FR2494597A1 - Catalyseur et procede d'hydrotraitement - Google Patents
Catalyseur et procede d'hydrotraitement Download PDFInfo
- Publication number
- FR2494597A1 FR2494597A1 FR8121684A FR8121684A FR2494597A1 FR 2494597 A1 FR2494597 A1 FR 2494597A1 FR 8121684 A FR8121684 A FR 8121684A FR 8121684 A FR8121684 A FR 8121684A FR 2494597 A1 FR2494597 A1 FR 2494597A1
- Authority
- FR
- France
- Prior art keywords
- catalyst
- pores
- diameter
- hydrotreatment
- nickel
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000003054 catalyst Substances 0.000 title claims abstract description 59
- 238000000034 method Methods 0.000 title claims abstract description 7
- 239000011148 porous material Substances 0.000 claims abstract description 23
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims abstract description 14
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims abstract description 13
- 238000009835 boiling Methods 0.000 claims abstract description 9
- 239000000470 constituent Substances 0.000 claims abstract description 7
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 26
- 229910052759 nickel Inorganic materials 0.000 claims description 13
- 229910052750 molybdenum Inorganic materials 0.000 claims description 12
- 239000011733 molybdenum Substances 0.000 claims description 12
- 238000001354 calcination Methods 0.000 claims description 10
- 229910017052 cobalt Inorganic materials 0.000 claims description 7
- 239000010941 cobalt Substances 0.000 claims description 7
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 7
- 229930195733 hydrocarbon Natural products 0.000 claims description 5
- 150000002430 hydrocarbons Chemical class 0.000 claims description 5
- 238000006243 chemical reaction Methods 0.000 claims description 3
- 239000004215 Carbon black (E152) Substances 0.000 claims description 2
- 230000003197 catalytic effect Effects 0.000 claims 2
- 230000000694 effects Effects 0.000 description 3
- 229910052739 hydrogen Inorganic materials 0.000 description 3
- 239000001257 hydrogen Substances 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 239000003245 coal Substances 0.000 description 2
- JKQOBWVOAYFWKG-UHFFFAOYSA-N molybdenum trioxide Chemical compound O=[Mo](=O)=O JKQOBWVOAYFWKG-UHFFFAOYSA-N 0.000 description 2
- 239000003079 shale oil Substances 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- -1 ammonium molybdate Chemical class 0.000 description 1
- APUPEJJSWDHEBO-UHFFFAOYSA-P ammonium molybdate Chemical compound [NH4+].[NH4+].[O-][Mo]([O-])(=O)=O APUPEJJSWDHEBO-UHFFFAOYSA-P 0.000 description 1
- 229940010552 ammonium molybdate Drugs 0.000 description 1
- 235000018660 ammonium molybdate Nutrition 0.000 description 1
- 239000011609 ammonium molybdate Substances 0.000 description 1
- 239000010426 asphalt Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000011280 coal tar Substances 0.000 description 1
- 239000000571 coke Substances 0.000 description 1
- 238000004939 coking Methods 0.000 description 1
- 239000010779 crude oil Substances 0.000 description 1
- 230000009849 deactivation Effects 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 239000005078 molybdenum compound Substances 0.000 description 1
- 150000002752 molybdenum compounds Chemical class 0.000 description 1
- KBJMLQFLOWQJNF-UHFFFAOYSA-N nickel(ii) nitrate Chemical compound [Ni+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O KBJMLQFLOWQJNF-UHFFFAOYSA-N 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 239000011295 pitch Substances 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 238000001694 spray drying Methods 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 239000011269 tar Substances 0.000 description 1
