FR2983073A1 - COLORING COMPOSITION COMPRISING A PARTICULAR HYDROPROPY COMPOUND IN A RICH BODY, METHODS AND DEVICE - Google Patents

Abstract

The subject of the present invention is a dyeing composition for keratin fibers, comprising at least one fatty substance; at least one surfactant; at least one dye of keratinous fibers; at least one basifying agent; at least one chemical oxidizing agent; at least one cationic compound of formula (i) below: in which R, R, R and R, which may be identical or different, represent an optionally substituted C -C alkyl or C -C alkylen radical, optionally interrupted by one or more heteroatoms; an optionally substituted benzyl radical; X- representing a cosmetically acceptable anion or mixture of anions, ensuring the electroneutrality of formula (i). * the fat content representing a total of at least 25% by weight relative to the total weight of the composition. The present invention also relates to a process using this composition and multi-compartment devices, suitable for the implementation of the invention.

Description

The subject of the present invention is a dyeing composition for keratin fibers, comprising one or more fatty substances and one or more surfactants, one or more dyes, and one or more dyes. particular capillaries, one or more particular cationic compounds, one or more alkalinizing agents, one or more chemical oxidizing agents and the content of fat in the composition representing a total of at least 25% by weight relative to the total weight of the composition. The present invention also relates to coloring processes using this composition, and a multi-compartment device, suitable for the implementation of this composition. Among the methods for staining human keratinous fibers, such as the hair, mention may be made of oxidation or permanent staining. More particularly, this mode of staining uses one or more oxidation dye precursors, usually one or more oxidation bases possibly associated with one or more couplers. In general, oxidation bases are chosen from ortho- or para-phenylenediamines, ortho- or para-aminophenols as well as heterocyclic compounds. These oxidation bases are colorless or weakly colored compounds which, combined with oxidizing products, make it possible to access colored species by a process of oxidative condensation. Very often, the shades obtained with these oxidation bases are varied by combining them with one or more couplers, the latter being chosen in particular from aromatic meta-diamines, meta-aminophenols, meta-diphenols and certain heterocyclic compounds, such as indole compounds. The variety of molecules involved in the oxidation bases and couplers allows a rich palette of colors to be obtained.

Also known direct or semi-permanent coloring. The method conventionally used in direct dyeing consists in applying to the keratin fibers direct dyes which are colored and coloring molecules, having an affinity for the fibers, to be allowed to pausate to allow the molecules to penetrate, by diffusion, into the interior of the body. the fiber, then rinse them.

The direct dyes generally employed are chosen from nitrobenzene, anthraquinone, nitropyridine, azo, methine, azomethine, xanthene, acridine, azine or triarylmethane direct dyes. This type of process does not require the use of an oxidizing agent to develop the coloring. However, it is not excluded to implement in order to obtain with coloring, a lightening effect. This is called direct or semipermanent coloring in lightening conditions. The permanent or semi-permanent coloring processes under lightening conditions therefore consist in using, with the dye composition, an aqueous composition comprising at least one oxidizing agent, under alkaline pH conditions in the vast majority of cases. This oxidizing agent has the role of degrading the melanin of the hair, which, depending on the nature of the oxidizing agent present, leads to a more or less pronounced lightening of the fibers. Thus, for relatively low lightening, the oxidizing agent is generally hydrogen peroxide. When greater lightening is desired, it is customary to use peroxygenated salts, such as persulfates for example, in the presence of hydrogen peroxide. Staining methods are usually carried out under alkaline conditions; the alkaline agent allowing both to activate the oxidizing agent and to facilitate the rise of dyes by causing an opening of the flakes of the fibers. Conventionally, the alkaline agent used is ammonia. It is very effective but has many disadvantages due to its high volatility, its strong unpleasant odor and the risk of intolerance (irritation, tingling) that it can cause.

When it was sought to replace the ammonia in whole or in part with one or more other conventional alkalizing agents, but the compositions are not as effective in terms of dye results. Recently, fatty-rich coloring compositions have been proposed, obtained by mixing two or three compositions and comprising, inter alia, a fat body. These compositions make it possible to lower the ammonia content or even to dispense with it while maintaining coloring levels at least as high as with conventional compositions comprising high concentrations of this alkaline agent. However, even under these conditions, the results obtained are not optimum, especially in terms of intensity and or chromaticity. This is particularly the case of hydrophobic dyes. One of the objectives of the present invention is to provide compositions for staining human keratinous fibers such as the hair which do not have the disadvantages of existing compositions.

In particular, the composition according to the invention to obtain satisfactory colors especially in terms of intensity and coverage or rise of the color at the root of the hair, which makes it possible to avoid a "root" effect of the coloration . In addition, it is possible to obtain very stable colorations with respect to light.

In addition, the invention makes it possible to achieve significant degrees of lightening while coloring, and without using persalts or force the amount of chemical oxidizing agent or alkalizing agent. These and other objects are achieved by the present invention which therefore relates to a coloring composition of keratinous fibers, in particular human keratinous fibers such as the hair, comprising: one or more fatty substances, one or more surfactants one or more keratinic fiber dyes, one or more alkalinizing agents, one or more chemical oxidizing agents, one or more cationic compounds of formula (I) below: R 2 + X R 4 NR 3 R 1 in which: the radicals R1, R2, R3 and R4, which may be identical or different, represent an optionally substituted alkyl radical, optionally interrupted by one or more heteroatoms; an optionally substituted C2-08 alkenyl radical, optionally interrupted by one or more heteroatoms; an optionally substituted benzyl radical; X- representing a cosmetically acceptable anion or mixture of anions, ensuring the electroneutrality of formula (i) - the fat content representing in total at least 25% by weight relative to the total weight of the composition. The subject of the invention is also a dyeing method using the composition of the invention, and devices with several compartments making it possible to use the composition of the invention. Thus, the use of the dyeing composition according to the invention leads to powerful, intense, chromatic and, moreover, selectively selective colorings, that is to say dyes which are homogeneous along the fiber.

The invention also makes it possible to cover keratinous fibers at their roots particularly particularly up to three centimeters from the base of said fibers. In addition, the colors obtained after treatment of the fibers remain stable, particularly with respect to light.

The invention also makes it possible to reduce the amounts of active agents of the invention such as dyes and / or alkalinizing agents and / or oxidizing agents without loss of dyeing efficiency of the composition. Moreover, the processes according to the invention make it possible to use less smelly formulations when they are applied to the hair or during their preparation. Other characteristics and advantages of the invention will emerge more clearly on reading the description and examples which follow. In what follows, and unless otherwise indicated, the boundaries of a domain of values are included in this field. The human keratinous fibers treated by the process according to the invention are preferably the hair. The expression "at least one" is equivalent to the expression "one or more". Fatty Bodies: As has been mentioned, the composition of the invention comprises one or more fatty substances. By "fatty substance" is meant an organic compound which is insoluble in water at ordinary temperature (25 ° C.) and at atmospheric pressure (760 mmHg) (solubility of less than 5% and preferably of 1%, even more preferentially at 0.1%). They have in their structure at least one hydrocarbon chain containing at least 6 carbon atoms or a chain of at least two siloxane groups. In addition, the fatty substances are generally soluble in organic solvents under the same conditions of temperature and pressure, such as for example chloroform, dichloromethane, carbon tetrachloride, ethanol, benzene, toluene, tetrahydrofuran (THF), Vaseline oil or decamethylcyclopentasiloxane. Preferably, the fatty substances of the invention do not contain salified or non-salified carboxylic acid groups (COOH or 000-). In particular, the fatty substances of the invention are neither polyoxyalkylenated nor polyglycerolated. By "oil" is meant a "fat" which is liquid at room temperature (25 ° C), and at atmospheric pressure (760 mm Hg).

The term "non-silicone oil" means an oil containing no silicon atom (Si) and a "silicone oil" an oil containing at least one silicon atom. More particularly, the fatty substances are chosen from among the hydrocarbons at 06-016, hydrocarbons containing more than 16 carbon atoms, non-silicone oils of animal origin, vegetable oils of the triglyceride type, synthetic triglycerides, and fluorinated oils. fatty alcohols, esters of fatty acids and / or fatty alcohol different from triglycerides and vegetable waxes, non-silicone waxes, silicones. It is recalled that for the purposes of the invention, the alcohols, esters and fatty acids more particularly have at least one hydrocarbon group, linear or branched, saturated or unsaturated, comprising 6 to 30 carbon atoms, which is optionally substituted, in particular by one or more hydroxyl groups (in particular 1 to 4). If unsaturated, these compounds may comprise one to three carbon-carbon double bonds, conjugated or otherwise. As regards the C 6 -C 16 hydrocarbons, the latter are linear, branched, optionally cyclic and preferably alkanes. By way of example, mention may be made of hexane, dodecane and isoparaffins, such as isohexadecane and isodecane. As hydrocarbon oils of animal origin, mention may be made of perhydrosqualene. Triglyceride oils of vegetable or synthetic origin are preferably chosen from liquid triglycerides of fatty acids containing from 6 to 30 carbon atoms, for example triglycerides of heptanoic or octanoic acids or, for example, sunflower oil or corn oil. , soya, squash, grape seed, sesame, hazelnut, apricot, macadamia, arara, sunflower, castor oil, avocado, triglycerides of caprylic / capric acids such as those sold by the company Stearineries Dubois or those sold under the names Miglyol® 810, 812 and 818 by the company Dynamit Nobel, jojoba oil, shea butter oil. The linear or branched hydrocarbons, of mineral or synthetic origin, of more than 16 carbon atoms, are preferably chosen from paraffin oils, petroleum jelly, liquid petroleum jelly, polydecenes, hydrogenated polyisobutene such as Parleam ®. The fluorinated oils may be chosen from perfluoromethylcyclopentane and perfluoro-1,3-dimethylcyclohexane, sold under the names "FLUTEC® PC1" and "FLUTEC® PC3" by BNFL Fluorochemicals; perfluoro-1,2-dimethylcyclobutane; perfluoroalkanes such as dodecafluoropentane and tetradecafluorohexane, sold under the names "PF 5050®" and "PF 5060®" by the company 3M, or bromoperfluorooctyl sold under the name "Foralkyl®" by the company Atochem; nonafluoro-methoxybutane and nonafluoroethoxyisobutane; perfluoromorpholine derivatives, such as 4-trifluoromethyl perfluoromorpholine sold under the name "PF 5052®" by the company 3M.

The fatty alcohols that are suitable for carrying out the invention are more particularly chosen from linear or branched saturated or unsaturated alcohols containing from 6 to 30 carbon atoms, preferably from 8 to 30 carbon atoms. There may be mentioned, for example, cetyl alcohol, stearyl alcohol and their mixture (cetylstearyl alcohol), octyldodecanol, 2-butyloctanol, 2-hexyldecanol, 2-undecylpentadecanol, oleic alcohol or linoleic alcohol. . With regard to fatty acid esters and / or fatty alcohols, advantageously different from the triglycerides mentioned previously; mention may in particular be made of linear or branched C 1 -C 26 saturated or unsaturated aliphatic mono or poly acid esters and linear or branched C 1 -C 20 saturated or unsaturated aliphatic mono or polyalcohols, the total number of carbon of the esters being greater or equal to 6, more preferably greater than or equal to 10. Among the monoesters, mention may be made of dihydroabietyl behenate; octyldodecyl behenate; isoketyl behenate; cetyl lactate; alkyl lactate at 0-12-015; isostearyl lactate; lauryl lactate; linoleyl lactate; oleyl lactate; (iso) stearyl octanoate; isocetyl octanoate; octyl octanoate; cetyl octanoate; decyl oleate; isocetyl isostearate; isocetyl laurate; isocetyl stearate; isodecyl octanoate; isodecyl oleate; isononyl isononanoate; isostearyl palmitate; methyl ricinoleate acetyl; myristyl stearate; octyl isononanoate; 2-ethylhexyl isononate; octyl palmitate; octyl pelargonate; octyl stearate; octyldodecyl erucate; oleyl erucate; ethyl palmitates and isopropyl palmitate, ethyl-2-hexyl palmitate, 2-octyldecyl palmitate, alkyl myristates such as isopropyl, butyl, cetyl, 2-octyldodecyl myristate; , styryl, hexyl stearate, butyl stearate, isobutyl stearate; dioctyl malate, hexyl laurate, 2-hexyldecyl laurate. Still within the scope of this variant, it is also possible to use esters of C 4 -C 22 di or tricarboxylic acids and of C 1 -C 22 alcohols and esters of mono di or tricarboxylic acids and of di, tri, alcohols. tetra or pentahydroxy in 02-026. These include: diethyl sebacate; diisopropyl sebacate; diisopropyl adipate; di-propyl adipate; dioctyl adipate; diisostearyl adipate; dioctyl maleate; glyceryl undecylenate; octyldodecyl stearoyl stearate; pentaerythrityl monoricinoleate; pentaerythrityl tetraisononanoate; pentaerythrityl tetrapelargonate; pentaerythrityl tetraisostearate; pentaerythrityl tetraoctanoate; propylene glycol dicaprylate; propylene glycol dicaprate, tridecyl erucate; triisopropyl citrate; triisotearyl citrate; glyceryl trilactate; glyceryl trioctanoate; trioctyldodecyl citrate; trioleyl citrate, propylene glycol dioctanoate; neopentyl glycol diheptanoate; diethylene glycol diisanonate; and polyethylene glycol distearates. Among the esters mentioned above, it is preferred to use ethyl, isopropyl, myristyl, cetyl, stearyl palmitates, ethyl-2-hexyl palmitate, 2-octyldecyl palmitate, myristates of alkyls such as isopropyl, butyl, cetyl, 2-octyldodecyl myristate, hexyl stearate, butyl stearate, isobutyl stearate; dioctyl malate, hexyl laurate, 2-hexyldecyl laurate and isononyl isononanate, cetyl octanoate.

