyl-trimethylammonium chloride described for example in EP 80976 and sold under the name Bina Quat P 100 by the company Ciba Geigy, the copolymer of acrylamide and of methosulphate of methacryloyloxyethyltrimethylammonium sold under the name Reten by the company Hercules, the vinylpyrrolidone / dialkylaminoalkyl acrylate or methacrylate copolymers quaternized or otherwise, such as the products sold under the name "Gafquat" by the company ISP, for example "Gafquat 734" or "Gafquat 755" or the products referred to as "Copolymer 845, 958 and 937". These polymers are described in FR 2077143 and FR 2393573, dimethylaminoethyl methacrylate / vinylcaprolactam / vinylpyrrolidone terpolymers such as the product sold under the name Gaffix VC 713 by the company ISP, vinylpyrrolidone / methacrylamidopropyl dimethylamine copolymers marketed in particular under the name Styleze CC 10 by ISP, - vinylpyrrolidone / dimethylamino-propyl methacrylamide quaternized copolymers such as the product sold under the name "Gafquat HS 100" by the company ISP. crosslinked polymers of methacryloyloxyalkyl (C1-C4) trialkyl (C1-C4) ammonium salts, such as the polymers obtained by homopolymerization of dimethylaminoethyl methacrylate quaternized with methyl chloride, or by copolymerization of acrylamide with dimethylaminoethyl methacrylate quaternized with chloride; of methyl, the homo or copolymerization being followed by crosslinking with an olefinically unsaturated compound, in particular methylenebisacrylamide. It is more particularly possible to use a crosslinked acrylamide / methacryloyloxyethyltrimethylammonium chloride copolymer (20/80 by weight) in the form of a dispersion containing 50% by weight of said copolymer in mineral oil. This dispersion is marketed under the name "Salcare® SC 92" by the company Ciba. It is also possible to use a crosslinked homopolymer of methacryloyloxyethyltrimethylammonium chloride containing about 50% by weight of the homopolymer in mineral oil or in a liquid ester. These dispersions are marketed under the names "Salcare® SC 95" and "Salcare® SC 96" by the company Ciba. (2) Cationic cellulose derivatives such as cellulose copolymers or cellulose derivatives grafted with a water-soluble quaternary ammonium monomer, and described especially in US 4131576, such as hydroxyalkyl celluloses, such as hydroxymethyl-, hydroxyethyl- or hydroxypropyl celluloses grafted in particular with a salt of methacryloylethyl trimethylammonium, methacrylmidopropyl trimethylammonium, dimethyl-diallylammonium.

The marketed products corresponding to this definition are more particularly the products sold under the name "Celquat L 200" and "Celquat H 100" by the company National Starch. (3) The cationic guar gums described more particularly in US 3589578 and US 4031307 such as guar gums containing cationic trialkylammonium groups. For example, guar gums modified with a salt (for example chloride) of 2,3-epoxypropyltrimethylammonium are used.

Such products are sold in particular under the trade names of Jaguar C13S, Jaguar C15, Jaguar C17 or Jaguar C162 by Meyhall. (4) Polymers consisting of piperazinyl units and straight or branched chain alkylene or hydroxyalkylene divalent radicals, optionally interrupted by oxygen, sulfur, nitrogen or aromatic or heterocyclic rings, as well as oxidation and / or quaternization of these polymers. Such polymers are described in particular in FR 2162025 and FR 2280361. (5) The water-soluble polyaminoamides prepared in particular by polycondensation of an acidic compound with a polyamine; these polyaminoamides may be crosslinked by an epihalohydrin, a diepoxide, a dianhydride, an unsaturated dianhydride, a bis-unsaturated derivative, a bis-halohydrin, a bisazetidinium, a bis-haloacyldiamine, an alkyl bis-halide or by a oligomer resulting from the reaction of a bifunctional compound reactive with a bis-halohydrin, a bis-azetidinium, a bis-haloacyldiamine, an alkyl bis-halide, a epilhalohydrin, a diepoxide or bis-unsaturated derivative; the crosslinking agent being used in proportions ranging from 0.025 to 0.35 moles per amine group of the polyaminoamide; these polyaminoamides can be alkylated or if they contain one or more tertiary amine functions, quaternized. Such polymers are especially described in FR 2252840 and FR 2368508; The polyamino amide derivatives resulting from the condensation of polyalkylene polyamines with polycarboxylic acids followed by alkylation with difunctional agents. Mention may be made, for example, of adipic acid-diacoylamino-hydroxyalkyldialoylene triamine polymers in which the alkyl radical is C1-C4 and preferably denotes methyl, ethyl or propyl. Such polymers are especially described in FR 1583363. Among these derivatives, mention may be made more particularly of the adipic acid / dimethylaminohydroxypropyl / diethylene triamine polymers sold under the name "Cartaretine F, F4 or F8" by the company Sandoz. (6) Polymers obtained by reaction of a polyalkylene polyamine comprising two primary amine groups and at least one secondary amine group with a dicarboxylic acid chosen from diglycolic acid and saturated C 3 -C 8 aliphatic dicarboxylic acids. The molar ratio between the polyalkylene polylamine and the dicarboxylic acid being between 0.8: 1 and 1.4: 1; the polyaminoamide resulting therefrom being reacted with epichlorohydrin in a molar ratio of epichlorohydrin relative to the secondary amine group of the polyaminoamide of between 0.5: 1 and 1.8: 1. Such polymers are described in particular in US Pat. No. 3,227,615 and US Pat. No. 6,613,447. Polymers of this type are in particular sold under the name "Hercosett 57", "PD 170" or "Delsette 101" by the company Hercules. (7) cyclopolymers of alkyl diallyl amine or of dialkyl diallyl ammonium, such as homopolymers or copolymers comprising, as main constituent of the chain, units corresponding to formulas (V) or (VI): (CQ2) k (CQ2) k - (CH2) t-CR9 C (R9) -CH2- - (CH2) t-CR9C (R9) -CH2-H2CCH, xH2CxCH2 (V) N + (VI) R (R8) R7 formulas in which k and t are equal to 0 or 1, the sum k + t being equal to 1; R 9 denotes a hydrogen atom or a methyl radical; R 7 and R 8, independently of one another, denote a C 1 -C 6 alkyl group; C8, a hydroxyalkyl group in which the alkyl group is C1-C5, an amidoalkyl group whose alkyl is C1-C4; R7 and R8 may also designate jointly with the nitrogen atom to which they are attached, a grouping heterocyclic, such as piperidinyl or morpholinyl; R7 and R8 independently of one another preferably denote a C1-C4 alkyl group; Y- is an organic or inorganic anion; such as bromide, chloride, acetate, borate, citrate, tartrate, bisulfate, bisulfite, sulfate, phosphate. These polymers are in particular described in FR 2080759 and FR 2190406.

