MX2013008751A - Copolimeros tribloque conicos. - Google Patents
Copolimeros tribloque conicos.Info
- Publication number
- MX2013008751A MX2013008751A MX2013008751A MX2013008751A MX2013008751A MX 2013008751 A MX2013008751 A MX 2013008751A MX 2013008751 A MX2013008751 A MX 2013008751A MX 2013008751 A MX2013008751 A MX 2013008751A MX 2013008751 A MX2013008751 A MX 2013008751A
- Authority
- MX
- Mexico
- Prior art keywords
- block
- conjugated diene
- tapered triblock
- monovinyl aromatic
- forming
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F297/00—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
- C08F297/02—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type
- C08F297/04—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type polymerising vinyl aromatic monomers and conjugated dienes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L95/00—Compositions of bituminous materials, e.g. asphalt, tar, pitch
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J153/00—Adhesives based on block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Adhesives based on derivatives of such polymers
- C09J153/02—Vinyl aromatic monomers and conjugated dienes
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S525/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S525/94—Hydrogenation of a polymer
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Civil Engineering (AREA)
- Engineering & Computer Science (AREA)
- Inorganic Chemistry (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Graft Or Block Polymers (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Sealing Material Composition (AREA)
Abstract
Un copolímero tribloque cónico que tiene distribución de vinilo controlada, bloque medio alargado con composición y estructura intermedia, aumento de compatibilidad entre sus bloques adyacentes, buenas características de procesamiento y un peso molecular promedio pico entre 25,000 y 300,000 es hecho mediante la polimerización de monómeros de dieno conjugado y de aromático de monovinilo, modificador polar e iniciador para hacer un primer bloque rico en dieno conjugado, formando un segundo bloque es un copolímero del monómero de dieno conjugado y de aromático de monovinilo y que es menos rico en dieno conjugado que el primer bloque, y formando un tercer bloque que es un homopolímero del monómero aromático de monovinilo. El primero, segundo y tercer bloques comprenden de 30 a 60, 20 a 50% por peso y 10 a 40% por peso del copolímero tribloque cónico, respectivamente. Los copolímeros tribloque cónicos se pueden usar como modificadores de asfalto, adhesivos, selladores, compatibilizadores, agentes de refuerzo y modificadores de impacto.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US201161437671P | 2011-01-30 | 2011-01-30 | |
PCT/IB2012/000244 WO2012101516A2 (en) | 2011-01-30 | 2012-01-30 | Tapered triblock copolymers |
Publications (1)
Publication Number | Publication Date |
---|---|
MX2013008751A true MX2013008751A (es) | 2014-03-12 |
Family
ID=46577859
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
MX2013008751A MX2013008751A (es) | 2011-01-30 | 2012-01-30 | Copolimeros tribloque conicos. |
Country Status (7)
Country | Link |
---|---|
US (1) | US8981008B2 (es) |
EP (1) | EP2668214B1 (es) |
CN (5) | CN103347912B (es) |
ES (1) | ES2611335T3 (es) |
MX (1) | MX2013008751A (es) |
