FR2688421B1 - Procede pour la fabrication d'une poudre microspherouidale a faible dispersite, poudre microspherouidale a faible dispersite ainsi obtenue, catalyseurs pour la polymerisation d'alpha-olefines et procede de polymerisation d'alpha-olefines. - Google Patents

Procede pour la fabrication d'une poudre microspherouidale a faible dispersite, poudre microspherouidale a faible dispersite ainsi obtenue, catalyseurs pour la polymerisation d'alpha-olefines et procede de polymerisation d'alpha-olefines.

Info

Publication number
FR2688421B1
FR2688421B1 FR9302429A FR9302429A FR2688421B1 FR 2688421 B1 FR2688421 B1 FR 2688421B1 FR 9302429 A FR9302429 A FR 9302429A FR 9302429 A FR9302429 A FR 9302429A FR 2688421 B1 FR2688421 B1 FR 2688421B1
Authority
FR
France
Prior art keywords
microspherouidal
olefins
alpha
powder
polymerization
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
FR9302429A
Other languages
English (en)
French (fr)
Other versions
FR2688421A1 (fr
Inventor
Derleth Helmut
Grosjean Abel
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Solvay SA
Original Assignee
Solvay SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Solvay SA filed Critical Solvay SA
Publication of FR2688421A1 publication Critical patent/FR2688421A1/fr
Application granted granted Critical
Publication of FR2688421B1 publication Critical patent/FR2688421B1/fr
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/24—Chromium, molybdenum or tungsten
    • B01J23/26—Chromium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B01J37/0027—Powdering
    • B01J37/0045—Drying a slurry, e.g. spray drying
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0072—Preparation of particles, e.g. dispersion of droplets in an oil bath
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0236—Drying, e.g. preparing a suspension, adding a soluble salt and drying
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B33/00—Silicon; Compounds thereof
    • C01B33/113—Silicon oxides; Hydrates thereof
    • C01B33/12—Silica; Hydrates thereof, e.g. lepidoic silicic acid
    • C01B33/16—Preparation of silica xerogels
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/908—Containing catalyst of specified particle size

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Dispersion Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Inorganic Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Silicon Compounds (AREA)
  • Physical Or Chemical Processes And Apparatus (AREA)
  • Polymerization Catalysts (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
FR9302429A 1992-03-10 1993-03-01 Procede pour la fabrication d'une poudre microspherouidale a faible dispersite, poudre microspherouidale a faible dispersite ainsi obtenue, catalyseurs pour la polymerisation d'alpha-olefines et procede de polymerisation d'alpha-olefines. Expired - Fee Related FR2688421B1 (fr)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
BE9200248A BE1005718A3 (fr) 1992-03-10 1992-03-10 Procede pour la fabrication d'une poudre microspheroidale a faible dispersite, poudre microspheroidale a faible dispersite ainsi obtenue, catalyseurs pour la polymerisation d'alpha-olefines et procede de polymerisation d'alpha-olefines.

Publications (2)

Publication Number Publication Date
FR2688421A1 FR2688421A1 (fr) 1993-09-17
FR2688421B1 true FR2688421B1 (fr) 1995-06-16

Family

ID=3886184

Family Applications (1)

Application Number Title Priority Date Filing Date
FR9302429A Expired - Fee Related FR2688421B1 (fr) 1992-03-10 1993-03-01 Procede pour la fabrication d'une poudre microspherouidale a faible dispersite, poudre microspherouidale a faible dispersite ainsi obtenue, catalyseurs pour la polymerisation d'alpha-olefines et procede de polymerisation d'alpha-olefines.

Country Status (6)

Country Link
US (2) US5716898A (de)
JP (1) JPH0680414A (de)
BE (1) BE1005718A3 (de)
DE (1) DE4307567A1 (de)
FR (1) FR2688421B1 (de)
GB (1) GB2264940B (de)

