FR2483400A1 - Procede de preparation d'hydrocarbures - Google Patents
Procede de preparation d'hydrocarbures Download PDFInfo
- Publication number
- FR2483400A1 FR2483400A1 FR8110709A FR8110709A FR2483400A1 FR 2483400 A1 FR2483400 A1 FR 2483400A1 FR 8110709 A FR8110709 A FR 8110709A FR 8110709 A FR8110709 A FR 8110709A FR 2483400 A1 FR2483400 A1 FR 2483400A1
- Authority
- FR
- France
- Prior art keywords
- weight
- parts
- mixture
- catalyst
- stage
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000000034 method Methods 0.000 title claims abstract description 33
- 229930195733 hydrocarbon Natural products 0.000 title claims abstract description 19
- 150000002430 hydrocarbons Chemical class 0.000 title claims abstract description 19
- 238000002360 preparation method Methods 0.000 title claims description 5
- 239000003054 catalyst Substances 0.000 claims abstract description 80
- 239000000203 mixture Substances 0.000 claims abstract description 59
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims abstract description 41
- 230000000694 effects Effects 0.000 claims abstract description 23
- 229910052742 iron Inorganic materials 0.000 claims abstract description 20
- 238000006243 chemical reaction Methods 0.000 claims abstract description 19
- 229910017052 cobalt Inorganic materials 0.000 claims abstract description 19
- 239000010941 cobalt Substances 0.000 claims abstract description 19
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims abstract description 19
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 claims abstract description 11
- 229910052707 ruthenium Inorganic materials 0.000 claims abstract description 11
- 229910052739 hydrogen Inorganic materials 0.000 claims abstract description 9
- 239000001257 hydrogen Substances 0.000 claims abstract description 9
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical class [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims abstract description 8
- 230000015572 biosynthetic process Effects 0.000 claims abstract description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 23
- 230000003197 catalytic effect Effects 0.000 claims description 21
- 230000001588 bifunctional effect Effects 0.000 claims description 15
- 239000007795 chemical reaction product Substances 0.000 claims description 15
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 13
- 239000000377 silicon dioxide Substances 0.000 claims description 11
- 239000010949 copper Substances 0.000 claims description 9
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims description 8
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 8
- 239000007864 aqueous solution Substances 0.000 claims description 8
- 238000001354 calcination Methods 0.000 claims description 8
- 229910052804 chromium Inorganic materials 0.000 claims description 8
- 239000011651 chromium Substances 0.000 claims description 8
- 238000001035 drying Methods 0.000 claims description 8
- 239000011777 magnesium Substances 0.000 claims description 7
- 230000009466 transformation Effects 0.000 claims description 7
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims description 6
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 6
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 6
- 229910002091 carbon monoxide Inorganic materials 0.000 claims description 6
- 229910052749 magnesium Inorganic materials 0.000 claims description 6
- 229910052700 potassium Inorganic materials 0.000 claims description 6
- 239000011591 potassium Substances 0.000 claims description 6
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 5
- 229910052802 copper Inorganic materials 0.000 claims description 5
- 239000004215 Carbon black (E152) Substances 0.000 claims description 4
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 4
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 claims description 4
- 239000010936 titanium Substances 0.000 claims description 4
- 229910052719 titanium Inorganic materials 0.000 claims description 4
- 229910052726 zirconium Inorganic materials 0.000 claims description 4
- 238000005470 impregnation Methods 0.000 claims description 3
- 159000000003 magnesium salts Chemical class 0.000 claims description 2
- 150000003839 salts Chemical class 0.000 claims description 2
- 239000000945 filler Substances 0.000 claims 1
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 abstract description 7
- 238000003786 synthesis reaction Methods 0.000 abstract description 2
- 229910002090 carbon oxide Inorganic materials 0.000 abstract 1
- 238000004519 manufacturing process Methods 0.000 abstract 1
- 238000002474 experimental method Methods 0.000 description 17
- 238000012360 testing method Methods 0.000 description 7
- 239000011701 zinc Substances 0.000 description 4
- 229910002092 carbon dioxide Inorganic materials 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- 239000007789 gas Substances 0.000 description 2
