FR2979630B1 - Copolymeres a blocs dont un polyanionique base sur un monomere anion de type tfsili comme electrolyte de batterie. - Google Patents

Copolymeres a blocs dont un polyanionique base sur un monomere anion de type tfsili comme electrolyte de batterie.

Info

Publication number
FR2979630B1
FR2979630B1 FR1157841A FR1157841A FR2979630B1 FR 2979630 B1 FR2979630 B1 FR 2979630B1 FR 1157841 A FR1157841 A FR 1157841A FR 1157841 A FR1157841 A FR 1157841A FR 2979630 B1 FR2979630 B1 FR 2979630B1
Authority
FR
France
Prior art keywords
tfsili
polyanionic
block copolymers
electrolyte battery
monomer type
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
FR1157841A
Other languages
English (en)
French (fr)
Other versions
FR2979630A1 (fr
Inventor
Renaud Bouchet
Abdelmaula Aboulaich
Sebastien Maria
Trang Phan
Didier Gigmes
Denis Bertin
Rachid Meziane
Jean Pierre Bonnet
Michel Armand
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Aix Marseille Universite
Original Assignee
Universite de Provence Aix Marseille I
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to FR1157841A priority Critical patent/FR2979630B1/fr
Application filed by Universite de Provence Aix Marseille I filed Critical Universite de Provence Aix Marseille I
Priority to ES12773016.6T priority patent/ES2560406T3/es
Priority to CA2846267A priority patent/CA2846267C/fr
Priority to EP12773016.6A priority patent/EP2753656B1/fr
Priority to KR1020147009099A priority patent/KR101927267B1/ko
Priority to PCT/FR2012/051982 priority patent/WO2013034848A1/fr
Priority to US14/239,905 priority patent/US9431677B2/en
Priority to JP2014527725A priority patent/JP6243842B2/ja
Priority to CN201280043240.9A priority patent/CN103874724B/zh
Publication of FR2979630A1 publication Critical patent/FR2979630A1/fr
Application granted granted Critical
Publication of FR2979630B1 publication Critical patent/FR2979630B1/fr
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/05Accumulators with non-aqueous electrolyte
    • H01M10/056Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
    • H01M10/0564Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of organic materials only
    • H01M10/0565Polymeric materials, e.g. gel-type or solid-type
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F293/00Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule
    • C08F293/005Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule using free radical "living" or "controlled" polymerisation, e.g. using a complexing agent
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/20Manufacture of shaped structures of ion-exchange resins
    • C08J5/22Films, membranes or diaphragms
    • C08J5/2206Films, membranes or diaphragms based on organic and/or inorganic macromolecular compounds
    • C08J5/2218Synthetic macromolecular compounds
    • C08J5/2231Synthetic macromolecular compounds based on macromolecular compounds obtained by reactions involving unsaturated carbon-to-carbon bonds
    • C08J5/2243Synthetic macromolecular compounds based on macromolecular compounds obtained by reactions involving unsaturated carbon-to-carbon bonds obtained by introduction of active groups capable of ion-exchange into compounds of the type C08J5/2231
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/05Accumulators with non-aqueous electrolyte
    • H01M10/052Li-accumulators
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/05Accumulators with non-aqueous electrolyte
    • H01M10/056Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
    • H01M10/0561Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of inorganic materials only
    • H01M10/0562Solid materials
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/36Selection of substances as active materials, active masses, active liquids
    • H01M4/38Selection of substances as active materials, active masses, active liquids of elements or alloys
    • H01M4/381Alkaline or alkaline earth metals elements
    • H01M4/382Lithium
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/36Selection of substances as active materials, active masses, active liquids
    • H01M4/58Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
    • H01M4/5825Oxygenated metallic salts or polyanionic structures, e.g. borates, phosphates, silicates, olivines
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2438/00Living radical polymerisation
    • C08F2438/02Stable Free Radical Polymerisation [SFRP]; Nitroxide Mediated Polymerisation [NMP] for, e.g. using 2,2,6,6-tetramethylpiperidine-1-oxyl [TEMPO]
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2353/00Characterised by the use of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Derivatives of such polymers
    • C08J2353/02Characterised by the use of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Derivatives of such polymers of vinyl aromatic monomers and conjugated dienes
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2387/00Characterised by the use of unspecified macromolecular compounds, obtained otherwise than by polymerisation reactions only involving unsaturated carbon-to-carbon bonds
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M2300/00Electrolytes
    • H01M2300/0017Non-aqueous electrolytes
    • H01M2300/0065Solid electrolytes
    • H01M2300/0082Organic polymers
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Manufacturing & Machinery (AREA)
  • Inorganic Chemistry (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • General Physics & Mathematics (AREA)
  • Physics & Mathematics (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • Dispersion Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Graft Or Block Polymers (AREA)
  • Secondary Cells (AREA)
  • Battery Electrode And Active Subsutance (AREA)
FR1157841A 2011-09-05 2011-09-05 Copolymeres a blocs dont un polyanionique base sur un monomere anion de type tfsili comme electrolyte de batterie. Expired - Fee Related FR2979630B1 (fr)

