FR2477128A1 - Composition vitreuse conductrice de cations alcalins et procede de preparation d'une telle composition - Google Patents
Composition vitreuse conductrice de cations alcalins et procede de preparation d'une telle composition Download PDFInfo
- Publication number
- FR2477128A1 FR2477128A1 FR8004547A FR8004547A FR2477128A1 FR 2477128 A1 FR2477128 A1 FR 2477128A1 FR 8004547 A FR8004547 A FR 8004547A FR 8004547 A FR8004547 A FR 8004547A FR 2477128 A1 FR2477128 A1 FR 2477128A1
- Authority
- FR
- France
- Prior art keywords
- composition
- lix
- glass
- ratio
- preparing
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 26
- 239000011521 glass Substances 0.000 title claims description 25
- 150000001768 cations Chemical class 0.000 title abstract description 6
- 238000004519 manufacturing process Methods 0.000 title description 3
- 229910016320 bLi2S Inorganic materials 0.000 claims abstract description 7
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Chemical group BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 claims abstract description 6
- 229910052794 bromium Inorganic materials 0.000 claims abstract description 6
- 238000000034 method Methods 0.000 claims abstract description 5
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical group [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 claims abstract description 4
- 239000000460 chlorine Substances 0.000 claims abstract description 4
- 229910052801 chlorine Inorganic materials 0.000 claims abstract description 4
- 125000001309 chloro group Chemical group Cl* 0.000 claims abstract description 4
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical group [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 claims abstract 2
- 229910052740 iodine Chemical group 0.000 claims abstract 2
- 239000011630 iodine Chemical group 0.000 claims abstract 2
- 229910052744 lithium Inorganic materials 0.000 claims description 7
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 claims description 6
- 229910001216 Li2S Inorganic materials 0.000 claims description 4
- PNDPGZBMCMUPRI-UHFFFAOYSA-N iodine Chemical group II PNDPGZBMCMUPRI-UHFFFAOYSA-N 0.000 claims description 4
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 claims description 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 3
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims description 3
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 3
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 3
- 229910052796 boron Inorganic materials 0.000 claims description 3
- 150000001875 compounds Chemical class 0.000 claims description 3
- 229910052732 germanium Inorganic materials 0.000 claims description 3
- GNPVGFCGXDBREM-UHFFFAOYSA-N germanium atom Chemical compound [Ge] GNPVGFCGXDBREM-UHFFFAOYSA-N 0.000 claims description 3
- 238000002844 melting Methods 0.000 claims description 3
- 230000008018 melting Effects 0.000 claims description 3
- 229910052760 oxygen Inorganic materials 0.000 claims description 3
- 239000001301 oxygen Substances 0.000 claims description 3
- 239000011574 phosphorus Substances 0.000 claims description 3
- 229910052698 phosphorus Inorganic materials 0.000 claims description 3
- 229920006395 saturated elastomer Polymers 0.000 claims description 3
- 229910052710 silicon Inorganic materials 0.000 claims description 3
- 239000010703 silicon Substances 0.000 claims description 3
- 239000011734 sodium Substances 0.000 claims description 3
- 229910052708 sodium Inorganic materials 0.000 claims description 3
- 229910052717 sulfur Inorganic materials 0.000 claims description 3
- 239000011593 sulfur Substances 0.000 claims description 3
- 125000001246 bromo group Chemical group Br* 0.000 claims description 2
- 238000010791 quenching Methods 0.000 claims description 2
- 239000011872 intimate mixture Substances 0.000 claims 1
- AMXOYNBUYSYVKV-UHFFFAOYSA-M lithium bromide Chemical compound [Li+].[Br-] AMXOYNBUYSYVKV-UHFFFAOYSA-M 0.000 description 6
- 239000011230 binding agent Substances 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