PL (1) | PL2668214T3 (es) |
WO (1) | WO2012101516A2 (es) |
Families Citing this family (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP5992312B2 (ja) | 2012-12-07 | 2016-09-14 | クレイトン・ポリマーズ・ユー・エス・エル・エル・シー | 塗装面の保護フィルム用粘着剤組成物およびその調製方法 |
JP6026255B2 (ja) | 2012-12-07 | 2016-11-16 | クレイトン・ポリマーズ・ユー・エス・エル・エル・シー | 塗装面の保護フィルム用粘着剤組成物およびその調製方法 |
KR102020485B1 (ko) | 2013-01-11 | 2019-09-11 | 삼성디스플레이 주식회사 | 블록 공중합체, 그 형성 방법 및 패턴 형성 방법 |
JP6628514B2 (ja) * | 2015-07-16 | 2020-01-08 | 旭化成株式会社 | 水添ブロック共重合体、並びにこれを用いた粘接着組成物、改質アスファルト組成物及び改質アスファルト混合物 |
CN108602990B (zh) * | 2016-01-26 | 2021-03-30 | 戴纳索尔伊莱斯托米罗斯公司 | 逆向递变热塑性弹性体 |
US10899864B2 (en) * | 2016-09-09 | 2021-01-26 | Dynasol Elastómeros, S.A. De C.V. | Polar modifier systems for high vinyl block copolymerization |
US20220411637A1 (en) | 2017-01-26 | 2022-12-29 | Dynasol Elastómeros, S.A. De C.V. | Counter Tapered Thermoplastic Elastomers |
KR102464763B1 (ko) * | 2017-11-17 | 2022-11-08 | 주식회사 엘지화학 | 블록 공중합체 조성물 제조방법, 이로부터 제조된 블록 공중합체 조성물을 포함하는 아스팔트 조성물 |
WO2020075063A1 (en) * | 2018-10-11 | 2020-04-16 | 3M Innovative Properties Company | Adhesive composition comprising a block copolymer having a polyvinyl aromatic block and poly(vinyl aromatic/isoprene) block, articles, and methods of bonding |
CN111072879B (zh) * | 2018-10-18 | 2021-07-30 | 中国石油化工股份有限公司 | 嵌段共聚物和嵌段共聚物组合物及其制备方法和硫化橡胶及应用和轮胎胎面和轮胎 |
US11525025B2 (en) * | 2018-12-14 | 2022-12-13 | Kraton Polymers Llc | Block copolymers and uses thereof |
US20200199334A1 (en) * | 2018-12-20 | 2020-06-25 | Dynasol Elastómeros, S.A. De C.V. | Dual Composition Block Copolymers |
CN114929766A (zh) * | 2019-11-07 | 2022-08-19 | 戴纳索尔伊莱斯托米罗斯公司 | 改性二烯共聚物及其用途 |
CN115010917B (zh) * | 2022-06-13 | 2023-11-17 | 佳化化学科技发展(上海)有限公司 | 一种烯丙基聚醚、制备方法及其制备泡沫稳定剂的用途 |
Family Cites Families (36)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3149182A (en) | 1957-10-28 | 1964-09-15 | Shell Oil Co | Process for preparing block copolymers utilizing organolithium catalysts |
US3281383A (en) | 1962-08-09 | 1966-10-25 | Phillips Petroleum Co | Branched polymers prepared from monolithium-terminated polymers and compounds having at least three reactive sites |
US3753936A (en) | 1970-02-18 | 1973-08-21 | Phillips Petroleum Co | Branched rubbery block copolymer adhesive |
JPS5232774B2 (es) | 1974-02-02 | 1977-08-24 | ||
JPS5216496B2 (es) | 1974-03-09 | 1977-05-10 | ||
US4208356A (en) | 1974-09-17 | 1980-06-17 | Asahi Kasei Kogyo Kabushiki Kaisha | Process for producing mixture of block copolymers |
US4049753A (en) * | 1976-04-19 | 1977-09-20 | Phillips Petroleum Company | Coupling of alkali metal-terminated polymers |
US4188432A (en) * | 1978-03-30 | 1980-02-12 | Shell Oil Company | Articles resistant to attack by fatty substances, made from polystyrene blends, and compositions |
JPS57108142A (en) | 1980-12-26 | 1982-07-06 | Bridgestone Corp | Rubber composition for tire |
US4530652A (en) | 1984-01-12 | 1985-07-23 | Buck Ollie G | Asphalt composition |
DE3751812T2 (de) | 1986-02-20 | 1997-01-30 | Asahi Chemical Ind | Kristallines Blockcopolymer und Verfahren zu dessen Herstellung |
US5306778A (en) | 1988-08-24 | 1994-04-26 | Japan Synthetic Rubber Co., Ltd. | Process for producing rubber-modified thermoplastic resin |
JP2606895B2 (ja) * | 1988-08-26 | 1997-05-07 | 三井東圧化学株式会社 | ブロック共重合ゴム変性スチレン系共重合体 |
