FR2874516A1 - Procede de regeneration d'un catalyseur contenant une zeolithe de type structural euo - Google Patents

Procede de regeneration d'un catalyseur contenant une zeolithe de type structural euo

Info

Publication number
FR2874516A1
FR2874516A1 FR0409282A FR0409282A FR2874516A1 FR 2874516 A1 FR2874516 A1 FR 2874516A1 FR 0409282 A FR0409282 A FR 0409282A FR 0409282 A FR0409282 A FR 0409282A FR 2874516 A1 FR2874516 A1 FR 2874516A1
Authority
FR
France
Prior art keywords
regenerating
zeolithe
catalyst containing
structural type
catalyst
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
FR0409282A
Other languages
English (en)
Other versions
FR2874516B1 (fr
Inventor
Sylvie Lacombe
Drisch Julia Magne
Eric Sanchez
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
IFP Energies Nouvelles IFPEN
Original Assignee
IFP Energies Nouvelles IFPEN
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by IFP Energies Nouvelles IFPEN filed Critical IFP Energies Nouvelles IFPEN
Priority to FR0409282A priority Critical patent/FR2874516B1/fr
Priority to US11/216,098 priority patent/US7405174B2/en
Publication of FR2874516A1 publication Critical patent/FR2874516A1/fr
Application granted granted Critical
Publication of FR2874516B1 publication Critical patent/FR2874516B1/fr
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/22Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by isomerisation
    • C07C5/27Rearrangement of carbon atoms in the hydrocarbon skeleton
    • C07C5/2729Changing the branching point of an open chain or the point of substitution on a ring
    • C07C5/2732Catalytic processes
    • C07C5/2737Catalytic processes with crystalline alumino-silicates, e.g. molecular sieves
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00Catalysts comprising molecular sieves
    • B01J29/90Regeneration or reactivation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J38/00Regeneration or reactivation of catalysts, in general
    • B01J38/04Gas or vapour treating; Treating by using liquids vaporisable upon contacting spent catalyst
    • B01J38/42Gas or vapour treating; Treating by using liquids vaporisable upon contacting spent catalyst using halogen-containing material
    • B01J38/44Gas or vapour treating; Treating by using liquids vaporisable upon contacting spent catalyst using halogen-containing material and adding simultaneously or subsequently free oxygen; using oxyhalogen compound
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/22Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by isomerisation
    • C07C5/27Rearrangement of carbon atoms in the hydrocarbon skeleton
    • C07C5/2767Changing the number of side-chains
    • C07C5/277Catalytic processes
    • C07C5/2775Catalytic processes with crystalline alumino-silicates, e.g. molecular sieves
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30After treatment, characterised by the means used
    • B01J2229/42Addition of matrix or binder particles
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00Catalysts comprising molecular sieves
    • B01J29/04Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/72Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65 containing iron group metals, noble metals or copper
    • B01J29/74Noble metals
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00Catalysts comprising molecular sieves
    • B01J29/04Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/72Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65 containing iron group metals, noble metals or copper
    • B01J29/76Iron group metals or copper
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00Catalysts comprising molecular sieves
    • B01J29/04Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/78Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65 containing arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/50Improvements relating to the production of bulk chemicals
    • Y02P20/52Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/50Improvements relating to the production of bulk chemicals
    • Y02P20/584Recycling of catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)

Abstract

On décrit un procédé de régénération d'un catalyseur comprenant au moins une zéolithe de type structural EUO sous forme acide et au moins un métal hydro-déshydrogénant, utilisé dans un procédé d'isomérisation d'une charge hydrocarbonée comprenant des composés aromatiques à huit atomes de carbone, comprenant au moins a) une étape d'élimination de la majeure partie du coke, déposé sur ledit catalyseur, par combustion en présence d'un gaz contenant de l'oxygène à une température inférieure ou égale à 600°C, et b) une étape d'oxychloration du produit issu de l'étape a), réalisée entre 200 et 550°C en présence d'au moins un mélange gazeux contenant au moins de l'oxygène, de l'eau et du chlore et/ou au moins un composé chloré.
FR0409282A 2004-09-02 2004-09-02 Procede de regeneration d'un catalyseur contenant une zeolithe de type structural euo Expired - Fee Related FR2874516B1 (fr)

Priority Applications (2)

Application Number Priority Date Filing Date Title
FR0409282A FR2874516B1 (fr) 2004-09-02 2004-09-02 Procede de regeneration d'un catalyseur contenant une zeolithe de type structural euo
US11/216,098 US7405174B2 (en) 2004-09-02 2005-09-01 Process for regeneration of a catalyst that contains an EUO-structural-type zeolite

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR0409282A FR2874516B1 (fr) 2004-09-02 2004-09-02 Procede de regeneration d'un catalyseur contenant une zeolithe de type structural euo

Publications (2)

Publication Number Publication Date
FR2874516A1 true FR2874516A1 (fr) 2006-03-03
FR2874516B1 FR2874516B1 (fr) 2006-12-08

Family

ID=34948310

Family Applications (1)

Application Number Title Priority Date Filing Date
FR0409282A Expired - Fee Related FR2874516B1 (fr) 2004-09-02 2004-09-02 Procede de regeneration d'un catalyseur contenant une zeolithe de type structural euo