The cyclopolymers preferably comprise at least one unit of formula (V). As regards the copolymers, they further comprise an acrylamide monomer. Among the polymers defined above, mention may be made more particularly of the homopolymer of dimethyldiallylammonium chloride sold under the name "Merquat 100" by the company Nalco (and its counterparts of low weight average molecular weight) and the copolymers of sodium chloride. diallyldimethylammonium and acrylamide sold under the name "Merquat 550". (8) The quaternary diammonium polymer containing repeating units corresponding to the formula: ## STR5 ## in which: R10, R11, R12 and R13, which are identical or different, represent aliphatic, alicyclic, or arylaliphatic C1-C20 radicals or hydroxyalkylaliphatic radicals whose alkyl radical is C1-C4, or R10, R11, R12 and R13, together or separately, together with the nitrogen atoms to which they are attached heterocycles optionally containing a second heteroatom other than nitrogen or R10, R11, R12 and R13 represent a linear or branched C1-C6 alkyl radical substituted with a nitrile, ester, acyl, amide or -00-0- R14-D or -00- NH-R14-D wherein R14 is alkylene and D is a quaternary ammonium group; Al and B1 represent linear or branched, C 2 -C 20 polymethylenic groups, saturated or unsaturated, and which may contain, bound to or intercalated in the main chain, one or more aromatic rings, or one or more oxygen atoms, sulfur or sulfoxide, sulfone, disulfide, amino, alkylamino, hydroxyl, quaternary ammonium, ureido, amide or ester groups, and X- is an anion derived from a mineral or organic acid; A1, R10 and R12 can form with the two nitrogen atoms to which they are attached a piperazine ring; furthermore, if Al denotes a linear or branched, saturated or unsaturated alkylene or hydroxyalkylene radical, B1 can also denote a group - (CH2) r, -CO-D-OC- (CH2) '- in which n is between 1 and 100 and preferably between 1 and 50, and D denotes: a) a glycol residue of formula: -O-Z-O-, where Z denotes a linear or branched hydrocarbon radical or a group corresponding to one of the following formulas : - (CH2-CH2-O) x-CH2-CH2-; - [CH 2 -CH (CH 3) -O] y -CH 2 -CH (CH 3) - where x and y denote an integer of 1 to 4, representing a defined and unique degree of polymerization or any number from 1 to 4 representing a degree of average polymerization; b) a bis-secondary diamine residue such as a piperazine derivative; c) a bis-primary diamine residue of formula: -NH-Y-NH-, where Y denotes a linear or branched hydrocarbon radical, or the radical -CH 2 -CH 2 -S-S-CH 2 -CH 2 -; d) a ureylene group of formula: -NH-CO-NH-. Preferably, X- is an anion such as chloride or bromide. These polymers have a number average molecular weight generally between 1000 and 100000.

Polymers of this type are described in particular in FR 2320330, FR 2270846, FR 2316271, FR 2336434, FR 2413907, US 2273780, US 2375853, US 2388614, US 2454547, US 3206462, US 2261002, US 2271378, US 3874870, US 4001432. , US 3929990, US 3966904, US 4005193, US 4025617, US 4025627, US 4025653, US 4026945 and US 4027020. It is more particularly possible to use polymers which consist of repeating units corresponding to the following formula (VIII): R10 1: Wherein R10, R11, R12 and R13, which may be identical or different, denote a C1-C4 alkyl or hydroxyalkyl radical, wherein R10, R11, R12 and R13, which may be identical or different, denote a C1-C4 alkyl or hydroxyalkyl radical, n-N- + (CI-12) n and p are integers ranging from about 2 to about 20 and X- is an anion derived from a mineral or organic acid. (9) Quaternary polyammonium polymers consisting of recurring units of formula (IX): CH 3 XX CH 3 N (CH 2) NH-CO D-NH (cH 2) p (CH 2) 2 O (CH 2) 2 CH 3 CH 3 in which p denotes an integer ranging from 1 to about 6, D can be zero or can represent a group - (CH2) r -CO- in which r denotes a number equal to 4 or 7, X- is an anion. Such polymers can be prepared according to the processes described in US 4157388, US 4702906, US 4719282. They are described in particular in the patent application EP 122324. Among them, mention may be made, for example, of the products "Mirapol A 15", " Mirapol AD1 "," Mirapol AZ1 "and" Mirapol 175 "sold by Miranol. (10) Quaternary polymers of vinylpyrrolidone and of vinylimidazole such as, for example, the products sold under the names Luviquat FC 905, FC 550 and FC 370 by the company BASF. (11) Polyamines such as Polyquart H sold by Cognis, referred to as "polyethylene glycol (15) tallow polyamine" in the CTFA dictionary. Other cationic polymers that may be used in the context of the invention are polyalkyleneimines, in particular polyethyleneimines, polymers containing vinylpyridine or vinylpyridinium units, condensates of polyamines and of epichlorohydrin, quaternary polyureylenes and chitin derivatives. (VIII) (IX) Of all the cationic polymers which may be used in the context of the present invention, it is preferred to use, alone or as mixtures, the polymers of families (1), (7), (8) (9). According to a more particular embodiment of the invention, it is preferred to use the polymers of families (7), (8) (9).

