FR2979630B1 - Copolymeres a blocs dont un polyanionique base sur un monomere anion de type tfsili comme electrolyte de batterie. - Google Patents

Copolymeres a blocs dont un polyanionique base sur un monomere anion de type tfsili comme electrolyte de batterie.

Info

Publication number
FR2979630B1
FR2979630B1 FR1157841A FR1157841A FR2979630B1 FR 2979630 B1 FR2979630 B1 FR 2979630B1 FR 1157841 A FR1157841 A FR 1157841A FR 1157841 A FR1157841 A FR 1157841A FR 2979630 B1 FR2979630 B1 FR 2979630B1
Authority
FR
France
Prior art keywords
tfsili
polyanionic
block copolymers
electrolyte battery
monomer type
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
FR1157841A
Other languages
English (en)
French (fr)
Other versions
FR2979630A1 (fr
Inventor
Renaud Bouchet
Abdelmaula Aboulaich
Sebastien Maria
Trang Phan
Didier Gigmes
Denis Bertin
Rachid Meziane
Jean Pierre Bonnet
Michel Armand
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Aix-Marseille Université
Original Assignee
Universite de Provence Aix Marseille I
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to FR1157841A priority Critical patent/FR2979630B1/fr
Application filed by Universite de Provence Aix Marseille I filed Critical Universite de Provence Aix Marseille I
Priority to CN201280043240.9A priority patent/CN103874724B/zh
Priority to EP12773016.6A priority patent/EP2753656B1/fr
Priority to PCT/FR2012/051982 priority patent/WO2013034848A1/fr
Priority to US14/239,905 priority patent/US9431677B2/en
Priority to ES12773016.6T priority patent/ES2560406T3/es
Priority to CA2846267A priority patent/CA2846267C/fr
Priority to KR1020147009099A priority patent/KR101927267B1/ko
Priority to JP2014527725A priority patent/JP6243842B2/ja
Publication of FR2979630A1 publication Critical patent/FR2979630A1/fr
Application granted granted Critical
Publication of FR2979630B1 publication Critical patent/FR2979630B1/fr
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

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Classifications

    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/056—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
    • H01M10/0564—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of organic materials only
    • H01M10/0565—Polymeric materials, e.g. gel-type or solid-type
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F293/00—Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule
    • C08F293/005—Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule using free radical "living" or "controlled" polymerisation, e.g. using a complexing agent
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/20—Manufacture of shaped structures of ion-exchange resins
    • C08J5/22—Films, membranes or diaphragms
    • C08J5/2206—Films, membranes or diaphragms based on organic and/or inorganic macromolecular compounds
    • C08J5/2218—Synthetic macromolecular compounds
    • C08J5/2231—Synthetic macromolecular compounds based on macromolecular compounds obtained by reactions involving unsaturated carbon-to-carbon bonds
    • C08J5/2243—Synthetic macromolecular compounds based on macromolecular compounds obtained by reactions involving unsaturated carbon-to-carbon bonds obtained by introduction of active groups capable of ion-exchange into compounds of the type C08J5/2231
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/052—Li-accumulators
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/056—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
    • H01M10/0561—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of inorganic materials only
    • H01M10/0562—Solid materials
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/38—Selection of substances as active materials, active masses, active liquids of elements or alloys
    • H01M4/381—Alkaline or alkaline earth metals elements
    • H01M4/382—Lithium
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
    • H01M4/5825—Oxygenated metallic salts or polyanionic structures, e.g. borates, phosphates, silicates, olivines
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2438/00—Living radical polymerisation
    • C08F2438/02—Stable Free Radical Polymerisation [SFRP]; Nitroxide Mediated Polymerisation [NMP] for, e.g. using 2,2,6,6-tetramethylpiperidine-1-oxyl [TEMPO]
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2353/00—Characterised by the use of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Derivatives of such polymers
    • C08J2353/02—Characterised by the use of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Derivatives of such polymers of vinyl aromatic monomers and conjugated dienes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2387/00—Characterised by the use of unspecified macromolecular compounds, obtained otherwise than by polymerisation reactions only involving unsaturated carbon-to-carbon bonds
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M2300/00—Electrolytes
    • H01M2300/0017—Non-aqueous electrolytes
    • H01M2300/0065—Solid electrolytes
    • H01M2300/0082—Organic polymers
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10—Energy storage using batteries

