FR2894987B1 - SPRING STEEL, AND METHOD OF MANUFACTURING A SPRING USING THE SAME, AND SPRING REALIZED IN SUCH A STEEL - Google Patents

SPRING STEEL, AND METHOD OF MANUFACTURING A SPRING USING THE SAME, AND SPRING REALIZED IN SUCH A STEEL

Info

Publication number
FR2894987B1
FR2894987B1 FR0512775A FR0512775A FR2894987B1 FR 2894987 B1 FR2894987 B1 FR 2894987B1 FR 0512775 A FR0512775 A FR 0512775A FR 0512775 A FR0512775 A FR 0512775A FR 2894987 B1 FR2894987 B1 FR 2894987B1
Authority
FR
France
Prior art keywords
spring
steel
traces
manufacturing
same
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
FR0512775A
Other languages
French (fr)
Other versions
FR2894987A1 (en
Inventor
Nao Yoshihara
Kazuhisa Kawata
Julie Angelique Mougin
Jacques Languillaume
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Ascometal SA
Kobe Steel Ltd
Original Assignee
Ascometal SA
Kobe Steel Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to FR0512775A priority Critical patent/FR2894987B1/en
Application filed by Ascometal SA, Kobe Steel Ltd filed Critical Ascometal SA
Priority to CN2006800474270A priority patent/CN101400818B/en
Priority to US12/097,313 priority patent/US20080308195A1/en
Priority to MEP-2009-344A priority patent/ME01062B/en
Priority to CA2633153A priority patent/CA2633153C/en
Priority to PCT/FR2006/002700 priority patent/WO2007080256A1/en
Priority to DE602006009705T priority patent/DE602006009705D1/en
Priority to PL06841905T priority patent/PL1966407T3/en
Priority to AT06841905T priority patent/ATE445026T1/en
Priority to RU2008128865/02A priority patent/RU2397270C2/en
Priority to SI200630437T priority patent/SI1966407T1/en
Priority to BRPI0619892A priority patent/BRPI0619892B1/en
Priority to EP06841905A priority patent/EP1966407B1/en
Priority to ES06841905T priority patent/ES2331539T3/en
Priority to KR1020087017219A priority patent/KR101048946B1/en
Priority to RSP-2009/0515A priority patent/RS51070B/en
Priority to JP2006334660A priority patent/JP4869051B2/en
Publication of FR2894987A1 publication Critical patent/FR2894987A1/en
Publication of FR2894987B1 publication Critical patent/FR2894987B1/en
Application granted granted Critical
Priority to NO20082766A priority patent/NO341748B1/en
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/02—Ferrous alloys, e.g. steel alloys containing silicon
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
    • C21D8/06—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of rods or wires
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
    • C21D8/06—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of rods or wires
    • C21D8/065—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of rods or wires of ferrous alloys
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D9/00—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
    • C21D9/02—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for springs
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/001—Ferrous alloys, e.g. steel alloys containing N
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/04—Ferrous alloys, e.g. steel alloys containing manganese
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/06—Ferrous alloys, e.g. steel alloys containing aluminium
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/34—Ferrous alloys, e.g. steel alloys containing chromium with more than 1.5% by weight of silicon
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
    • C22C38/42—Ferrous alloys, e.g. steel alloys containing chromium with nickel with copper
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
    • C22C38/44—Ferrous alloys, e.g. steel alloys containing chromium with nickel with molybdenum or tungsten
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
    • C22C38/46—Ferrous alloys, e.g. steel alloys containing chromium with nickel with vanadium
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
    • C22C38/48—Ferrous alloys, e.g. steel alloys containing chromium with nickel with niobium or tantalum
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
    • C22C38/50—Ferrous alloys, e.g. steel alloys containing chromium with nickel with titanium or zirconium
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D2211/00—Microstructure comprising significant phases
    • C21D2211/004—Dispersions; Precipitations

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Manufacturing & Machinery (AREA)
  • Heat Treatment Of Articles (AREA)
  • Heat Treatment Of Steel (AREA)
  • Wire Processing (AREA)
  • Springs (AREA)

