FR2465015A1 - Procede pour la recuperation electrolytique de lithium a partir de saumures - Google Patents
Procede pour la recuperation electrolytique de lithium a partir de saumures Download PDFInfo
- Publication number
- FR2465015A1 FR2465015A1 FR8019302A FR8019302A FR2465015A1 FR 2465015 A1 FR2465015 A1 FR 2465015A1 FR 8019302 A FR8019302 A FR 8019302A FR 8019302 A FR8019302 A FR 8019302A FR 2465015 A1 FR2465015 A1 FR 2465015A1
- Authority
- FR
- France
- Prior art keywords
- lithium
- aluminum
- brine
- electrolysis
- per liter
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 title claims abstract description 54
- 229910052744 lithium Inorganic materials 0.000 title claims abstract description 54
- 238000000034 method Methods 0.000 title claims abstract description 28
- 238000011084 recovery Methods 0.000 title claims abstract description 10
- 239000012267 brine Substances 0.000 title description 46
- HPALAKNZSZLMCH-UHFFFAOYSA-M sodium;chloride;hydrate Chemical compound O.[Na+].[Cl-] HPALAKNZSZLMCH-UHFFFAOYSA-M 0.000 title description 46
- 229910052782 aluminium Inorganic materials 0.000 claims abstract description 53
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims abstract description 52
- 238000005868 electrolysis reaction Methods 0.000 claims abstract description 31
- 239000000243 solution Substances 0.000 claims description 9
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 7
- 229910052749 magnesium Inorganic materials 0.000 claims description 7
- 239000011777 magnesium Substances 0.000 claims description 7
- 239000007864 aqueous solution Substances 0.000 claims description 6
- 239000002244 precipitate Substances 0.000 claims description 6
- JFBZPFYRPYOZCQ-UHFFFAOYSA-N [Li].[Al] Chemical compound [Li].[Al] JFBZPFYRPYOZCQ-UHFFFAOYSA-N 0.000 claims description 3
- 229910052783 alkali metal Inorganic materials 0.000 claims description 2
- 150000001340 alkali metals Chemical class 0.000 claims description 2
- FCVHBUFELUXTLR-UHFFFAOYSA-N [Li].[AlH3] Chemical class [Li].[AlH3] FCVHBUFELUXTLR-UHFFFAOYSA-N 0.000 claims 1
- JEGUKCSWCFPDGT-UHFFFAOYSA-N h2o hydrate Chemical compound O.O JEGUKCSWCFPDGT-UHFFFAOYSA-N 0.000 claims 1
- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 abstract description 7
- 229910001416 lithium ion Inorganic materials 0.000 abstract description 7
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 21
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 6
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 6
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 description 5
- 239000000920 calcium hydroxide Substances 0.000 description 5
- 229910001861 calcium hydroxide Inorganic materials 0.000 description 5
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 description 4
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 4
- 239000012153 distilled water Substances 0.000 description 4
- 230000000737 periodic effect Effects 0.000 description 4
- 239000007787 solid Substances 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- BHPQYMZQTOCNFJ-UHFFFAOYSA-N Calcium cation Chemical compound [Ca+2] BHPQYMZQTOCNFJ-UHFFFAOYSA-N 0.000 description 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 3
- 229910010098 LiAlOx Inorganic materials 0.000 description 3
- JLVVSXFLKOJNIY-UHFFFAOYSA-N Magnesium ion Chemical compound [Mg+2] JLVVSXFLKOJNIY-UHFFFAOYSA-N 0.000 description 3
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 3
- 241000212342 Sium Species 0.000 description 3
- FKNQFGJONOIPTF-UHFFFAOYSA-N Sodium cation Chemical compound [Na+] FKNQFGJONOIPTF-UHFFFAOYSA-N 0.000 description 3
- 229910000831 Steel Inorganic materials 0.000 description 3
- 235000013361 beverage Nutrition 0.000 description 3
- 229940006460 bromide ion Drugs 0.000 description 3
- 229910001424 calcium ion Inorganic materials 0.000 description 3
- 239000003792 electrolyte Substances 0.000 description 3
- 238000001914 filtration Methods 0.000 description 3
- 239000011521 glass Substances 0.000 description 3
- 229910001425 magnesium ion Inorganic materials 0.000 description 3
- 229910052700 potassium Inorganic materials 0.000 description 3
- 239000011591 potassium Substances 0.000 description 3
- 238000001556 precipitation Methods 0.000 description 3
- 229910052708 sodium Inorganic materials 0.000 description 3
- 239000011734 sodium Substances 0.000 description 3
- 239000011780 sodium chloride Substances 0.000 description 3
- 229910001415 sodium ion Inorganic materials 0.000 description 3
- 239000010959 steel Substances 0.000 description 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 241001676573 Minium Species 0.000 description 2
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 description 2
- -1 aluminum compound Chemical class 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 239000012065 filter cake Substances 0.000 description 2
