FR2975101B1 - Resines et composites hybrides thermodurs / supramoleculaires pouvant etre faconnes a chaud et recycles - Google Patents

Resines et composites hybrides thermodurs / supramoleculaires pouvant etre faconnes a chaud et recycles

Info

Publication number
FR2975101B1
FR2975101B1 FR1154010A FR1154010A FR2975101B1 FR 2975101 B1 FR2975101 B1 FR 2975101B1 FR 1154010 A FR1154010 A FR 1154010A FR 1154010 A FR1154010 A FR 1154010A FR 2975101 B1 FR2975101 B1 FR 2975101B1
Authority
FR
France
Prior art keywords
thermosetting resin
resin precursor
hardener
composites
resins
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
FR1154010A
Other languages
English (en)
French (fr)
Other versions
FR2975101A1 (fr
Inventor
Ludwik Leibler
Damien Montarnal
Francois Genes Tournilhac
Mathieu Capelot
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Centre National de la Recherche Scientifique CNRS
Arkema France SA
Original Assignee
Centre National de la Recherche Scientifique CNRS
Arkema France SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to FR1154010A priority Critical patent/FR2975101B1/fr
Application filed by Centre National de la Recherche Scientifique CNRS, Arkema France SA filed Critical Centre National de la Recherche Scientifique CNRS
Priority to BR112013029011A priority patent/BR112013029011A2/pt
Priority to EP12720486.5A priority patent/EP2707413A1/fr
Priority to CN201280034101.XA priority patent/CN103687888B/zh
Priority to PCT/EP2012/058616 priority patent/WO2012152859A1/fr
Priority to JP2014509731A priority patent/JP6099630B2/ja
Priority to US14/116,541 priority patent/US9359467B2/en
Publication of FR2975101A1 publication Critical patent/FR2975101A1/fr
Application granted granted Critical
Publication of FR2975101B1 publication Critical patent/FR2975101B1/fr
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/14Polycondensates modified by chemical after-treatment
    • C08G59/1433Polycondensates modified by chemical after-treatment with organic low-molecular-weight compounds
    • C08G59/1477Polycondensates modified by chemical after-treatment with organic low-molecular-weight compounds containing nitrogen
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29BPREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
    • B29B17/00Recovery of plastics or other constituents of waste material containing plastics
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C67/00Shaping techniques not covered by groups B29C39/00 - B29C65/00, B29C70/00 or B29C73/00
    • B29C67/24Shaping techniques not covered by groups B29C39/00 - B29C65/00, B29C70/00 or B29C73/00 characterised by the choice of material
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/40Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
    • C08G59/42Polycarboxylic acids; Anhydrides, halides or low molecular weight esters thereof
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G83/00Macromolecular compounds not provided for in groups C08G2/00 - C08G81/00
    • C08G83/008Supramolecular polymers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L63/00Compositions of epoxy resins; Compositions of derivatives of epoxy resins
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L67/00Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
    • C08L67/08Polyesters modified with higher fatty oils or their acids, or with resins or resin acids
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29KINDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2063/00Use of EP, i.e. epoxy resins or derivatives thereof, as moulding material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29KINDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2105/00Condition, form or state of moulded material or of the material to be shaped
    • B29K2105/24Condition, form or state of moulded material or of the material to be shaped crosslinked or vulcanised
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/62Plastics recycling; Rubber recycling

Landscapes

  • Chemical & Material Sciences (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Environmental & Geological Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Epoxy Resins (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Separation, Recovery Or Treatment Of Waste Materials Containing Plastics (AREA)
FR1154010A 2011-05-10 2011-05-10 Resines et composites hybrides thermodurs / supramoleculaires pouvant etre faconnes a chaud et recycles Expired - Fee Related FR2975101B1 (fr)

Priority Applications (7)

Application Number Priority Date Filing Date Title
FR1154010A FR2975101B1 (fr) 2011-05-10 2011-05-10 Resines et composites hybrides thermodurs / supramoleculaires pouvant etre faconnes a chaud et recycles
EP12720486.5A EP2707413A1 (fr) 2011-05-10 2012-05-10 Resines et composites hybrides thermodurs/supramoleculaires pouvant etre faconnes a chaud et recycles
CN201280034101.XA CN103687888B (zh) 2011-05-10 2012-05-10 可热成形和可回收的热固性/超分子混合复合材料和树脂
PCT/EP2012/058616 WO2012152859A1 (fr) 2011-05-10 2012-05-10 Resines et composites hybrides thermodurs/supramoleculaires pouvant etre faconnes a chaud et recycles
BR112013029011A BR112013029011A2 (pt) 2011-05-10 2012-05-10 compostos e resinas híbridos termoendurecíveis/supramoleculares que podem ser formados e reciclados sob ação de calor
JP2014509731A JP6099630B2 (ja) 2011-05-10 2012-05-10 熱間成形およびリサイクルすることができる熱硬化性物質/超分子ハイブリッド複合体および樹脂
US14/116,541 US9359467B2 (en) 2011-05-10 2012-05-10 Thermoset/supramolecular hybrid composites and resins that can be hot-formed and recycled