Abstract

A spring steel has the following composition (by wt.%): (A) Carbon (C) = 0.45 - 0.70; (B) Silicon (Si) = 1.65 - 2.50; (C) Manganese (Mn) = 0.20 - 0.75; (D) Chromium (Cr) = 0.60 - 2; (E) Nickel (Ni) = 0.15 - 1; (F) Molybdenum (Mo) = traces - 1; (G) Vanadium (V) = 0.003 - 0.8; (H) Copper (Cu) = 0.10 - 1; (I) Titanium (Ti) = 0.020 - 0.2; (J) Niobium (Nb) = traces - 0.2; (K) Aluminum (Al) = 0.002 - 0.050; (L) Phosphorus (P) = traces - 0.015; (M) Sulfer (S) = traces - 0.015; (N) Oxygen (O) = traces - 0.0020; (O) Nitrogen (N) = 0.0020 - 0.0110; (P) Remainder iron (Fe) and production impurities; (Q) a calculated carbon equivalent (C eq). Independent claims are also included for: (1) the fabrication of this spring steel; (2) a spring made from this steel.
FR0512775A 2005-12-15 2005-12-15 SPRING STEEL, AND METHOD OF MANUFACTURING A SPRING USING THE SAME, AND SPRING REALIZED IN SUCH A STEEL Expired - Fee Related FR2894987B1 (en)

Priority Applications (18)

Application Number Priority Date Filing Date Title
FR0512775A FR2894987B1 (en) 2005-12-15 2005-12-15 SPRING STEEL, AND METHOD OF MANUFACTURING A SPRING USING THE SAME, AND SPRING REALIZED IN SUCH A STEEL
EP06841905A EP1966407B1 (en) 2005-12-15 2006-12-11 Spring steel, method for producing a spring using said steel and a spring made from such steel
US12/097,313 US20080308195A1 (en) 2005-12-15 2006-12-11 Steel For Springs, Process Of Manufacture For Spring Using This Steel, And Spring Made From Such Steel
CA2633153A CA2633153C (en) 2005-12-15 2006-12-11 Steel for springs, process of manufacture for spring using this steel, and spring made from such steel
PCT/FR2006/002700 WO2007080256A1 (en) 2005-12-15 2006-12-11 Spring steel, method for producing a spring using said steel and a spring made from such steel
DE602006009705T DE602006009705D1 (en) 2005-12-15 2006-12-11 SPRING STEEL, METHOD FOR PRODUCING A SPRING OF THIS STEEL AND A SPRING OF THIS STEEL
PL06841905T PL1966407T3 (en) 2005-12-15 2006-12-11 Spring steel, method for producing a spring using said steel and a spring made from such steel
AT06841905T ATE445026T1 (en) 2005-12-15 2006-12-11 SPRING STEEL, METHOD FOR PRODUCING A SPRING FROM THIS STEEL AND A SPRING FROM THIS STEEL
ES06841905T ES2331539T3 (en) 2005-12-15 2006-12-11 STEEL FOR SPRINGS, AND MANUFACTURING PROCEDURE OF A SPRING IN WHICH SUCH STEEL IS USED, AND SPRING MADE WITH THIS STEEL.
SI200630437T SI1966407T1 (en) 2005-12-15 2006-12-11 Spring steel, method for producing a spring using said steel and a spring made from such steel
CN2006800474270A CN101400818B (en) 2005-12-15 2006-12-11 Spring steel, method for producing a spring using said steel and a spring made from such steel
MEP-2009-344A ME01062B (en) 2005-12-15 2006-12-11 Spring steel, method for producing a spring using said steel and a spring made from such steel
RU2008128865/02A RU2397270C2 (en) 2005-12-15 2006-12-11 Spring steel, procedure for fabrication of spring out of this steel ans spring out of this steel
KR1020087017219A KR101048946B1 (en) 2005-12-15 2006-12-11 Spring steel, method for producing spring using same and spring produced therefrom
RSP-2009/0515A RS51070B (en) 2005-12-15 2006-12-11 Spring steel, method for producing a spring using said steel and a spring made from such steel
BRPI0619892A BRPI0619892B1 (en) 2005-12-15 2006-12-11 spring steel, spring steelmaking process and spring steel fabricated with such steel
JP2006334660A JP4869051B2 (en) 2005-12-15 2006-12-12 Spring steel, spring manufacturing method using this steel, and spring obtained from this steel
NO20082766A NO341748B1 (en) 2005-12-15 2008-06-16 Spring steel, method of making a spring using said steel and a spring made of such steel