- 239000007784 solid electrolyte Substances 0.000 description 3
- 229910018091 Li 2 S Inorganic materials 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 239000003708 ampul Substances 0.000 description 2
- 239000003792 electrolyte Substances 0.000 description 2
- 239000011244 liquid electrolyte Substances 0.000 description 2
- JKQOBWVOAYFWKG-UHFFFAOYSA-N molybdenum trioxide Chemical compound O=[Mo](=O)=O JKQOBWVOAYFWKG-UHFFFAOYSA-N 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 description 1
- 229910005896 NiPS3 Inorganic materials 0.000 description 1
- 229910003092 TiS2 Inorganic materials 0.000 description 1
- 239000004480 active ingredient Substances 0.000 description 1
- 238000000137 annealing Methods 0.000 description 1
- 150000001485 argon Chemical class 0.000 description 1
- 239000012300 argon atmosphere Substances 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 239000004020 conductor Substances 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 150000004820 halides Chemical class 0.000 description 1
- -1 lithium halides Chemical class 0.000 description 1
- 229910001416 lithium ion Inorganic materials 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 238000010583 slow cooling Methods 0.000 description 1
- ZNOKGRXACCSDPY-UHFFFAOYSA-N tungsten(VI) oxide Inorganic materials O=[W](=O)=O ZNOKGRXACCSDPY-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C3/00—Glass compositions
- C03C3/32—Non-oxide glass compositions, e.g. binary or ternary halides, sulfides or nitrides of germanium, selenium or tellurium
- C03C3/321—Chalcogenide glasses, e.g. containing S, Se, Te
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C4/00—Compositions for glass with special properties
- C03C4/18—Compositions for glass with special properties for ion-sensitive glass
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M6/00—Primary cells; Manufacture thereof
- H01M6/14—Cells with non-aqueous electrolyte
- H01M6/18—Cells with non-aqueous electrolyte with solid electrolyte
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- General Chemical & Material Sciences (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Electrochemistry (AREA)
- Manufacturing & Machinery (AREA)
- Glass Compositions (AREA)
- Conductive Materials (AREA)
- Inorganic Compounds Of Heavy Metals (AREA)
- Primary Cells (AREA)
- Electric Double-Layer Capacitors Or The Like (AREA)
- Fuel Cell (AREA)
Priority Applications (7)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR8004547A FR2477128A1 (fr) | 1980-02-29 | 1980-02-29 | Composition vitreuse conductrice de cations alcalins et procede de preparation d'une telle composition |
| IL61783A IL61783A (en) | 1980-02-29 | 1980-12-22 | Alkaline cation conductive vitreous compound and its preparation |
| US06/226,404 US4331750A (en) | 1980-02-29 | 1981-01-19 | Alkaline cation conductive vitreous composition and a method of preparing such a composition |
| EP81101278A EP0036105B1 (fr) | 1980-02-29 | 1981-02-23 | Composition vitreuse conductrice de cations alcalins, procédé de préparation d'une telle composition et générateur électrochimique en faisant application |
| AT81101278T ATE5675T1 (de) | 1980-02-29 | 1981-02-23 | Glasartiges alkalikationleitendes material, verfahren zu seiner herstellung und eine dieses material verwendende elektrochemische zelle. |
| DE8181101278T DE3161677D1 (en) | 1980-02-29 | 1981-02-23 | Vitreous alcali-cation conducting composition, method of preparing such a composition and an electrochemical cell using such a composition |
| JP2757281A JPS56134536A (en) | 1980-02-29 | 1981-02-26 | Alkaline cation conductive glass composition and manufacture thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR8004547A FR2477128A1 (fr) | 1980-02-29 | 1980-02-29 | Composition vitreuse conductrice de cations alcalins et procede de preparation d'une telle composition |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| FR2477128A1 true FR2477128A1 (fr) | 1981-09-04 |
| FR2477128B1 FR2477128B1 (enrdf_load_stackoverflow) | 1982-06-18 |
Family
ID=9239161