DE69032963T2 (de) | 1989-05-19 | 1999-08-19 | Japan Synthetic Rubber Co Ltd | (Modifiziertes) hydriertes Dien-Blockcopolymer und dieses enthaltende Zusammensetzung |
US5100938A (en) | 1989-08-10 | 1992-03-31 | The Dow Chemical Company | Bituminous compositions and methods of application to surfaces |
US5071920A (en) | 1989-11-24 | 1991-12-10 | The Dow Chemical Company | Tapered block copolymers |
US5047484A (en) | 1989-11-24 | 1991-09-10 | The Dow Chemical Company | Tapered block copolymers |
US5256736A (en) * | 1991-05-08 | 1993-10-26 | Phillips Petroleum Company | Tapered block copolymers of conjugated dienes and monovinylarenes |
US5436298A (en) | 1993-09-30 | 1995-07-25 | Phillips Petroleum Company | Block copolymers of monovinylarenes and conjugated dienes and preparation thereof |
CA2134026C (en) * | 1993-11-15 | 1998-06-09 | William J. Trepka | Tapered block copolymers of monovinylarenes and conjugated dienes |
TW334443B (en) | 1994-04-11 | 1998-06-21 | Shell Int Research | Linear block copolymers, process for their preparation and adhesive compositions |
ZA961141B (en) | 1995-02-20 | 1996-08-23 | Shell Int Research | Bituminous composition |
GB2310859A (en) | 1996-03-08 | 1997-09-10 | Shell Int Research | Adhesive compositions comprising block copolymers |
US6376606B1 (en) * | 1998-01-06 | 2002-04-23 | General Electric Co. | Semi-transparent blends of polyphenylene ether and styrenic copolymers |
TW446733B (en) * | 1998-03-05 | 2001-07-21 | Japan Elastomer Co Ltd | Block copolymer composition for modifying asphalt and asphalt composition comprising the same |
CN1118496C (zh) * | 2000-04-20 | 2003-08-20 | 江苏圣杰实业有限公司 | 共轭二烯和/或单乙烯基芳烃聚合物的制备方法 |
JP4623246B2 (ja) * | 2000-08-11 | 2011-02-02 | ジェイエスアール クレイトン エラストマー株式会社 | アスファルト改質用共重合体(組成物)、およびアスファルト組成物 |
US6987142B2 (en) | 2002-02-07 | 2006-01-17 | Kraton Polymers U.S. Llc | Adhesives and sealants from controlled distribution block copolymers |
DE10218161A1 (de) | 2002-04-23 | 2003-11-13 | Basf Ag | Initiatorzusammensetzung und Verfahren zur anionischen Polymerisation |
DE10307058A1 (de) | 2003-02-19 | 2004-09-02 | Basf Ag | Verfahren zur anionischen Polymerisation von α-Methylstyrol |
CN1247642C (zh) * | 2003-07-11 | 2006-03-29 | 中国石油天然气股份有限公司 | 含无规渐变链段的单形态辐射状嵌段共聚物及其制备方法 |
US7517934B2 (en) * | 2003-07-31 | 2009-04-14 | Basf Corporation | Modified anionically polymerized polymers |
EP1799730B1 (en) * | 2004-09-27 | 2010-05-12 | Dow Global Technologies Inc. | Asymmetric linear tapered monoalkenyl arene-conjugated diene block copolymers |
KR100969106B1 (ko) | 2005-11-14 | 2010-07-09 | 크레이튼 폴리머즈 리서치 비.브이. | 역청질 결합제 조성물의 제조방법 |
US7858693B2 (en) | 2006-03-24 | 2010-12-28 | Kratonpolymers U.S. Llc | Unhydrogenated block copolymer compositions |
US8883927B2 (en) | 2007-11-28 | 2014-11-11 | Dynasol Elastómeros, S.A. De C.V. | Radial multi-block copolymers |
-
2012
- 2012-01-30 WO PCT/IB2012/000244 patent/WO2012101516A2/en active Application Filing
- 2012-01-30 MX MX2013008751A patent/MX2013008751A/es not_active Application Discontinuation
- 2012-01-30 ES ES12739465.8T patent/ES2611335T3/es active Active
- 2012-01-30 CN CN201280006975.4A patent/CN103347912B/zh active Active
- 2012-01-30 EP EP12739465.8A patent/EP2668214B1/en active Active
- 2012-01-30 CN CN201810454493.4A patent/CN108587535B/zh active Active
- 2012-01-30 US US13/361,740 patent/US8981008B2/en active Active
- 2012-01-30 CN CN201810199395.0A patent/CN108409926B/zh active Active
