FR2435485A1 - Procede de preparation de polymeres tres absorbants - Google Patents

Procede de preparation de polymeres tres absorbants

Info

Publication number
FR2435485A1
FR2435485A1 FR7922212A FR7922212A FR2435485A1 FR 2435485 A1 FR2435485 A1 FR 2435485A1 FR 7922212 A FR7922212 A FR 7922212A FR 7922212 A FR7922212 A FR 7922212A FR 2435485 A1 FR2435485 A1 FR 2435485A1
Authority
FR
France
Prior art keywords
heat treatment
preparation
absorbent polymers
polymer
subjected
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
FR7922212A
Other languages
English (en)
Other versions
FR2435485B1 (fr
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Sumitomo Chemical Co Ltd
Original Assignee
Sumitomo Chemical Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from JP11045178A external-priority patent/JPS5536273A/ja
Priority claimed from JP11337678A external-priority patent/JPS5538863A/ja
Application filed by Sumitomo Chemical Co Ltd filed Critical Sumitomo Chemical Co Ltd
Publication of FR2435485A1 publication Critical patent/FR2435485A1/fr
Application granted granted Critical
Publication of FR2435485B1 publication Critical patent/FR2435485B1/fr
Granted legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00—Chemical modification by after-treatment
    • C08F8/44—Preparation of metal salts or ammonium salts
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
    • A61L15/00—Chemical aspects of, or use of materials for, bandages, dressings or absorbent pads
    • A61L15/16—Bandages, dressings or absorbent pads for physiological fluids such as urine or blood, e.g. sanitary towels, tampons
    • A61L15/42—Use of materials characterised by their function or physical properties
    • A61L15/60—Liquid-swellable gel-forming materials, e.g. super-absorbents
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F20/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
    • C08F20/02—Monocarboxylic acids having less than ten carbon atoms, Derivatives thereof
    • C08F20/04—Acids, Metal salts or ammonium salts thereof
    • C08F20/06—Acrylic acid; Methacrylic acid; Metal salts or ammonium salts thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F261/00—Macromolecular compounds obtained by polymerising monomers on to polymers of oxygen-containing monomers as defined in group C08F16/00
    • C08F261/02—Macromolecular compounds obtained by polymerising monomers on to polymers of oxygen-containing monomers as defined in group C08F16/00 on to polymers of unsaturated alcohols
    • C08F261/04—Macromolecular compounds obtained by polymerising monomers on to polymers of oxygen-containing monomers as defined in group C08F16/00 on to polymers of unsaturated alcohols on to polymers of vinyl alcohol
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00—Chemical modification by after-treatment
    • C08F8/30—Introducing nitrogen atoms or nitrogen-containing groups
    • C08F8/32—Introducing nitrogen atoms or nitrogen-containing groups by reaction with amines
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S524/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S524/916—Hydrogel compositions

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Hematology (AREA)
  • Dispersion Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Epidemiology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)

Abstract

L'invention concerne un procédé de production de gels hydrophiles très absorbants de l'eau, qui consiste à polymériser de l'acide acrylique et/ou de l'acide méthacrylique en présence d'alcool polyvinylique pour obtenir un polymère que l'on soumet ensuite à une neutralisation suivie d'un traitement thermique ou à un traitement thermique suivi d'une neutralisation, ou à polymériser un sel d'acide acrylique et/ou d'acide méthacrylique en présence d'alcool polyvinylique pour obtenir un polymère que l'on soumet ensuite à un traitement thermique.
FR7922212A 1978-09-07 1979-09-05 Procede de preparation de polymeres tres absorbants Granted FR2435485A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP11045178A JPS5536273A (en) 1978-09-07 1978-09-07 Production of macromolecular material with high water-absorbing property
JP11337678A JPS5538863A (en) 1978-09-13 1978-09-13 Preparation of highly water-absorbing polymeric material

Publications (2)

Publication Number Publication Date
FR2435485A1 true FR2435485A1 (fr) 1980-04-04
FR2435485B1 FR2435485B1 (fr) 1984-03-23

Family

ID=26450082

Family Applications (1)

Application Number Title Priority Date Filing Date
FR7922212A Granted FR2435485A1 (fr) 1978-09-07 1979-09-05 Procede de preparation de polymeres tres absorbants

Country Status (5)

Country Link
US (1) US4320040A (fr)
CA (1) CA1134977A (fr)
DE (1) DE2935712A1 (fr)
FR (1) FR2435485A1 (fr)
GB (1) GB2030990B (fr)