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR0512775A FR2894987B1 (en) 2005-12-15 2005-12-15 SPRING STEEL, AND METHOD OF MANUFACTURING A SPRING USING THE SAME, AND SPRING REALIZED IN SUCH A STEEL

Publications (2)

Publication Number Publication Date
FR2894987A1 FR2894987A1 (en) 2007-06-22
FR2894987B1 true FR2894987B1 (en) 2008-03-14

Family

ID=36933407

Family Applications (1)

Application Number Title Priority Date Filing Date
FR0512775A Expired - Fee Related FR2894987B1 (en) 2005-12-15 2005-12-15 SPRING STEEL, AND METHOD OF MANUFACTURING A SPRING USING THE SAME, AND SPRING REALIZED IN SUCH A STEEL

Country Status (18)

Country Link
US (1) US20080308195A1 (en)
EP (1) EP1966407B1 (en)
JP (1) JP4869051B2 (en)
KR (1) KR101048946B1 (en)
CN (1) CN101400818B (en)
AT (1) ATE445026T1 (en)
BR (1) BRPI0619892B1 (en)
CA (1) CA2633153C (en)
DE (1) DE602006009705D1 (en)
ES (1) ES2331539T3 (en)
FR (1) FR2894987B1 (en)
ME (1) ME01062B (en)
NO (1) NO341748B1 (en)
PL (1) PL1966407T3 (en)
RS (1) RS51070B (en)
RU (1) RU2397270C2 (en)
SI (1) SI1966407T1 (en)
WO (1) WO2007080256A1 (en)

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ES2425413T3 (en) 2006-11-22 2013-10-15 Novo Nordisk A/S Method for preparing activated carboxypeptidase
CN102268604A (en) * 2007-07-20 2011-12-07 株式会社神户制钢所 Steel wire material for spring and its producing method
JP4694537B2 (en) * 2007-07-23 2011-06-08 株式会社神戸製鋼所 Spring wire with excellent fatigue characteristics
US8328169B2 (en) * 2009-09-29 2012-12-11 Chuo Hatsujo Kabushiki Kaisha Spring steel and spring having superior corrosion fatigue strength
JP5653022B2 (en) * 2009-09-29 2015-01-14 中央発條株式会社 Spring steel and spring with excellent corrosion fatigue strength
CN102151693B (en) * 2010-12-02 2012-01-11 大冶特殊钢股份有限公司 Method for rolling low-hardness small-sized spring steel
JP5711539B2 (en) 2011-01-06 2015-05-07 中央発條株式会社 Spring with excellent corrosion fatigue strength
CN103014533B (en) * 2011-10-19 2015-02-04 宝钢集团新疆八一钢铁有限公司 Technique for prolonging fatigue life of 50CrVA plate spring
KR101353649B1 (en) 2011-12-23 2014-01-20 주식회사 포스코 Wire rod and steel wire having high corrosion resistance, method of manufacturing spring and steel wire for spring
WO2013105344A1 (en) * 2012-01-11 2013-07-18 株式会社神戸製鋼所 Steel for bolts, bolt, and method for producing bolt
CN102735749A (en) * 2012-06-28 2012-10-17 吴江市宏达探伤器材有限公司 Magnetic particle inspection test block and preparation method thereof
JP2015034324A (en) * 2013-08-08 2015-02-19 山陽特殊製鋼株式会社 Steel excellent in rolling fatigue life
CN103499595B (en) * 2013-10-17 2016-01-13 武汉钢铁(集团)公司 Spring steel clip foreign material chemical composition microcell method for quantitative measuring
KR101446135B1 (en) 2013-12-26 2014-10-02 주식회사 세아베스틸 Steel for suspension spring with high strength and excellent fatigue and method producing the same
JP6282571B2 (en) * 2014-10-31 2018-02-21 株式会社神戸製鋼所 Manufacturing method of high strength hollow spring steel
CN105112799A (en) * 2015-09-01 2015-12-02 广西南宁智翠科技咨询有限公司 Special spring wire for vehicle engine
CN105178224B (en) * 2015-10-09 2017-05-03 耿志斌 Road and bridge collision avoidance protective device
KR101745192B1 (en) 2015-12-04 2017-06-09 현대자동차주식회사 Ultra high strength spring steel
KR101776462B1 (en) * 2015-12-04 2017-09-20 현대자동차주식회사 Coil spring steel
KR101745196B1 (en) * 2015-12-07 2017-06-09 현대자동차주식회사 Ultra high strength spring steel
KR101776490B1 (en) * 2016-04-15 2017-09-08 현대자동차주식회사 High strength spring steel having excellent corrosion resistance
KR101776491B1 (en) * 2016-04-15 2017-09-20 현대자동차주식회사 High strength spring steel having excellent corrosion resistance
JP6356309B1 (en) * 2016-10-19 2018-07-11 三菱製鋼株式会社 High-strength spring, method for manufacturing the same, steel for high-strength spring, and method for manufacturing the same
DE102017107487A1 (en) 2017-04-07 2018-10-11 Schaeffler Technologies AG & Co. KG Method for producing a torsion bar spring and stabilizer for a chassis of a motor vehicle
WO2018216317A1 (en) * 2017-05-25 2018-11-29 住友電気工業株式会社 Canted coil spring and connector
BR112019025042A2 (en) * 2017-06-15 2020-06-16 Nippon Steel Corporation LAMINATED STEEL FOR SPRING STEEL
CN107550124A (en) * 2017-09-07 2018-01-09 南通通联海绵塑料有限公司 A kind of sponges spring mattress manufacture method
EP3796101A1 (en) * 2019-09-20 2021-03-24 Nivarox-FAR S.A. Hairspring for clock movement
CN114134431B (en) * 2021-05-10 2022-12-30 江阴兴澄特种钢铁有限公司 2000 Mpa-grade high-strength high-toughness high-hardenability spring steel by square billet continuous casting and rolling and manufacturing method thereof
CN113930680B (en) * 2021-09-29 2023-03-17 武汉钢铁有限公司 Low-temperature-resistant high-strength spring flat steel and production method thereof
JP2023120677A (en) 2022-02-18 2023-08-30 日本発條株式会社 Inclusion evaluation method
CN115125450B (en) * 2022-06-29 2023-03-21 浙江伊思灵双第弹簧有限公司 Microalloyed spring and manufacturing process thereof
CN114990451A (en) * 2022-08-05 2022-09-02 山东联美弹簧科技股份有限公司 Microalloyed steel for automobile spring stabilizer bar and preparation method thereof
CN115961215B (en) * 2022-12-09 2024-10-18 铜陵有色金神耐磨材料有限责任公司 High-wear-resistance Cr-Mo steel lining plate for light semi-autogenous mill and preparation method

