FR2421846A1 - Procede de preparation de zeolites aluminosilicate cristallines - Google Patents

Procede de preparation de zeolites aluminosilicate cristallines

Info

Publication number
FR2421846A1
FR2421846A1 FR7908477A FR7908477A FR2421846A1 FR 2421846 A1 FR2421846 A1 FR 2421846A1 FR 7908477 A FR7908477 A FR 7908477A FR 7908477 A FR7908477 A FR 7908477A FR 2421846 A1 FR2421846 A1 FR 2421846A1
Authority
FR
France
Prior art keywords
roh
crystalline aluminosilicate
aluminosilicate zeolites
zeolites
preparing crystalline
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
FR7908477A
Other languages
English (en)
Other versions
FR2421846B1 (fr
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shell Internationale Research Maatschappij BV
Original Assignee
Shell Internationale Research Maatschappij BV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shell Internationale Research Maatschappij BV filed Critical Shell Internationale Research Maatschappij BV
Publication of FR2421846A1 publication Critical patent/FR2421846A1/fr
Application granted granted Critical
Publication of FR2421846B1 publication Critical patent/FR2421846B1/fr
Granted legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C15/00—Cyclic hydrocarbons containing only six-membered aromatic rings as cyclic parts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/36—Pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11
    • C01B39/38—Type ZSM-5
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/36—Pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11
    • C01B39/38—Type ZSM-5
    • C01B39/40—Type ZSM-5 using at least one organic template directing agent
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/02—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon
    • C07C1/04—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon from carbon monoxide with hydrogen
    • C07C1/0425—Catalysts; their physical properties
    • C07C1/043—Catalysts; their physical properties characterised by the composition
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/02—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon
    • C07C1/04—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon from carbon monoxide with hydrogen
    • C07C1/0425—Catalysts; their physical properties
    • C07C1/043—Catalysts; their physical properties characterised by the composition
    • C07C1/0435—Catalysts; their physical properties characterised by the composition containing a metal of group 8 or a compound thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/20—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/32—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen
    • C07C5/373—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen with simultaneous isomerisation
    • C07C5/393—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen with simultaneous isomerisation with cyclisation to an aromatic six-membered ring, e.g. dehydrogenation of n-hexane to benzene
    • C07C5/41—Catalytic processes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Geology (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)

Abstract

Procédé pour la préparation de zéolites aluminosilicate cristallines ayant un rapport molaire SiO1 /Al2 O3 d'au moins 12 et un indice de contrainte compris entre 1 et 12. Un mélange aqueux contient un composé d'un métal alcalin ou alcalino-terreux M, un composé de l'alumium, un composé de silicium, un alcool (ROH) et de l'ammoniac. Les composés sont présents dans les rapports molaires suivants : s 1 O2 : Al2 O3 >= 12 ; (M)2/n O : S1O2 = 0,01-1,0 ; H2 0 : (M)2/n O = 10-500 ; ROH : Al 2 O3 = 5-500 ; ROH : NH3 >2. On a trouvé que les zéolites de cette classe sont très utilisables comme catalyseurs dans de nombreux types de procédés de conversion, en particulier dans la transformation de composés aliphatiques en hydrocarbures aromatiques.
FR7908477A 1978-04-06 1979-04-04 Procede de preparation de zeolites aluminosilicate cristallines Granted FR2421846A1 (fr)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
NL7803662A NL7803662A (nl) 1978-04-06 1978-04-06 Werkwijze voor de bereiding van zeolieten.

Publications (2)

Publication Number Publication Date
FR2421846A1 true FR2421846A1 (fr) 1979-11-02
FR2421846B1 FR2421846B1 (fr) 1980-10-24

Family

ID=19830606

Family Applications (1)

Application Number Title Priority Date Filing Date
FR7908477A Granted FR2421846A1 (fr) 1978-04-06 1979-04-04 Procede de preparation de zeolites aluminosilicate cristallines

Country Status (7)

