FR2946048B1 - Systeme catalytique pour la polymerisation de dienes conjugues,procede de polymerisation et polymere fonctionnel obtenu - Google Patents

Systeme catalytique pour la polymerisation de dienes conjugues,procede de polymerisation et polymere fonctionnel obtenu

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Publication number
FR2946048B1
FR2946048B1 FR0902650A FR0902650A FR2946048B1 FR 2946048 B1 FR2946048 B1 FR 2946048B1 FR 0902650 A FR0902650 A FR 0902650A FR 0902650 A FR0902650 A FR 0902650A FR 2946048 B1 FR2946048 B1 FR 2946048B1
Authority
FR
France
Prior art keywords
polymerization
polymer obtained
functional polymer
conjugated dienes
catalytic system
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
FR0902650A
Other languages
English (en)
French (fr)
Other versions
FR2946048A1 (fr
Inventor
Guillaume Cortial
Floch Pascal Le
Francois Nief
Julien Thuilliez
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Michelin Recherche et Technique SA Switzerland
ECOLE POLYTECH
Centre National de la Recherche Scientifique CNRS
Ecole Polytechnique
Societe de Technologie Michelin SAS
Original Assignee
Michelin Recherche et Technique SA Switzerland
ECOLE POLYTECH
Centre National de la Recherche Scientifique CNRS
Ecole Polytechnique
Societe de Technologie Michelin SAS
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=41651169&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=FR2946048(B1) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Michelin Recherche et Technique SA Switzerland, ECOLE POLYTECH, Centre National de la Recherche Scientifique CNRS, Ecole Polytechnique, Societe de Technologie Michelin SAS filed Critical Michelin Recherche et Technique SA Switzerland
Priority to FR0902650A priority Critical patent/FR2946048B1/fr
Priority to CN201080023918.8A priority patent/CN102449002B/zh
Priority to BRPI1011131A priority patent/BRPI1011131A8/pt
Priority to PCT/EP2010/003306 priority patent/WO2010139449A1/fr
Priority to JP2012513505A priority patent/JP5623514B2/ja
Priority to KR1020117031572A priority patent/KR101706925B1/ko
Priority to EP10722954A priority patent/EP2438095A1/fr
Publication of FR2946048A1 publication Critical patent/FR2946048A1/fr
Priority to US13/709,446 priority patent/US9315590B2/en
Publication of FR2946048B1 publication Critical patent/FR2946048B1/fr
Application granted granted Critical
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/54—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with other compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F136/00—Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F136/02—Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F136/04—Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
    • C08F136/06—Butadiene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/44—Polymerisation in the presence of compounding ingredients, e.g. plasticisers, dyestuffs, fillers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F36/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F36/02—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F36/04—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
    • C08F36/06—Butadiene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/46—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides selected from alkali metals
    • C08F4/463—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides selected from alkali metals selected from sodium or potassium
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/52—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides selected from boron, aluminium, gallium, indium, thallium or rare earths
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/54—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with other compounds thereof
    • C08F4/545—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with other compounds thereof rare earths being present, e.g. triethylaluminium + neodymium octanoate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/02—Elements
    • C08K3/04—Carbon
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L15/00—Compositions of rubber derivatives
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L9/00—Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F236/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F236/02—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F236/04—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
    • C08F236/06—Butadiene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F236/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F236/02—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F236/04—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
    • C08F236/08—Isoprene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
    • C08F2500/21—Rubbery or elastomeric properties

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Polymerization Catalysts (AREA)
FR0902650A 2009-06-02 2009-06-02 Systeme catalytique pour la polymerisation de dienes conjugues,procede de polymerisation et polymere fonctionnel obtenu Expired - Fee Related FR2946048B1 (fr)

Priority Applications (8)

Application Number Priority Date Filing Date Title
FR0902650A FR2946048B1 (fr) 2009-06-02 2009-06-02 Systeme catalytique pour la polymerisation de dienes conjugues,procede de polymerisation et polymere fonctionnel obtenu
JP2012513505A JP5623514B2 (ja) 2009-06-02 2010-06-01 共役ジエン重合用の触媒系、重合方法および得られる官能化ポリマー
BRPI1011131A BRPI1011131A8 (pt) 2009-06-02 2010-06-01 Sistema catalítico, processo de preparação de um sistema catalítico, elastômero diênico funcionalizado, e, composição de borracha
PCT/EP2010/003306 WO2010139449A1 (fr) 2009-06-02 2010-06-01 Systeme catalytique pour la polymerisation de dienes conjugues, procede de polymerisation et polymere fonctionnel obtenu
CN201080023918.8A CN102449002B (zh) 2009-06-02 2010-06-01 用于共轭二烯聚合的催化体系、聚合方法和所得到的官能聚合物
KR1020117031572A KR101706925B1 (ko) 2009-06-02 2010-06-01 공액 디엔 중합용 촉매계, 중합방법 및 수득된 관능성 중합체
EP10722954A EP2438095A1 (fr) 2009-06-02 2010-06-01 Systeme catalytique pour la polymerisation de dienes conjugues, procede de polymerisation et polymere fonctionnel obtenu
US13/709,446 US9315590B2 (en) 2009-06-02 2012-12-10 Catalytic system for conjugated diene polymerisation, polymerisation method and functional polymer obtained