- 238000002309 gasification Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 150000003754 zirconium Chemical class 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 229910004298 SiO 2 Inorganic materials 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- RHZUVFJBSILHOK-UHFFFAOYSA-N anthracen-1-ylmethanolate Chemical compound C1=CC=C2C=C3C(C[O-])=CC=CC3=CC2=C1 RHZUVFJBSILHOK-UHFFFAOYSA-N 0.000 description 1
- 239000003830 anthracite Substances 0.000 description 1
- 239000010426 asphalt Substances 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 210000000988 bone and bone Anatomy 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- 150000001844 chromium Chemical class 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 150000001868 cobalt Chemical class 0.000 description 1
- 239000000571 coke Substances 0.000 description 1
- 238000000151 deposition Methods 0.000 description 1
- 210000000540 fraction c Anatomy 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- 239000003077 lignite Substances 0.000 description 1
- 239000002480 mineral oil Substances 0.000 description 1
- 235000010446 mineral oil Nutrition 0.000 description 1
- 239000004058 oil shale Substances 0.000 description 1
- 239000006069 physical mixture Substances 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 230000001131 transforming effect Effects 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
- C10G2/30—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
- C10G2/32—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts
- C10G2/33—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used
- C10G2/331—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used containing group VIII-metals
- C10G2/332—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used containing group VIII-metals of the iron-group
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/74—Iron group metals
- B01J23/745—Iron
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/78—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with alkali- or alkaline earth metals
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
- C07C1/02—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon
- C07C1/04—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon from carbon monoxide with hydrogen
- C07C1/0425—Catalysts; their physical properties
- C07C1/043—Catalysts; their physical properties characterised by the composition
- C07C1/0435—Catalysts; their physical properties characterised by the composition containing a metal of group 8 or a compound thereof
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
- C07C1/02—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon
- C07C1/04—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon from carbon monoxide with hydrogen
- C07C1/0425—Catalysts; their physical properties
- C07C1/043—Catalysts; their physical properties characterised by the composition
- C07C1/0435—Catalysts; their physical properties characterised by the composition containing a metal of group 8 or a compound thereof
- C07C1/044—Catalysts; their physical properties characterised by the composition containing a metal of group 8 or a compound thereof containing iron
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
- C07C1/02—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon
- C07C1/04—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon from carbon monoxide with hydrogen
- C07C1/0425—Catalysts; their physical properties
- C07C1/0445—Preparation; Activation
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
- C07C1/02—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon
- C07C1/04—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon from carbon monoxide with hydrogen
- C07C1/0485—Set-up of reactors or accessories; Multi-step processes
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
- C10G2/30—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
- C10G2/32—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts
- C10G2/33—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used
- C10G2/331—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used containing group VIII-metals
- C10G2/333—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used containing group VIII-metals of the platinum-group
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
- C07C2521/02—Boron or aluminium; Oxides or hydroxides thereof
- C07C2521/04—Alumina
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
- C07C2521/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
- C07C2521/08—Silica
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
- C07C2521/10—Magnesium; Oxides or hydroxides thereof
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/02—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the alkali- or alkaline earth metals or beryllium
- C07C2523/04—Alkali metals
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- C07C2523/24—Chromium, molybdenum or tungsten
- C07C2523/26—Chromium
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals
- C07C2523/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals of the platinum group metals
- C07C2523/46—Ruthenium, rhodium, osmium or iridium
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
- C07C2523/72—Copper