The composition may also comprise, as fatty ester, esters and diesters of C 6 -C 30, preferably C 12 -C 22, fatty acid sugars. It is recalled that "sugar" is understood to mean oxygenated hydrocarbon compounds which have several alcohol functions, with or without an aldehyde or ketone function, and which contain at least 4 carbon atoms. These sugars can be monosaccharides, oligosaccharides or polysaccharides. Suitable sugars include, for example, sucrose (or sucrose), glucose, galactose, ribose, fucose, maltose, fructose, mannose, arabinose, xylose, lactose, and their derivatives. especially alkyls, such as methyl derivatives such as methylglucose.

The esters of sugars and of fatty acids may be chosen in particular from the group comprising the esters or mixtures of esters of sugars described previously and of linear or branched, saturated C 6 -C 30, preferably C 12 -C 22, fatty acids. or unsaturated. If unsaturated, these compounds may comprise one to three carbon-carbon double bonds, conjugated or otherwise.

The esters according to this variant may also be chosen from mono-, di-, tri- and tetraesters, polyesters and mixtures thereof. These esters may be for example oleate, laurate, palmitate, myristate, behenate, cocoate, stearate, linoleate, linolenate, caprate, arachidonates, or mixtures thereof, such as, in particular, the mixed oleo-palmitate, oleostearate and palmitrate stearate esters.

More particularly, the mono- and di-esters are used, and especially the mono- or dioleate, stearate, behenate, oleopalmitate, linoleate, linolenate, oleostearate, sucrose, glucose or methylglucose. By way of example, mention may be made of the product sold under the name Glucate® DO by the company Amerchol, which is a methylglucose dioleate. Mention may also be made, by way of examples, of esters or mixtures of esters of fatty acid sugar: the products sold under the names F160, F140, F110, F90, F70, SL40 by the company Crodesta, respectively denoting sucrose palmito-stearates of 73% monoester and 27% di- and tri-ester, 61% monoester and 39% di-, tri- and tetraester, 52% monoester and 48% monoester; % di-, tri- and tetraester, 45% monoester and 55% di-, tri- and tetraester, 39% monoester and 61% di-, tri-, and tetra. -ester, and sucrose mono-laurate; the products sold under the name Ryoto Sugar Esters, for example referenced B370 and corresponding to sucrose behenate formed from 20% monoester and 80% di-triester-polyester; the sucrose mono-dipalmito-stearate marketed by Goldschmidt under the name Tegosoft® PSE. The non-silicone wax or waxes are chosen in particular from carnauba wax, candelilla wax, and alfa wax, paraffin wax, ozokerite, vegetable waxes such as olive wax or rice wax. hydrogenated jojoba wax or the absolute waxes of flowers such as the essential wax of blackcurrant sold by the company BERTIN (France), animal waxes such as beeswax, or modified beeswax (cerabellina) ; other waxes or waxy raw materials that can be used according to the invention are, in particular, marine waxes, such as the one sold by SOPHIM under the reference M82, and polyethylene or polyolefin waxes in general. The silicones that can be used in the cosmetic compositions of the present invention are volatile or cyclic, linear or branched, volatile or non-volatile silicones, modified or not with organic groups, having a viscosity of 5 × 10 -6 to 2.5 m 2 / s at 25 ° C. C and preferably 1.10-5 to 1m2 / s. The silicones that can be used in accordance with the invention can be in the form of oils, waxes, resins or gums. Preferably, the silicone is chosen from polydialkylsiloxanes, in particular polydimethylsiloxanes (PDMS), and organomodified polysiloxanes comprising at least one functional group chosen from poly (oxyalkylene) groups, amino groups and alkoxy groups.

Organopolysiloxanes are further defined in Walter Noll's "Chemistry and Technology of Silicones" (1968), Academie Press. They can be volatile or nonvolatile. When volatile, the silicones are more particularly chosen from those having a boiling point of between 60 ° C. and 260 ° C., and even more particularly from: (i) cyclic polydialkylsiloxanes containing from 3 to 7, preferably from 4 to 5 silicon atoms. It is, for example, octamethylcyclotetrasiloxane sold in particular under the name VOLATILE SILICONE® 7207 by UNION CARBIDE or SILBIONE® 70045 V2 by RHODIA, decamethylcyclopentasiloxane marketed under the name VOLATILE SILICONE® 7158 by UNION CARBIDE, and SILBIONE® 70045 V5 by RHODIA, as well as their mixtures. Mention may also be made of cyclocopolymers of the dimethylsiloxane / methylalkylsiloxane type, such as the VOLATILE® SILICONE FZ 3109 marketed by UNION CARBIDE, of formula: ## STR3 ## Examples of cyclic polydialkylsiloxane mixtures with organic compounds derived from silicon, such as the mixture of octamethylcyclotetrasiloxane and tetramethylsilylpentaerythritol (50/50), are also mentioned. the mixture of octamethylcyclotetrasiloxane and oxy-1,1 '- (hexa-2,2,2', 2 ', 3,3'-trimethylsilyloxy) bis-neopentane (ii) linear volatile polydialkylsiloxanes having 2 to 9 atoms of silicon and having a viscosity less than or equal to 5 × 10 -6 m 2 / s at 25 ° C. It is, for example, decamethyltetrasiloxane marketed in particular under the name "SH 200" 25 by Toray Silicone. entering this class are also described in the article published in Cosmetics and Toiletries, Vol. 91, Jan. 76, p. 27-32 - TODD & BYERS "Volatile Silicone fluids for cosmetics". Non-volatile polydialkylsiloxanes, polydialkylsiloxane gums and resins, polyorganosiloxanes modified with the above organofunctional groups and mixtures thereof are preferably used. These silicones are more particularly chosen from polydialkylsiloxanes, among which may be mentioned mainly polydimethylsiloxanes with trimethylsilyl end groups. The viscosity of the silicones is measured at 25 ° C. according to the ASTM 445 Appendix C standard. Among these polydialkylsiloxanes, mention may be made, without limitation, of the following commercial products: SILBIONE® oils of the 47 and 70 047 series or the MIRASIL® oils marketed by RHODIA, such as, for example, 70 047 V 500 000; the oils of the MIRASIL® series marketed by RHODIA; the oils of the 200 series of Dow Corning, such as DC200 having a viscosity of 60,000 mm 2 / s; - VISCASIL® oils from GENERAL ELECTRIC and some oils from SF series (SF 96, SF 18) from GENERAL ELECTRIC. Mention may also be made of polydimethylsiloxanes with dimethylsilanol end groups known under the name of dimethiconol (CTFA), such as the oils of the 48 series from the company RHODIA.

In this class of polydialkylsiloxanes, mention may also be made of the products sold under the names "ABIL WAX® 9800 and 9801" by GOLDSCHMI DT, which are polydialkyl (C1-C20) siloxanes. The silicone gums that can be used in accordance with the invention are in particular polydialkylsiloxanes, preferably polydimethylsiloxanes having high average molecular weights of between 200,000 and 1,000,000 used alone or in a mixture in a solvent. This solvent may be chosen from volatile silicones, polydimethylsiloxane (PDMS) oils, polyphenylmethylsiloxane (PPMS) oils, isoparaffins, polyisobutylenes, methylene chloride, pentane, dodecane, tridecane or their mixtures.

More particularly useful products according to the invention are mixtures such as: - mixtures formed from a hydroxyl end-of-the-chain polydimethylsiloxane, or dimethiconol (CTFA) and a cyclic polydimethylsiloxane also called cyclomethicone (CTFA) such that the product Q2 1401 sold by Dow Corning; mixtures of a polydimethylsiloxane gum and a cyclic silicone such as the product SF 1214 Silicone Fluid from the company General Electric, this product is an SF 30 gum corresponding to a dimethicone, having a number average molecular weight of 500,000 solubilized in SF 1202 Silicone Fluid oil corresponding to decamethylcyclopentasiloxane; mixtures of two PDMSs of different viscosities, and more particularly of a PDMS gum and a PDMS oil, such as the product SF 1236 from the company General Electric. The product SF 1236 is the mixture of an SE 30 gum defined above having a viscosity of 20 m 2 / s and an SF 96 oil with a viscosity of 5 × 10 -6 m 2 / s. This product preferably comprises 15% of SE gum and 85% of an SF 96 oil. The organopolysiloxane resins that can be used in accordance with the invention are crosslinked siloxane systems containing the units: R 2 SiO 2/2, R 3 SiO 1/2, RSiO 3 Wherein R represents an alkyl having 1 to 16 carbon atoms. Among these products, those that are particularly preferred are those in which R denotes a C1-C4 lower alkyl group, more particularly methyl. Among these resins may be mentioned the product marketed under the name "Dow Corning 593" or those sold under the names "Silicone Fluid SS 4230 and SS 4267" by the company General Electric and which are silicones of dimethyl / trimethyl siloxane structure. Mention may also be made of the trimethylsiloxysilicate type resins sold in particular under the names X22-4914, X21-5034 and X21-5037 by the company Shin-Etsu.

The organomodified silicones that may be used in accordance with the invention are silicones as defined above and comprising in their structure one or more organofunctional groups attached via a hydrocarbon-based group. In addition to the silicones described above, the organomodified silicones may be polydiarylsiloxanes, especially polydiphenylsiloxanes, and polyalkylarylsiloxanes functionalized with the organofunctional groups mentioned above. The polyalkylarylsiloxanes are especially chosen from polydimethyl / methylphenylsiloxanes, linear and / or branched polydimethyl / diphenylsiloxanes with a viscosity ranging from 1 × 10 -5 to 5 × 10 -2 m 2 / s at 25 ° C. Among these polyalkylarylsiloxanes include by way of example the products sold under the following names: SILBIONE® oils of the 70 641 series from RHODIA; . RHODORSIL® 70 633 and 763 RHODIA series of oils; . DOW CORNING 556 COSMETIC GRAD FLUID oil from DOW CORNING; . silicones of the PK series from BAYER, such as the product PK20; . silicones of the PN and PH series of BAYER, such as the PN1000 and PH1000 products; . certain oils of the SF series of GENERAL ELECTRIC such as SF 1023, SF 1154, SF 1250, SF 1265. Among the organomodified silicones, mention may be made of polyorganosiloxanes comprising: polyethyleneoxy and / or polypropyleneoxy groups optionally comprising C 6 -alkyl groups; 024 such as the products known as dimethicone copolyol marketed by the company Dow Corning under the name DC 1248 or the oils SILWET® L 722, L 7500, L 77, L 711 of the company UNION CARBIDE and the alkyl (C12) -methicone copolyol sold by the company Dow Corning under the name Q2 5200; substituted or unsubstituted amine groups such as the products sold under the name GP 4 Silicone Fluid and GP 7100 by the company Genesee or the products sold under the names Q2 8220 and Dow Corning 929 or 939 by the company Dow Corning. The substituted amino groups are, in particular, C 1 -C 4 aminoalkyl groups; alkoxylated groups, such as the product sold under the name "Silicone Copolymer F-755" by SWS Silicones and Abil Wax® 2428, 2434 and 2440 by the company GOLDSCHMIDT.