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR1154010A FR2975101B1 (fr) 2011-05-10 2011-05-10 Resines et composites hybrides thermodurs / supramoleculaires pouvant etre faconnes a chaud et recycles

Publications (2)

Publication Number Publication Date
FR2975101A1 FR2975101A1 (fr) 2012-11-16
FR2975101B1 true FR2975101B1 (fr) 2013-04-26

Family

ID=46062274

Family Applications (1)

Application Number Title Priority Date Filing Date
FR1154010A Expired - Fee Related FR2975101B1 (fr) 2011-05-10 2011-05-10 Resines et composites hybrides thermodurs / supramoleculaires pouvant etre faconnes a chaud et recycles

Country Status (7)

Country Link
US (1) US9359467B2 (https=)
EP (1) EP2707413A1 (https=)
JP (1) JP6099630B2 (https=)
CN (1) CN103687888B (https=)
BR (1) BR112013029011A2 (https=)
FR (1) FR2975101B1 (https=)
WO (1) WO2012152859A1 (https=)

Families Citing this family (38)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2495277B (en) * 2011-09-29 2017-12-13 Escape Enviro Ltd Exercise weight structure
FR3000075B1 (fr) * 2012-12-21 2015-11-13 Arkema France Systemes catalytiques pour resines thermodurcissables deformables
FR3004988B1 (fr) * 2013-04-26 2015-04-03 Arkema France Structure multicouche comportant une couche de materiau supramoleculaire et son procede de fabrication
US20150125646A1 (en) 2013-11-05 2015-05-07 Espci Innov Self-Healing Thermally Conductive Polymer Materials
FR3020366B1 (fr) 2014-04-24 2017-10-27 Arkema France Composition pour la fabrication de resines vitrimeres de type epoxy/anhyride comprenant un catalyseur organique
FR3020368B1 (fr) 2014-04-24 2017-10-27 Arkema France Composition pour la fabrication de resines vitrimeres de type epoxy/anhyride comprenant un polyol
FR3020367B1 (fr) 2014-04-24 2017-10-27 Arkema France Catalyseur a base de titane pour resines vitrimeres de type epoxy/anhyride
FR3020496A1 (fr) 2014-04-24 2015-10-30 Arkema France Utilisation d'une composition de resine thermodurcissable de type vitrimere pour la fabrication de pieces d'isolation electrique
WO2016009392A1 (en) 2014-07-18 2016-01-21 Sabic Global Technologies B.V. Methods of forming dynamic cross-linked polymer compositions
US20170173847A1 (en) 2014-07-18 2017-06-22 Sabic Global Technologies B.V. Thermoforming of Dynamic Cross-Linked Polymer Compositions
EP3233978B1 (en) * 2014-12-19 2021-03-03 Universiteit Gent Compositions comprising a polymeric network
JPWO2016117398A1 (ja) * 2015-01-19 2017-11-09 株式会社日立製作所 樹脂組成物、塗料、電子部品、モールド変圧器、モータコイル、ケーブル
WO2016149400A1 (en) 2015-03-16 2016-09-22 Sabic Global Technologies B.V. Fibrillated polymer compositions and methods of their manufacture
CN107427970A (zh) 2015-03-26 2017-12-01 沙特基础工业全球技术公司 动态交联聚合物组合物在焊接应用中的用途
WO2016154567A1 (en) 2015-03-26 2016-09-29 Sabic Global Technologies B.V. Fibrillated dynamic cross-linked polymer compositions and methods of their manufacture and use
WO2016174104A1 (en) 2015-04-27 2016-11-03 Julius-Maximilians-Universität Würzburg Modified bacterial nanocellulose and its uses in chip cards and medicine
WO2017006263A1 (en) 2015-07-06 2017-01-12 Sabic Global Technologies B.V. Methods of forming dynamic cross-linked polymer compositions
WO2017007812A1 (en) 2015-07-06 2017-01-12 Sabic Global Technologies B.V. Fibrillated dynamic cross-linked polymer compositions and methods of their manufacture and use
WO2017189974A1 (en) 2016-04-28 2017-11-02 Sabic Global Technologies B.V. Methods of forming dynamic cross-linked polymer compositions using functional monomeric chain extenders under batch process
EP3448907A2 (en) 2016-04-28 2019-03-06 SABIC Global Technologies B.V. Methods of forming dynamic cross-linked polymer compositions using functional, polymeric chain extenders under batch process
EP3515977A1 (en) 2016-09-26 2019-07-31 SABIC Global Technologies B.V. Dynamic cross-linked networks comprising non-networking flame retardants
US20190256705A1 (en) 2016-09-26 2019-08-22 Sabic Global Technologies B.V. Networking flame retardant dynamic cross-linked networks