Priority Applications (9)

Application Number Priority Date Filing Date Title
FR1157841A FR2979630B1 (fr) 2011-09-05 2011-09-05 Copolymeres a blocs dont un polyanionique base sur un monomere anion de type tfsili comme electrolyte de batterie.
CA2846267A CA2846267C (fr) 2011-09-05 2012-09-05 Copolymeres a blocs dont un polyanionique base sur un monomere anion de type tfsili comme electrolyte de batterie
EP12773016.6A EP2753656B1 (fr) 2011-09-05 2012-09-05 COPOLYMERES A BLOCS DONT UN POLYANIONIQUE BASE SUR UN MONOMERE ANION DE TYPE TFSILi COMME ELECTROLYTE DE BATTERIE
KR1020147009099A KR101927267B1 (ko) 2011-09-05 2012-09-05 배터리 전해질로서 tfsili 음이온 단량체에 기초한 다가음이온을 함유하는 블록 공중합체
ES12773016.6T ES2560406T3 (es) 2011-09-05 2012-09-05 Copolímeros de bloque que incluyen un polianiónico basado en un monómero anión de tipo TFSILi como electrolito de batería
PCT/FR2012/051982 WO2013034848A1 (fr) 2011-09-05 2012-09-05 COPOLYMERES A BLOCS DONT UN POLYANIONIQUE BASE SUR UN MONOMERE ANION DE TYPE TFSILi COMME ELECTROLYTE DE BATTERIE
US14/239,905 US9431677B2 (en) 2011-09-05 2012-09-05 Block copolymer including a polyanion based on a TFSILi anion monomer as a battery electrolyte
JP2014527725A JP6243842B2 (ja) 2011-09-05 2012-09-05 電池電解液としてTFSI−Liアニオンモノマーに基づくポリアニオンを含むブロックコポリマー
CN201280043240.9A CN103874724B (zh) 2011-09-05 2012-09-05 作为电池电解质的包含基于TFSILi阴离子单体的聚阴离子的嵌段共聚物

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR1157841A FR2979630B1 (fr) 2011-09-05 2011-09-05 Copolymeres a blocs dont un polyanionique base sur un monomere anion de type tfsili comme electrolyte de batterie.

Publications (2)

Publication Number Publication Date
FR2979630A1 FR2979630A1 (fr) 2013-03-08
FR2979630B1 true FR2979630B1 (fr) 2013-10-04

Family

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FR1157841A Expired - Fee Related FR2979630B1 (fr) 2011-09-05 2011-09-05 Copolymeres a blocs dont un polyanionique base sur un monomere anion de type tfsili comme electrolyte de batterie.

Country Status (9)

Country Link
US (1) US9431677B2 (enExample)
EP (1) EP2753656B1 (enExample)
JP (1) JP6243842B2 (enExample)
KR (1) KR101927267B1 (enExample)
CN (1) CN103874724B (enExample)
CA (1) CA2846267C (enExample)
ES (1) ES2560406T3 (enExample)
FR (1) FR2979630B1 (enExample)
WO (1) WO2013034848A1 (enExample)

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CA2846267A1 (fr) 2013-03-14
CN103874724A (zh) 2014-06-18
EP2753656B1 (fr) 2015-11-04
KR101927267B1 (ko) 2018-12-10
JP2014529863A (ja) 2014-11-13
JP6243842B2 (ja) 2017-12-06
KR20140061501A (ko) 2014-05-21
US9431677B2 (en) 2016-08-30
FR2979630A1 (fr) 2013-03-08
CN103874724B (zh) 2016-10-19
ES2560406T3 (es) 2016-02-18
EP2753656A1 (fr) 2014-07-16
CA2846267C (fr) 2019-10-29
US20140272600A1 (en) 2014-09-18

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