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| FR8004547A Granted FR2477128A1 (fr) | 1980-02-29 | 1980-02-29 | Composition vitreuse conductrice de cations alcalins et procede de preparation d'une telle composition |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US4331750A (enrdf_load_stackoverflow) |
| EP (1) | EP0036105B1 (enrdf_load_stackoverflow) |
| JP (1) | JPS56134536A (enrdf_load_stackoverflow) |
| AT (1) | ATE5675T1 (enrdf_load_stackoverflow) |
| DE (1) | DE3161677D1 (enrdf_load_stackoverflow) |
| FR (1) | FR2477128A1 (enrdf_load_stackoverflow) |
| IL (1) | IL61783A (enrdf_load_stackoverflow) |
Families Citing this family (37)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2918940C2 (de) * | 1979-05-10 | 1984-08-09 | Max Planck Gesellschaft zur Förderung der Wissenschaften e.V., 3400 Göttingen | Festes Ionenleitermaterial, seine Verwendung und Verfahren zu seiner Herstellung |
| US4444857A (en) * | 1981-06-17 | 1984-04-24 | Societe Anonyme Dite: Gipelec | Electrochemical cell including a solid electrolyte made from a cation conductive vitreous compound |
| FR2521125A1 (fr) * | 1982-02-09 | 1983-08-12 | Centre Nat Rech Scient | Materiaux vitreux a conductivite ionique, leur preparation et leurs applications electrochimiques |
| FR2525396A1 (fr) * | 1982-04-16 | 1983-10-21 | Gipelec | Pile au lithium comportant un electrolyte solide forme par une composition vitreuse conductrice |
| US4542108A (en) * | 1982-05-06 | 1985-09-17 | The United States Of America As Represented By The United States Department Of Energy | Glass capable of ionic conduction and method of preparation |
| US4432891A (en) * | 1982-05-06 | 1984-02-21 | The United States Of America As Represented By The United States Department Of Energy | Glass capable of ionic conduction and method of preparation |
| FR2544301A1 (fr) * | 1983-04-15 | 1984-10-19 | Centre Nat Rech Scient | Nouveaux materiaux vitreux intercalaires possedant notamment des proprietes semi-conductrices, leur fabrication et les applications electrochimiques de ces materiaux et de leur structure vitreuse de base |
| US4465745A (en) * | 1983-06-29 | 1984-08-14 | Union Carbide Corporation | Crystalline solid lithium cation conductive electrolyte |
| US4465746A (en) * | 1983-06-29 | 1984-08-14 | Union Carbide Corporation | Vitreous solid lithium cation conductive electrolyte |
| JPS60221965A (ja) * | 1984-04-18 | 1985-11-06 | Sanyo Electric Co Ltd | 固体電解質電池 |
| US4585714A (en) * | 1985-06-28 | 1986-04-29 | Union Carbide Corporation | Quaternary vitreous solid lithium cation conductive electrolyte |
| US4599284A (en) * | 1985-10-01 | 1986-07-08 | Union Carbide Corporation | Vitreous phosphorus oxide-sulfide solid lithium electrolyte |
| US5455206A (en) * | 1990-09-14 | 1995-10-03 | Kaun; Thomas D. | Corrosion resistant ceramic materials |
| US5085953A (en) * | 1990-09-18 | 1992-02-04 | Eveready Battery Company, Inc. | Vitreous compositions based on Li3 PO4 and LiPO3 as network formers and network modifiers |
| US5227148A (en) * | 1990-09-18 | 1993-07-13 | Eveready Battery Company, Inc. | Vitreous compositions based on Li3 PO4 and LiPO3 as network formers and network modifiers |
| US5786110A (en) * | 1992-06-22 | 1998-07-28 | Arizona Board Of Regents | Alkali-metal-ion conducting electrolytes |
| US20030157409A1 (en) * | 2002-02-21 | 2003-08-21 | Sui-Yang Huang | Polymer lithium battery with ionic electrolyte |
| JP5287739B2 (ja) | 2009-05-01 | 2013-09-11 | トヨタ自動車株式会社 | 固体電解質材料 |
| JP5349427B2 (ja) * | 2010-08-26 | 2013-11-20 | トヨタ自動車株式会社 | 硫化物固体電解質材料、正極体およびリチウム固体電池 |
| JP5443445B2 (ja) | 2011-07-06 | 2014-03-19 | トヨタ自動車株式会社 | 硫化物固体電解質材料、リチウム固体電池、および、硫化物固体電解質材料の製造方法 |
| JP2014028717A (ja) * | 2012-07-31 | 2014-02-13 | Idemitsu Kosan Co Ltd | 固体電解質 |
| US11984553B2 (en) | 2014-12-02 | 2024-05-14 | Polyplus Battery Company | Lithium ion conducting sulfide glass fabrication |
| US20190173128A1 (en) | 2014-12-02 | 2019-06-06 | Polyplus Battery Company | Making and inspecting a web of vitreous lithium sulfide separator sheet and lithium electrode assemblies and battery cells |
| US12294050B2 (en) | 2014-12-02 | 2025-05-06 | Polyplus Battery Company | Lithium ion conducting sulfide glass fabrication |