More particularly, the fatty substances are chosen from liquid or pasty compounds at room temperature (25 ° C.) and at atmospheric pressure. Preferably, the fatty substance is a liquid compound at a temperature of 25 ° C. and at atmospheric pressure. The fatty substances are advantageously chosen from 06-016 hydrocarbons, hydrocarbons containing more than 16 carbon atoms, triglycerides, fatty alcohols, fatty acid esters and / or fatty alcohol esters other than triglycerides, and silicones. , or their mixtures. Preferably, the fatty substance is chosen from liquid petrolatum, 06-16 alkanes, polydecenes, liquid esters of fatty acid and / or fatty alcohol, liquid fatty alcohols or mixtures thereof. Better still, the fatty substance is chosen from liquid petrolatum and alkanes in 06-016, polydecenes. The composition according to the invention comprises at least 25% by weight of fatty substances. The composition according to the invention more particularly has a fat content ranging from 25 to 80% by weight, preferably from 30 to 70% by weight, still more advantageously from 30 to 60% by weight, relative to the weight of the composition.

Surfactants: The composition of the invention also comprises one or more surfactants. In particular, the surfactant or surfactants are chosen from anionic, amphoteric, zwitterionic, cationic surfactants different from the compounds of formula (I) or nonionic, and preferably nonionic. The term "anionic surfactant" is understood to mean a surfactant comprising as ionic or ionizable groups only anionic groups. These anionic groups are preferably chosen from -C (O) OH, -C (O) O-, -SO3H, -S (O) 20-, -OS (O) 20H, -SO (O) 20- , -P (O) OH2, -P (O) 20-, -P (O) O2, -P (OH) 2, = P (O) OH, -P (OH) O-, = P (O) 0-, = POH, = PO-, the anionic parts comprising a cationic counterion such as an alkali metal, an alkaline earth metal, or an ammonium. As examples of anionic surfactants that may be used in the composition according to the invention, mention may be made of alkyl sulphates, alkyl ether sulphates, alkylamido ether sulphates, alkylaryl polyether sulphates, monoglyceride sulphates, alkyl sulphonates, alkyl amide sulphonates and alkyl aryl sulphonates. , alpha-olefin sulfonates, paraffin sulfonates, alkyl sulfosuccinates, alkyl ether sulfosuccinates, alkyl amide sulfosuccinates, alkyl sulfon acetates, acyl sarcosinates, acyl glutamates, alkyl sulfosuccinamates, acyl isethionates and N-acyltaurates, alkyl monoesters and polyglycoside-polycarboxylic acids, acyllactylates, D-galactoside-uronic acid salts, alkyl ether-carboxylic acid salts, alkyl aryl ether-carboxylic acid salts, acid salts. alkyl amidoether carboxylic acids, and the corresponding non-salified forms of all these compounds, alkyl and acyl groups of all these compounds having from 6 to 24 carbon atoms and the aryl group denoting a phenyl group. These compounds may be oxyethylenated and then preferably comprise from 1 to 50 ethylene oxide units. The salts of C 6 -C 24 alkyl monoesters and of polyglycoside-polycarboxylic acids may be chosen from among the polyglycoside-citrates of alkyl at 06-024, polyglycoside-tartrates of C6-O24 alkyl and polyglycoside-sulphosuccinates. C6-024 alkyl. When the agent or the anionic surfactants are in the salt form, they may be chosen from alkali metal salts such as the sodium or potassium salt and preferably sodium salt, ammonium salts, amine salts and in particular aminoalcohols or alkaline earth metal salts such as magnesium salts. By way of example of aminoalcohol salts, mention may be made in particular of the salts of mono-, di- and triethanolamine, the salts of mono-, di- or triisopropanolamine and the salts of 25-amino-2-methyl-1-propanol. 2-amino-2-methyl-1,3-propanediol and tris (hydroxymethyl) amino methane. The alkali metal or alkaline earth metal salts and in particular the sodium or magnesium salts are preferably used. Of the abovementioned anionic surfactants, it is preferred to use (C6-C24) alkyl sulfates, C6-C24 alkyl ethersulfates comprising from 2 to 50 ethylene oxide units, especially in the form of alkali metal salts, ammonium, aminoalcohols, and alkaline earth metals, or a mixture of these compounds. In particular, it is preferred to use (C 12 -C 20) alkyl sulphates, C 12 -C 20 alkyl ether sulphates comprising from 2 to 20 ethylene oxide units, especially in the form of alkali metal salts, ammonium salts, aminoalcohols, and alkaline earth metals, or a mixture of these compounds. More preferably, it is preferred to use sodium lauryl ether sulfate with 2.2 moles of ethylene oxide. The amphoteric or zwitterionic surfactant (s), preferably non-silicone, which may be used in the present invention may be in particular derivatives of secondary or tertiary aliphatic amines, optionally quaternized, in which the aliphatic group is a linear or branched chain containing 8 to 22 carbon atoms, said amine derivatives containing at least one anionic group such as, for example, a carboxylate, sulfonate, sulfate, phosphate or phosphonate group. Mention may in particular be made of (C 8 -C 20) alkyl betaines, sulphobetaines, (C 8 -C 20) alkylamido (C 3 -C 8) alkyl betaines and (C 8 -C 20) alkylamidalkyl (C 6 -C 8) sulphobetaines. Among the derivatives of secondary or tertiary aliphatic amines, optionally quaternized, which may be used, as defined above, there may also be mentioned the compounds of the following respective structures (A1) and (A2): Ra-C (O) -NH-CH2 Embedded image in which: Ra represents a C10-C30 alkyl or alkenyl group derived from a RaCOOH acid, preferably present in hydrolyzed coconut oil, a heptyl, nonyl or undecyl group; Rb represents a beta-hydroxyethyl group; and R1 is carboxymethyl; M + represents a cationic counterion derived from an alkaline earth metal, such as sodium, an ammonium ion or an ion derived from an organic amine, and X -, represents an organic or inorganic anionic counterion, such as that chosen from halides, acetates, phosphates, nitrates, (C 1 -C 4) alkyl sulphates, (C 1 -C 4) alkyl or (C 1 -C 4) alkylarylsulfonates, in particular methylsulphate and ethylsulphate; or else M + and X- are absent; Ra-C (O) -NH-CH 2 -CH 2 -N (B) (131) (A2) Formula (A2) wherein: B is -CH 2 -CH 2 -O-X '; B 'represents the group - (CH2), Y', with z = 1 or 2; X 'represents the group -CH2-C (O) OH, -CH2-C (O) OZ', -CH2-CH2-C (O) OH, -CH2-CH2-C (O) OZ ', or hydrogen atom; Y 'represents the group -C (O) OH, -C (O) OZ', -CH2-CH (OH) -SO3H or the group -CH2-CH (OH) -SO3-Z '; Z 'represents a cationic counterion derived from an alkaline or alkaline earth metal, such as sodium, an ammonium ion or an ion derived from an organic amine; Ra, represents a C10-C30 alkyl or alkenyl group of a Ra-C (O) OH acid, preferably present in coconut oil or hydrolyzed linseed oil, an alkyl group, especially C17 and its iso form, an unsaturated 017 group. These compounds are classified in the CTFA dictionary, 5th edition, 1993, under the names cocoamphodiacétate disodium, lauroamphodiacétate disodium, caprylamphodiacétate disodium, capryloamphodiacétate disodium, cocoamphodipropionate disodium, lauroamphodipropionate disodium, caprylamphodipropionate disodium, capryloamphodipropionate disodium, acid lauroamphodipropionic, cocoamphodipropionic acid. By way of example, mention may be made of cocoamphodiacetate marketed by Rhodia under the trade name MIRANOL® C2M concentrate. Among the amphoteric or zwitterionic surfactants mentioned above, use is preferably made of alkyl (C 8 -C 20) betaines such as cocobetaine, (C 8 -C 20) alkylamido (C 3 -C 8) alkyl betaines such as cocamidopropylbetaine, and their mixtures. More preferably, the amphoteric or zwitterionic surfactant (s) is (are) chosen from cocamidopropylbetaine and cocobetaine. The cationic surfactant (s) that may be used in the composition according to the invention comprise, for example, primary, secondary or tertiary fatty amine salts, optionally polyoxyalkylenated, quaternary ammonium salts, and mixtures thereof. As quaternary ammonium salts, mention may be made, for example: - those corresponding to the following general formula (A3), and different surfactants of formula (i): R8 / Rio XR (R1, (A3) Formula (A3) in which: R8 to R11, which may be identical or different, represent an aliphatic group, linear or branched, containing from 1 to 30 carbon atoms, or an aromatic group such as aryl or alkylaryl, it being understood that at least one of the groups R8 to R11 comprise from 8 to 30 carbon atoms, and preferably from 12 to 24 carbon atoms, and X-, represents an organic or inorganic anionic counterion, such as that chosen from the halides, acetates, phosphates, nitrates, (C 1 -C 4) alkyl sulphates, (C 1 -C 4) alkyl or (C 1 -C 4) alkylarylsulfonates, in particular methylsulphate and ethylsulphate, The aliphatic groups of R 8 to R 11 may also contain heteroatoms such as oxygen, nitrogen, sulfur and halogens. Aliphatic forms of R8 to R11 are for example selected from C1-C30alkyl, C1-C30alkoxy, polyoxyalkylene (C2-06), C1-C30alkylamide, (C12-C22alkyl) amidoalkyl (C2-C6) , (C 12 -C 22) alkyl, and C 1 -C 30 hydroxyalkyl, X- is an anionic counterion selected from halides, phosphates, acetates, lactates, (C1-C4) alkyl sulfates, (C1-C4) alkyl- or alkyl (C1-C4) arylsulphonates. Among the quaternary ammonium salts of formula (A3), tetraalkylammonium chlorides, for example dialkyldimethylammonium or alkyltrimethylammonium chlorides in which the alkyl group comprises from about 12 to 22 carbon atoms, are preferred. carbon, in particular behenyltrimethylammonium, distearyl dimethylammonium, cetyltrimethylammonium, benzyldimethylstearylammonium chlorides, or distearoylethylhydroxyethylmethylammonium methosulphate, dipalmitoylethylhydroxyethylammonium methosulphate or distearoylethylhydroxyethylammonium methosulphate, or, finally, palmitylamidopropyltrimethylammonium chloride or stearamidopropyldimethyl (myristyl acetate) ammonium chloride sold under the name CERAPHYL® 70 by VAN DYK; the quaternary ammonium salts of imidazoline, for example those of the following formula (A4): embedded image in which: R12 represents an alkenyl or alkyl group having 8 to 30 carbon atoms, for example fatty acid derivatives of tallow; R13 represents a hydrogen atom, a C1-C4 alkyl group or an alkenyl or alkyl group having from 8 to 30 carbon atoms; R14 represents a C1-C4 alkyl group; R15 represents a hydrogen atom, a C1-C4 alkyl group; X represents an organic or inorganic anionic counterion, such as that selected from halides, phosphates, acetates, lactates, (C1-C4) alkyl sulphates, (C1-C4) alkyl or (C1-C4) alkyl aryls. sulfonates. Preferably, R12 and R13 denote a mixture of alkenyl or alkyl groups containing from 12 to 21 carbon atoms, for example fatty acid derivatives of tallow, R14 denotes a methyl group, R15 denotes a hydrogen atom. Such a product is sold, for example, under the name REWOQUAT® W 75 by the company R EVVO - quaternary di- or triammonium salts, in particular of the following formula (A5): R 19 -N- (CH 2) N- R21 R18 (A5) Formula (A5) wherein: R16 is an alkyl group having about 16 to 30 carbon atoms, optionally hydroxylated and / or interrupted by one or more oxygen atoms; R 17 is selected from hydrogen, an alkyl group having 1 to 4 carbon atoms or a group - (CH 2) 3 -N + (R 1sa) (R 17a) (R 1sa), X; R16a, R17a, R18a, R18, R19, R20 and R21, which are identical or different, are chosen from hydrogen and an alkyl group comprising from 1 to 4 carbon atoms; and 2X-X-, which may be identical or different, represent an organic or inorganic anionic counterion, such as that chosen from halides, acetates, phosphates, nitrates, (C 1 -C 4) alkylsulphates, alkyl (C 1 -C 4) - or alkyl radicals. (C1-C4) aryl sulfonates, in particular methylsulfate and ethylsulfate.