According to an even more advantageous embodiment of the invention, the polymers of the families (7) and (8) are used alone or in mixtures, and even more preferably the polymers with recurring units of formulas (\ N) and (U) following: CH 3 CH 3 1 1 A-N-- (CH 2) 3 -N + - (CH 2) 6 1- Cl-1 Cl-CH 3 CH 3 and in particular those whose molecular weight, determined by gel permeation chromatography, is between 9500 and 9900; ## STR2 ## and in particular those whose molecular weight, determined by gel permeation chromatography, is about 1200.degree. C. (CH.sub.2) .sub.3.

Generally, the content of cationic polymer (s) represents from 0.01 to 10% by weight, more particularly from 0.05 to 6% by weight, and even more preferentially between 0.1% and 5% by weight. by weight relative to the weight of the composition. Nonionic guar gums According to a particularly advantageous embodiment of the invention, the composition comprises at least one nonionic guar gum. By nonionic guar gum is meant unmodified nonionic guar gums and modified nonionic guar gums. The unmodified nonionic guar gums are, for example, the products sold under the name VIDOGUM GH 175 by the company UNIPECTINE, and under the names MEYPRO-GUAR 50 and JAGUAR C by the company Rhodia Chimie. The modified non-ionic guar gums are especially modified with C1-C6 hydroxyalkyl groups. (W) Among the hydroxyalkyl groups, there may be mentioned, by way of example, hydroxymethyl, hydroxyethyl, hydroxypropyl and hydroxybutyl groups. These hydroxyalkyl guar gums are well known in the state of the art and may, for example, be prepared by reacting corresponding alkene oxides, such as, for example, propylene oxides, with guar gum so as to obtain a guar gum modified with hydroxypropyl groups. The level of hydroxyalkylation, which corresponds to the number of alkylene oxide molecules consumed by the number of free hydroxyl functions present on the guar gum, preferably varies from 0.4 to 1.2. Such nonionic guar gums optionally modified with hydroxyalkyl groups are for example sold under the trade names Jaguar HP8, Jaguar HP60 and Jaguar HP120, Jaguar DC 293 and Jaguar HP 105 by the company Rhodia Chimie or under the name GALACTASOL 4H4FD2 by the AQUALON company. Nonionic guar gums modified with hydroxyalkyl groups, more especially hydroxypropyl groups, modified with groups containing at least one C 6 -C 30 fatty chain are also suitable. By way of example of such compounds, mention may be made, inter alia, of the product ESAFLOR HM 22® (C22 alkyl chain) sold by the company LAMBERTI, the products RE210-18® (C14 alkyl chain) and RE205-1® (C20 alkyl chain) sold by RHONE POU LENC. More particularly, the content of gum (s) of nonionic guar (s), if this or these compound (s) is or are present, ranges from 0.001 to 10% by weight, preferably from 0.01 to 5% by weight. weight, relative to the total weight of the composition. Alkaline agent The composition according to the invention p may optionally comprise, according to a particularly advantageous embodiment of the invention, at least one alkaline agent. This agent may be chosen from inorganic or organic or hybrid alkaline agents or mixtures thereof. The inorganic alkaline agent (s) is (are) preferably chosen from ammonia, alkali carbonates or bicarbonates, such as sodium or potassium carbonates and sodium or potassium bicarbonates, sodium or potassium hydroxides, or mixtures thereof. The organic alkaline agent (s) is (are) preferably chosen from organic amines whose pKb at 25 ° C. is less than 12, and preferably less than 10, and even more advantageously less than 6. It should be noted that this is pKb corresponding to the highest basicity function. As hybrid compounds, mention may be made of the salts of the amines mentioned above with acids such as carbonic acid and hydrochloric acid.

The organic alkaline agent (s) are, for example, chosen from alkanolamines, oxyethylenated and / or oxypropylenated ethylenediamines, amino acids and compounds of the following formula: ## STR2 ## in which W is a C 1 -C 6 alkylene radical optionally substituted by a hydroxyl group or a C1-C6 alkyl radical; Rx, Ry, Rz and Rt, identical or different, represent a hydrogen atom, a C1-C6 alkyl or C1-C6 hydroxyalkyl, C1-C6 aminoalkyl radical. Examples of such amines include 1,3-diaminopropane, 1,3-diaminopropanol, spermine and spermidine.

By alkanolamine is meant an organic amine comprising a primary, secondary or tertiary amine function, and one or more linear or branched C 1 -C 8 alkyl groups carrying one or more hydroxyl radicals. Alkanolamines such as mono-, di- or trialkanolamines comprising one to three identical or different C 1 -C 4 hydroxyalkyl radicals are particularly suitable for carrying out the invention. Among compounds of this type, mention may be made of monoethanolamine, diethanolamine, triethanolamine, monoisopropanolamine, diisopropanolamine, N-dimethylaminoethanolamine, 2-amino-2-methyl-1-propanol, triisopropanolamine, 2-amino -2-methyl-1,3-propanediol, 3-amino-1,2-propanediol, 3-dimethylamino-1,2-propanediol, tris-hydroxymethylamino-methane. More particularly, the amino acids that can be used are of natural or synthetic origin, in their L, D, or racemic form, and comprise at least one acid function chosen more particularly from the carboxylic, sulphonic, phosphonic or phosphoric acid functions. Amino acids can be in neutral or ionic form. As amino acids that may be used in the present invention, mention may in particular be made of aspartic acid, glutamic acid, alanine, arginine, ornithine, citrulline, asparagine, carnitine and cysteine. , glutamine, glycine, histidine, lysine, isoleucine, leucine, methionine, N-phenylalanine, proline, serine, taurine, threonine, tryptophan, tyrosine and valine.