US20190276590A1 (en) 2016-11-15 2019-09-12 Sabic Global Technologies B.V. Methods of forming dynamic cross-linked polymer compositions using functional chain extenders under continuous process
WO2018093853A1 (en) 2016-11-15 2018-05-24 Sabic Global Technologies B.V. Methods of forming dynamic cross-linked pollymer compositions using functional chain extenders under batch process
WO2018100514A1 (en) 2016-11-30 2018-06-07 Sabic Global Technologies B.V. Improvement of impact properties of dynamically cross-linked networks by using reactive impact modifiers
EP3336123A1 (en) 2016-12-13 2018-06-20 SABIC Global Technologies B.V. Tuning network formation of dynamically cross-linked networks based on selection of crosslinker and catalyst
EP3351581A1 (en) 2017-01-18 2018-07-25 SABIC Global Technologies B.V. Dynamically cross-linked poly (amides) prepared via the incorporation of polyamines/ammonium salts in the solid state
DE102017125178B4 (de) * 2017-10-26 2022-12-08 Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e. V. Elektrisches Bauteil mit selbstheilender Lackeschichtung, Verfahren zu dessen Herstellung, Verfahren zur Selbstheilung des elektrischen Bauteils nach elektrischem Durchschlag sowie Verwendung einer Lackbeschichtung als selbstheilende Beschichtung
CA3025965A1 (en) * 2017-12-01 2019-06-01 Oil Service, Inc. Weighted training equipment
US11097146B2 (en) * 2017-12-01 2021-08-24 Caxy Sports, Llc Weighted training equipment
EP3569645A1 (en) 2018-05-18 2019-11-20 SABIC Global Technologies B.V. Reinforced dynamically crosslinked polyester network
CN109206891B (zh) * 2018-08-20 2021-03-12 青岛汇智领先新材料科技有限公司 一种可自修复的热固性环氧树脂基复合材料及制备方法
KR20210105991A (ko) * 2019-01-18 2021-08-27 더 보드 오브 트러스티스 오브 더 리랜드 스탠포드 쥬니어 유니버시티 신축성 배터리를 위한 동적 결합된 초분자 폴리머
EP3741807A1 (en) 2019-05-24 2020-11-25 SABIC Global Technologies B.V. Polymer compositions with low warpage
KR20240042072A (ko) * 2021-08-12 2024-04-01 국립대학법인 나고야공업대학 가교 폴리에스테르 수지
WO2025091014A1 (en) 2023-10-27 2025-05-01 Anthro Energy, Inc. System and method for improved battery structural properties
CN118444446B (zh) * 2024-07-04 2024-10-11 江苏亨通光电股份有限公司 一种蝶形光缆及其生产工艺
CN120795737B (zh) * 2025-07-14 2026-02-24 本溪丰源耐火材料有限公司 一种耐高温涂料及其制备方法

Family Cites Families (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BE759668A (fr) * 1969-11-28 1971-06-01 Unilever Emery Epoxyharspoeders en de verwerking daarvan
US3624932A (en) * 1970-04-06 1971-12-07 Borden Inc Apparatus for harvesting mollusks
US5470609A (en) 1992-12-07 1995-11-28 Gencorp Inc. Repair of plastic substrates utilizing powder coating compositions
US5496907A (en) * 1993-03-02 1996-03-05 H. B. Fuller Licensing & Financing, Inc. Wet adhesion monomers with ureido functionality and polymers prepared therefrom
US6194490B1 (en) * 1998-02-27 2001-02-27 Vantico, Inc. Curable composition comprising epoxidized natural oils
US6518330B2 (en) 2001-02-13 2003-02-11 Board Of Trustees Of University Of Illinois Multifunctional autonomically healing composite material
FR2924715B1 (fr) 2007-12-06 2012-10-12 Arkema France Materiau forme de molecules arborescentes comportant des groupes associatifs
FR2925505B1 (fr) * 2007-12-24 2010-04-02 Arkema France Procede de preparation d'un materiau forme de molecules arborescentes comportant des groupes associatifs
FR2930947B1 (fr) 2008-05-07 2011-03-11 Arkema France Composition renfermant un polymere vinylique halogene et un copolymere porteur de groupes associatifs
KR101239571B1 (ko) 2008-11-24 2013-03-06 바스프 에스이 열잠재성 염기를 포함하는 경화성 조성물
FR2944025B1 (fr) * 2009-04-02 2011-04-01 Arkema France Utilisation en tant qu'absorbeur de chocs, d'un materiau forme de molecules arborescentes comportant des groupes associatifs
FR2946350B1 (fr) * 2009-06-04 2012-05-11 Arkema France Utilisation de molecules porteuses de groupes associatifs comme durcisseurs de resines thermodurcissables
CN102905877B (zh) * 2010-05-31 2016-08-24 阿肯马法国公司 可热加工和回收的酸硬化性环氧热固性树脂和复合材料
US20150125646A1 (en) * 2013-11-05 2015-05-07 Espci Innov Self-Healing Thermally Conductive Polymer Materials