| US11749834B2 (en) | 2014-12-02 | 2023-09-05 | Polyplus Battery Company | Methods of making lithium ion conducting sulfide glass |
| US10164289B2 (en) | 2014-12-02 | 2018-12-25 | Polyplus Battery Company | Vitreous solid electrolyte sheets of Li ion conducting sulfur-based glass and associated structures, cells and methods |
| US10147968B2 (en) | 2014-12-02 | 2018-12-04 | Polyplus Battery Company | Standalone sulfide based lithium ion-conducting glass solid electrolyte and associated structures, cells and methods |
| US12051824B2 (en) | 2020-07-10 | 2024-07-30 | Polyplus Battery Company | Methods of making glass constructs |
| US10601071B2 (en) | 2014-12-02 | 2020-03-24 | Polyplus Battery Company | Methods of making and inspecting a web of vitreous lithium sulfide separator sheet and lithium electrode assemblies |
| US10868293B2 (en) | 2017-07-07 | 2020-12-15 | Polyplus Battery Company | Treating sulfide glass surfaces and making solid state laminate electrode assemblies |
| US10629950B2 (en) | 2017-07-07 | 2020-04-21 | Polyplus Battery Company | Encapsulated sulfide glass solid electrolytes and solid-state laminate electrode assemblies |
| WO2017197039A1 (en) | 2016-05-10 | 2017-11-16 | Polyplus Battery Company | Solid-state laminate electrode assemblies and methods of making |
| US11631889B2 (en) | 2020-01-15 | 2023-04-18 | Polyplus Battery Company | Methods and materials for protection of sulfide glass solid electrolytes |
| US10862171B2 (en) | 2017-07-19 | 2020-12-08 | Polyplus Battery Company | Solid-state laminate electrode assembly fabrication and making thin extruded lithium metal foils |
| US12021187B2 (en) | 2020-08-04 | 2024-06-25 | Polyplus Battery Company | Surface treatment of a sulfide glass solid electrolyte layer |
| US12034116B2 (en) | 2020-08-04 | 2024-07-09 | Polyplus Battery Company | Glass solid electrolyte layer, methods of making glass solid electrolyte layer and electrodes and battery cells thereof |
| US12021238B2 (en) | 2020-08-04 | 2024-06-25 | Polyplus Battery Company | Glassy embedded solid-state electrode assemblies, solid-state batteries and methods of making electrode assemblies and solid-state batteries |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2341953A1 (fr) * | 1976-02-19 | 1977-09-16 | Anvar | Nouveaux materiaux a conductivite ionique, applicables a la constitution d'electrolytes solides pour piles et batteries seches |
| FR2387192A1 (fr) * | 1977-04-15 | 1978-11-10 | France Etat | Conducteurs cationiques amorphes du lithium |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4049879A (en) * | 1976-04-19 | 1977-09-20 | Exxon Research & Engineering Co. | Intercalated transition metal phosphorus trisulfides |
-
1980
- 1980-02-29 FR FR8004547A patent/FR2477128A1/fr active Granted
- 1980-12-22 IL IL61783A patent/IL61783A/xx unknown
-
1981
- 1981-01-19 US US06/226,404 patent/US4331750A/en not_active Expired - Fee Related
- 1981-02-23 AT AT81101278T patent/ATE5675T1/de not_active IP Right Cessation
- 1981-02-23 DE DE8181101278T patent/DE3161677D1/de not_active Expired
- 1981-02-23 EP EP81101278A patent/EP0036105B1/fr not_active Expired
- 1981-02-26 JP JP2757281A patent/JPS56134536A/ja active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2341953A1 (fr) * | 1976-02-19 | 1977-09-16 | Anvar | Nouveaux materiaux a conductivite ionique, applicables a la constitution d'electrolytes solides pour piles et batteries seches |
| FR2387192A1 (fr) * | 1977-04-15 | 1978-11-10 | France Etat | Conducteurs cationiques amorphes du lithium |
Non-Patent Citations (2)
| Title |
|---|
| EXBK/ * |
| EXBK/77 * |
Also Published As
| Publication number | Publication date |
|---|---|
| IL61783A (en) | 1984-04-30 |
| FR2477128B1 (enrdf_load_stackoverflow) | 1982-06-18 |
| IL61783A0 (en) | 1981-01-30 |
| JPS56134536A (en) | 1981-10-21 |
| US4331750A (en) | 1982-05-25 |
| ATE5675T1 (de) | 1984-01-15 |
| DE3161677D1 (en) | 1984-01-26 |
| EP0036105A1 (fr) | 1981-09-23 |
| EP0036105B1 (fr) | 1983-12-21 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| ST | Notification of lapse |