Advantageously, the amino acids are basic amino acids comprising an additional amine function optionally included in a ring or in a ureido function. Such basic amino acids are preferably chosen from those corresponding to the following formula: ## STR2 ## where R denotes a group chosen from: NH - (C1-12) 2NH2 - (CHINH-C NH - ( C1-12) 3NI-12 - (CH2) 2NHCONH2 The compounds corresponding to the above formula are histidine, lysine, arginine, ornithine, citrulline The organic amine can also be chosen from the following formulas: Organic amines of the heterocyclic type In addition to the histidine already mentioned in the amino acids, mention may be made of pyridine, piperidine, imidazole, triazole, tetrazole, benzimidazole, etc. The organic amine may also be chosen from Amino acid dipeptides As amino acid dipeptides which can be used in the present invention, mention may be made in particular of carnosine, anserin and balenine. The organic amine is chosen from compounds containing a guanidine function. amines of this type which can be used in the In the present invention, arginine, already mentioned as amino acid, creatine, creatinine, 1,1-dimethylguanidine, 1,1-diethylguanidine, glycocyamine, metformin, agmatine, n-amidinoalanine, 3-guanidinopropionic acid, 4-guanidinobutyric acid and 2- ([amino (imino) methyl] amino) ethane-1-sulfonic acid. As hybrid compounds, mention may in particular be made of guanidine carbonate or monoethanolamine hydrochloride. According to one embodiment of the invention, the dyeing composition used in the process of the invention contains, as alkaline agent, ammonia and / or at least one alkanolamine and / or at least one amino acid. basic, more preferably ammonia and / or at least one alkanolamine.

Preferably, the alkaline agent is chosen from ammonia, monoethanolamine, or mixtures thereof. Even more preferably the alkaline agent is an alkanolamine, better is monoethanolamine.

Advantageously, the composition has a content of alkaline agent (s), and preferably of organic amine (s), when it is present, ranging from 0.01 to 30% by weight, preferably from 0.1 to 20% by weight, better still from 1 to 10% by weight relative to the weight of said composition. Note that this content is expressed in NH3 in the case where the alkaline agent is ammonia.

Oxidizing agent The composition according to the invention also comprises at least one oxidizing agent. It should be noted that the oxidizing agents present in the composition are different from the oxygen in the air. In particular, the oxidizing agent or agents that are suitable for the present invention are, for example, chosen from hydrogen peroxide, urea peroxide, alkali metal bromates or ferricyanides, peroxygenated salts such as, for example, persulfates and perborates. , peracids and their precursors and alkali or alkaline earth metal percarbonates. Advantageously, the oxidizing agent is hydrogen peroxide. The oxidizing agent or agents generally represent from 0.1 to 50%, preferably from 1 to 20% by weight relative to the total weight of the composition according to the invention.

Additives The composition may also contain various adjuvants conventionally used in compositions for the dyeing or lightening of hair, such as anionic, nonionic or amphoteric polymers or mixtures thereof; cationic surfactants; antioxidants; penetrants; sequestering agents; perfumes ; dispersants; film-forming agents; ceramides; preservatives; opacifying agents. The adjuvants above are generally present in an amount for each of them between 0.01 and 20% by weight relative to the weight of the composition. The composition according to the invention may comprise water and / or one or more organic solvents.

As organic solvent, mention may be made, for example, of linear or branched, preferably saturated monoalcohols or dols, comprising 2 to 10 carbon atoms, such as ethyl alcohol, isopropyl alcohol and hexylene glycol (2 methyl 2,4-pentanediol), neopentyl glycol and 3-methyl-1,5-pentanediol, butylene glycol, dipropylene glycol and propylene glycol; aromatic alcohols such as benzyl alcohol, phenylethyl alcohol; polyols with more than two hydroxyl functions such as glycerol; polyol ethers such as, for example, ethylene glycol monomethyl, monoethyl and monobutyl ethers, propylene glycol or its ethers such as, for example, propylene glycol monomethyl ether; and the alkyl ethers of diethylene glycol, especially C1-C4, for example, monoethyl ether or monobutyl ether diethylene glycol, alone or in mixture. The organic solvents, when they are present, generally represent between 1 and 40% by weight relative to the total weight of the dye composition, and preferably between 5 and 30% by weight relative to the total weight of the dyeing composition. Preferably the composition is aqueous. In this case it preferably comprises from 30 to 95% of water by weight, better still from 40 to 90% of water by weight, and still more preferably from 50 to 85% of water by weight relative to the total weight of the composition. . The pH of the composition according to the invention, if it is aqueous, generally varies from 6 to 11, preferably from 8.5 to 11. It can be adjusted by adding acidifying agents such as hydrochloric acid, (ortho) ) phosphoric, sulfuric acid, boric acid, as well as carboxylic acids such as acetic acid, lactic acid, citric acid, or sulfonic acids. Alkaline agents such as those mentioned above can also be used.

Staining Process The composition described above is applied to dry or moist keratinous fibers. It is usually left in place on the fibers for a period, generally, from 1 minute to 1 hour, preferably from 5 minutes to 30 minutes.