Families Citing this family (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5662840A (en) * 1994-06-10 1997-09-02 Fmc Corporation Process for making gel microbeads
IT1275412B (it) * 1995-06-01 1997-08-05 Enichem Spa Procedimento per la preparazione di ossidi misti silice-allumina porosi in forma sferica
KR20000016801A (ko) * 1996-06-21 2000-03-25 매기오 로버트 에이 지지 응집체 및 그에 지지된 올레핀 중합화 촉매
US6703047B2 (en) * 2001-02-02 2004-03-09 Incept Llc Dehydrated hydrogel precursor-based, tissue adherent compositions and methods of use
DE19943167A1 (de) * 1999-09-09 2001-03-15 Elenac Gmbh Verfahren zur Herstellung von geträgerten Chromkatalysatoren
DE19943206A1 (de) * 1999-09-09 2001-03-15 Elenac Gmbh Verfahren zum Herstellen von Philips-Katalysatoren für die Polymerisation von Olefinen mit verbesserten Produktivitäten im Particle-Form-Verfahren
US10258382B2 (en) * 2007-01-18 2019-04-16 Roger P. Jackson Rod-cord dynamic connection assemblies with slidable bone anchor attachment members along the cord
US6642427B2 (en) * 2001-05-14 2003-11-04 The Procter & Gamble Company Wearable article having a temperature change element
US20050222546A1 (en) * 2004-04-01 2005-10-06 The Procter & Gamble Company Disposable absorbent article having refastenable side seams and a wetness sensation member
DE102004006104A1 (de) * 2004-02-06 2005-08-25 Basell Polyolefine Gmbh Verfahren zur Herstellung von geträgerten Katalysatoren für die Polymerisation
DE102004006113A1 (de) * 2004-02-06 2005-08-25 Basell Polyolefine Gmbh Verfahren zur Herstellung von Trägern für Katalysatoren
US7597882B2 (en) * 2006-04-24 2009-10-06 Incept Llc Protein crosslinkers, crosslinking methods and applications thereof
WO2008044873A1 (en) * 2006-10-10 2008-04-17 Korea Institute Of Industrial Technology Method for preparing permanently hydrophobic aerogel and permanently hydrophobic aerogel prepared by using the method
BRPI0814023A2 (pt) * 2007-07-05 2017-10-03 Grace Gmbh & Co Kg Método para fabricar catalisadores suportados por óxido inorgânico
US7918433B2 (en) * 2008-06-25 2011-04-05 General Electric Company Transition piece mounting bracket and related method
JP5358556B2 (ja) * 2010-12-24 2013-12-04 日本ポリエチレン株式会社 エチレン重合用触媒及びそれを用いたエチレン系重合体の製造方法
US11267914B2 (en) 2016-12-29 2022-03-08 Chevron Phillips Chemical Company Lp Methods of preparing a catalyst
US10654953B2 (en) * 2016-12-29 2020-05-19 Chevron Phillips Chemical Company Lp Methods of preparing a catalyst
US20200369803A1 (en) 2016-12-29 2020-11-26 Chevron Phillips Chemical Company Lp Methods of Preparing a Catalyst

Family Cites Families (25)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB137934A (en) * 1919-02-14 1920-01-29 George Holt Thomas Improvements in the transmission of power
US1506118A (en) * 1923-08-07 1924-08-26 Francis X Govers Method of preparing siliceous material
US3070426A (en) * 1959-08-11 1962-12-25 Grace W R & Co Process for preparing low surface area silica
GB1077908A (en) * 1965-05-05 1967-08-02 Grace W R & Co Process for the production of silica gels
US3974101A (en) * 1970-10-08 1976-08-10 Phillips Petroleum Company Olefin polymerization catalyst
US4119569A (en) * 1973-05-24 1978-10-10 Phillips Petroleum Company Olefin polymerization catalyst
US3960826A (en) * 1973-07-27 1976-06-01 National Petro Chemicals Corporation Olefin polymerization process
JPS51115586A (en) * 1975-04-03 1976-10-12 Nippon Oil Co Ltd Method of preparing polyolefins
US4053436A (en) * 1975-08-26 1977-10-11 Phillips Petroleum Company Spray dried titanium-containing catalyst for stress crack resistant polymer
DE2540278C2 (de) * 1975-09-10 1982-09-16 Basf Ag, 6700 Ludwigshafen Verfahren zum Herstellen von Olefinpolymerisaten
US4081407A (en) * 1976-03-18 1978-03-28 Phillips Petroleum Company Catalyst support prepared by alcohol treatment of hydrogels
NL7707961A (nl) * 1977-07-18 1979-01-22 Stamicarbon Werkwijze ter bereiding van poreus, zuiver siliciumdioxyde.
US4169926A (en) * 1978-01-16 1979-10-02 Phillips Petroleum Company Inorganic hydrogels and uses thereof
EP0037182B2 (de) * 1980-03-24 1991-06-12 Imperial Chemical Industries Plc Herstellung eines getrockneten Übergangsmetallproduktes
DE3269975D1 (en) * 1981-08-07 1986-04-24 Ici Plc Spraying solid
US4382022A (en) * 1981-11-25 1983-05-03 Phillips Petroleum Company Silica having titanium incorporated through use of peroxide
US4436883A (en) * 1982-01-20 1984-03-13 Phillips Petroleum Company Polymerization using a support formed by heating silica gel in inert atmosphere
DE3329016A1 (de) * 1983-08-11 1985-02-28 Basf Ag, 6700 Ludwigshafen Verfahren zum herstellen von polymerisaten des ethylens mittels eines kieselsaeure-xerogel/chromtrioxid-katalysators
US4596862A (en) * 1984-12-24 1986-06-24 Phillips Petroleum Company Olefin polymerization using chromium on fluorided aluminophosphate
DE3634534A1 (de) * 1986-10-10 1988-04-14 Basf Ag Verfahren zum herstellen von homo- sowie copolymerisaten des ethens mittels eines chromtrioxid-katalysators
JPH0699135B2 (ja) * 1989-02-20 1994-12-07 富士デヴィソン株式会社 球状シリカゲルの製造法
US5352645A (en) * 1989-04-14 1994-10-04 E. I. Du Pont De Nemours And Company Silica microspheres, method of improving attrition resistance and use
JP2545282B2 (ja) * 1989-04-17 1996-10-16 日東化学工業株式会社 球状シリカ粒子の製造方法
DE3938723A1 (de) * 1989-11-23 1991-05-29 Basf Ag Katalysator zur herstellung von hochmolekularen homo- oder copolymerisaten des ethens sowie dessen herstellung
US5229096A (en) * 1990-11-19 1993-07-20 Scm Chemicals, Inc. Silica gel