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US5776267A (en) * 1995-10-27 1998-07-07 Kabushiki Kaisha Kobe Seiko Sho Spring steel with excellent resistance to hydrogen embrittlement and fatigue
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JP4476846B2 (en) * 2005-03-03 2010-06-09 株式会社神戸製鋼所 High strength spring steel with excellent cold workability and quality stability
JP4476863B2 (en) * 2005-04-11 2010-06-09 株式会社神戸製鋼所 Steel wire for cold forming springs with excellent corrosion resistance

Also Published As

Publication number Publication date
JP2007224413A (en) 2007-09-06
KR20080090424A (en) 2008-10-08
BRPI0619892B1 (en) 2016-06-07
NO341748B1 (en) 2018-01-15
EP1966407A1 (en) 2008-09-10
RU2397270C2 (en) 2010-08-20
US20080308195A1 (en) 2008-12-18
JP4869051B2 (en) 2012-02-01
RS51070B (en) 2010-10-31
NO20082766L (en) 2008-07-14
CA2633153C (en) 2013-05-07
RU2008128865A (en) 2010-01-20
KR101048946B1 (en) 2011-07-12
ES2331539T3 (en) 2010-01-07
ME01062B (en) 2012-10-20
BRPI0619892A2 (en) 2011-10-25
CA2633153A1 (en) 2007-07-19
FR2894987A1 (en) 2007-06-22
CN101400818A (en) 2009-04-01
WO2007080256A1 (en) 2007-07-19
SI1966407T1 (en) 2009-12-31
EP1966407B1 (en) 2009-10-07
DE602006009705D1 (en) 2009-11-19
PL1966407T3 (en) 2010-04-30
CN101400818B (en) 2012-08-29
ATE445026T1 (en) 2009-10-15

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