- 230000001131 transforming effect Effects 0.000 description 1
- 238000005292 vacuum distillation Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G49/00—Treatment of hydrocarbon oils, in the presence of hydrogen or hydrogen-generating compounds, not provided for in a single one of groups C10G45/02, C10G45/32, C10G45/44, C10G45/58 or C10G47/00
- C10G49/02—Treatment of hydrocarbon oils, in the presence of hydrogen or hydrogen-generating compounds, not provided for in a single one of groups C10G45/02, C10G45/32, C10G45/44, C10G45/58 or C10G47/00 characterised by the catalyst used
- C10G49/04—Treatment of hydrocarbon oils, in the presence of hydrogen or hydrogen-generating compounds, not provided for in a single one of groups C10G45/02, C10G45/32, C10G45/44, C10G45/58 or C10G47/00 characterised by the catalyst used containing nickel, cobalt, chromium, molybdenum, or tungsten metals, or compounds thereof
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/61—Surface area
- B01J35/615—100-500 m2/g
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/63—Pore volume
- B01J35/635—0.5-1.0 ml/g
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/64—Pore diameter
- B01J35/647—2-50 nm
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/64—Pore diameter
- B01J35/651—50-500 nm
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Materials Engineering (AREA)
- Catalysts (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US20894880A | 1980-11-21 | 1980-11-21 |
Publications (2)
Publication Number | Publication Date |
---|---|
FR2494597A1 true FR2494597A1 (fr) | 1982-05-28 |
FR2494597B1 FR2494597B1 (ja) | 1985-01-04 |
Family
ID=22776714
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
FR8121684A Granted FR2494597A1 (fr) | 1980-11-21 | 1981-11-19 | Catalyseur et procede d'hydrotraitement |
Country Status (12)
Country | Link |
---|---|
JP (1) | JPS5946666B2 (ja) |
AU (1) | AU540245B2 (ja) |
CA (1) | CA1159039A (ja) |
DE (1) | DE3145718A1 (ja) |
ES (1) | ES507340A1 (ja) |
FR (1) | FR2494597A1 (ja) |
GB (1) | GB2087747B (ja) |
IT (1) | IT1143446B (ja) |
MX (2) | MX172430B (ja) |
NL (1) | NL8105267A (ja) |
SE (1) | SE448951B (ja) |
ZA (1) | ZA817732B (ja) |
Families Citing this family (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE3522538A1 (de) * | 1984-06-22 | 1986-01-02 | Chiyoda Chemical Engineering & Construction Co. Ltd., Yokohama, Kanagawa | Verfahren und katalysator zur hydrierung von kohleteerpech |
EP0178774B1 (en) * | 1984-09-12 | 1991-02-20 | Nippon Kokan Kabushiki Kaisha | A hydrogenation catalyst for coal tar, a method of hydrogenation of coal tar with use of such catalyst, and a method of producing super needle coke from the hydrogenation product of coal tar |
GC0000065A (en) | 1998-09-01 | 2004-06-30 | Japan Energy Corp | Hydrocracking catalyst, producing method threof, and hydrocracking method. |
JP4493997B2 (ja) * | 2003-12-10 | 2010-06-30 | 財団法人石油産業活性化センター | 炭化水素油の水素化脱硫触媒及びその製造方法 |
WO2008019581A1 (fr) | 2006-08-11 | 2008-02-21 | China Petroleum & Chemical Corporation | Alumine ayant une structure poreuse complexe, et catalyseur et procédé d'hydrogénation sélective de l'essence de craquage |
JP4902424B2 (ja) * | 2007-05-21 | 2012-03-21 | Jx日鉱日石エネルギー株式会社 | 水素化精製触媒及び水素化精製方法 |
Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3361526A (en) * | 1964-06-19 | 1968-01-02 | Grace W R & Co | Process for producing alumina having a narrow pore size distribution |
FR1592580A (ja) * | 1967-10-27 | 1970-05-19 | ||
US3843509A (en) * | 1972-01-06 | 1974-10-22 | Toa Nenryo Kogyo Kk | Method of catalytic conversion of heavy hydrocarbon oils |
US3952069A (en) * | 1973-01-26 | 1976-04-20 | Gulf Research & Development Company | Hydrogenation of aromatics |
US4008149A (en) * | 1975-04-18 | 1977-02-15 | Toa Nenryo Kogyo Kabushiki Kaisha | Process of hydro-refining hydrocarbon oils |
US4013547A (en) * | 1976-01-22 | 1977-03-22 | Union Oil Company Of California | Desulfurization of residual petroleum oils with a catalyst calcined at higher temperatures |
GB2073162A (en) * | 1980-04-01 | 1981-10-14 | Grace W R & Co | Extruded alumina catalyst support having controlled distribution of pore sizes |
Family Cites Families (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
NL261905A (ja) * | 1960-03-02 |
-
1981
- 1981-11-05 CA CA000389545A patent/CA1159039A/en not_active Expired
- 1981-11-09 ZA ZA817732A patent/ZA817732B/xx unknown
- 1981-11-13 AU AU77476/81A patent/AU540245B2/en not_active Ceased
- 1981-11-19 DE DE19813145718 patent/DE3145718A1/de active Granted
- 1981-11-19 FR FR8121684A patent/FR2494597A1/fr active Granted
- 1981-11-19 MX MX016070A patent/MX172430B/es unknown
- 1981-11-19 MX MX190208A patent/MX160789A/es unknown
- 1981-11-20 JP JP56187655A patent/JPS5946666B2/ja not_active Expired
- 1981-11-20 NL NL8105267A patent/NL8105267A/nl not_active Application Discontinuation
- 1981-11-20 ES ES507340A patent/ES507340A1/es not_active Expired
- 1981-11-20 GB GB8135076A patent/GB2087747B/en not_active Expired
- 1981-11-20 SE SE8106925A patent/SE448951B/sv not_active IP Right Cessation
- 1981-11-20 IT IT49747/81A patent/IT1143446B/it active
Patent Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3361526A (en) * | 1964-06-19 | 1968-01-02 | Grace W R & Co | Process for producing alumina having a narrow pore size distribution |
FR1592580A (ja) * | 1967-10-27 | 1970-05-19 | ||
US3843509A (en) * | 1972-01-06 | 1974-10-22 | Toa Nenryo Kogyo Kk | Method of catalytic conversion of heavy hydrocarbon oils |
US3952069A (en) * | 1973-01-26 | 1976-04-20 | Gulf Research & Development Company | Hydrogenation of aromatics |
US4008149A (en) * | 1975-04-18 | 1977-02-15 | Toa Nenryo Kogyo Kabushiki Kaisha | Process of hydro-refining hydrocarbon oils |
US4013547A (en) * | 1976-01-22 | 1977-03-22 | Union Oil Company Of California | Desulfurization of residual petroleum oils with a catalyst calcined at higher temperatures |
GB2073162A (en) * | 1980-04-01 | 1981-10-14 | Grace W R & Co | Extruded alumina catalyst support having controlled distribution of pore sizes |
Also Published As
Publication number | Publication date |
---|---|
ZA817732B (en) | 1982-10-27 |
AU540245B2 (en) | 1984-11-08 |
GB2087747B (en) | 1984-07-04 |
DE3145718C2 (ja) | 1987-06-19 |
IT1143446B (it) | 1986-10-22 |
ES507340A0 (es) | 1985-03-01 |
JPS57117343A (en) | 1982-07-21 |
IT8149747A0 (it) | 1981-11-20 |
ES507340A1 (es) | 1985-03-01 |
AU7747681A (en) | 1982-05-27 |
SE8106925L (sv) | 1982-05-22 |
DE3145718A1 (de) | 1982-06-16 |
MX160789A (es) | 1990-05-17 |
CA1159039A (en) | 1983-12-20 |
FR2494597B1 (ja) | 1985-01-04 |
NL8105267A (nl) | 1982-06-16 |
SE448951B (sv) | 1987-03-30 |
JPS5946666B2 (ja) | 1984-11-14 |
MX172430B (es) | 1993-12-16 |
GB2087747A (en) | 1982-06-03 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
ST | Notification of lapse |