Such compounds are, for example, Finquat CT-P proposed by Finetex (Quaternium 89), Finquat CT proposed by Finetex (Quaternium 75), quaternary ammonium salts containing one or more ester functions, such as those of the following formula (A6): ## STR2 ## ) in which: R 22 is chosen from C 1 -C 6 alkyl groups and C 1 -C 6 hydroxyalkyl or dihydroxyalkyl groups; R 23 is chosen from: O - the R 26 group - the linear or C 1 -C 22 hydrocarbon-based R 27 groups branched, saturated or unsaturated, - the hydrogen atom, R 25 is selected from: O R2-8C - - the group - R29 hydrocarbon groups C1-C6, linear or branched, saturated or unsaturated, - the atom hydrogen, R24, R26 and R28, which may be identical or different, are chosen from linear or branched, saturated or unsaturated hydrocarbon groups of 07-021; r, s and t, which may be identical or different, are integers of from 2 to 6, r1 and t1 which are identical or different, equal to 0 or 1 with r2 + r1 = 2r and t1 + t2 = 2t - y is an integer from 1 to 10, - x and z, which may be identical or different, are integers ranging from 0 to 10, - X- represents an anionic counterion, organic or inorganic, provided that the sum x + y + z is from 1 to 15, that when x is 0 then R23 is R27 and when z is 0 then R25 is R29. The alkyl groups R22 may be linear or branched, and more particularly linear.

Preferably, R 22 denotes a methyl, ethyl, hydroxyethyl or dihydroxypropyl group, and more particularly a methyl or ethyl group. Advantageously, the sum x + y + z is from 1 to 10. When R 23 is a hydrocarbon R 27 group, it may be long and have 12 to 22 carbon atoms, or short and have from 1 to 3 carbon atoms.

When R 25 is a hydrocarbon R 29 group, it preferably has 1 to 3 carbon atoms. Advantageously, R24, R26 and R28, which are identical or different, are chosen from linear or branched, saturated or unsaturated Cil-021 hydrocarbon groups, and more particularly from linear or branched, saturated Cil-021 alkyl and alkenyl groups. or unsaturated. Preferably, x and z, which are identical or different, are equal to 0 or 1. Advantageously, y is equal to 1. Preferably, r, s and t, identical or different, are equal to 2 or 3, and even more particularly are equal to 2 .

The anionic counterion X- is preferably a halide, such as chloride, bromide or iodide; a (C1-C4) alkyl sulphate; (C1-C4) alkyl or (C1-C4) alkyl aryl sulfonate. However, it is possible to use methanesulphonate, phosphate, nitrate, tosylate, an anion derived from an organic acid such as acetate or lactate or any other anion compatible with ammonium with an ester function.

The anionic counterion X- is even more particularly chloride, methylsulfate or ethylsulfate. In the composition according to the invention, the ammonium salts of formula (A6) are used more particularly in which: R22 denotes a methyl or ethyl group, x and y are equal to 1, z is equal to 0 or 1, - r, s and t are equal to 2, - R23 is chosen from: O - the group R2C - the methyl, ethyl or C14-C22 hydrocarbon groups, - the hydrogen atom, - R25 is chosen from : O - the group R2c - the hydrogen atom, - R24, R26 and R28, identical or different, are chosen from linear or branched, saturated or unsaturated C13-C17 hydrocarbon groups, and preferably from groups C13-C17 alkyl and alkenyl, linear or branched, saturated or unsaturated. Advantageously, the hydrocarbon radicals are linear.

Examples of the compounds of formula (A6) include salts, especially diacyloxyethyldimethylammonium, diacyloxyethylhydroxyethylmethylammonium, monoacyloxyethyldihydroxyethylmethylammonium, triacyloxyethylmethylammonium, monoacyloxyethylhydroxyethyldimethylammonium, and mixtures thereof, especially diacyloxyethyldimethylammonium chloride or methylsulfate. The acyl groups preferably have from 14 to 18 carbon atoms and come more particularly from a vegetable oil such as palm oil or sunflower oil. When the compound contains more than one acyl group, the latter groups may be identical or different. These products are obtained, for example, by direct esterification of triethanolamine, triisopropanolamine, alkyldiethanolamine or alkyldisopropanolamine, optionally oxyalkylenated, with fatty acids or with mixtures of fatty acids of plant or animal origin, or with transesterification of their methyl esters. This esterification is followed by quaternization using an alkylating agent such as an alkyl halide, preferably methyl or ethyl, a dialkyl sulphate, preferably methyl or ethyl sulphate. methyl methanesulfonate, methyl para-toluenesulfonate, glycol or glycerol chlorohydrin. Such compounds are, for example, sold under the names DEHYQUART® by the company HENKEL, STEPANQUAT® by the company STEPAN, NOXAMIUM® by the company CECA, REWOQUAT® VVE 18 by the company REWO-WITCO. The composition according to the invention may contain, for example, a mixture of quaternary ammonium mono-, di- and triester salts with a majority by weight of diester salts. It is also possible to use the ammonium salts containing at least one ester function described in US-A-4874554 and US-A-4137180. The behenoylhydroxypropyltrimethylammonium chloride proposed by KAO can be used under the name Quatarmin BTC 131.

Preferably the ammonium salts containing at least one ester function contain two ester functions. Among the cationic surfactants that may be present in the composition according to the invention, it is more particularly preferred to choose the salts of cetyltrimethylammonium, behenyltrimethylammonium, dipalmitoylethylhydroxyethylmethylammonium, and mixtures thereof, and more particularly behenyltrimethylammonium chloride, cetyltrimethylammonium chloride, dipalmitoylethylhydroxyethylammonium methosulfate, and mixtures thereof. Examples of nonionic surfactants useful in the composition used according to the invention are described, for example, in "Handbook of Surfactants" by M. R. PORTER, Blackie & Son editions (Glasgow and London), 1991, pp. 116-178. They are chosen in particular from alcohols, alpha-diols and (C1-C20) alkyl phenols, these compounds being polyethoxylated, polypropoxylated and / or polyglycerolated, and having at least one fatty chain comprising, for example, from 8 to 18 atoms. carbon number, the number of ethylene oxide groups and / or propylene oxide ranging in particular from 2 to 50 and the number of glycerol groups ranging in particular from 2 to 30. Mention may also be made of ethylene oxide copolymers and propylene, optionally oxyethylenated fatty acid and sorbitan esters, sucrose fatty acid esters, polyoxyalkylenated fatty acid esters, optionally oxyalkylenated alkylpolyglycosides, alkylglucoside esters, N-derivatives and the like. alkylglucamine and N-acyl-methylglucamine, aldobionamides and amine oxides. The nonionic surfactants are more particularly chosen from mono or polyoxyalkylenated, mono- or polyglycerolated nonionic surfactants. The oxyalkylenated units are more particularly oxyethylenated units, oxypropylene, or their combination, preferably oxyethylenated. As examples of oxyalkylenated nonionic surfactants, mention may be made of: oxyalkylenated (C 8 -C 24) alkyl phenols; saturated or unsaturated, linear or branched, oxyalkylenated C 8 -C 30 alcohols; saturated or unsaturated, linear or branched, oxyalkylenated C 8 -C 30 amides; saturated or unsaturated, linear or branched, C 8 -C 30 acid esters of polyethylene glycols; saturated or unsaturated, linear or branched C 8 -C 30 acid esters of polyoxyethylenated sorbitol; vegetable oils oxyethylenated, saturated or not; condensates of ethylene oxide and / or propylene oxide, among others, alone or in mixtures. Oxyethylenated and / or oxypropylenated silicones. Surfactants having a number of moles of ethylene oxide and / or propylene of between 1 and 100, preferably between 2 and 50, preferably between 2 and 30. Advantageously, the nonionic surfactants do not comprise oxypropylene units. According to a preferred embodiment of the invention, the oxyalkylenated nonionic surfactants are chosen from oxyethylenated C 8 -C 30 alcohols comprising from 1 to 100 moles of ethylene oxide; linear or branched, saturated or unsaturated C8-C30 acid esters, and polyoxyethylenated sorbitol esters comprising from 1 to 100 moles of ethylene oxide. By way of example of mono- or poly-glycerolated nonionic surfactants, the C 8 -C 40 mono- or polyglycerolated alcohols are preferably used.

In particular, mono- or polyglycerolated C 8 -C 40 alcohols correspond to the following formula (A7): R 2 90- [CH 2 -CH (CH 2 OH) -O] '- H (A 7) Formula (A 7) in which: - R29 represents a linear or branched, C6-C40, preferably C8-C30, alkyl or alkenyl radical; and m represents a number ranging from 1 to 30 and preferably from 1 to 10. By way of example of compounds of formula (A7) which are suitable in the context of the invention, mention may be made of 4-lauryl alcohol. glycerol moles (INCI name: POLYGLYCERYL-4 LAURYL ETHER), lauric alcohol with 1.5 moles of glycerol, oleic alcohol with 4 moles of glycerol (INCI name: POLYGLYCERYL-4 OLEYL ETHER), oleic alcohol to 2 moles of glycerol (INCI name: POLYGLYCERYL-2 OLEYL ETHER), cetearyl alcohol to 2 moles of glycerol, cetearyl alcohol to 6 moles of glycerol, oleocetyl alcohol to 6 moles of glycerol, and octadecanol to 6 moles of glycerol. The alcohol of formula (A7) can represent a mixture of alcohols in the same way that the value of m represents a statistical value, which means that in a commercial product can coexist several species of polyglycerolated fatty alcohols in the form of a mixed. Among the mono- or poly-glycerolated alcohols, it is more particularly preferred to use the C8 / C10 alcohol with one mole of glycerol, the C10 / C12 alcohol with 1 mole of glycerol and the C12 alcohol with 1.5 mole of glycerol.

Preferably, the surfactant used in the process of the invention in the composition is a mono or polyoxyalkylene nonionic surfactant, especially mono or polyoxyethylenated, mono or polyoxypropylenated, or a combination thereof, more particularly mono or polyoxyethylenes.

Preferably, the surfactant or surfactants are chosen from nonionic surfactants or from anionic surfactants. More particularly, the surfactant (s) present in the composition are chosen from nonionic surfactants. Even more preferentially, the nonionic surfactants are chosen from polyoxyethylenated sorbitol esters and polyoxyethylenated fatty alcohols, and mixtures thereof.

In the composition of the invention, the amount of the surfactant (s) in the composition preferably ranges from 0.1 to 50% by weight, more preferably from 0.5 to 20% by weight, relative to the total weight of the composition. Hair dyes: The composition of the invention comprises one or more dyes of keratin fibers. These dyes or dyes of keratin fibers may be chosen from synthetic or natural dyes. The synthetic dyes can be chosen from synthetic oxidation dyes and synthetic direct dyes.