The temperature during the dyeing process is typically between room temperature (between 15 and 25 ° C) and 80 ° C, preferably between room temperature and 60 ° C.

At the end of the treatment, the human keratinous fibers are advantageously rinsed with water. They can optionally be washed with a shampoo followed by rinsing with water, before being dried or allowed to dry.

The composition applied in the process according to the invention is generally prepared extemporaneously before application, by mixing at least two formulations.

In particular, a formulation (A) without a chemical oxidizing agent different from the oxygen in the air and comprising at least one direct dye and a formulation (B) comprising at least one oxidizing agent different from the oxygen of the air; one and / or the other of the compositions comprising at least one fatty substance, at least one cationic polymer, at least one amphoteric or zwitterionic surfactant; at least one nonionic surfactant; at least one anionic surfactant. Advantageously, the formulation (A) comprises at least one amphoteric or zwitterionic surfactant; at least one nonionic surfactant; at least one anionic surfactant. Advantageously, the formulations (A) and (B) are aqueous.

By aqueous formulation is meant a composition comprising at least 5% by weight of water, relative to the weight of this formulation. Preferably, an aqueous formulation comprises more than 10% by weight of water, and still more preferably more than 20% by weight of water. Preferably, the formulation (A) comprises at least one fatty substance, preferably at a content of at least 50% by weight, and still more preferably at least 50% by weight of liquid fatty substances at room temperature (25 ° C. C), relative to the weight of this formulation (A). Advantageously, the formulation (A) is an emulsion, direct (oil in water, H / E) or inverse (water in oil, W / O), and preferably direct (O / W).

More particularly, the formulation (A) comprises at least one basifying agent. As for the formulation (B) comprising the oxidizing agent as defined above, it may also comprise one or more acidifying agents as indicated above.

Usually, the pH of the oxidizing composition, when it is aqueous, is less than 7. Preferably, the oxidizing composition comprises hydrogen peroxide as oxidizing agent, in aqueous solution, the concentration of which varies, more particularly from 0.1 to 50%, more particularly between 0.5 and 20%, and even more preferably between 1 and 15% by weight relative to the weight of the oxidizing composition. According to a particular variant of the invention, the composition (B) comprises at least one fatty substance. Preferably, in the case of this variant, the fatty substance content is at least 5% by weight, preferably at least 10% by weight, more preferably at least 15% by weight of liquid fatty substances. the ambient temperature (25 ° C), relative to the weight of this formulation.

According to another advantageous variant of the invention, the formulation (B) comprises at least one cationic polymer. Furthermore, the formulations (A) and (B) are preferably mixed before use, in a weight ratio (A) / (B) of from 0.2 to more preferably from 0.5 to 2.

In addition, the composition used in the process according to the invention, that is to say the composition resulting from the mixing of the two formulations (A) and (B), preferably has a fat content of from minus 10% by weight of fatty substance, relative to the weight of the composition resulting from the mixture of the two aforementioned formulations.

All that has been described above concerning the ingredients of the composition according to the invention remains valid in the case of formulations (A) and (B), the contents taking into account the dilution ratio during mixing. The following examples serve to illustrate the invention without being limiting in nature. EXAMPLE The following compositions are prepared (the amounts are expressed in g% of active ingredients) Composition 1: Ethanolamine 5 Sodium laureth sulfate at 2.2 EO 1.75 Hydroxypropyl guar 1 Ascorbic acid 0.5 N, N-bis (2 -hydroxyethyl) -p-phenylenediamine sulfate 0.073 EDTA 0.2 Hydrogenated Castor Oil PEG-40 1 Coco-betaine 3 Sodium Chloride 0.65 Sodium Metabisulfite 0.5 Basic Yellow 87 0.3 Basic Orange 31 0.225 Mineral Oil 60 water Qsp 100 Composition 2: Tocopherol 0.1 Sodium stannate 0.04 Pentasodium pentetate 0.06 Polyquaternium-6 0.2 Glycerine 0.5 Cetearyl alcohol 6 Hexadimethrin chloride 0.15 Hydrogen peroxide 6 Tetrasodium pyrophosphate 0 , 03 Mineral oil 20 PEG-4 rapeseedamide 1,19 Steareth-20 5 Phosphoric acid Qs pH 2.2 Water Qsp 100 Method of application: The two compositions are mixed at the time of use in the following proportions: 10 g of the composition 1 with 15 g of the composition 2. The resulting mixture is applied easily on locks of dark brown hair at a rate of 10g of mixture per 1g of hair, for 30 minutes at room temperature (20 ° C). The hair is then easily rinsed, then washed with standard shampoo and dried. A coppery light brown color is obtained.

Claims (26)

