FR2472581A1 - Catalyseurs de polymerisation de l'ethylene comprenant des composes de plusieurs metaux de transition, et procede de polymerisation utilisant lesdits catalyseurs. - Google Patents
Catalyseurs de polymerisation de l'ethylene comprenant des composes de plusieurs metaux de transition, et procede de polymerisation utilisant lesdits catalyseurs. Download PDFInfo
- Publication number
- FR2472581A1 FR2472581A1 FR7931911A FR7931911A FR2472581A1 FR 2472581 A1 FR2472581 A1 FR 2472581A1 FR 7931911 A FR7931911 A FR 7931911A FR 7931911 A FR7931911 A FR 7931911A FR 2472581 A1 FR2472581 A1 FR 2472581A1
- Authority
- FR
- France
- Prior art keywords
- catalysts
- ethylene
- polymerization
- catalyst
- temperature
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000003054 catalyst Substances 0.000 title claims abstract description 61
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 title claims abstract description 31
- 239000005977 Ethylene Substances 0.000 title claims abstract description 31
- 238000006116 polymerization reaction Methods 0.000 title claims abstract description 19
- 238000000034 method Methods 0.000 title claims abstract description 18
- 229910052723 transition metal Inorganic materials 0.000 title claims abstract description 12
- 150000003624 transition metals Chemical class 0.000 title claims abstract description 12
- 150000001875 compounds Chemical class 0.000 title claims description 6
- 239000002685 polymerization catalyst Substances 0.000 title claims description 4
- VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 claims abstract description 16
- 239000012190 activator Substances 0.000 claims abstract description 10
- YONPGGFAJWQGJC-UHFFFAOYSA-K titanium(iii) chloride Chemical compound Cl[Ti](Cl)Cl YONPGGFAJWQGJC-UHFFFAOYSA-K 0.000 claims abstract description 10
- 229910052736 halogen Inorganic materials 0.000 claims abstract description 5
- 125000005843 halogen group Chemical group 0.000 claims abstract description 5
- 230000000379 polymerizing effect Effects 0.000 claims abstract description 5
- 239000010936 titanium Substances 0.000 claims description 20
- 229910052751 metal Inorganic materials 0.000 claims description 14
- 239000002184 metal Substances 0.000 claims description 14
- 230000000737 periodic effect Effects 0.000 claims description 12
- 238000000227 grinding Methods 0.000 claims description 10
- -1 magnesium halide Chemical class 0.000 claims description 10
- 230000003197 catalytic effect Effects 0.000 claims description 9
- 239000011777 magnesium Substances 0.000 claims description 6
- 150000002739 metals Chemical class 0.000 claims description 6
- 239000004215 Carbon black (E152) Substances 0.000 claims description 5
- 125000004432 carbon atom Chemical group C* 0.000 claims description 5
- 150000004678 hydrides Chemical class 0.000 claims description 5
- 229930195733 hydrocarbon Natural products 0.000 claims description 5
- 238000004519 manufacturing process Methods 0.000 claims description 5
- 150000002902 organometallic compounds Chemical class 0.000 claims description 5
- 239000006104 solid solution Substances 0.000 claims description 5
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 claims description 4
- 150000002430 hydrocarbons Chemical class 0.000 claims description 4
- 229910052749 magnesium Inorganic materials 0.000 claims description 4
- 239000000243 solution Substances 0.000 claims description 3
- 239000001273 butane Substances 0.000 claims description 2
- 150000001805 chlorine compounds Chemical class 0.000 claims description 2
- 239000007788 liquid Substances 0.000 claims description 2
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 claims description 2
- OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 claims description 2
- 239000001294 propane Substances 0.000 claims description 2
- 239000000725 suspension Substances 0.000 claims description 2
- 150000001768 cations Chemical class 0.000 claims 1
- 239000011343 solid material Substances 0.000 claims 1
- 229910010062 TiCl3 Inorganic materials 0.000 abstract description 4
- 150000002366 halogen compounds Chemical class 0.000 abstract 1
- 125000002524 organometallic group Chemical group 0.000 abstract 1
- 229920000642 polymer Polymers 0.000 description 15
- UAEPNZWRGJTJPN-UHFFFAOYSA-N methylcyclohexane Chemical compound CC1CCCCC1 UAEPNZWRGJTJPN-UHFFFAOYSA-N 0.000 description 14
- GYNNXHKOJHMOHS-UHFFFAOYSA-N methyl-cycloheptane Natural products CC1CCCCCC1 GYNNXHKOJHMOHS-UHFFFAOYSA-N 0.000 description 7
