FR2431512A1 - Procede de production de copolymeres sequences propylene/ethylene - Google Patents
Procede de production de copolymeres sequences propylene/ethyleneInfo
- Publication number
- FR2431512A1 FR2431512A1 FR7918623A FR7918623A FR2431512A1 FR 2431512 A1 FR2431512 A1 FR 2431512A1 FR 7918623 A FR7918623 A FR 7918623A FR 7918623 A FR7918623 A FR 7918623A FR 2431512 A1 FR2431512 A1 FR 2431512A1
- Authority
- FR
- France
- Prior art keywords
- ethylene
- propylene
- polymerization
- carried out
- polymerizing
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- QQONPFPTGQHPMA-UHFFFAOYSA-N Propene Chemical compound CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 title abstract 7
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical group C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 title abstract 6
- 239000005977 Ethylene Substances 0.000 title abstract 6
- 238000000034 method Methods 0.000 title abstract 3
- 229920001577 copolymer Polymers 0.000 title 1
- 238000006116 polymerization reaction Methods 0.000 abstract 5
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 abstract 5
- 238000006243 chemical reaction Methods 0.000 abstract 3
- HQQADJVZYDDRJT-UHFFFAOYSA-N ethene;prop-1-ene Chemical group C=C.CC=C HQQADJVZYDDRJT-UHFFFAOYSA-N 0.000 abstract 3
- 239000000203 mixture Substances 0.000 abstract 3
- 230000000379 polymerizing effect Effects 0.000 abstract 3
- 229920001400 block copolymer Polymers 0.000 abstract 2
- -1 propylene-ethylene Chemical group 0.000 abstract 2
- 230000003287 optical effect Effects 0.000 abstract 1
- 230000000704 physical effect Effects 0.000 abstract 1
- 239000002685 polymerization catalyst Substances 0.000 abstract 1
- 238000012721 stereospecific polymerization Methods 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F297/00—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
- C08F297/06—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type
- C08F297/08—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type polymerising mono-olefins
- C08F297/083—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type polymerising mono-olefins the monomers being ethylene or propylene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F297/00—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
- C08F297/06—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type
- C08F297/08—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type polymerising mono-olefins
- C08F297/083—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type polymerising mono-olefins the monomers being ethylene or propylene
- C08F297/086—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type polymerising mono-olefins the monomers being ethylene or propylene the block polymer contains at least three blocks
Abstract
Procédé de production d'un copolymère séquencé propylène-éthylène en soumettant du propylène et de l'éthylene à une polymérisation en trois étapes en utilisant un catalyseur de polymérisation stéréospécifique, caractérisé en ce qu'on effectue première étape de la polymérisation en introduisant du propylène seul ou un mélange de propylène/éthylène tel que le rapport de réaction éthylène/propylène soit de 6/94 ou moins, en polymérisant ainsi 60 à 95% en poids de la quantité polymérisée totale; on effectue la polymérisation de la seconde etape en introduisant un mélange propylène/éthylène tel que le rapport de réaction éthylène/propylène soit de 41/59 à 69/31, en polymérisant ainsi de 1 à 20 % du poids de la quantité polymérisée totale; et on effectue la troisième étape de polymérisation en introduisant de l'éthylène seul ou un mélange propylène/éthylène tel que le rapport de réaction éthylène/propylène soit de 90/10 ou plus, en polymérisant ainsi de 4 à 35 % en poids de la quantité polymérisée totale, chaque étape de polymérisation étant effectuée en discontinu. Ce procédé donne des copolymères séquences propylène-éthylène ayant un bon équilibre des propriétés physiques et optiques.