The synthetic oxidation dyes may be selected from oxidation bases and couplers. The oxidation bases may be chosen from heterocyclic bases, benzene bases and their salts; The benzene oxidation bases according to the invention are particularly chosen from para-phenylenediamines, bis-phenylalkylenediamines, para-aminophenols and ortho-aminophenols, and their addition salts. Among the paraphenylenediamines, there may be mentioned, for example, para-phenylenediamine, paratoluylenediamine, 2-chloro-para-phenylenediamine, 2,3-dimethyl-para-phenylenediamine, 2,6-dimethyl paraphenylenediamine, 2,6-diethyl paraphenylenediamine, 2,5-dimethyl-para-phenylenediamine, N, N-dimethyl-para-phenylenediamine, N, N-diethyl-para-phenylenediamine, N, N-dipropyl-para-phenylenediamine, 4-amino-N, N-diethyl-3-methylaniline, N, N- bis - ((3-hydroxyethyl) paraphenylenediamine, 4-N, N-bis - ((3-hydroxyethyl) amino 2-methyl aniline, 4-N, N-bis - ((3-hydroxyethyl) amino 2-chloro aniline, 2 (3-hydroxyethyl paraphenylenediamine, 2-fluoro-para-phenylenediamine, 2-isopropyl-para-phenylenediamine, N-U3-hydroxypropyl) para-phenylenediamine, 2-hydroxymethyl-para-phenylenediamine, N, N-dimethyl-3-methyl-para-phenylenediamine, N N- (ethyl, 3-hydroxyethyl) para-phenylenediamine, N - ([3,7-dihydroxypropyl) paraphenylenediamine, N- (4'-aminophenyl) paraphenylenediamine, N-phenyl paraphenylenediamine, 2 (3-hydroxyethyloxy) paraphenylenediamine, 2- (3-acetylaminoethyloxy) paraphenylenediamine, N - ((3-methoxyethyl) paraphenylenediamine, 4- aminophenylpyrrolidine, 2-thienyl paraphenylenediamine, hydroxyethylamino 5-amino toluene, 3-hydroxy 1- (4'-aminophenyl) pyrrolidine and their addition salts with an acid. Of the paraphenylenediamines mentioned above, paraphenylenediamine, paratoluylenediamine, 2-isopropyl paraphenylenediamine, 2 (3-hydroxyethyl paraphenylenediamine, 2 (3-hydroxyethyloxy) paraphenylenediamine, 2,6-dimethyl paraphenylenediamine, 2,6 ethyl paraphenylenediamine, 2,3-dimethyl paraphenylenediamine, N, N-bis - ((3-hydroxyethyl) paraphenylenediamine, 2-chloro-para-phenylenediamine, 2 (3-acetylaminoethyloxy) para-phenylenediamine, and their acid addition salts Particularly preferred among the bis-phenylalkylenediamines are N, N'-bis ((3hydroxyethyl) N, N'-bis (4'-aminophenyl) -1,3-diamino propanol). N, N'-bis - ((3hydroxyethyl) N, N'-bis- (4'-aminophenyl) ethylenediamine, N, N'-bis- (4-aminophenyl) tetramethylenediamine, N, N'-bis - ((3-hydroxyethyl) N, N'-bis- (4-aminophenyl) tetramethylenediamine, N, N'-bis- (4-methylaminophenyl) tetramethylen ediamine, N, N'-bis (ethyl) N, N'-bis (4'-amino, 3'-methylphenyl) ethylenediamine, 1,8-bis (2,5-diamino phenoxy) -3 , 6-dioxaoctane, and their addition salts. Among para-aminophenols, para-aminophenol, 4-amino-3-methylphenol, 4-amino-3-fluoro phenol, 4-amino-3-chlorophenol, 4- amino 3-hydroxymethyl phenol, 4-amino-2-methylphenol, 4-amino-2-hydroxymethylphenol, 4-amino-2-methoxymethylphenol, 4-amino-2-aminomethylphenol, 4-amino-2 - ( 3-hydroxyethylaminomethyl) phenol, 4-amino-2-fluoro phenol, and their addition salts with an acid Among the ortho-aminophenols, there may be mentioned, by way of example, 2-amino phenol, 2- amino-5-methylphenol, 2-amino-6-methylphenol, 5-acetamido-2-amino phenol and their addition salts The heterocyclic bases according to the invention are more particularly chosen from pyridine derivatives, derivatives thereof, pyrimidines and pyrazole derivatives and their addition salts.

Among the pyridine derivatives, mention may be made of the compounds described for example in patents GB 1 026 978 and GB 1 153 196, such as 2,5-diaminopyridine, 2- (4-methoxyphenyl) amino 3-amino pyridine, 3,4-diamino pyridine, and their addition salts. Other pyridinic oxidation bases which are useful in the dyeing process according to the invention are the 3-amino pyrazolo [1,5-a] -pyridines oxidation bases or their addition salts, described for example in the application Patent FR 2801308. By way of example, mention may be made of pyrazolo [1,5-a] pyridin-3-ylamine; 2-acetylamino pyrazolo [1,5-a] pyridin-3-ylamine; 2-morpholin-4-yl-pyrazolo [1,5-a] pyridin-3-ylamine; 3-amino-pyrazolo [1,5-a] pyridin-2-carboxylic acid; 2-methoxy-pyrazolo [1,5-a] pyridin-3-ylamino; (3-amino-pyrazolo [1,5-a] pyridin-7-yl) -methanol; 2- (3-Amino-pyrazolo [1,5-a] pyridin-5-yl) -ethanol; 2- (3-Amino-pyrazolo [1,5-a] pyridin-7-yl) -ethanol; (3-Aminopyrazolo [1,5-a] pyridin-2-yl) -methanol; 3,6-diamino-pyrazolo [1,5-a] pyridine; 3,4-diamino-pyrazolo [1,5-a] pyridine; pyrazolo [1,5-a] pyridine-3,7-diamine; 7-morpholin-4-yl-pyrazolo [1,5-a] pyridin-3-ylamine; pyrazolo [1,5-a] pyridine-3,5-diamine; 5-morpholin-4-yl-pyrazolo [1,5-a] pyridin-3-ylamine; 2 - [(3-amino-pyrazolo [1,5-a] pyridin-5-yl) - (2-hydroxyethyl) amino] ethanol; 2 - [(3-Amino-pyrazolo [1,5-a] pyridin-7-yl) - (2-hydroxyethyl) amino] ethanol; 3-amino-pyrazolo [1,5-a] pyridin-5-ol; 3-aminopyrazolo [1,5-a] pyridin-4-ol; 3-amino-pyrazolo [1,5-a] pyridin-6-ol; 3-aminopyrazolo [1,5-a] pyridin-7-ol; as well as their addition salts.

Among the pyrimidine derivatives, mention may be made of the compounds described, for example, in DE 2359399; JP 88-169571; JP 05-63124; EP 0770375 or patent application WO 96/15765 such as 2,4,5,6-tetraaminopyrimidine, 4-hydroxy 2,5,6-triaminopyrimidine, 2-hydroxy 4,5,6-triaminopyrimidine, 2 , 4-dihydroxy-5,6-diaminopyrimidine, 2,5,6-triaminopyrimidine and their addition salts and tautomeric forms, when tautomeric equilibrium exists. Among the pyrazole derivatives, mention may be made of the compounds described in DE 3843892, DE 4133957 and patent applications WO 94/08969, WO 94/08970, FR-A-2 733 749 and DE 195 43 988 as the 4.5 1-methyl pyrazole, 4,5-diamino-1 - ((3hydroxyethyl) pyrazole, 3,4-diamino pyrazole, 4,5-diamino-1- (4'-chlorobenzyl) pyrazole, diamino 1,3-dimethyl pyrazole, 4,5-diamino-3-methyl-1-phenyl pyrazole, 4,5-diamino-1-methyl-3-phenylpyrazole, 4-amino-1,3-dimethyl-5-hydrazino pyrazole, 1-Benzyl-4,5-diamino-3-methyl-pyrazole, 4,5-diamino-3-tert-butyl-1-methyl-pyrazole, 4,5-diamino-1-tert-butyl-3-methyl-pyrazole, 4,5 -diamino 1 - ((3-hydroxyethyl) 3-methyl pyrazole, 4,5-diamino-1-ethyl-3-methyl-pyrazole, 4,5-diamino-1-ethyl-3- (4'-methoxyphenyl) pyrazole, 5-diamino-1-ethyl-3-hydroxymethyl pyrazole, 4,5-diamino-3-hydroxymethyl-1-methyl-pyrazole, 4,5-diamino-3-hydroxymethyl-1-isopropyl pyrazole, 4,5-diamino-3-meth 1-isopropyl pyrazole, 4-amino 5- (2'-aminoethyl) amino 1,3-dimethyl pyrazole, 3,4,5-triamino pyrazole, 1-methyl 3,4,5-triamino pyrazole, 3,5-diamino-1-methyl-4-methylamino pyrazole, 3,5-diamino 4 - ((3-hydroxyethyl) amino-1-methyl pyrazole, and their addition salts. It is also possible to use 4-5-diamino 1- (3-methoxyethyl) pyrazole. Preferably, a 4,5-diaminopyrazole and even more preferably 4,5-diamino-1 - ((3-hydroxyethyl) pyrazole and / or one of its salts will be used as pyrazole derivatives. also mentioned diamino N, Ndihydropyrazolopyrazolones and in particular those described in application FR-A-2,886,136 such as the following compounds and their addition salts: 2,3-diamino-6,7-dihydro-1H, 5H-pyrazolo [1,2-a] pyrazol-1-one, 2-amino-3-ethylamino-6,7-dihydro-1H, 5Hpyrazolo [1,2-a] pyrazol-1-one, 2-amin-3- isopropylamino-6,7-dihydro-1H, 5H-pyrazolo [1,2-a] pyrazol-1-one, 2-amino-3- (pyrrolidin-1-yl) -6,7-dihydro-1H, 5H pyrazolo [1,2-a] pyrazol-1-one, 4,5-diamino-1,2-dimethyl-1,2-dihydro-pyrazol-3-one, 4,5-diamino-1,2-diethyl -1,2-dihydro-pyrazol-3-one, 4,5-diamino-1,2-di- (2-hydroxyethyl) -1,2-dihydro-pyrazol-3-one, 2-amino-3- ( 2-hydroxyethyl) amino-6,7-dihydro-1H, 5H-pyrazolo [1,2-a] pyrazol-1-one, 2-amino-3-dimethylamino-6,7-dihydro-1H, 5H-pyrazolo [ 1,2-a] pyrazol-1-one, 2,3 amino-5,6,7,8-tetrahydro-1H, 6H-pyridazino [1,2-a] pyrazol-1-one, 4-aminodo-1,2-diethyl-5- (pyrrolidin-1-yl) 1,2-dihydro-pyrazol-3-one, 4-amin-5- (3-di-methylamino-pyrrolidin-1-yl) -1,2-diethyl-1,2-dihydro-pyrazol-3- one, 2,3-diamino-6-hydroxy-6,7-dihydro-1H, 5H-pyrazolo [1,2-a] pyrazol-1-one. It will be preferred to use 2,3-diamino-6,7-dihydro-1H, 5H-pyrazolo [1,2-a] pyrazol-1-one and / or a salt thereof. As heterocyclic bases, 4,5-diamino-1 - ([3-hydroxyethyl) pyrazole and / or 2,3-diamino-6,7-dihydro-1H, 5H-pyrazolo [1,2] will preferably be used. -a] pyrazol-1-one and / or a salt thereof. The oxidation base (s) according to the invention are each advantageously from 0.0001 to 10% by weight relative to the total weight of the composition and preferably from 0.005 to 5% by weight relative to the total weight of the composition. The composition of the invention may optionally comprise one or more couplers. Among these couplers, there may be mentioned meta-phenylenediamines, meta-aminophenols, meta-diphenols, naphthalenic couplers, heterocyclic couplers and their addition salts.

By way of example, mention may be made of 1,3-dihydroxybenzene, 1,3-dihydroxy-2-methylbenzene, 4-chloro-1,3-dihydroxybenzene and 2,4-diamino-1- hydroxyethyloxy) benzene, 2-amino-4- (1-hydroxyethylamino) -1-methoxybenzene, 1,3-diamino benzene, 1,3-bis (2,4-diaminophenoxy) propane, 3-ureido aniline, 3-ureido-dimethylamino benzene, sesamol, 1-11-hydroxyethylamino-3,4-methylenedioxybenzene, α-naphthol, 2-methyl-1-naphthol, 6-hydroxyindole, 4-hydroxyindole, 4-hydroxy N-methylindole, 2-amino-3-hydroxypyridine, 6-hydroxybenzomorpholine 3,5-diamino-2,6-dimethoxypyridine, 1-N- (11-hydroxyethyl) amino-3 , 4-methylene dioxybenzene, 2,6-bis- (11-hydroxyethylamino) toluene, 6-hydroxy indoline, 2,6-dihydroxy-4-methyl pyridine, 1-H-3-methyl pyrazole 5-one, 1-phenyl-3-methyl-pyrazole-5-one, 2,6-dimethyl-pyrazolo [1,5-b] -1,2,4-triazole, 2,6-dimethyl [3,2-c] -1, 2,4-triazole, 6-methyl pyraz olo [1,5-a] benzimidazole, their addition salts with an acid, and mixtures thereof. The coupler (s) are each advantageously from 0.0001 to 10% by weight relative to the total weight of the composition, and preferably from 0.005 to 5% by weight relative to the total weight of the composition of the invention. In general, the addition salts of the oxidation bases and couplers that can be used in the context of the invention are chosen especially from the addition salts with an acid such as hydrochlorides, hydrobromides, sulphates, citrates, succinates, tartrates, lactates, tosylates, benzenesulfonates, phosphates and acetates. The composition of the invention may further comprise one or more synthetic direct dyes.