- 2012-01-30 CN CN201810454517.6A patent/CN108641268B/zh active Active
- 2012-01-30 PL PL12739465T patent/PL2668214T3/pl unknown
- 2012-01-30 CN CN201810454571.0A patent/CN108559288B/zh active Active
Also Published As
Publication number | Publication date |
---|---|
EP2668214A2 (en) | 2013-12-04 |
CN108641268A (zh) | 2018-10-12 |
CN108409926B (zh) | 2021-09-14 |
CN103347912B (zh) | 2018-06-05 |
EP2668214B1 (en) | 2016-10-05 |
US8981008B2 (en) | 2015-03-17 |
WO2012101516A3 (en) | 2012-11-22 |
CN108559288A (zh) | 2018-09-21 |
CN103347912A (zh) | 2013-10-09 |
PL2668214T3 (pl) | 2017-04-28 |
WO2012101516A2 (en) | 2012-08-02 |
CN108409926A (zh) | 2018-08-17 |
CN108559288B (zh) | 2020-10-27 |
CN108587535A (zh) | 2018-09-28 |
US20120196996A1 (en) | 2012-08-02 |
EP2668214A4 (en) | 2014-10-29 |
CN108587535B (zh) | 2020-05-05 |
CN108641268B (zh) | 2020-08-04 |
ES2611335T3 (es) | 2017-05-08 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
MX2013008751A (es) | Copolimeros tribloque conicos. | |
WO2007078819A3 (en) | Low surface energy block co-polymer preparation methods and applications | |
WO2010026178A3 (de) | Fällungspolymerisation in gegenwart von glycerinmonostearat | |
FR2979630B1 (fr) | Copolymeres a blocs dont un polyanionique base sur un monomere anion de type tfsili comme electrolyte de batterie. | |
SG11201811355XA (en) | Method for producing modified conjugated diene-based polymer, modified conjugated diene-based polymer, polymer composition, crosslinked body, tire and compound | |
WO2014189939A3 (en) | Thermoplastic elastomers via reversible addition-fragmentation chain transfer polymerization of triglycerides | |
WO2012134700A3 (en) | Process to produce enhanced melt strength ethylene/alpha-olefin copolymers and articles thereof | |
MY165740A (en) | A latex comprising water and a styrenic block copolymer and a process for preparing articles therefrom | |
JP2017527668A5 (es) | ||
WO2010039628A3 (en) | POLYMER BLENDS WITH ETHYLENE/α-OLEFIN INTERPOLYMERS | |
MY160673A (en) | Method for producing modified conjugated diene polymer, modified conjugated diene polymer, and composition of modified conjugated diene polymer | |
WO2011014022A3 (ko) | 메탈로센 화합물, 이를 포함하는 촉매 조성물 및 이를 이용하여 제조된 올레핀계 중합체 | |
MY185943A (en) | Acrylic rubber graft copolymer and thermoplastic resin composition | |
WO2007016499A3 (en) | Methods of producing vinyl aromatic polymers using (meth)acrylic macroinitiators | |
DK2152770T3 (da) | Isotactic polystyrene having reactive groups | |
WO2018047008A3 (en) | Polar modifier systems for high vinyl block copolymerization | |
WO2011155571A9 (ja) | 熱可塑性エラストマー組成物及びその成形品 | |
WO2006128795A3 (de) | Verwendung von amphiphilen blockcopolymeren zur herstellung von polymerblends | |
MX2017013010A (es) | Iniciadores para la copolimerizacion de monomeros de dieno y monomeros aromaticos de vinilo. | |
MX2018002167A (es) | Polimero elastomerico. | |
EP1205499A3 (en) | Unsaturated nitrile-conjugated diene rubber composition and production process of the rubber | |
MY178743A (en) | Thermoplastic resin composition | |
DE502006002387D1 (en) | Verstärkte thermoplastische formmassen | |
MX2022005463A (es) | Copolimeros de dieno modificados y su uso. | |
WO2010011022A3 (ko) | 아스팔트 개질제 조성물 및 이를 함유하는 아스팔트 조성물 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
FA | Abandonment or withdrawal |