- QQONPFPTGQHPMA-UHFFFAOYSA-N Propene Chemical compound CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 6
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 6
- 229910052719 titanium Inorganic materials 0.000 description 6
- 229910052720 vanadium Inorganic materials 0.000 description 6
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 5
- 229910052739 hydrogen Inorganic materials 0.000 description 5
- 239000001257 hydrogen Substances 0.000 description 5
- GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 description 5
- 239000004698 Polyethylene Substances 0.000 description 4
- 229910021551 Vanadium(III) chloride Inorganic materials 0.000 description 4
- 239000000155 melt Substances 0.000 description 4
- 229920000573 polyethylene Polymers 0.000 description 4
- HQYCOEXWFMFWLR-UHFFFAOYSA-K vanadium(iii) chloride Chemical compound [Cl-].[Cl-].[Cl-].[V+3] HQYCOEXWFMFWLR-UHFFFAOYSA-K 0.000 description 4
- 238000004458 analytical method Methods 0.000 description 3
- 239000006185 dispersion Substances 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 3
- 239000004711 α-olefin Substances 0.000 description 3
- 229910021556 Chromium(III) chloride Inorganic materials 0.000 description 2
- CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 229910010061 TiC13 Inorganic materials 0.000 description 2
- 125000001931 aliphatic group Chemical group 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 239000011651 chromium Substances 0.000 description 2
- QSWDMMVNRMROPK-UHFFFAOYSA-K chromium(3+) trichloride Chemical compound [Cl-].[Cl-].[Cl-].[Cr+3] QSWDMMVNRMROPK-UHFFFAOYSA-K 0.000 description 2
- 238000003801 milling Methods 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 1
- 101100386054 Saccharomyces cerevisiae (strain ATCC 204508 / S288c) CYS3 gene Proteins 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 239000012986 chain transfer agent Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000004587 chromatography analysis Methods 0.000 description 1
- 229960000359 chromic chloride Drugs 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011636 chromium(III) chloride Substances 0.000 description 1
- 235000007831 chromium(III) chloride Nutrition 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 238000007334 copolymerization reaction Methods 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- HRXSKIOIHQEGAI-UHFFFAOYSA-M diethylalumanylium;fluoride Chemical compound CC[Al](F)CC HRXSKIOIHQEGAI-UHFFFAOYSA-M 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 239000000395 magnesium oxide Substances 0.000 description 1
- 229910052750 molybdenum Inorganic materials 0.000 description 1
- 239000011733 molybdenum Substances 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 101150035983 str1 gene Proteins 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- LFXVBWRMVZPLFK-UHFFFAOYSA-N trioctylalumane Chemical compound CCCCCCCC[Al](CCCCCCCC)CCCCCCCC LFXVBWRMVZPLFK-UHFFFAOYSA-N 0.000 description 1
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 1
- 229910052721 tungsten Inorganic materials 0.000 description 1
- 239000010937 tungsten Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/906—Comminution of transition metal containing catalyst
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Priority Applications (8)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR7931911A FR2472581A1 (fr) | 1979-12-28 | 1979-12-28 | Catalyseurs de polymerisation de l'ethylene comprenant des composes de plusieurs metaux de transition, et procede de polymerisation utilisant lesdits catalyseurs. |
| US06/218,095 US4388219A (en) | 1979-12-28 | 1980-12-19 | Catalyst for polymerizing ethylene, comprising compounds of several transition metals, and a polymerization process using said catalyst |
| EP80401846A EP0032339B1 (fr) | 1979-12-28 | 1980-12-23 | Catalyseurs de polymérisation de l'éthylène, leur procédé de fabrication et un procédé de polymérisation utilisant lesdits catalyseurs |
| AU65810/80A AU548917B2 (en) | 1979-12-28 | 1980-12-23 | Catalyst for polymerising ethylene |
| DE8080401846T DE3063928D1 (en) | 1979-12-28 | 1980-12-23 | Ethylene polymerisation catalysts, process for their manufacture and polymerisation process using said catalysts |
| AT80401846T ATE3869T1 (de) | 1979-12-28 | 1980-12-23 | Katalysatoren zur aethylenpolymerisation, verfahren zu ihrer herstellung und diese katalysatoren verwendendes polymerisationsverfahren. |
| JP18297780A JPS5699209A (en) | 1979-12-28 | 1980-12-25 | Catalyst* its manufacture and ethylene polymerization therewith |