The latter are more particularly chosen from ionic or nonionic species, preferably cationic or nonionic species. As examples of suitable synthetic direct dyes, mention may be made of azo direct dyes; methinic; carbonyls; azinic; nitro (hetero) aryl; tri- (hetero) aryl methanes; porphyrins; phthalocyanines, alone or in mixtures.

More particularly, the azo dyes comprise a function -N = N- whose two nitrogen atoms are not simultaneously engaged in a ring. However, it is not excluded that one of the two nitrogen atoms of the sequence -N = N- is engaged in a cycle. The dyes of the family of methines are more particularly compounds comprising at least one sequence chosen from> C = C <and -N = C <whose two atoms are not simultaneously engaged in a ring. It is however specified that one of the nitrogen or carbon atoms of the chains can be engaged in a cycle. More particularly, the dyes of this family are derived from methine, azomethine, mono- and di-arylmethane compounds, indoamines (or diphenylamines), indophenols, indoanilines, carbocyanines, azacabocyanines and their isomers, diazacarbocyanines and their isomers, tetraazacarbocyanines, hemicyanines. As regards the dyes of the carbonyl family, mention may be made, for example, of the dyes chosen from acridone, benzoquinone, anthraquinone, naphthoquinone, benzanthrone, anthranthrone, pyranthrone, pyrazolanthrone, pyrimidinoanthrone, flavanthrone, idanthrone, flavone, (iso) violanthrone, isoindolinone, benzimidazolone, isoquinolinone, anthrapyridone, pyrazoloquinazolone, perinone, quinacridone, quinophthalone, indigo, thioindigo, naphthalimide, anthrapyrimidine, diketopyrrolopyrrole, coumarin. As regards the dyes of the family of cyclic azines, there may be mentioned in particular azine, xanthene, thioxanthene, fluorindine, acridine, (di) oxazine, (di) thiazine, pyronine. The nitro (hetero) aromatic dyes are more particularly nitrobenzene or nitro pyridinic direct dyes. With regard to porphyrin or phthalocyanine dyes, it is possible to use cationic or non-cationic compounds, optionally comprising one or more metals or metal ions, for example alkali and alkaline earth metals, zinc and silicon. By way of example of particularly suitable direct dyes, mention may be made of the nitro dyes of the benzene series; azo direct dyes; azomethines; methinic; azacarbocyanines such as tetraazacarbocyanines (tetraazapentamethines); quinone direct dyes and in particular anthraquinone, naphthoquinone or benzoquinone dyes; direct azine dyes; xanthenics; triarylmethanics; indoamines; indigoids; phthalocyanines, porphyrins alone or in mixtures. When present, the synthetic direct dye (s) more particularly represent from 0.0001 to 10% by weight of the total weight of the composition, and preferably from 0.005 to 5% by weight. The composition may also comprise one or more natural dyes. Among the natural dyes that can be used according to the invention, mention may be made of lawsone, juglone, alizarin, purpurin, carminic acid, kermesic acid and purpurogallin. protocatechaldehyde, indigo, isatin, curcumin, spinulosin, apigenidine, orceins, brasiline, brasiline, hematoxylin, hematein. It is also possible to use the extracts or decoctions containing these natural dyes, and in particular poultices or extracts made from henna. When present, the natural dye or dyes more particularly represent from 0.0001 to 10% by weight of the total weight of the composition, and preferably from 0.005 to 5% by weight. Preferably, the dye (s) of the keratinous fibers of the composition of the invention have a logP greater than or equal to 1.5. Even more preferentially, the dye or dyes of the keratin fibers of the composition of the invention have a logP greater than or equal to 2.

The logP value conventionally represents the coefficient of partition of the dye between octanol and water. The logP can be calculated according to the method described in the article by Meylan and Howard "Atom / Fragment contribution method for estimating octanol-water partition coefficient", J. Pharm. Sci. 84: 83-92, 1995. This value can also be calculated from many commercially available software that determines LogP based on the structure of a molecule. By way of example, mention may be made of the Epiwin software from the United States Environmental Agency. Basifying agents: The composition according to the invention also comprises one or more alkalinizing agents. The basifying agent (s) may be inorganic or organic or hybrid. The inorganic alkalinizing agent (s) is (are) preferably chosen from ammonia, alkali carbonates or bicarbonates, such as sodium or potassium carbonates or bicarbonates, sodium or potassium hydroxides, or mixtures thereof. The organic basifying agent (s) are preferably chosen from organic amines whose pKb at 25 ° C. is less than 12, and preferably less than 10, and even more advantageously less than 6. It should be noted that this is pKb corresponding to the highest basicity function. In addition, the organic amines do not comprise a fatty chain, alkyl or alkenyl, comprising more than ten carbon atoms. The organic basifying agent (s) are, for example, chosen from alkanolamines, ethylenediamines that are oxyethylenated and / or oxypropylenated, amino acids and compounds of the following formula (I): ## STR2 ## Formula (I) in which W is a divalent C 1 -C 6 alkylene radical optionally substituted by one or more hydroxyl groups or a C 1 -C 6 alkyl radical, and / or optionally interrupted by one or more heteroatoms such as O or NR '; Rx, Ry, Rz, Rt, Ri, and the same or different, represent a hydrogen atom, a C1-C6 alkyl or C1-C6 hydroxyalkyl, C1-C6 aminoalkyl radical. Examples of amines of formula (I) are 1,3-diaminopropane, 1,3-diaminopropanol, spermine and spermidine. By alkanolamine is meant an organic amine comprising a primary, secondary or tertiary amine function, and one or more linear or branched C 1 -C 8 alkyl groups carrying one or more hydroxyl radicals. In particular, the organic amines chosen from alkanolamines, such as mono-, di- or trialkanolamines, comprising one to three identical or different C 1 -C 4 hydroxyalkyl radicals are suitable in particular for carrying out the invention.

Among compounds of this type, mention may be made of monoethanolamine (MEA), diethanolamine, triethanolamine, monoisopropanolamine, diisopropanolamine, N-dimethylaminoethanolamine, 2-amino-2-methyl-1-propanol and triisopropanolamine. 2-amino-2-methyl-1,3-propanediol, 3-amino-1,2-propanediol, 3-dimethylamino-1,2-propanediol, tris-hydroxymethylamino-methane.

More particularly, the amino acids that can be used are of natural or synthetic origin, in their L, D, or racemic form, and comprise at least one acid function chosen more particularly from the carboxylic, sulphonic, phosphonic or phosphoric acid functions. Amino acids can be in neutral or ionic form.

As amino acids that may be used in the present invention, mention may in particular be made of aspartic acid, glutamic acid, alanine, arginine, ornithine, citrulline, asparagine, carnitine and cysteine. , glutamine, glycine, histidine, lysine, isoleucine, leucine, methionine, N-phenylalanine, proline, serine, taurine, threonine, tryptophan, tyrosine and valine.

Advantageously, the amino acids are basic amino acids comprising an additional amine function optionally included in a ring or in a ureido function. Such basic amino acids are preferably chosen from those corresponding to the following formula (II), as well as their salts: embedded image in which formula (II): ## STR2 ## in which R represents a group chosen from: NH; - (C1-12) 3NI-12; - (CH2) 2NC-12; - (CH2) 2NHCONH2; and - (CH 2) 2 NH-C-NH 2 NH The compounds corresponding to formula (II) are histidine, lysine, arginine, ornithine, citrulline. The organic amine may also be chosen from heterocyclic organic amines. In addition to the histidine already mentioned in the amino acids, mention may be made, in particular, of pyridine, piperidine, imidazole, triazole, tetrazole and benzimidazole. The organic amine may also be selected from amino acid dipeptides. As amino acid dipeptides that may be used in the present invention, carnosine, anserin and whale may be mentioned in particular. The organic amine may also be chosen from compounds containing a guanidine function. As amino amines of this type which can be used in the present invention, mention may in addition be made of arginine already mentioned as amino acid, creatine, creatinine, 1,1-dimethylguanidine, 1,1 diethylguanidine, glycocyamine, metformin, agmatine, n-amidinoalanine, 3-guanidinopropionic acid, 4-guanidinobutyric acid and 2 - ([amino (imino) methyl] amino acid) ethane-1-sulfonic acid. As hybrid compounds, mention may be made of the salts of the amines mentioned above with acids such as carbonic acid and hydrochloric acid. In particular, guanidine carbonate or monoethanolamine hydrochloride can be used.

Preferably, the alkalinizing agent (s) present in the composition of the invention are chosen from alkanolamines, amino acids in neutral or ionic form, in particular basic amino acids, and preferably corresponding to those of formula (II). Even more preferentially, the alkalinizing agent (s) are chosen from monoethanolamine (MEA) and basic amino acids, in neutral or ionic form. More preferably, the alkalinizing agent (s) are chosen from alkanolamines such as monoethanolamine.

Advantageously, the composition according to the invention has a content of alkalinizing agent (s) ranging from 0.01 to 30% by weight, preferably from 0.1 to 20% by weight relative to the weight of the composition. According to a first particular embodiment, the composition according to the invention, or the process according to the invention does not use ammonia or a salt thereof, as alkalinizing agent. According to a second embodiment, if the composition or the process according to the invention employed ammonia or one of its salts as alkalinizing agent, its content would advantageously not exceed 0.03% by weight (expressed in NH3), preferably would not exceed 0.01% by weight, relative to the weight of the composition of the invention. Preferably, if the composition comprises ammonia or a salt thereof, then the amount of alkalinizing agent (s) other than ammonia is greater than that of ammonia (expressed as NH 3).

Chemical Oxidizing Agent: The composition of the invention comprises one or more chemical oxidizing agents. By chemical oxidizing agent is meant an oxidizing agent different from the oxygen of the air. More particularly, the chemical oxidizing agent (s) is (are) chosen from hydrogen peroxide, urea peroxide, alkali metal bromates, peroxygenated salts such as, for example, persulfates, perborates, peracids and their precursors and percarbonates. of alkali or alkaline earth metals. This oxidizing agent is advantageously constituted by hydrogen peroxide and especially in aqueous solution (hydrogen peroxide) whose concentration may vary, more particularly from 0.1 to 50% by weight, and even more preferably from 0.5 to 20% by weight. by weight, better from 1 to 15% by weight relative to the weight of the composition. Preferably, the composition of the invention does not contain peroxygenated salts.

Cationic Compounds of Formula (i) The composition of the invention comprises one or more cationic compounds of formula (I): R 2 + X R 4 N -R 3 R 1 in which the radicals R 1, R 2, R 3 and R 4, identical or different, represent an optionally substituted C1-C8 alkyl radical, optionally interrupted by one or more heteroatoms, chosen more particularly from oxygen, or interrupted by an amino group comprising a hydrogen atom or a C1-02 alkyl group; an optionally substituted C2-08 alkenyl radical, optionally interrupted by one or more heteroatoms, chosen more particularly from oxygen, or interrupted by an amino group comprising a hydrogen atom or a C102 alkyl group; an optionally substituted benzyl radical; X- representing a cosmetically acceptable anion or mixture of anions, ensuring the electroneutrality of formula (i). Preferably, the alkyl or alkenyl radicals respectively comprise from 1 to 6 and from 2 to 6 carbon atoms. The optional substituent or substituents of the alkyl or alkenyl radicals may be chosen from halogen atoms, the hydroxy group, the amino or mono- or dialkyl C 1 -C 4 amino groups, the optionally substituted phenyl group and the C 1 -C 4 alkoxy groups. C2-04 alkenyloxy groups, SO3H group and its salts, CO2H group and its salts. The optional substituent (s) of the phenyl or benzyl groups may be chosen from halogen atoms, (C 1 -C 4) alkyl groups, (C 2 -C 4) alkenyl groups, hydroxy groups, amino or mono or C 1 -C 4 dialkyl groups. amino, C1-C4 alkoxy groups, C2-04 alkenyloxy groups, SO3H group and its salts, CO2H group and its salts. Even more preferably, at least 3 of the radicals R1 to R4 denote a methyl or ethyl radical. The anion or mixture of anions is advantageously chosen from hydroxide anions, halides, phosphates, sulphates, carbonates, hydrogenocarbonates, bisulphates, acetates, lactates, (C1-C4) alkyl sulphates, (C1-C4) alkyl- or alkyl (C1-C4) arylsulphonates. Examples of compounds of formula (I) that may be mentioned include tetraethylammonium, tetrabutylammonium, benzyltriethylammonium, benzyltrimethylammonium, benzyltributylammonium and tributylmethylammonium salts; the salts being chosen from hydroxides, bromides, fluorides, chlorides, sulphates, alkyl sulphates (methylethyl sulphates), hydrogen sulphates, monobasic phosphates, acetates, para-toluene sulphonates, or mixtures thereof. The content of compound (s) of formula (i) in the composition represents from 0.05 to 30% by weight, preferably from 0.1 to 25% by weight, better still from 0.5 to 20% by weight, more preferably from 1 to 15% by weight relative to the total weight of the composition.