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2598712A1 (fr) * 1986-05-19 1987-11-20 Nippon Synthetic Chem Ind Procede pour la production de resines a base de polymeres d'acide (meth)acrylique, a capacite elevee d'absorption d'eau
EP0248963A2 (fr) * 1986-06-10 1987-12-16 American Colloid Company Polymères absorbants traités en surface
WO1989007455A1 (fr) * 1988-02-12 1989-08-24 Zaepffel Brigitte Copolymere hydrophile reticule a usage medical et paramedical
FR2693202A1 (fr) * 1992-07-06 1994-01-07 Hoechst France Polymères amphiphiles hydrosolubles, leur procédé de préparation et leur application comme épaississant.
WO1995010553A1 (fr) * 1993-10-12 1995-04-20 The Dow Chemical Company Polymeres gonflables a l'eau presentant une couleur amelioree
EP0872491A1 (fr) * 1997-04-14 1998-10-21 Nippon Shokubai Co., Ltd. Résine absorbante à haute résistance à la pression, couche jetable à base de cette résine, résine absorbante ainsi que son procédé de fabrication

Families Citing this family (52)

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JPS58180233A (ja) * 1982-04-19 1983-10-21 Nippon Shokubai Kagaku Kogyo Co Ltd 吸収剤
EP0114316B1 (fr) * 1982-12-27 1987-09-30 Miles Laboratories, Inc. Moyen d'examen, appareillage d'examen et méthode de détermination de la force ionique ou du poids spécifique d'un échantillon liquide
US4664816A (en) * 1985-05-28 1987-05-12 Texaco Inc. Encapsulated water absorbent polymers as lost circulation additives for aqueous drilling fluids
US4633950A (en) * 1985-05-28 1987-01-06 Texaco Inc. Method for controlling lost circulation of drilling fluids with hydrocarbon absorbent polymers
US4635726A (en) * 1985-05-28 1987-01-13 Texaco Inc. Method for controlling lost circulation of drilling fluids with water absorbent polymers
US4575539A (en) * 1985-06-03 1986-03-11 E. R. Squibb & Sons, Inc. Drug delivery systems including novel interpenetrating polymer networks and method
FR2601026B1 (fr) * 1986-04-15 1988-09-16 Rhone Poulenc Chimie Matiere seche hydratable en un gel aqueux contenant des particules de polymeres dispersees, procede pour sa preparation et son application en biologie
JPH0692467B2 (ja) * 1986-10-06 1994-11-16 信越化学工業株式会社 可逆性含水ゲルとその製造方法
US4766173A (en) * 1987-05-11 1988-08-23 Nalco Chemical Company Method for reducing residual acrylic acid in acrylic acid polymer gels
US5034139A (en) * 1989-06-19 1991-07-23 Nalco Chemical Company Polymer composition comprising phosphorous-containing gelling agent and process thereof
JPH0466125A (ja) * 1990-07-04 1992-03-02 Nippon Zeon Co Ltd 吸水剤、吸水剤の製造方法および吸水剤を用いた粉粒体の水分低減方法
JPH0779593B2 (ja) * 1991-03-18 1995-08-30 悦子 須郷 動物飼育用材料およびその製造方法
US5209768A (en) * 1991-06-14 1993-05-11 American Colloid Company Method of improving sod growth
US5303663A (en) * 1992-05-08 1994-04-19 Soil Injection Layering Systems, Inc. Subsurface particle injection methods
DE4244548C2 (de) * 1992-12-30 1997-10-02 Stockhausen Chem Fab Gmbh Pulverförmige, unter Belastung wäßrige Flüssigkeiten sowie Blut absorbierende Polymere, Verfahren zu ihrer Herstellung und ihre Verwendung in textilen Konstruktionen für die Körperhygiene
US5340874A (en) * 1993-07-07 1994-08-23 Air Products And Chemicals, Inc. Modified polyvinyl alcohol and a solid state process for modification of polyvinyl alcohol by free radical grafting
US5350801A (en) * 1993-07-07 1994-09-27 Air Products And Chemicals, Inc. Solid state process for modification of polyvinyl alcohol using Michael-type addition
JP2736600B2 (ja) * 1993-09-27 1998-04-02 呉羽化学工業株式会社 ガスバリヤー性フィルム及びその製造方法
US5610208A (en) 1994-02-17 1997-03-11 Nippon Shokubai Co., Ltd. Water-absorbent agent, method for production thereof, and water-absorbent composition
US5693707A (en) * 1994-09-16 1997-12-02 Air Products And Chemicals, Inc. Liquid absorbent composition for nonwoven binder applications