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
- C07C2523/74—Iron group metals
- C07C2523/745—Iron
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
- C07C2523/74—Iron group metals
- C07C2523/75—Cobalt
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
- C07C2523/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups C07C2523/02 - C07C2523/36
- C07C2523/78—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups C07C2523/02 - C07C2523/36 with alkali- or alkaline earth metals or beryllium
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
- C07C2523/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups C07C2523/02 - C07C2523/36
- C07C2523/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups C07C2523/02 - C07C2523/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- C07C2523/85—Chromium, molybdenum or tungsten
- C07C2523/86—Chromium
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- General Chemical & Material Sciences (AREA)
- Materials Engineering (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| NL8003215A NL8003215A (nl) | 1980-06-03 | 1980-06-03 | Werkwijze voor de bereiding van koolwaterstoffen. |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| FR2483400A1 true FR2483400A1 (fr) | 1981-12-04 |
| FR2483400B1 FR2483400B1 (enrdf_load_stackoverflow) | 1985-05-03 |
Family
ID=19835408
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| FR8110709A Granted FR2483400A1 (fr) | 1980-06-03 | 1981-05-29 | Procede de preparation d'hydrocarbures |
Country Status (16)
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2496094A1 (fr) * | 1980-12-12 | 1982-06-18 | Shell Int Research | Procede pour la preparation de composes organiques contenant de l'oxygene et d'hydrocarbures paraffiniques |
Families Citing this family (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NL8006484A (nl) * | 1980-11-28 | 1982-06-16 | Shell Int Research | Werkwijze voor de bereiding van koolwaterstoffen. |
| CA1196617A (en) * | 1982-07-14 | 1985-11-12 | George E. Morris | Catalyst composition, method for its production and its use in the production of hydrocarbons from synthesis gas |
| EP0109702B1 (en) * | 1982-11-22 | 1988-03-09 | Shell Internationale Researchmaatschappij B.V. | Process for the preparation of hydrocarbons |
| CA1240708A (en) * | 1983-11-15 | 1988-08-16 | Johannes K. Minderhoud | Process for the preparation of hydrocarbons |
| CA1234158A (en) * | 1983-11-15 | 1988-03-15 | Johannes K. Minderhoud | Process for the preparation of hydrocarbons |
| GB8330606D0 (en) * | 1983-11-16 | 1983-12-21 | Shell Int Research | Preparation of hydrocarbons and fuel gas |
| NL8400609A (nl) * | 1984-02-28 | 1985-09-16 | Shell Int Research | Werkwijze voor de bereiding van koolwaterstoffen. |
| US4617320A (en) * | 1984-06-27 | 1986-10-14 | Union Carbide Corporation | Enhanced conversion of syngas to liquid motor fuels |
| US4617283A (en) * | 1984-06-27 | 1986-10-14 | Union Carbide Corporation | Catalyst for converting synthesis gas to liquid motor fuels |
| US4556645A (en) * | 1984-06-27 | 1985-12-03 | Union Carbide Corporation | Enhanced catalyst for conversion of syngas to liquid motor fuels |
| CA1236454A (en) * | 1984-06-27 | 1988-05-10 | John J. Tsai | Monomeric cationic glycoside derivatives |
| US4632941A (en) * | 1984-06-27 | 1986-12-30 | Union Carbide Corporation | Enhanced catalyst and process for converting synthesis gas to liquid motor fuels |
| US4579830A (en) * | 1984-06-27 | 1986-04-01 | Union Carbide Corporation | Enhanced catalyst for converting synthesis gas to liquid motor fuels |
| US4663355A (en) * | 1984-06-27 | 1987-05-05 | Union Carbide Corporation | Catalyst and process for converting synthesis gas to liquid motor fuels |
| GB2243616A (en) * | 1990-05-04 | 1991-11-06 | Shell Int Research | Preparation of paraffinic and aromatic hydrocarbons |
| US6331573B1 (en) * | 2000-02-29 | 2001-12-18 | Chevron U.S.A. Inc. | Increased liquid sensitivity during fischer-tropsch synthesis by olefin incorporation |
| WO2004052535A1 (en) * | 2002-12-06 | 2004-06-24 | Dow Global Technologies Inc. | Dehydrogenation catalyst and process for preparing the same |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2388781A1 (fr) * | 1977-04-28 | 1978-11-24 | Shell Int Research | Procede pour la preparation d'hydrocarbures a partir de melanges de gaz d'une faible teneur en hydrogene |
| FR2460712A1 (fr) * | 1979-07-13 | 1981-01-30 | Shell Int Research | Procede pour la preparation de catalyseurs de fischer-tropsch et application de ces catalyseurs a la preparation d'hydrocarbures |
| FR2463111A1 (fr) * | 1979-08-06 | 1981-02-20 | Shell Int Research | Procede de preparation d'hydrocarbures a partir d'oxyde de carbone et d'hydrogene |
-
1980
- 1980-06-03 NL NL8003215A patent/NL8003215A/nl not_active Application Discontinuation
-
1981
- 1981-03-18 CA CA000373306A patent/CA1152535A/en not_active Expired
- 1981-03-26 IN IN331/CAL/81A patent/IN154191B/en unknown
- 1981-05-22 BE BE1/10229A patent/BE888922A/nl not_active IP Right Cessation
- 1981-05-29 FR FR8110709A patent/FR2483400A1/fr active Granted