REVENDICATIONS1. A coloring composition of human keratin fibers comprising: (a) at least one direct dye; (b) at least one amphoteric or zwitterionic surfactant; (c) at least one nonionic surfactant; (d) at least one anionic surfactant; (e) at least one fatty substance; (f) at least one cationic polymer; (g) at least one oxidizing agent different from the oxygen of the air. 2. Composition according to claim 1, characterized in that the direct dye (s) are chosen from azo direct dyes; (poly) methine dyes such as cyanines, hemicyanins, and styryl dyes; carbonyls; azinic; nitro (hetero) aryl; tri- (hetero) aryl methanes; porphyrins; phthalocyanines and natural direct dyes, alone or in mixtures. 3. Composition according to any one of the preceding claims, characterized in that it comprises iv) one or more cationic direct dyes. 4. Composition according to any one of the preceding claims, characterized in that it comprises iv) one or more cationic dyes hydrazono of formula (II) and (1111), or azo (IV), and (V) following: Hét + -C (Ra) = NN (Rb) -Ar, Q-Het + -N (Ra) -N = C (Rb) -Ar, Q- (II) (1111) Het + -N = N-Ar, Q-Ar + -N = N-Ar ", Q- (IV) (V) formulas (II) to (III) in which: - Het + represents a cationic heteroaryl radical, preferably with an endocyclic cationic charge such as imidazolium, indolium, or pyridinium, optionally preferably substituted by at least one (C1-C8) alkyl group such as methyl; -Ar + represents an aryl radical, such as phenyl or naphthyl, with an exocyclic cationic charge, preferably ammonium, particularly tri (C1C8) alkylammonium such as trimethylammonium; represents an aryl group, in particular phenyl, which is optionally substituted, preferably with one or more electron donor groups such as ei) (C1-C8) optionally substituted alkyl, ii) (C1-C8) optionally substituted alkoxy, iii) (di) (C1-C8) (alkyl) amino optionally substituted on the one or more alkyl groups by a hydroxyl group, iv ) optionally substituted aryl (C1-C8) alkylamino, v) N- (C1-C8) alkyl-N-aryl (C1-C8) alkylamino or Ar represents a julolidine group; Ar "represents an optionally substituted (hetero) aryl group such as phenyl or pyrazolyl, optionally substituted, preferably with one or more (C1-C8) alkyl, hydroxyl, (di) (C1-C8) (alkyl) amino, C8) groups; alkoxy or phenyl; - Ra and Rb, identical or different, representing a hydrogen atom or a group (C1-C8) alkyl optionally substituted, preferably with a hydroxyl group; - or the substituent Ra with a substituent of Hee and / or Rb with a substituent of Ar together with the atoms bearing them a (hetero) cycloalkyl, especially Ra and Rb, representing a hydrogen atom or a (C1-C4) alkyl group optionally substituted by a hydroxyl group; C2- represents an organic or inorganic anionic counterion such as a halide or an alkyl sulphate; more particularly the cationic direct dyes of formula (II) to (V) are endocyclically cationic charges. 5. Composition according to any one of the preceding claims, characterized in that it comprises iv) one or more cationic dyes hydrazono of formula (II-1) and (IV-1) following R4 R1 + // 1 ± R ' NC = NN N R2 \ H II N = NNIQ \ 3 Cf R2 z "-NR R1 (II-1) (IV-1) formulas (II-1) and (IV-1) in which: - R1 represents a grouping (C1-C4) alkyl such as methyl; R2 and R3, which may be identical or different, represent a hydrogen atom or a (C1-C4) alkyl group such as methyl, and R4 represents a hydrogen atom or a grouping electron-donor such as (C1-C8) alkyl optionally substituted, (C1-C8) alkoxy optionally substituted, (di) (C1-C8) (alkyl) amino optionally substituted on the alkyl group (s) with a hydroxyl group, particularly R4 is an atom of hydrogen, - Z represents a CH group or a nitrogen atom, preferentially CH, - C2- is anionic counterion as defined previously particularly halide such as chloride or an alkylsulfate such as methylsulfate or mesytyl. 6. Composition according to any one of the preceding claims, characterized in that it comprises at least one additional dye chosen from oxidation bases and couplers. 7. Composition according to any one of the preceding claims, characterized in that the amphoteric or zwitterionic surfactants are chosen from derivatives of secondary or tertiary aliphatic amines, optionally quaternized, in which the aliphatic group is a linear or branched chain comprising from 8 to 22 carbon atoms, said amine derivatives containing at least one anionic group such as, for example, a carboxylate, sulfonate, sulfate, phosphate or phosphonate group. 8. Composition according to the preceding claim, characterized in that the surfactant (s) amphoteric (s) or zwitterionic (s) are chosen from the following compounds, alone or in mixtures: * alkyl (C8-C20) betaines, * (C8-C20) alkylsulfobetaines, * (C8-C20) alkylamido (C3-C8) alkylbetaines, * (C8-C20) alkylamid (C6-C8) alkylsulfobetaines, * structural compounds (B1 ): Ra-C (O) -NH-CH2-CH2-N + (Rb) (Rc) -CH2C (O) O-, W, X (B1) Formula wherein: Ra represents an alkyl or alkenyl group; C10-C30 derived from RaCOOH acid, preferably present in hydrolyzed coconut oil, heptyl, nonyl or undecyl; Rb represents a beta-hydroxyethyl group; and - R, represents a carboxymethyl group; W represents a cationic counterion derived from an alkaline earth metal, such as sodium, an ammonium ion or an ion derived from an organic amine, and X represents an organic or inorganic anionic counterion, such as that chosen from halides, acetates, phosphates, nitrates, (C 1 -C 4) alkyl sulphates, (C 1 -C 4) alkyl or (C 1 -C 4) alkylarylsulfonates, in particular methylsulphate and ethylsulphate; or else W and X- are absent; the compounds of the following structure (B1): Ra-C (O) -NH-CH2-CH2-N (B) (B ') (B2) Formula in which: B represents the group -CH2-CH2-O- X '; B 'represents the group - (CH2), Y', with z = 1 or 2; X 'represents the group -CH2-C (O) OH, -CH2-C (O) OZ', -CH2-CH2-C (O) OH, -CH2-CH2-C (O) OZ ', or hydrogen atom; Y 'represents the group -C (O) OH, -C (O) OZ', -CH2-CH (OH) -SO3H or the group -CH2-CH (OH) -SO3-Z '; Z 'represents a cationic counterion derived from an alkaline