Solvent: The composition according to the invention may also comprise one or more organic solvents.

By way of organic solvent, mention may be made, for example, of linear or branched C 2 -C 4 alkanols, such as ethanol and isopropanol; glycerol; polyols and polyol ethers such as 2-butoxyethanol, propylene glycol, dipropylene glycol, propylene glycol monomethyl ether, diethylene glycol monoethyl ether and monomethyl ether, and aromatic alcohols or ethers such as benzyl alcohol or phenoxyethanol, and mixtures thereof . The solvent or solvents, if present, represent a content usually ranging from 1 to 40% by weight relative to the weight of the composition and preferably from 5 to 30% by weight. Other additives: The composition according to the invention can also include various adjuvants conventionally used in compositions for dyeing hair, such as anionic, cationic, nonionic, amphoteric, zwitterionic polymers or mixtures thereof; mineral thickeners, and in particular fillers such as clays, talc; organic thickeners, in particular anionic, cationic, nonionic and amphoteric polymeric associative thickeners; antioxidants; penetrants; sequestering agents; perfumes ; dispersants; film-forming agents; ceramides; preservatives; opacifying agents.

The adjuvants above are generally present in an amount for each of them ranging from 0.01% to 20% by weight relative to the weight of the composition. The composition may in particular comprise one or more inorganic thickening agents chosen from organophilic clays, fumed silicas, or mixtures thereof.

The organophilic clay may be selected from montmorillonite, bentonite, hectorite, attapulgite, sepiolite, and mixtures thereof. The clay is preferably a bentonite or a hectorite. These clays can be modified with a chemical compound chosen from quaternary amines, tertiary amines, amino acetates, imidazolines, amine soaps, fatty sulphates, alkyl aryl sulphonates, amine oxides, and mixtures thereof.

As organophilic clays, mention may be made of quaternium-18 bentonites such as those sold under the names Bentone 3, Bentone 38, Bentone 38V by Rheox, Tixogel VP by United catalyst, Claytone 34, Claytone 40, Claytone XL by Southern Clay Company; stearalkonium bentonites such as those sold under the names Bentone 27 by Rheox, Tixogel LG by United Catalyst, Claytone AF, Claytone APA by Southern Clay; quaternium-18 / benzalkonium bentonite such as those sold under the names Claytone HT, Claytone PS by Southern Clay. The fumed silicas can be obtained by high temperature hydrolysis of a volatile silicon compound in an oxyhydrogen flame, producing a finely divided silica. This process makes it possible in particular to obtain hydrophilic silicas which have a large number of silanol groups on their surface. Such hydrophilic silicas are, for example, sold under the names "AEROSIL 130®", "AEROSIL 200®", "AEROSIL 255®", "AEROSIL 300®", "AEROSIL 380®" by the company Degussa, "CAB-O- SIL HS-5® "," CAB-O-SIL EH-5® "," CAB-O-SIL LM-130® "," CAB-O-SIL MS-55® "," CAB-O-SIL M -5® "by the company Cabot. It is possible to chemically modify the surface of the silica by chemical reaction in order to reduce the number of silanol groups. In particular, it is possible to substitute silanol groups with hydrophobic groups: a hydrophobic silica is then obtained. The hydrophobic groups may be: trimethylsiloxyl groups, which are especially obtained by treatment of fumed silica in the presence of hexamethyldisilazane. Silicas thus treated are called "silica silylate" according to the CTFA (6th edition, 1995). They are for example marketed under the references "AEROSIL R812®" by the company Degussa, "CAB-0-SIL TS-530®" by Cabot. - Dimethylsilyloxyl or polydimethylsiloxane groups, which are obtained in particular by treatment of fumed silica in the presence of polydimethylsiloxane or dimethyldichlorosilane. Silicas thus treated are called "Silica dimethyl silylate" according to the CTFA (6th edition, 1995). They are for example sold under the references "AEROSIL R972®", "AEROSIL R974®" by the company Degussa, "CAB-O-SIL TS-610®", "CAB-O-SIL TS-720®" by the company Pooch. The fumed silica preferably has a particle size that may be nanometric to micrometric, for example ranging from about 5 to 200 nm.

Preferably, the composition comprises a hectorite, an organomodified bentonite or an optionally modified pyrogenic silica.

When present, the mineral thickening agent represents from 1 to 30% by weight relative to the weight of the composition. The composition may also include one or more organic thickeners.

These thickening agents may be chosen from fatty acid amides (diethanol or coconut monoethanol amide, oxyethylenated alkyl ether carboxylic acid monoethanolamide), polymeric thickeners such as cellulosic thickeners (hydroxyethylcellulose, hydroxypropylcellulose, carboxymethylcellulose), guar gum and its derivatives (hydroxypropylguar), gums of microbial origin (xanthan gum, scleroglucan gum), crosslinked homopolymers of acrylic acid or acrylamidopropanesulfonic acid and associative polymers (polymers comprising hydrophilic zones, and fatty-chain hydrophobic zones (alkyl, alkenyl comprising at least 10 carbon atoms) capable, in an aqueous medium, of reversibly associating with each other or with other molecules).

According to one particular embodiment, the organic thickener is chosen from cellulose thickeners (hydroxyethylcellulose, hydroxypropylcellulose, carboxymethylcellulose), guar gum and its derivatives (hydroxypropylguar), gums of microbial origin (xanthan gum, scleroglucan gum). ), the crosslinked homopolymers of acrylic acid or acrylamidopropanesulfonic acid, and preferably from cellulosic thickeners with in particular hydroxyethylcellulose. The content of organic thickening agent (s), if present, usually ranges from 0.01% to 20% by weight, based on the weight of the composition, preferably from 0.1 to 5% by weight.

The composition of the invention may be in various forms, such as, for example, a solution, an emulsion (milk or cream) or a gel. Processes of the invention: The composition according to the invention is applied to dry or moist keratinous fibers. It is usually left in place on the fibers for a period, generally, from 1 minute to 1 hour, preferably from 5 minutes to 30 minutes. The temperature during the dyeing process is typically between room temperature (between 15 and 25 ° C) and 80 ° C, preferably between room temperature and 60 ° C.

At the end of the treatment, the human keratinous fibers are advantageously rinsed with water. They can optionally be washed with a shampoo followed by rinsing with water, before being dried or allowed to dry.

The composition according to the invention is generally prepared by mixing at least two compositions, preferably two or three compositions. In a first variant of the invention, the composition according to the invention is derived from the mixture of two compositions.

In particular, a composition (A) comprising at least one dye of keratinous fibers and at least one basifying agent and a composition (B) comprising at least one chemical oxidizing agent are mixed; at least one of compositions (A) and (B) comprising at least one fatty substance, at least one surfactant, and at least one compound of formula (i) the fat content of the composition according to the invention, resulting from the mixture of compositions (A) and (B) comprising at least 25% by weight of fat. At least one of the compositions (A) and (B) is advantageously aqueous. By aqueous composition is meant a composition comprising at least 5% by weight of water, relative to the weight of this composition.

Preferably, an aqueous composition comprises more than 10% by weight of water, and still more preferably more than 20% by weight of water. Preferably the composition (A) is aqueous. Preferably the composition (B) is also aqueous. In this variant, the composition (A) preferably comprises at least 50% by weight of fatty substances, and even more preferably at least 50% by weight of liquid fatty substances at ambient temperature (25 ° C.), relative to the weight of this composition (A). Preferably the composition (A) is an emulsion, direct (oil in water, H / E) or inverse (water in oil, W / O), and preferably direct (O / W).

In this variant the compositions (A) and (B) are preferably mixed in a weight ratio (A) / (B) ranging from 0.2 to 0.5 to 2 better. In a second variant of the invention the composition according to the invention is derived from the mixture of three compositions. In particular, the three compositions are aqueous or at least one of them is anhydrous.

More particularly, the term "anhydrous cosmetic composition" in the meaning of the invention is intended to mean a cosmetic composition having a water content of less than 5% by weight, preferably less than 2% by weight and even more preferably less than 1% by weight. % by weight, based on the weight of said composition. It should be noted that the water present in the composition is more particularly "bound water", as the water of crystallization of the salts or traces of water absorbed by the raw materials used in the production of the compositions according to the invention. 'invention. Preferably, two aqueous compositions (B ') and (C') and an anhydrous composition (A ') are used.

The anhydrous composition (A ') then preferably comprises at least one fatty substance, and more preferably at least one liquid fatty substance. The composition (B ') then preferably comprises at least one dye of the keratinous fibers. The composition (C ') then preferably comprises at least one chemical oxidizing agent. According to this preferred embodiment of the second variant, the alkalinizing agent (s) are included in the compositions (A ') and / or (B') and preferably only in the composition (B '). With regard to the surfactant (s) and the compound (s) of formula (i), at least each of them is included in at least one of the compositions (A '), (B') and ( C '). According to this preferred embodiment, the composition according to the invention, that is to say derived from the mixture of the three compositions (A '), (B') and (C '), has a fat content of at least 25% by weight of fatty substance, relative to the weight of the composition resulting from the mixture of the three aforementioned compositions. In this variant, the compositions (Al, (B ') and (C') are preferably mixed in a weight ratio [(A ') + (B')] / (C ') ranging from 0.2 to 10, more particularly from 0.5 to 2 and in a weight ratio (A ') / (B') ranging from 0.5 to 10, preferably from 1 to 5. Devices: Finally, the invention relates to a first device for several compartments comprising a first compartment containing the composition (A) as described above and at least one second compartment containing the composition (B) as described above, the compositions (A) and (B) of the compartments being intended to be mixed before application, to give a composition according to the invention, the amount of fat represents at least 25% by weight relative to the weight of the formulation from the mixture of compositions (A) and (B). invention also relates to a second multi-compartment device comprising a first compartment containing a nt the composition (A ') as described above and a second compartment containing a cosmetic composition (B') as described above and at least a third compartment comprising the composition (C ') as described above, the compositions compartments being intended to be mixed before application, to give the composition according to the invention; the amount of fatty substance in the composition representing at least 25% by weight relative to the weight of the composition according to the invention, that is to say from the mixture of the compositions (A '), (B') and ( C '). The following examples serve to illustrate the invention without being limiting in nature. EXAMPLE 1 The following compositions are prepared in which the quantities are expressed in grams of product as such). Composition A Petrolatum oil 64.5 Octyl-2 dodecanol 11.5 Modified distearyl dimethyl ammonium hectorite 3 Propylene carbonate 1 Sorbitan mono-laurate oxyethylenated (40E) 11 Glycol distearate 8 Oxyethylenated lauryl alcohol (20E) 1 Composition Composition B1 B2 Propylene glycol 6.2 6.2 Ethyl alcohol 8.25 8.25 Hexylene glycol (2 methyl -2,4 pentanediol) 3 3 Dipropylene glycol 3 3 Monoethanolamine 14.5 14.5 Sodium metabisulfite 0.7 0.7 Vitamin C: L-ascorbic acid 0.25 0.25 Diethylene triamine pentaacetic acid, salt 1 1 pentasodium in 40% aqueous solution Hydroxyethyl cellulose (Natrosol 250 HHR, Aqualon) 3.5 3.5 2 - [(3-Aminopyrazolo [ 1,5-a] pyridin-2-yl) oxy] ethanol 2 10-2 moles 2 10-2 moles hydrochloride Thymol 2 10-2 moles 2 10-2 moles Tetrabutylammonium sulfate 25 - Water Qsp 100g Qsp 100g Composition C ( oxidant) Cetylstearyl alcohol (Nafol 1618F) 8 Glycerine 0.5 Vaseline oil 20 Cetylstearyl alcohol oxyethylenated (33 0E) 3 Amide of oxyethylenated rapeseed acids (40E) 1.2 Tetrasodium pyrophosphate 0.03 Diethylene triamine pentaacetic acid, 0.15 pentasodium salt in 40% aqueous solution Phosphoric acid 0.1 Polycondensate tetramethyl hexamethylenediamine / 0.1 dichloro 1,3 -propylene (40% aqueous solution) Polydimethyl diallyl ammonium chloride (40% aqueous solution) Hydrogen peroxide 50% aqueous solution 6 Sodium stannate 0.04 Vitamin E 0.1 Phosphoric acid Qs pH 2.2 water Qsp 100 g At the time of use, the following are mixed (by weight): - 10 parts of the composition A - 4 parts of the composition B1 or the composition B2 - 16 parts of the composition C The mixture obtained is then applied on strands of natural hair with 90% natural white hair. The "mixing / wicking" bath ratio is 10/1 (g / g), respectively.