EP0708119A1 (fr) 1994-10-21 1996-04-24 Air Products And Chemicals, Inc. Compositions aqueuses de polymères absorbant de l'eau auto-réticulants
DE69529469T2 (de) * 1994-10-24 2003-11-20 Sanyo Chemical Industries, Ltd. Wasserabsorbierende harzdispersion und polyurethanzusammensetzung
US5969052A (en) * 1996-12-31 1999-10-19 Kimberly Clark Worldwide, Inc. Temperature sensitive polymers and water-dispersible products containing the polymers
DE19752128A1 (de) * 1997-11-25 1999-07-29 Stockhausen Chem Fab Gmbh Verfahren zur Herstellung von wasserlöslichen bzw. wasserquellbaren Polymerisaten mit sehr niedrigem Restmonomergehalt, danach hergestellte Produkte und deren Verwendung
DE19752127A1 (de) 1997-11-25 1999-07-29 Stockhausen Chem Fab Gmbh Verfahren zur Herstellung von synthetischen Polymerisaten mit sehr niedrigem Restmonomergehalt, danach hergestellte Produkte und deren Verwendung
US6041546A (en) * 1998-05-26 2000-03-28 Nodirt Exotic Planters, Inc. Planter pouch
FR2784580B1 (fr) 1998-10-16 2004-06-25 Biosepra Inc Microspheres de polyvinyl-alcool et procedes de fabrication de celles-ci
ES2158737B1 (es) * 1999-09-01 2002-03-16 Galante Agustin Gomez Transformacion de residuos liquidos contaminados en una sustancia gelatinosa.
US20010006267A1 (en) * 1999-12-27 2001-07-05 Nobuyuki Harada Production processes for basic water-absorbent resin and water-absorbing agent, and use thereof
US20030212022A1 (en) * 2001-03-23 2003-11-13 Jean-Marie Vogel Compositions and methods for gene therapy
ES2551164T3 (es) 2000-03-24 2015-11-16 Biosphere Medical, Inc. Microesferas para embolización activa
US6613703B1 (en) 2000-04-27 2003-09-02 Kimberly-Clark Worldwide, Inc. Thermoplastic nonwoven web chemically reacted with a cyclodextrin compound
US6976537B1 (en) 2002-01-30 2005-12-20 Turbo-Chem International, Inc. Method for decreasing lost circulation during well operation
AU2003295886A1 (en) * 2002-11-27 2004-06-23 Isp Investments Inc. Tough polymers
WO2005019286A1 (fr) * 2003-08-20 2005-03-03 Shionogi & Co., Ltd. Nouvelle composition pour revetements
TWI353360B (en) 2005-04-07 2011-12-01 Nippon Catalytic Chem Ind Production process of polyacrylic acid (salt) wate
EP1879554B2 (fr) 2005-05-09 2018-03-07 Biosphere Medical, S.A. Compositions et procedes d'utilisation de microspheres et agents de contraste non ioniques
TWI394789B (zh) 2005-12-22 2013-05-01 Nippon Catalytic Chem Ind 吸水性樹脂組成物及其製造方法、吸收性物品
TW200728324A (en) * 2005-12-22 2007-08-01 Nippon Catalytic Chem Ind Production method of hydrophilic polymer
EP1986706B1 (fr) * 2006-01-30 2011-08-17 Biosphere Medical, Inc. Particules d'embolisation intravasculaires poreuses et leurs procédés de fabrication
US20080033366A1 (en) 2006-01-30 2008-02-07 Surgica Corporation Compressible intravascular embolization particles and related methods and delivery systems
EP1837348B9 (fr) 2006-03-24 2020-01-08 Nippon Shokubai Co.,Ltd. Résine absorbant l'eau et son procédé de fabrication
WO2009123699A2 (fr) * 2008-03-31 2009-10-08 Rhodia Inc. Compositions de polymère sensibles aux stimuli, à positionnement autonome, dans des additifs pour le sol et procédés d'utilisation
JP2012507562A (ja) * 2008-10-30 2012-03-29 ダビド リウ 微小球性多孔質生体適合性足場並びにその製造方法及び装置
EP2484439B1 (fr) 2009-09-29 2022-12-14 Nippon Shokubai Co., Ltd. Absorbant particulaire d'eau et son procédé de fabrication
CN103497271A (zh) * 2013-10-08 2014-01-08 苏州新区华士达工程塑胶有限公司 具有可塑性的塑胶配方
CN108835111A (zh) * 2018-07-30 2018-11-20 江苏常丰农化有限公司 一种2,4-d水凝胶的制备方法
WO2021168378A1 (fr) 2020-02-20 2021-08-26 Polygreen Ltd. Produit absorbant multi-couche et procédé de préparation d'une couche absorbante
CN114075361A (zh) * 2020-08-12 2022-02-22 苏州怒鲨智能科技有限公司 一种柔性传感器用透明导电凝胶材料及其制备方法
CN112941914B (zh) * 2021-01-19 2022-05-17 温州华特热熔胶股份有限公司 一种防潮热熔丝及其制备方法
CN114481619A (zh) * 2022-01-10 2022-05-13 南通大学 一种吸湿发热织物及其制备方法和应用
CN115138349B (zh) * 2022-08-02 2023-09-29 扬州工业职业技术学院 用于含芳香化合物废水处理的两亲性多孔高分子材料