Country Status (2)

Country Link
US (1) US7405174B2 (fr)
FR (1) FR2874516B1 (fr)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2022084077A1 (fr) 2020-10-23 2022-04-28 IFP Energies Nouvelles Procede de preparation d'un catalyseur a base d'izm-2 par un traitement thermique specifique et utilisation dudit catalyseur pour l'isomerisation de charges paraffiniques en distillats moyens

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8057707B2 (en) * 2008-03-17 2011-11-15 Arkems Inc. Compositions to mitigate coke formation in steam cracking of hydrocarbons
FR2976941B1 (fr) * 2011-06-24 2014-11-21 IFP Energies Nouvelles Procede ameliore d'isomerisation d'une coupe c8 aromatique
CN107999148B (zh) * 2017-10-10 2020-11-06 浙江海洋大学 一种水溶液体系脱硫催化剂的复活方法
US20220126281A1 (en) * 2021-06-30 2022-04-28 Uop Llc Process for regenerating a dehydrogenation catalyst

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2337196A1 (fr) * 1975-12-30 1977-07-29 Raffinage Cie Francaise Procede de regeneration de catalyseurs de conversion d'hydrocarbures
JPS58164527A (ja) * 1982-03-24 1983-09-29 Teijin Yuka Kk キシレン類の異性化方法
EP0283343A1 (fr) * 1987-03-06 1988-09-21 Institut Français du Pétrole Procédé d'activation d'un catalyseur d'isomérisation de paraffines normales
EP0923987A1 (fr) * 1997-12-22 1999-06-23 Institut Français du Pétrole Catalyseur contenant une zéolithe EUO et son utilisation en isomérisation des composés C8 aromatiques
FR2777207A1 (fr) * 1998-04-10 1999-10-15 Inst Francais Du Petrole Procede d'activation des catalyseurs d'isomerisation des composes aromatiques a huit atomes de carbone
EP1181978A1 (fr) * 2000-08-23 2002-02-27 Institut Francais Du Petrole Catalyseur bimétaliique supporté comportant une forte interaction entre un métal du groupe VIII de l'étain et son utilisation dans un procédé de reformage catalytique

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CH661206A5 (fr) * 1983-09-23 1987-07-15 Debiopharm Sa Procede pour la preparation d'un medicament destine au traitement de maladies hormonodependantes.
US5106798A (en) * 1990-07-12 1992-04-21 Exxon Research And Engineering Company Method for regenerating a Group VIII noble metal deactivated catalyst
FR2761910B1 (fr) * 1997-04-14 1999-05-14 Inst Francais Du Petrole Procede et enceinte de regeneration d'un catalyseur de production d'aromatiques ou de reformage avec oxychloration amelioree
US6057486A (en) * 1997-12-22 2000-05-02 Institut Francais Du Petrole Catalyst containing a zeolite EUO and the use of the catalyst in a process for isomerizing aromatic compounds containing 8 carbon atoms per molecule
US6313363B1 (en) * 1998-04-10 2001-11-06 Institut Francais Du Petrole Process for isomerizing aromatic compounds containing eight carbon atoms

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2337196A1 (fr) * 1975-12-30 1977-07-29 Raffinage Cie Francaise Procede de regeneration de catalyseurs de conversion d'hydrocarbures
JPS58164527A (ja) * 1982-03-24 1983-09-29 Teijin Yuka Kk キシレン類の異性化方法
EP0283343A1 (fr) * 1987-03-06 1988-09-21 Institut Français du Pétrole Procédé d'activation d'un catalyseur d'isomérisation de paraffines normales
EP0923987A1 (fr) * 1997-12-22 1999-06-23 Institut Français du Pétrole Catalyseur contenant une zéolithe EUO et son utilisation en isomérisation des composés C8 aromatiques
FR2777207A1 (fr) * 1998-04-10 1999-10-15 Inst Francais Du Petrole Procede d'activation des catalyseurs d'isomerisation des composes aromatiques a huit atomes de carbone
EP1181978A1 (fr) * 2000-08-23 2002-02-27 Institut Francais Du Petrole Catalyseur bimétaliique supporté comportant une forte interaction entre un métal du groupe VIII de l'étain et son utilisation dans un procédé de reformage catalytique

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
PATENT ABSTRACTS OF JAPAN vol. 007, no. 285 (C - 201) 20 December 1983 (1983-12-20) *

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2022084077A1 (fr) 2020-10-23 2022-04-28 IFP Energies Nouvelles Procede de preparation d'un catalyseur a base d'izm-2 par un traitement thermique specifique et utilisation dudit catalyseur pour l'isomerisation de charges paraffiniques en distillats moyens
FR3115475A1 (fr) 2020-10-23 2022-04-29 IFP Energies Nouvelles Procede de preparation d’un catalyseur a base d’izm-2 par un traitement thermique specifique et utilisation dudit catalyseur pour l’isomerisation de charges paraffiniques en distillats moyens

Also Published As

Publication number Publication date
US20060046924A1 (en) 2006-03-02
FR2874516B1 (fr) 2006-12-08
US7405174B2 (en) 2008-07-29

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