| US06/477,846 US4489198A (en) | 1979-12-28 | 1983-03-22 | Polymerization of ethylene with a catalyst comprising several transition metal compounds |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR7931911A FR2472581A1 (fr) | 1979-12-28 | 1979-12-28 | Catalyseurs de polymerisation de l'ethylene comprenant des composes de plusieurs metaux de transition, et procede de polymerisation utilisant lesdits catalyseurs. |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| FR2472581A1 true FR2472581A1 (fr) | 1981-07-03 |
| FR2472581B1 FR2472581B1 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1984-07-20 |
Family
ID=9233259
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| FR7931911A Granted FR2472581A1 (fr) | 1979-12-28 | 1979-12-28 | Catalyseurs de polymerisation de l'ethylene comprenant des composes de plusieurs metaux de transition, et procede de polymerisation utilisant lesdits catalyseurs. |
Country Status (7)
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS58225106A (ja) * | 1982-06-24 | 1983-12-27 | Mitsubishi Petrochem Co Ltd | ポリエチレンの製造法 |
| GB8318207D0 (en) * | 1983-07-05 | 1983-08-03 | Du Pont Canada | Preparation of triethyl dimethyl siloxalane |
| JPH0780968B2 (ja) * | 1987-09-09 | 1995-08-30 | 住友化学工業株式会社 | オレフィン重合体の製造法 |
| JP2758415B2 (ja) * | 1988-11-17 | 1998-05-28 | 三菱化学株式会社 | α−オレフィン重合体の製造 |
| US4929584A (en) * | 1989-03-30 | 1990-05-29 | Shell Oil Company | Alkylation of Benzene compounds with detergent range olefins |
| US4925822A (en) * | 1989-03-30 | 1990-05-15 | Shell Oil Company | Disproportionation catalyst and process |
| CN108143009B (zh) † | 2011-12-30 | 2020-11-03 | 菲利普莫里斯生产公司 | 具有气流检测功能的气溶胶产生装置 |
Family Cites Families (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR1260454A (fr) * | 1959-07-17 | 1961-05-05 | Exxon Research Engineering Co | Nouveau catalyseur de polymérisation d'alpha-oléfines, constitué de composés co-cristallisés du titane, du vanadium et de l'aluminium |
| GB888709A (en) * | 1959-07-17 | 1962-01-31 | Exxon Research Engineering Co | Cocrystallized vanadium-titanium catalyst components |
| US3531420A (en) * | 1966-10-19 | 1970-09-29 | Exxon Research Engineering Co | Tetrahalides of transition metals reduced with activated aluminum powder |
| GB1284121A (en) * | 1968-07-10 | 1972-08-02 | Mitsubishi Chem Ind | alpha-OLEFINE POLYMERISATION CATALYST COMPONENT |
| ZA707173B (en) * | 1969-10-24 | 1971-09-29 | Mitsui Petrochemical Ind | Process for the polymerization of olefins and catalyst therefor |
| US4133944A (en) * | 1973-03-29 | 1979-01-09 | Imperial Chemical Industries Limited | Ethylene polymerization |
| JPS51133386A (en) * | 1975-05-15 | 1976-11-19 | Nippon Oil Co Ltd | A process for manufacturing a polyolefin |
| JPS6023687B2 (ja) * | 1975-10-23 | 1985-06-08 | 日石三菱株式会社 | オレフインと極性モノマーとの共重合法 |
| NL7613855A (nl) * | 1975-12-18 | 1977-06-21 | Sumitomo Chemical Co | Werkwijze voor het polymeriseren van olefinen. |
| ES456321A1 (es) * | 1976-02-25 | 1978-01-16 | Charbonnages Ste Chimique | Procedimiento mejorado de polimerizacion ionica del etileno bajo alta presion. |
| FR2399445A1 (fr) * | 1977-08-01 | 1979-03-02 | Charbonnages Ste Chimique | Procede controle de polymerisation de l'ethylene par injection separee des constituants catalytiques |
-
1979
- 1979-12-28 FR FR7931911A patent/FR2472581A1/fr active Granted
-
1980
- 1980-12-19 US US06/218,095 patent/US4388219A/en not_active Expired - Lifetime
- 1980-12-23 AU AU65810/80A patent/AU548917B2/en not_active Ceased
- 1980-12-23 EP EP80401846A patent/EP0032339B1/fr not_active Expired
- 1980-12-23 DE DE8080401846T patent/DE3063928D1/de not_active Expired
- 1980-12-23 AT AT80401846T patent/ATE3869T1/de not_active IP Right Cessation
- 1980-12-25 JP JP18297780A patent/JPS5699209A/ja active Granted
-
1983
- 1983-03-22 US US06/477,846 patent/US4489198A/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| EP0032339A1 (fr) | 1981-07-22 |
| AU6581080A (en) | 1981-07-02 |
| EP0032339B1 (fr) | 1983-06-22 |
| US4489198A (en) | 1984-12-18 |
| DE3063928D1 (en) | 1983-07-28 |
| FR2472581B1 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1984-07-20 |
| ATE3869T1 (de) | 1983-07-15 |
| JPH0231085B2 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1990-07-11 |
| US4388219A (en) | 1983-06-14 |
| AU548917B2 (en) | 1986-01-09 |
| JPS5699209A (en) | 1981-08-10 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| CD | Change of name or company name | ||
| TP | Transmission of property |