The exposure time is 30 minutes at 27 ° C. At the end of this time, the locks are rinsed, then washed with shampoo and dried. The rise in staining (AEab *) was evaluated in the CIE L * a * b * system.

In this system L * a * b *, L * represents the intensity of the color, a * indicates the green / red color axis and b * the blue / yellow color axis. The lower the value of L *, the darker or more intense the color. The value of AE * was calculated from the values of L * a * b * according to the following equation (i): AE * = V (L * -Lo *) 2 + (a * - ao *) 2 + (b * -bo *) (i) The increase in staining (AELab *) was calculated on untreated locks of hair (Lo *, ao * and bo *) and on locks of colored hair (L *, a * and b *). The higher the value of AEab *, the better the climb.

Results Composition L * a * B * AE * Gain in AE * 57.93 0.76 14.32 ---- B1 32.48 14.21 7.68 29.54 7.1 B2 39.75 13.19 10.03 22.44 It is observed that in the presence of the compound of formula (i ) according to the invention, the rise of the coloring on wick is significantly improved. EXAMPLE 2 The following compositions are prepared in which the amounts are expressed in grams of active materials).

Composition A Petrolatum oil 64.5 Octyl-2 dodecanol 11.5 Modified distearyl dimethyl ammonium hectorite 3 Propylene carbonate 1 Sorbitan mono-laurate oxyethylenated (40E) 11 Glycol distearate 8 Oxyethylenated lauryl alcohol (20E) 1 Composition Composition B1 B2 Propylene glycol 6.2 6.2 Ethyl alcohol 8.25 8.25 Hexylene glycol (2 methyl -2,4 pentanediol) 3 3 Dipropylene glycol 3 3 Monoethanolamine 14.5 14.5 Sodium metabisulfite 0.7 0.7 Vitamin C: L-ascorbic acid 0.25 0.25 Diethylene triamine pentaacetic acid, salt 1 1 pentasodium in 40% aqueous solution Hydroxyethyl cellulose (Natrosol 250 HHR, Aqualon) 3.5 3.5 Direct Red 17 3 3 Tetrabutylammonium sulphate 25 - Water Qsp 100g Qsp 100g Composition C (oxidizing agent) Cetylstearyl alcohol (Nafol 1618F) 8 Glycerine 0.5 Vaseline oil 20 Cetylstearyl alcohol oxyethylenated (33 0E) 3 Amide of oxyethylenated (40E) 1,2-pyrophosphate rapeseed acids tetrasodium 0.03 Diethylene triamine acid Pentacetic acid, 0.15 pentasodium salt in 40% aqueous solution Phosphoric acid 0.1 Polycondensate tetramethyl hexamethylenediamine / 0.1 dichloro 1,3-propylene (40% aqueous solution) Polydimethyl diallyl ammonium chloride (aqueous 0.2 40%) Hydrogen peroxide in 50% aqueous solution 6 Sodium stannate 0.04 Vitamin E 0.1 Phosphoric acid Qs pH 2.2 water Qsp 100g At the time of use, mix (by weight): - 10 parts of composition A - 4 parts of composition B1 or composition B2 - 16 parts of composition C The mixture obtained is then applied to strands of natural hair with 90% natural white hair. The "mixing / wicking" bath ratio is 10/1 (g / g), respectively.

The exposure time is 30 minutes at 27 ° C. At the end of this time, the locks are rinsed, then washed with shampoo and dried. The rise in staining (AEab *) was evaluated in the CIE L * a * b * system.

In this system L * a * b *, L * represents the intensity of the color, a * indicates the green / red color axis and b * the blue / yellow color axis. The lower the value of L *, the darker or more intense the color. The value of AE * was calculated from the values of L * a * b * according to the following equation (i): AE * = V (L * -Lo *) 2 + (a * - ao *) 2 + (b * -bo *) (i) The increase in staining (AELab *) was calculated on untreated locks of hair (Lo *, ao * and bo *) and on locks of colored hair (L *, a * and b *). The higher the value of AEab *, the better the climb.

Results Composition L * a * B * AE * Gain in AE * 57.93 0.76 14.32 ---- B1 51.09 22.86 5.38 24.81 8.74 B2 57.16 15.89 8.99 16.07 It is observed that in the presence of the compound of formula (i ) according to the invention, the rise of the coloring on wick is significantly improved.

Claims (20)

REVENDICATIONS1. Coloring composition for keratinous fibers, in particular human keratin fibers, comprising: one or more fatty substances, one or more surfactants, one or more keratinic fiber dyes, one or more alkalinizing agents, one or more oxidizing agents chemical, - one or more cationic compounds of formula (I) below: R2 + X R4 N -R3 R1 in which the radicals R1, R2, R3 and R4, which may be identical or different, represent an optionally substituted C1-C8 alkyl radical, optionally interrupted by one or more heteroatoms; an optionally substituted C2-C8 alkenyl radical, optionally interrupted by one or more heteroatoms; an optionally substituted benzyl radical; X- representing a cosmetically acceptable anion or mixture of anions, ensuring the electroneutrality of formula (i) - the fat content representing in total at least 25% by weight relative to the total weight of the composition, 2. Composition according to the preceding claim, characterized in that the one or more fatty substances are chosen from C6-C16 hydrocarbons, hydrocarbons containing more than 16 carbon atoms, non-silicone oils of animal origin, vegetable oils from triglycerides, synthetic triglycerides, fluorinated oils, fatty alcohols, fatty acid esters and / or fatty alcohol esters other than triglycerides and vegetable waxes, non-silicone waxes, silicones. 3. Composition according to any one of the preceding claims, characterized in that the one or more fatty substances are liquid at ambient temperature and at atmospheric pressure. 4. Composition according to any one of the preceding claims, characterized in that the fatty substance or fats are chosen from petrolatum oil, C6-C16 alkanes, polydecenes, esters of fatty acids or alcohols. fatty, liquid, or mixtures thereof. 5. Composition according to any one of the preceding claims, characterized in that the concentration of fatty substance ranges from 25 to 80% by weight, preferably from 30 to 70% by weight, still more advantageously from 30 to 60% by weight. relative to the total weight of the composition. 6. Composition according to any one of the preceding claims, characterized in that the surfactant or surfactants are chosen from nonionic surfactants, preferably mono- or polyoxyalkylenated and mono- or polyglycerolated nonionic surfactants. 7. Composition according to any one of the preceding claims, characterized in that the dye (s) of the keratinous fibers are chosen from synthetic direct dyes. 8. Composition according to any one of claims 1 to 6, characterized in that the dye (s) of the keratinous fibers are chosen from oxidation bases and couplers. 9. Composition according to the preceding claim, characterized in that the oxidation base (s) are chosen from para-phenylenediamines, bisphenylalkylenediamines, para-aminophenols, ortho-aminophenols, heterocyclic bases and their addition salts. 10. Composition according to any one of claims 1 to 6, characterized in that the dye (s) of the keratinous fibers are chosen from natural dyes. 11. Composition according to any one of the preceding claims, characterized in that the dye (s) of the keratinous fibers have a logP greater than or equal to 1.5 and preferably greater than or equal to 2. 12. Composition according to any one of the preceding claims, characterized in that the compound (s) of formula (i) are chosen from tetraethylammonium salts, tetrabutylammonium, benzyltriethylammonium, benzyltrimethylammonium, benzyltributylammonium, tributylmethylammonium; the salts being chosen from hydroxides, bromides, fluorides, chlorides, sulphates, alkyl sulphates (methyl ethyl sulphates), hydrogen sulphates, monobasic phosphates, acetates, para-toluene sulphonates, or mixtures thereof. 13. Composition according to any one of the preceding claims, characterized in that the alkalinizing agent (s) are inorganic, organic or hybrid and preferably chosen from ammonia, alkali carbonates or bicarbonates, such as sodium carbonates or bicarbonates or potassium hydroxides, sodium or potassium hydroxides, organic amines chosen from alkanolamines, ethylenediamines which are oxyethylenated and / or oxypropylenated, amino acids and compounds of formula (I) or mixtures thereof: ## STR2 ## (I) formula (I) wherein W is a divalent C1-C6 alkylene radical optionally substituted by one or more hydroxyl groups or a C1-C6 alkyl radical, and / or optionally interrupted by one or more heteroatoms such as O, or NR '; Rx, Ry, Rz, Rt, R, and the same or different, represent a hydrogen atom, a C1-C6 alkyl or C1-C6 hydroxyalkyl, C1-C6 aminoalkyl. 14. Composition according to the preceding claim, wherein the alkalinizing agent (s) are chosen from alkanolamines, amino acids in neutral or ionic form and preferably from alkanolamines. 15. Composition according to any one of the preceding claims, characterized in that the chemical oxidizing agent is hydrogen peroxide. 16. A process for dyeing keratinous fibers, in particular human keratinous fibers, comprising applying to said fibers a composition according to any one of claims 1 to 15. 17. Method according to the preceding claim, characterized in that the composition is derived from the mixture of two compositions; preferably a composition (A) comprising at least one keratinous fiber dye and at least one basifying agent and a composition (B) comprising at least one chemical oxidizing agent, at least one of compositions (A) and (B) ) comprising at least one fatty substance, at least one surfactant and at least one compound of formula (i); the fat content of the composition resulting from the mixture of compositions (A) and (B) comprising at least 25% by weight of fat. 18. The method of claim 16, characterized in that the composition is derived from the mixture of three compositions, preferably two aqueous compositions (B ') and (C') and an anhydrous composition (A '), the composition anhydrous composition (A ') comprising at least one fatty substance, the composition (B') comprising at least one dye of the keratinous fibers, the composition (C ') comprising at least one chemical oxidizing agent, one or more alkalinizing agents being included in the compositions (A ') and / or (B') and preferably only in the compositions (B '), one or more surface-active agents and at least one compound of formula (i) being included in at least one of the compositions ( A '), (B') and (C '), the fat content of the composition resulting from the mixture of the three compositions (A'), (B ') and (C') comprising at least 25% by weight of fat body. 19. Multi-compartment device comprising a first compartment containing the composition (A) as in claim 17 and at least a second compartment containing the composition (B) as described in claim 17, the compositions of the compartments being intended to be mixed before application, provided that the amount of fatty substance represents at least 25% by weight relative to the weight of the composition resulting from the mixture of (A) and (B) 20. Multi-compartment device comprising a first compartment containing the composition (A ') as described in claim 18; and a second compartment containing a cosmetic composition (B ') as described in claim 18 and at least one third compartment comprising the composition (C') as described in claim 18; the compositions of the compartments being intended to be mixed before application provided that the amount of fatty substance represents at least 25% by weight relative to the weight of the composition resulting from the mixture of (A '), (B') and (C ') ') .15