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • General Chemical & Material Sciences (AREA)
  • Electrochemistry (AREA)
  • Manufacturing & Machinery (AREA)
  • Inorganic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • General Physics & Mathematics (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Dispersion Chemistry (AREA)
  • Graft Or Block Polymers (AREA)
  • Secondary Cells (AREA)
  • Battery Electrode And Active Subsutance (AREA)
FR1157841A 2011-09-05 2011-09-05 Copolymeres a blocs dont un polyanionique base sur un monomere anion de type tfsili comme electrolyte de batterie. Expired - Fee Related FR2979630B1 (fr)

Priority Applications (9)

Application Number Priority Date Filing Date Title
FR1157841A FR2979630B1 (fr) 2011-09-05 2011-09-05 Copolymeres a blocs dont un polyanionique base sur un monomere anion de type tfsili comme electrolyte de batterie.
EP12773016.6A EP2753656B1 (fr) 2011-09-05 2012-09-05 COPOLYMERES A BLOCS DONT UN POLYANIONIQUE BASE SUR UN MONOMERE ANION DE TYPE TFSILi COMME ELECTROLYTE DE BATTERIE
PCT/FR2012/051982 WO2013034848A1 (fr) 2011-09-05 2012-09-05 COPOLYMERES A BLOCS DONT UN POLYANIONIQUE BASE SUR UN MONOMERE ANION DE TYPE TFSILi COMME ELECTROLYTE DE BATTERIE
US14/239,905 US9431677B2 (en) 2011-09-05 2012-09-05 Block copolymer including a polyanion based on a TFSILi anion monomer as a battery electrolyte
CN201280043240.9A CN103874724B (zh) 2011-09-05 2012-09-05 作为电池电解质的包含基于TFSILi阴离子单体的聚阴离子的嵌段共聚物
ES12773016.6T ES2560406T3 (es) 2011-09-05 2012-09-05 Copolímeros de bloque que incluyen un polianiónico basado en un monómero anión de tipo TFSILi como electrolito de batería
CA2846267A CA2846267C (fr) 2011-09-05 2012-09-05 Copolymeres a blocs dont un polyanionique base sur un monomere anion de type tfsili comme electrolyte de batterie
KR1020147009099A KR101927267B1 (ko) 2011-09-05 2012-09-05 배터리 전해질로서 tfsili 음이온 단량체에 기초한 다가음이온을 함유하는 블록 공중합체
JP2014527725A JP6243842B2 (ja) 2011-09-05 2012-09-05 電池電解液としてＴＦＳＩ−Ｌｉアニオンモノマーに基づくポリアニオンを含むブロックコポリマー

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR1157841A FR2979630B1 (fr) 2011-09-05 2011-09-05 Copolymeres a blocs dont un polyanionique base sur un monomere anion de type tfsili comme electrolyte de batterie.

Publications (2)

Publication Number Publication Date
FR2979630A1 FR2979630A1 (fr) 2013-03-08
FR2979630B1 true FR2979630B1 (fr) 2013-10-04

Family

ID=47022950

Family Applications (1)

Application Number Title Priority Date Filing Date
FR1157841A Expired - Fee Related FR2979630B1 (fr) 2011-09-05 2011-09-05 Copolymeres a blocs dont un polyanionique base sur un monomere anion de type tfsili comme electrolyte de batterie.

Country Status (9)

Country Link
US (1) US9431677B2 (enExample)
EP (1) EP2753656B1 (enExample)
JP (1) JP6243842B2 (enExample)
KR (1) KR101927267B1 (enExample)
CN (1) CN103874724B (enExample)
CA (1) CA2846267C (enExample)
ES (1) ES2560406T3 (enExample)
FR (1) FR2979630B1 (enExample)
WO (1) WO2013034848A1 (enExample)

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EP2753656B1 (fr) 2015-11-04
WO2013034848A1 (fr) 2013-03-14
EP2753656A1 (fr) 2014-07-16
US9431677B2 (en) 2016-08-30
CN103874724A (zh) 2014-06-18
KR101927267B1 (ko) 2018-12-10
KR20140061501A (ko) 2014-05-21
US20140272600A1 (en) 2014-09-18
CA2846267A1 (fr) 2013-03-14
CN103874724B (zh) 2016-10-19
FR2979630A1 (fr) 2013-03-08
ES2560406T3 (es) 2016-02-18

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