- 239000000706 filtrate Substances 0.000 description 2
- 239000011888 foil Substances 0.000 description 2
- XMBWDFGMSWQBCA-UHFFFAOYSA-M iodide Chemical compound [I-] XMBWDFGMSWQBCA-UHFFFAOYSA-M 0.000 description 2
- 229940006461 iodide ion Drugs 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 230000002441 reversible effect Effects 0.000 description 2
- 239000002699 waste material Substances 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- 229910010093 LiAlO Inorganic materials 0.000 description 1
- 229910001209 Low-carbon steel Inorganic materials 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- ONGZMKPEWCAXFS-UHFFFAOYSA-L [Cl+].[Cl-].[K+].[Cl-] Chemical compound [Cl+].[Cl-].[K+].[Cl-] ONGZMKPEWCAXFS-UHFFFAOYSA-L 0.000 description 1
- JJVNQNRVLYDOKY-UHFFFAOYSA-K [Na+].[Mg+2].[Cl-].[Cl-].[Cl-].[K+] Chemical compound [Na+].[Mg+2].[Cl-].[Cl-].[Cl-].[K+] JJVNQNRVLYDOKY-UHFFFAOYSA-K 0.000 description 1
- 150000008044 alkali metal hydroxides Chemical class 0.000 description 1
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 1
- 150000001342 alkaline earth metals Chemical class 0.000 description 1
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical group [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 description 1
- 150000004645 aluminates Chemical class 0.000 description 1
- ANBBXQWFNXMHLD-UHFFFAOYSA-N aluminum;sodium;oxygen(2-) Chemical compound [O-2].[O-2].[Na+].[Al+3] ANBBXQWFNXMHLD-UHFFFAOYSA-N 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 238000005119 centrifugation Methods 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 230000008030 elimination Effects 0.000 description 1
- 238000003379 elimination reaction Methods 0.000 description 1
- NBVXSUQYWXRMNV-UHFFFAOYSA-N fluoromethane Chemical compound FC NBVXSUQYWXRMNV-UHFFFAOYSA-N 0.000 description 1
- XMBWDFGMSWQBCA-UHFFFAOYSA-N hydrogen iodide Chemical compound I XMBWDFGMSWQBCA-UHFFFAOYSA-N 0.000 description 1
- 238000011221 initial treatment Methods 0.000 description 1
- 239000002198 insoluble material Substances 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 229910003002 lithium salt Inorganic materials 0.000 description 1
- 159000000002 lithium salts Chemical class 0.000 description 1
- 230000002934 lysing effect Effects 0.000 description 1
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 description 1
- 239000000347 magnesium hydroxide Substances 0.000 description 1
- 229910001862 magnesium hydroxide Inorganic materials 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000001103 potassium chloride Substances 0.000 description 1
- 235000011164 potassium chloride Nutrition 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 238000004062 sedimentation Methods 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 229910001388 sodium aluminate Inorganic materials 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 229910052723 transition metal Inorganic materials 0.000 description 1
- 150000003624 transition metals Chemical class 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B1/00—Electrolytic production of inorganic compounds or non-metals
- C25B1/01—Products
- C25B1/14—Alkali metal compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Manufacture And Refinement Of Metals (AREA)
- Electrolytic Production Of Metals (AREA)
- Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
- Water Treatment By Electricity Or Magnetism (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US06/073,353 US4251338A (en) | 1979-09-07 | 1979-09-07 | Electrolytic recovery of lithium from brines |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| FR2465015A1 true FR2465015A1 (fr) | 1981-03-20 |
Family
ID=22113218
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| FR8019302A Withdrawn FR2465015A1 (fr) | 1979-09-07 | 1980-09-05 | Procede pour la recuperation electrolytique de lithium a partir de saumures |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US4251338A (enExample) |
| DE (1) | DE3032544C2 (enExample) |
| FR (1) | FR2465015A1 (enExample) |
| GB (1) | GB2057506B (enExample) |
| GR (1) | GR70278B (enExample) |
| IT (1) | IT1132616B (enExample) |
Families Citing this family (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2050184C1 (ru) * | 1993-02-16 | 1995-12-20 | Научно-производственное акционерное общество "Экостар" | Способ получения гранулированного сорбента для извлечения лития из рассолов |
| US5711019A (en) * | 1996-01-31 | 1998-01-20 | The United States Of America As Represented By The United States Department Of Energy | Method for treating electrolyte to remove Li2 O |
| US8641992B2 (en) | 2008-07-18 | 2014-02-04 | Ady Resources Limited | Process for recovering lithium from a brine |