or alkaline earth metal, such as sodium, an ammonium ion or an ion derived from an organic amine; Ra, represents a C10-C30 alkyl or alkenyl group of an acid Ra-C (O) OH which is preferably present in coconut oil or in hydrolyzed linseed oil, an alkyl group, especially in O17 and its iso form, unsaturated 017 group, compounds of formula (B'2); Ra-NH-CH (Y ") - (CH2) nC (O) -NH- (CH2) n -N (Rd) (Re) (B'2) Formula wherein: ^ Y" represents the group -C (O) OH, -C (O) OZ-, -CH2-CH (OH) -SO3H or the group -CH2-CH (OH) -SO3-Z-; Rd and Re, independently of one another, represent a C 1 -C 6 alkyl or hydroxyalkyl radical; represents a cationic counterion derived from an alkaline or alkaline earth metal, such as sodium, an ammonium ion or an ion; derived from an organic amine; R e represents a C 10 -C 30 alkyl or alkenyl group of a Ra-C (O) OH acid, preferably present in coconut oil or in hydrolysed linseed oil. and n ', independently of each other, denote an integer ranging from 1 to 3. 9. Composition according to any one of the preceding claims, characterized in that the content of amphoteric surfactant (s) uzwitterérioniques (s) ranges from 0.1 to 30% by weight, preferably from 0.5 to 20% by weight. % by weight, and more preferably from 1 to 10% by weight, relative to the total weight of the composition. 10. Composition according to any one of the preceding claims, characterized in that the nonionic surfactant or surfactants are chosen from oxyalkylenated or glycerolated nonionic surfactants, in particular the following surfactants, alone or as mixtures: alkyls (C8 -C24) oxyalkylenated phenols; saturated or unsaturated, linear or branched, oxyalkylenated or glycerolated C8-C30 alcohols; - C8-C30 fatty acid amides, saturated or unsaturated, linear or branched, oxyalkylenated; saturated or unsaturated linear or branched C 8 -C 30 acid esters of polyethylene glycols; - C8-C30 acid esters, saturated or unsaturated, linear or branched, and preferably oxyethylenated sorbitol; esters of sucrose fatty acids, alkyl (C 8 -C 30) polyglycosides, C 6 -C 30 alkenyl polyglycosides, optionally oxyalkylenated (0 to 10 OE) and comprising 1 to 15 glucose units, alkyl esters, (C8-C30) glucosides, - oxyethylenated vegetable oils, saturated or not; condensates of ethylene oxide and / or propylene oxide, among others, alone or in mixtures; derivatives of N-alkyl (C8-C30) glucamine and N-acyl (C8-C30) -methylglucamine; aldobionamides; amine oxides; Oxyethylenated and / or oxypropylenated silicones; The oxyalkylenated units being more particularly oxyethylenated units, oxypropylene, or their combination, preferably oxyethylenated; the number of moles of ethylene oxide and / or propylene is preferably from 1 to 100, more preferably from 2 to 50; the number of moles of glycerol ranges from 1 to 30. 11. Composition according to any one of the preceding claims, characterized in that the content of nonionic surfactant (s) ranges from 0.1 to 30% by weight, preferably from 1 to 20% by weight, and more preferred from 1 to 10% by weight, based on the total weight of the composition. 12. Composition according to any one of the preceding claims, characterized in that the anionic surfactant or surfactants are chosen from alkyl sulphates, alkyl ether sulphates, alkylamido ether sulphates, alkylaryl polyether sulphates, monoglyceride sulphates, alkyl sulphonates and alkyl amide sulphonates. alkylarylsulfonates, alpha-olefin-sulfonates, paraffin-sulfonates, alkylsulfosuccinates, alkylethersulfosuccinates, alkylamide-sulfosuccinates, alkylsulfoacetates, acylsarcosinates, acylglutamates, alkylsulfosuccinamates, acylisethionates and Nacyltaurates, salts alkyl monoesters and polyglycoside-polycarboxylic acids, acyllactylates, D-galactoside-uronic acid salts, alkyl ether-carboxylic acid salts, alkyl aryl ether-carboxylic acid salts, alkyl amidoether carboxylic acids, and the corresponding non-salified forms of all these compounds the alkyl and acyl groups of all these compounds having from 6 to 40 carbon atoms and the aryl group denoting a phenyl group; these compounds may be oxyethylenated and then preferably comprise from 1 to 50 ethylene oxide units. 13. Composition according to any one of the preceding claims, characterized in that the content of anionic surfactant (s) ranges from 0.1 to 30% by weight, preferably from 1 to 20% by weight, and more preferably from 1 to 10% by weight, relative to the total weight of the composition. 14. Composition according to any one of the preceding claims, characterized in that the one or more fatty substances are chosen from C 6 -C 16 alkanes, non-silicone oils of mineral, plant, animal or synthetic origin, fatty alcohols, fatty acid esters and / or fatty alcohol esters, non-silicone waxes and silicones, or mixtures thereof. 15. Composition according to any one of the preceding claims, characterized in that the fatty substance or fats are chosen from liquid petrolatum, C6-C16 alkanes, polydecenes, fatty acid esters and / or dicarboxylic acids. fatty alcohols, liquids, or mixtures thereof. 16. Composition according to any one of the preceding claims, characterized in that the concentration of fatty substance is at least 10% by weight, more particularly at least 15% by weight, preferably at least 15% by weight. at least 20% by weight, and up to 70% by weight relative to the total weight of the composition. 