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR0902650A FR2946048B1 (fr) 2009-06-02 2009-06-02 Systeme catalytique pour la polymerisation de dienes conjugues,procede de polymerisation et polymere fonctionnel obtenu

Publications (2)

Publication Number Publication Date
FR2946048A1 FR2946048A1 (fr) 2010-12-03
FR2946048B1 true FR2946048B1 (fr) 2012-12-28

Family

ID=41651169

Family Applications (1)

Application Number Title Priority Date Filing Date
FR0902650A Expired - Fee Related FR2946048B1 (fr) 2009-06-02 2009-06-02 Systeme catalytique pour la polymerisation de dienes conjugues,procede de polymerisation et polymere fonctionnel obtenu

Country Status (8)

Country Link
US (1) US9315590B2 (enExample)
EP (1) EP2438095A1 (enExample)
JP (1) JP5623514B2 (enExample)
KR (1) KR101706925B1 (enExample)
CN (1) CN102449002B (enExample)
BR (1) BRPI1011131A8 (enExample)
FR (1) FR2946048B1 (enExample)
WO (1) WO2010139449A1 (enExample)

Families Citing this family (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2946048B1 (fr) * 2009-06-02 2012-12-28 Michelin Soc Tech Systeme catalytique pour la polymerisation de dienes conjugues,procede de polymerisation et polymere fonctionnel obtenu
FR2946047B1 (fr) * 2009-06-02 2011-07-29 Michelin Soc Tech Nouveaux composes organometallique a base d'un metal appartenant a la 2eme colonne de la classification periodique et procede de preparation
JP5965169B2 (ja) * 2012-03-16 2016-08-03 株式会社ブリヂストン 重合触媒組成物、及び重合体組成物の製造方法
WO2016080764A1 (ko) * 2014-11-20 2016-05-26 주식회사 엘지화학 공액 디엔의 중합용 촉매 조성물
FR3029920B1 (fr) 2014-12-12 2016-12-09 Univ Claude Bernard Lyon Polyolefine fonctionnelle ou telechelique, ses derives, et son procede de preparation
FR3029918B1 (fr) 2014-12-12 2018-01-26 Universite Claude Bernard Lyon 1 Agent de transfert pour la preparation d'une polyolefine fonctionnelle ou telechelique
KR20170000756A (ko) 2015-06-24 2017-01-03 주식회사 엘지화학 공액 디엔계 중합체 제조용 촉매 조성물 및 이를 이용하여 제조된 공액 디엔계 중합체
FR3044664B1 (fr) * 2015-12-08 2017-12-29 Michelin & Cie Copolymere monofonctionnel ou telechelique de 1,3-diene et d'ethylene ou d'alpha-monoolefine.
FR3044663B1 (fr) * 2015-12-08 2017-12-29 Michelin & Cie Copolymere monofonctionnel ou telechelique de 1,3-butadiene et d'ethylene.
FR3061181B1 (fr) 2016-12-22 2019-07-05 Universite Claude Bernard Lyon 1 Copolymere d'ethylene et de derive styrenique, sa preparation et son utilisation
FR3068973B1 (fr) * 2017-07-11 2020-08-28 Centre Nat Rech Scient Procede de fonctionnalisation d'un polydiene stereo-regulier
KR102193437B1 (ko) 2017-10-30 2020-12-21 주식회사 엘지화학 공액디엔 중합용 촉매의 제조방법, 촉매 및 이를 이용한 공액디엔계 중합체의 제조방법
WO2019110915A1 (fr) 2017-12-05 2019-06-13 Compagnie Generale Des Etablissements Michelin Procede continu de preparation d'un elastomere dienique

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FR2946047B1 (fr) * 2009-06-02 2011-07-29 Michelin Soc Tech Nouveaux composes organometallique a base d'un metal appartenant a la 2eme colonne de la classification periodique et procede de preparation
FR2946048B1 (fr) * 2009-06-02 2012-12-28 Michelin Soc Tech Systeme catalytique pour la polymerisation de dienes conjugues,procede de polymerisation et polymere fonctionnel obtenu

Also Published As

Publication number Publication date
JP5623514B2 (ja) 2014-11-12
CN102449002A (zh) 2012-05-09
US9315590B2 (en) 2016-04-19
KR20120031186A (ko) 2012-03-30
WO2010139449A1 (fr) 2010-12-09
BRPI1011131A2 (pt) 2018-02-06
FR2946048A1 (fr) 2010-12-03
KR101706925B1 (ko) 2017-02-15
JP2012528906A (ja) 2012-11-15
CN102449002B (zh) 2014-09-24
BRPI1011131A8 (pt) 2018-04-03
US20130274407A1 (en) 2013-10-17
EP2438095A1 (fr) 2012-04-11

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