| US9051827B1 (en) | 2009-09-02 | 2015-06-09 | Simbol Mining Corporation | Selective removal of silica from silica containing brines |
| US10190030B2 (en) | 2009-04-24 | 2019-01-29 | Alger Alternative Energy, Llc | Treated geothermal brine compositions with reduced concentrations of silica, iron and lithium |
| US8741256B1 (en) | 2009-04-24 | 2014-06-03 | Simbol Inc. | Preparation of lithium carbonate from lithium chloride containing brines |
| US8637428B1 (en) | 2009-12-18 | 2014-01-28 | Simbol Inc. | Lithium extraction composition and method of preparation thereof |
| US12168748B2 (en) | 2009-04-24 | 2024-12-17 | Terralithium Llc | Treated geothermal brine compositions with reduced concentration of silica, iron and lithium |
| US9034294B1 (en) | 2009-04-24 | 2015-05-19 | Simbol, Inc. | Preparation of lithium carbonate from lithium chloride containing brines |
| US10683563B2 (en) | 2009-06-24 | 2020-06-16 | Terralithium Llc | Treated geothermal brine compositions with reduced concentrations of silica, iron and manganese |
| US10935006B2 (en) | 2009-06-24 | 2021-03-02 | Terralithium Llc | Process for producing geothermal power, selective removal of silica and iron from brines, and improved injectivity of treated brines |
| PT3594382T (pt) | 2010-02-17 | 2025-10-27 | Terralithium Llc | Processo para a preparação de carbonato de lítio de elevada pureza |
| US10604414B2 (en) | 2017-06-15 | 2020-03-31 | Energysource Minerals Llc | System and process for recovery of lithium from a geothermal brine |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB896314A (en) * | 1960-03-18 | 1962-05-16 | Peter Spence & Sons Ltd | Preparation of an alumina based catalyst |
| US3506393A (en) * | 1968-09-26 | 1970-04-14 | Dow Chemical Co | Purification of lithium aluminates |
Family Cites Families (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US836781A (en) * | 1906-05-15 | 1906-11-27 | Camille Poulenc | Process of obtaining lithium salts. |
| US1964161A (en) * | 1929-02-11 | 1934-06-26 | Walter A Kuhnert | Method of treating brine containing soluble silica |
| US3007771A (en) * | 1956-11-30 | 1961-11-07 | American Potash & Chem Corp | Manufacture of lithium carbonate |
| US2977185A (en) * | 1957-01-29 | 1961-03-28 | Dow Chemical Co | Process for the recovery and separation of lithium and aluminum from lithium aluminate complex |
| US2980497A (en) * | 1957-01-29 | 1961-04-18 | Dow Chemical Co | Recovery of lithium from lithium aluminate complex |
| US2964381A (en) * | 1957-01-29 | 1960-12-13 | Dow Chemical Co | Recovery of lithium |
| US3112172A (en) * | 1960-12-05 | 1963-11-26 | Dept Of Natural Resources Of T | Production of various lithium salts |
| US3306700A (en) * | 1964-03-06 | 1967-02-28 | Dow Chemical Co | Method of lithium recovery |
| US3597340A (en) * | 1968-11-05 | 1971-08-03 | Lithium Corp | Recovery of lithium as lioh.h20 from aqueous chloride brines containing lithium chloride and sodium chloride |
| US3715290A (en) * | 1969-09-11 | 1973-02-06 | Kurita Water Ind Ltd | Method and apparatus for preparation of aluminium coagulating agent |
| US3857920A (en) * | 1971-07-29 | 1974-12-31 | Department Of Health Education | Recovery of lithium carbonate |
| US4159246A (en) * | 1975-09-10 | 1979-06-26 | Kohei Deguchi | Removal of fluorine from water |
| US4036713A (en) * | 1976-03-04 | 1977-07-19 | Foote Mineral Company | Process for the production of high purity lithium hydroxide |
| US4149953A (en) * | 1977-05-31 | 1979-04-17 | R. H. Bouligny, Inc. | Apparatus for removing impurities from waste water |
| US4152229A (en) * | 1978-04-19 | 1979-05-01 | London Laboratories Limited | Apparatus and method for removal of soluble metal ions from aqueous effluent |
-
1979
- 1979-09-07 US US06/073,353 patent/US4251338A/en not_active Expired - Lifetime
-
1980
- 1980-08-05 GR GR62607A patent/GR70278B/el unknown
- 1980-08-29 DE DE3032544A patent/DE3032544C2/de not_active Expired
- 1980-09-02 IT IT24409/80A patent/IT1132616B/it active
- 1980-09-05 FR FR8019302A patent/FR2465015A1/fr not_active Withdrawn
- 1980-09-05 GB GB8028673A patent/GB2057506B/en not_active Expired
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB896314A (en) * | 1960-03-18 | 1962-05-16 | Peter Spence & Sons Ltd | Preparation of an alumina based catalyst |
| US3506393A (en) * | 1968-09-26 | 1970-04-14 | Dow Chemical Co | Purification of lithium aluminates |
Also Published As
| Publication number | Publication date |
|---|---|
| US4251338A (en) | 1981-02-17 |
| GB2057506B (en) | 1983-05-18 |
| DE3032544C2 (de) | 1982-04-01 |
| IT8024409A0 (it) | 1980-09-02 |
| GR70278B (enExample) | 1982-09-03 |
| GB2057506A (en) | 1981-04-01 |
| IT1132616B (it) | 1986-07-02 |
| DE3032544A1 (de) | 1981-03-12 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| RE | Withdrawal of published application |