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP8915178A JPS5516048A (en) | 1978-07-20 | 1978-07-20 | Preparation of propylene-ethylene block copolymer |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| FR2431512A1 true FR2431512A1 (fr) | 1980-02-15 |
| FR2431512B1 FR2431512B1 (fr) | 1983-11-25 |
Family
ID=13962849
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| FR7918623A Granted FR2431512A1 (fr) | 1978-07-20 | 1979-07-18 | Procede de production de copolymeres sequences propylene/ethylene |
Country Status (11)
| Country | Link |
|---|---|
| JP (1) | JPS5516048A (fr) |
| BE (1) | BE877781A (fr) |
| BR (1) | BR7904624A (fr) |
| CA (1) | CA1126899A (fr) |
| DE (1) | DE2929053A1 (fr) |
| FR (1) | FR2431512A1 (fr) |
| GB (1) | GB2025994B (fr) |
| HU (1) | HU181967B (fr) |
| IT (1) | IT1165262B (fr) |
| NL (1) | NL7905624A (fr) |
| SG (1) | SG8283G (fr) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2501214A1 (fr) * | 1981-03-05 | 1982-09-10 | Mitsui Toatsu Chemicals | Procede de production de copolymere sequence de propylene |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5910724B2 (ja) * | 1979-08-24 | 1984-03-10 | 旭化成株式会社 | エチレンの連続重合法 |
| JPS5883016A (ja) * | 1981-11-13 | 1983-05-18 | Mitsui Petrochem Ind Ltd | プロピレンブロツク共重合体の製法 |
| JPS58122909A (ja) * | 1982-01-19 | 1983-07-21 | Idemitsu Petrochem Co Ltd | プロピレン−エチレン共重合体の製造方法 |
| JPS59120611A (ja) * | 1982-12-27 | 1984-07-12 | Idemitsu Petrochem Co Ltd | プロピレンブロツク共重合体の製造方法 |
| JPS6049009A (ja) * | 1983-08-30 | 1985-03-18 | Mitsubishi Petrochem Co Ltd | プロピレン重合体の製造方法 |
| JPH0618841B2 (ja) * | 1986-01-28 | 1994-03-16 | 三井東圧化学株式会社 | プロピレンのブロツク共重合体の製造方法 |
| EP0457455B2 (fr) * | 1990-05-14 | 2008-07-02 | Union Carbide Chemicals & Plastics Technology Corporation | Compositions de polymères |
-
1978
- 1978-07-20 JP JP8915178A patent/JPS5516048A/ja active Granted
-
1979
- 1979-07-18 HU HU79SU1028A patent/HU181967B/hu unknown
- 1979-07-18 DE DE19792929053 patent/DE2929053A1/de not_active Withdrawn
- 1979-07-18 FR FR7918623A patent/FR2431512A1/fr active Granted
- 1979-07-19 BR BR7904624A patent/BR7904624A/pt unknown
- 1979-07-19 CA CA332,100A patent/CA1126899A/fr not_active Expired
- 1979-07-19 BE BE1/9468A patent/BE877781A/fr not_active IP Right Cessation
- 1979-07-19 NL NL7905624A patent/NL7905624A/nl not_active Application Discontinuation
- 1979-07-19 GB GB7925210A patent/GB2025994B/en not_active Expired
- 1979-07-19 IT IT24500/79A patent/IT1165262B/it active
-
1983
- 1983-02-28 SG SG82/83A patent/SG8283G/en unknown
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2501214A1 (fr) * | 1981-03-05 | 1982-09-10 | Mitsui Toatsu Chemicals | Procede de production de copolymere sequence de propylene |
Also Published As
| Publication number | Publication date |
|---|---|
| FR2431512B1 (fr) | 1983-11-25 |
| IT1165262B (it) | 1987-04-22 |
| DE2929053A1 (de) | 1980-01-31 |
| GB2025994B (en) | 1982-11-03 |
| NL7905624A (nl) | 1980-01-22 |
| BE877781A (fr) | 1979-11-16 |
| JPS5516048A (en) | 1980-02-04 |
| CA1126899A (fr) | 1982-06-29 |
| JPS6150087B2 (fr) | 1986-11-01 |
| BR7904624A (pt) | 1980-04-08 |
| IT7924500A0 (it) | 1979-07-19 |
| SG8283G (en) | 1983-09-16 |
| HU181967B (en) | 1983-11-28 |
| GB2025994A (en) | 1980-01-30 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| ST | Notification of lapse |