Citations (3)

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Publication number Priority date Publication date Assignee Title
FR2017986A1 (fr) * 1968-09-04 1970-05-29 Int Minerals & Chem Corp
JPS5256148A (en) * 1975-10-16 1977-05-09 Agency Of Ind Science & Technol Process for preparing active substances having improved
GB1490128A (en) * 1976-05-14 1977-10-26 Revertex Ltd Hydrophilic polymeric materials and method of making them

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US3272749A (en) * 1965-03-31 1966-09-13 Alco Chemical Corp Drilling mud and additive therefor
US3935099A (en) * 1974-04-03 1976-01-27 The United States Of America As Represented By The Secretary Of Agriculture Method of reducing water content of emulsions, suspensions, and dispersions with highly absorbent starch-containing polymeric compositions
GB1530178A (en) * 1975-07-24 1978-10-25 Sumitomo Chemical Co Water-insoluble hydrophilic gels and a method for the preparation of the same
JPS5265597A (en) * 1975-11-27 1977-05-31 Sumitomo Chem Co Ltd Preparation of high polimeric materials with improved water absorption

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2017986A1 (fr) * 1968-09-04 1970-05-29 Int Minerals & Chem Corp
JPS5256148A (en) * 1975-10-16 1977-05-09 Agency Of Ind Science & Technol Process for preparing active substances having improved
GB1490128A (en) * 1976-05-14 1977-10-26 Revertex Ltd Hydrophilic polymeric materials and method of making them

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
CA1977 *

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2598712A1 (fr) * 1986-05-19 1987-11-20 Nippon Synthetic Chem Ind Procede pour la production de resines a base de polymeres d'acide (meth)acrylique, a capacite elevee d'absorption d'eau
EP0248963A2 (fr) * 1986-06-10 1987-12-16 American Colloid Company Polymères absorbants traités en surface
EP0248963A3 (en) * 1986-06-10 1989-07-12 American Colloid Company Surface treated absorbent polymers
WO1989007455A1 (fr) * 1988-02-12 1989-08-24 Zaepffel Brigitte Copolymere hydrophile reticule a usage medical et paramedical
FR2693202A1 (fr) * 1992-07-06 1994-01-07 Hoechst France Polymères amphiphiles hydrosolubles, leur procédé de préparation et leur application comme épaississant.
WO1995010553A1 (fr) * 1993-10-12 1995-04-20 The Dow Chemical Company Polymeres gonflables a l'eau presentant une couleur amelioree
EP0872491A1 (fr) * 1997-04-14 1998-10-21 Nippon Shokubai Co., Ltd. Résine absorbante à haute résistance à la pression, couche jetable à base de cette résine, résine absorbante ainsi que son procédé de fabrication
US6184433B1 (en) 1997-04-14 2001-02-06 Nippon Shokubai Co., Ltd. Pressure-resistant absorbent resin, disposable diaper using the resin, and absorbent resin, and method for production thereof

Also Published As

Publication number Publication date
FR2435485B1 (fr) 1984-03-23
CA1134977A (fr) 1982-11-02
GB2030990B (en) 1982-12-22
DE2935712A1 (de) 1980-03-20
US4320040A (en) 1982-03-16
GB2030990A (en) 1980-04-16

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