- 1981-06-01 JP JP8258181A patent/JPS5724314A/ja active Pending
- 1981-06-01 BR BR8103445A patent/BR8103445A/pt unknown
- 1981-06-01 ES ES502652A patent/ES502652A0/es active Granted
- 1981-06-01 SE SE8103437A patent/SE446971B/sv not_active IP Right Cessation
- 1981-06-01 GB GB8116650A patent/GB2077754B/en not_active Expired
- 1981-06-01 DE DE19813121752 patent/DE3121752A1/de active Granted
- 1981-06-01 AT AT0243881A patent/AT371793B/de not_active IP Right Cessation
- 1981-06-01 IT IT22074/81A patent/IT1136783B/it active
- 1981-06-01 AU AU71211/81A patent/AU539212B2/en not_active Ceased
- 1981-06-02 NZ NZ197260A patent/NZ197260A/xx unknown
- 1981-06-02 ZA ZA00813658A patent/ZA813658B/xx unknown
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2388781A1 (fr) * | 1977-04-28 | 1978-11-24 | Shell Int Research | Procede pour la preparation d'hydrocarbures a partir de melanges de gaz d'une faible teneur en hydrogene |
| FR2460712A1 (fr) * | 1979-07-13 | 1981-01-30 | Shell Int Research | Procede pour la preparation de catalyseurs de fischer-tropsch et application de ces catalyseurs a la preparation d'hydrocarbures |
| FR2463111A1 (fr) * | 1979-08-06 | 1981-02-20 | Shell Int Research | Procede de preparation d'hydrocarbures a partir d'oxyde de carbone et d'hydrogene |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2496094A1 (fr) * | 1980-12-12 | 1982-06-18 | Shell Int Research | Procede pour la preparation de composes organiques contenant de l'oxygene et d'hydrocarbures paraffiniques |
Also Published As
| Publication number | Publication date |
|---|---|
| IT8122074A0 (it) | 1981-06-01 |
| DE3121752C2 (enrdf_load_stackoverflow) | 1989-06-01 |
| NL8003215A (nl) | 1982-01-04 |
| SE446971B (sv) | 1986-10-20 |
| GB2077754B (en) | 1983-06-02 |
| BE888922A (nl) | 1981-11-23 |
| CA1152535A (en) | 1983-08-23 |
| BR8103445A (pt) | 1982-02-24 |
| ES8303269A1 (es) | 1983-02-01 |
| DE3121752A1 (de) | 1982-01-28 |
| FR2483400B1 (enrdf_load_stackoverflow) | 1985-05-03 |
| AU539212B2 (en) | 1984-09-13 |
| IN154191B (enrdf_load_stackoverflow) | 1984-09-29 |
| GB2077754A (en) | 1981-12-23 |
| JPS5724314A (en) | 1982-02-08 |
| AU7121181A (en) | 1981-12-10 |
| ES502652A0 (es) | 1983-02-01 |
| IT1136783B (it) | 1986-09-03 |
| SE8103437L (sv) | 1981-12-04 |
| AT371793B (de) | 1983-07-25 |
| ATA243881A (de) | 1982-12-15 |
| NZ197260A (en) | 1983-11-18 |
| ZA813658B (en) | 1982-06-30 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| FR2483400A1 (fr) | Procede de preparation d'hydrocarbures | |
| FR2495134A1 (fr) | Procede de preparation d'hydrocarbures | |
| RU2017517C1 (ru) | Катализатор для конверсии синтез-газа в углеводороды и способ получения углеводородов | |
| RU2450044C2 (ru) | Способ активации катализатора синтеза фишера-тропша | |
| O'Brien et al. | Activity and selectivity of precipitated iron Fischer-Tropsch catalysts | |
| FR2463111A1 (fr) | Procede de preparation d'hydrocarbures a partir d'oxyde de carbone et d'hydrogene | |
| FR2509718A1 (fr) | Procede de preparation de composes organiques | |
| EP0188530A1 (en) | IMPROVED CONVERSION OF SYNTHESIS GAS TO LIQUID FUELS FOR ENGINES. | |
| FR2496094A1 (fr) | Procede pour la preparation de composes organiques contenant de l'oxygene et d'hydrocarbures paraffiniques | |
| US7226954B2 (en) | Integrated process and apparatus for producing liquid fuels | |
| EP0753562B1 (fr) | Procédé de conversion du gaz de synthèse en phase liquide | |
| US6331573B1 (en) | Increased liquid sensitivity during fischer-tropsch synthesis by olefin incorporation | |
| US7468396B2 (en) | Process for directly producing mixed linear alpha-alcohols having 1 to 18 carbon atoms from synthesis gas | |
| FR2462389A1 (fr) | Procede de preparation de silicates cristallins | |
| Schlesinger et al. | Chemicals from the Fischer-Tropsch synthesis | |
| CA2359428C (fr) | Procede de conversion de gaz de synthese en presence d'un catalyseur comprenant un element du groupe viii, disperse sur un support a base d'alumine modifiee par impregnation aqueuse de silicate d'ammonium quaternaire | |
| Luo et al. | Effect of palladium on iron Fischer–Tropsch synthesis catalysts | |
| US7968610B2 (en) | Process for stabilizing the performances of a catalyst for Fischer Tropsch reaction | |
| FR2513626A1 (fr) | Procede pour la production d'hydrocarbures | |
| Davis | Technology development for iron Fischer-Tropsch catalysts | |
| BE1006539A4 (fr) | Procede de synthese d'hydrocarbures a partir de gaz de synthese en presence d'un catalyseur a base de cobalt. | |
| EP2617796B1 (en) | Acetylene enhanced conversion of syngas to fischer-tropsch hydrocarbon products | |
| EP1094049B1 (fr) | Procédé de synthèse d'hydrocarbures à partir de gaz de synthèse en présence d'un alliage métallique de Raney dispersé dans une phase liquide | |
| CA2280397C (fr) | Procede de synthese fischer-tropsch en presence d'un catalyseur dont les particules metalliques ont une taille controlee | |
| KR100974542B1 (ko) | 철계 촉매 및 ｃ5-ｃ7의 노말탄화수소 초임계 유체를 사용한 피셔-트롭쉬 합성방법 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| ST | Notification of lapse |