Also Published As

Publication number Publication date
JPH0680414A (ja) 1994-03-22
GB9304892D0 (en) 1993-04-28
FR2688421A1 (fr) 1993-09-17
DE4307567A1 (de) 1993-09-16
US5716898A (en) 1998-02-10
BE1005718A3 (fr) 1993-12-28
GB2264940B (en) 1995-06-21
GB2264940A (en) 1993-09-15
US5726260A (en) 1998-03-10

Similar Documents

Publication Publication Date Title
FR2688421B1 (fr) Procede pour la fabrication d'une poudre microspherouidale a faible dispersite, poudre microspherouidale a faible dispersite ainsi obtenue, catalyseurs pour la polymerisation d'alpha-olefines et procede de polymerisation d'alpha-olefines.
CA2008907A1 (en) Catalysts for the polymerization of olefins
FR2681599B1 (fr) Oxydes d'alkyl-bis-acyl-phosphines et leur application comme photo-amorceurs pour la polymerisation de composes ethyleniques.
CA2183102A1 (en) Polymerization catalyst systems, their production and use
SG44347A1 (en) Process for polymerising olefin with a ziegler- natta catalyst
ZA93666B (en) Process for the gas-phase polymerization of alpha-olefins.
CA2135225A1 (en) Organometallic fluorenyl compounds, preparation, and use
CA2065745A1 (en) Monocyclopentadienyl transition metal olefin polymerization catalysts
CA2098381A1 (en) Preparation of metal coordination complexes
MY121287A (en) Cyclopentaphenanthrenyl titanium complexes and polymerization process
HUT71965A (en) Organo-aluminoxy products process for making thereof and their use for producing polymers
EP0611772A3 (de) Katalysatorbestandteil für Alpha-olefinpolymerisation und Verfahren zur Herstellung von Alpha-olefinpolymere unter Anwendung derselben.
EP0611773A3 (de) Katalysatorbestandteil für Alpha-olefinpolymerisation und Verfahren zur Herstellung von Alpha-olefinpolymere unter Anwendung derselben.
CA2108860A1 (en) Cyclopentadienyl Group 6b Alpha-Olefin Polymerization Catalysts and Process for Polymerizing Alpha-Olefins
ZA959800B (en) Supported catalyst component supported catalyst their preparation and addition polymerization process
FR2732349B1 (fr) Procede pour la preparation d'un copolymere d'ethylene / alpha-olefine
ES8706331A1 (es) Un procedimiento para recubrir substratos por electro-recubrimiento con una composicion a base de polimeros hechos de monomeros alfa-olefinicos polares
ZA90406B (en) Particulate materials,their production and use
DZ1594A1 (fr) Procédé pour la préparation d'un constituant solide de catalyseur pour la polymérisation ou la copolymérisation de l'éthylène.
FR2691970B1 (fr) Procede de preparation d'un catalyseur de polymerisation.
FR2660660B1 (fr) Perfectionnement au procede de fabrication de polymeres radicalaires de l'ethylene utilisables pour l'enduction d'un metal.
CA2067525A1 (en) Organometallic fluorenyl compounds, preparation and use
CA2238241A1 (en) Olefin polymerization processes and products thereof
FR2734570B1 (fr) Procede de preparation d'un catalyseur de type ziegler-natta
YU164782A (en) Process for the polymerisation and co-polymerization of alpha-olefines including ethylene, homogeneous or heterogeneous, with one or more conjugated diolefines

Legal Events

Date Code Title Description
ER Errata listed in the french official journal (bopi)

Free format text: 37/93

TP Transmission of property

Free format text: PUBLIE A TORT DANS LE BOPI 98/03 SUIVANT LA NOTIFICATION DANS LE BOPI 98/07

TP Transmission of property
ST Notification of lapse