Also Published As

Publication number Publication date
EP2707413A1 (fr) 2014-03-19
CN103687888A (zh) 2014-03-26
JP6099630B2 (ja) 2017-03-22
FR2975101A1 (fr) 2012-11-16
US20140088223A1 (en) 2014-03-27
JP2014513192A (ja) 2014-05-29
BR112013029011A2 (pt) 2017-01-17
WO2012152859A1 (fr) 2012-11-15
US9359467B2 (en) 2016-06-07
CN103687888B (zh) 2016-08-17

Similar Documents

Publication Publication Date Title
FR2975101B1 (fr) Resines et composites hybrides thermodurs / supramoleculaires pouvant etre faconnes a chaud et recycles
MX2012013798A (es) Resinas termoestables epoxi acidas y compuestos que se pueden formar en caliente y reciclar.
Mukherjee et al. Sustainable production of hydroxymethylfurfural and levulinic acid: Challenges and opportunities
MX352784B (es) Resinas y compuestos termoendurecidos de epoxi-anhidridos que pueden ser conformados en caliente y reciclados.
EP4279523A3 (en) Esterified acids for use in polymeric materials
PH12018500043A1 (en) Polyethylene terephthalate depolymerization
BR112017002723A2 (pt) método para produzir furfural a partir de material de biomassa contendo pentosana.
BR112012016143B8 (pt) método para proporcionar uma carga de alimentação biobaseada
BR112014019944A8 (pt) Método para a produção contínua de um anidrido de ácido
JP2015519263A5 (https=)
MY181276A (en) Polyester and method for preparing such a polyester
BR112014009505A2 (pt) material compósito por meio de polimerização in situ de resinas (met)acrílicas termoplásticas e seu uso
CL2014002849A1 (es) Agente de curado para resina epoxi que es producto de reaccion entre metaxililendiamina o paraxililendiamina y u7n acido carboxilico insaturado; composición de resina epoxi y adhesivo para barrera de gas y laminado con barrera de gas.
MX371000B (es) Materiales de compuestos de resinas termoestables que comprenden partículas de endurecimiento entre las láminas.
EP2532710A4 (en) Phenol resin composition, process for production thereof, curable resin composition, cured products tehreof, and printed wiring board
BR112013021411A2 (pt) endurecedores de alta latência para resinas epóxi
CL2014002850A1 (es) Agente de curado para resina epoxi que comprende: i) el producto de reaccion entre metaxililendiamina o paraxililendiamina y acido acrilico o derivados del acido acrilico y ii) el producto de reaccion entre metaxililendiamina o paraxililendiamina y acidos carboxilicos insaturados, composición de resina epoxi y adhesivo para barrera de gas y laminado con barrera de gas.
AR058867A1 (es) Etanolisis de pet para formar det y la oxidacion del mismo
IN2014DN07375A (https=)
BR112012032981A2 (pt) composição de resina epóxi curável livre de diluente para preparar um compósito, processo para preparar uma composição ou sistema de resina curável, livre de diluente, produto compósito curado e processo para preparar produto compósito curado
WO2014162238A3 (en) A process for recycling a metalized polyester film
TR201900876T4 (tr) Taş granülat ve poliester reçine konglomerasından tabakaların veya blokların üretimi için bir işlem.
BR112013000535A2 (pt) recipientes rotulados e processos de produção de recipientes rotulados
RU2012155687A (ru) Отверждаемые композиции
WO2013093053A3 (en) Improvements in or relating to fibre reinforced materials

Legal Events

Date Code Title Description
PLFP Fee payment

Year of fee payment: 6

PLFP Fee payment

Year of fee payment: 7

PLFP Fee payment

Year of fee payment: 8

PLFP Fee payment

Year of fee payment: 10

PLFP Fee payment

Year of fee payment: 11

ST Notification of lapse

Effective date: 20230105