17. Composition according to any one of the preceding claims, characterized in that the cationic polymer or polymers have a charge density of at least 1 meq / g. 18. Composition according to any one of the preceding claims, characterized in that the cationic polymer (s) are chosen from the following polymers, alone or in mixtures: (1) Homopolymers or copolymers derived from acrylic esters or amides or methacrylics and comprising at least one of the following units of formulas (I), (II), (III) or (IV): ## STR5 ## Embedded image in which: R3, which may be identical or different, denote a hydrogen atom or a radical; R6 (III) wherein R3, R1, R1, R1, R1, R1, R1, R1 and R3 CH3; A, which may be identical or different, represent a linear or branched C 1 -C 6 alkyl group or a hydroxyalkyl group whose alkyl is C 1 -C 4; R4, R5, R6, which may be identical or different, represent a C1-C18 alkyl group or a benzyl radical; R1 and R2, which may be identical or different, represent hydrogen or a C1-C6 alkyl group; (2) Cationic cellulose derivatives; (3) cationic guar gums; (4) Polymers consisting of piperazinyl units and divalent linear or branched alkyl or hydroxyalkyl radicals, optionally interrupted by oxygen, sulfur, nitrogen or aromatic or heterocyclic rings, as well as oxidation products and / or quaternizing these polymers: (5) water-soluble polyaminoamides, optionally crosslinked; (6) Polymers obtained by reacting a polyalkylene polyamine having two primary amine groups and at least one secondary amine group with a dicarboxylic acid; (7) Cyclopolymers of alkyl diallyl amine or of dialkyl diallyl ammonium, in the form of homopolymers or copolymers comprising, as main constituent of the chain, units corresponding to formulas (V) or (VI): (CH 2) k (CH 2 ) - (CH2) t-CR C (R9) -CH2-I 9 - (CH2) t-CR9 C (R9) -CH2-H2C IC H2C H2 (V) N + Y (VI) / R7 R7 formulas in which k and t are 0 or 1, the sum k + t being equal to 1; R9 denotes a hydrogen atom or a methyl radical; R7 and R8, independently of each other, denote a C1-C8 alkyl group, a hydroxyalkyl group in which the alkyl group is C1-C5, an amidoalkyl group whose alkyl is C1-C4; R7 and R8 may also designate together with the nitrogen atom to which they are attached, a heterocyclic group; Y- is an organic or mineral anion; (8) Quaternary diammonium polymers containing repeating units corresponding to the formula: ## STR2 ## wherein R10, R11, R12 and R12 are as follows: R13, which may be identical or different, represent linear, branched or cyclic, saturated, unsaturated or aromatic, C1-C20 hydrocarbon radicals, linear or branched hydroxyalkyl radicals, the alkyl part of which is C1-C4, and C1-C4 alkyl radicals; -C6 linear or branched, substituted with a nitrile group, ester, acyl, amide or -CO-O-R14-D or -CO-NH-R14-D with R14 representing an alkyl radical and D a quaternary ammonium group, or form together or separately, with the nitrogen atoms to which they are attached, heterocycles optionally containing a second heteroatom other than nitrogen, Al and B1 represent linear or non-linear, optionally saturated or unsubstituted C 2 -C 20 radicals, optionally substituted or interrupted by one or more c aromatic rings, oxygen atoms, sulfur atoms or groups carrying at least one of these atoms; X- denotes an organic or mineral anion; A1, R10 and R12 can form with the two nitrogen atoms to which they are attached a piperazine ring; in addition, if Al denotes a linear or branched, saturated or unsaturated alkylene or hydroxyalkylene radical, B1 can also denote a - (CH2) n -CO-D-OC- (CH2) n- group in which n is between 1 and 100; and D denotes a glycol, bis-secondary diamine, bis-primary diamine, ureylene residue; (9) Quaternary polyammonium polymers consisting of repeating units of formula (IX): ## STR2 ## Where p denotes an integer ranging from 1 to 6, D may be zero or may represent a group - (CH 2) r -CO-- in which r denotes a number equal to 4 or to 7, X- is an organic or mineral anion; (10) Quaternary polymers of vinylpyrrolidone and vinylimidazole; (11) Polyamines. 19. Composition according to claim 18, characterized in that the cationic polymer or polymers are chosen from polymers (1), (7), (8), (9), preferably (7), (8), (9) , alone or in mixtures. 20. Composition according to any one of the preceding claims, characterized in that the content of cationic polymer (s) represents from 0.01 to 10% by weight, more particularly from 0.05 to 6% by weight. and even more preferentially between 0.1 and 5% by weight relative to the weight of the composition. 21. Composition according to any one of the preceding claims, characterized in that the oxidizing agent other than the oxygen in the air is hydrogen peroxide. 22. A process for staining human keratin fibers in which a composition according to any one of Claims 1 to 21.35 is applied. 23. Method according to the preceding claim wherein the composition is obtained by mixing a first composition free of oxidizing agent other than oxygen in the air, comprising at least one direct dye, optionally at least one additional dye; with a second composition comprising at least one oxidizing agent different from the oxygen of the air; one or the other of the two compositions comprising at least one fatty substance, at least one cationic polymer, at least one amphoteric or zwitterionic surfactant, at least one nonionic surfactant, at least one anionic surfactant; the first composition preferably comprising at least one amphoteric or zwitterionic surfactant; at least one nonionic surfactant, at least one anionic surfactant. 24. A process according to any one of claims 22 or 23 wherein the mixture of the first and second composition has a fat content of at least 10% by weight relative to the weight of the mixture. 25. A process according to any one of claims 22 to 24, wherein the oxidizing composition comprises at least one cationic polymer. 26. Multi-compartment device suitable for carrying out the method according to claim 22, comprising a compartment containing a composition devoid of an oxidizing agent other than oxygen in the air comprising at least one direct dye, optionally at least one additional dye; a compartment containing an oxidizing composition; one and / or the other of the compositions of the two compartments comprising at least one fatty substance, at least one cationic polymer, at least one amphoteric or zwitterionic surfactant; at least one nonionic surfactant, at least one anionic surfactant; the two compartments being mixed before use to obtain a composition according to any one of claims 1 to 21 and the first composition preferably comprising at least one amphoteric or zwitterionic surfactant; at least one nonionic surfactant, at least one anionic surfactant.