Country Link
JP (1) JPS54151600A (fr)
CA (1) CA1135679A (fr)
DE (1) DE2913552A1 (fr)
FR (1) FR2421846A1 (fr)
GB (1) GB2018232B (fr)
IT (1) IT1112972B (fr)
NL (1) NL7803662A (fr)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2478063A1 (fr) * 1980-03-13 1981-09-18 Snam Progetti Procede pour la preparation de silicates d'aluminium ayant une structure du genre zeolite
EP0051741A1 (fr) * 1980-11-06 1982-05-19 BASF Aktiengesellschaft Procédé de préparation d'un aluminosilicate cristallin (zéolite) et son emploi comme catalyseur
EP0183376A2 (fr) * 1984-10-18 1986-06-04 Nippon Oil Co. Ltd. Procédé de déparaffinage d'huiles d'hydrocarbure

Families Citing this family (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3066649D1 (en) * 1979-12-07 1984-03-22 British Petroleum Co Plc Process for the production of crystalline aluminosilicates and their use as catalysts and catalyst supports
US4532226A (en) * 1980-03-17 1985-07-30 Mobil Oil Corporation Zeolite catalysts modified with Group VI A metal
US4276438A (en) * 1980-05-27 1981-06-30 Mobil Oil Corporation Shape selective reactions with group IB modified zeolite catalysts
EP0038116B1 (fr) * 1980-04-11 1984-04-18 Mobil Oil Corporation Méthode donnant lieu à des réactions sélectives avec des catalyseurs de zéolithes modifiés par du cadmium
US4374045A (en) 1980-05-27 1983-02-15 Mobil Oil Corporation Group IB metal modified zeolite catalysts
JPS577820A (en) * 1980-06-18 1982-01-16 Mitsubishi Heavy Ind Ltd Novel crystalline silicate and its manufacture
JPS5711819A (en) * 1980-06-24 1982-01-21 Mitsubishi Heavy Ind Ltd Preparation of crystalline zeolite
US4371457A (en) 1980-10-29 1983-02-01 Mobil Oil Corporation Zeolites modified with group VA metals
US4302621A (en) * 1980-10-29 1981-11-24 Mobil Oil Corporation Shape selective reactions utilizing zeolites modified with Group V A metals
NZ205457A (en) * 1982-09-07 1986-03-14 British Petroleum Co Plc The production of crystalline aluminosilicates of the type designated theta-1 and uses thereof
JPS59184723A (ja) * 1983-04-06 1984-10-20 Res Assoc Petroleum Alternat Dev<Rapad> 結晶性メタロシリケ−トの製造法
JPS59184722A (ja) * 1983-04-06 1984-10-20 Res Assoc Petroleum Alternat Dev<Rapad> 結晶性メタロシリケ−トの製造方法
JPS60195018A (ja) * 1984-03-16 1985-10-03 Agency Of Ind Science & Technol モルデナイト型ゼオライトの製造方法
JPS61200928A (ja) * 1985-03-04 1986-09-05 Agency Of Ind Science & Technol 低級オレフインの製造方法
GB8823705D0 (en) * 1988-10-10 1988-11-16 Unilever Plc Liquid detergent products
US5599520A (en) * 1994-11-03 1997-02-04 Garces; Juan M. Synthesis of crystalline porous solids in ammonia
EP1424128B1 (fr) 2002-12-01 2008-12-31 Süd-Chemie Ag Utilisation d'un catalyseur à base d'un aluminosilicate cristallin
EP2130586A1 (fr) 2008-06-06 2009-12-09 Total Petrochemicals Research Feluy Procédé de fabrication de métallosilicates cristallins

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2130430A1 (fr) * 1971-03-18 1972-11-03 Mobil Oil Corp

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2130430A1 (fr) * 1971-03-18 1972-11-03 Mobil Oil Corp

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2478063A1 (fr) * 1980-03-13 1981-09-18 Snam Progetti Procede pour la preparation de silicates d'aluminium ayant une structure du genre zeolite
EP0051741A1 (fr) * 1980-11-06 1982-05-19 BASF Aktiengesellschaft Procédé de préparation d'un aluminosilicate cristallin (zéolite) et son emploi comme catalyseur
EP0183376A2 (fr) * 1984-10-18 1986-06-04 Nippon Oil Co. Ltd. Procédé de déparaffinage d'huiles d'hydrocarbure
EP0183376A3 (en) * 1984-10-18 1986-10-29 Nippon Oil Co. Ltd. Method for dewaxing hydrocarbon oil

Also Published As

Publication number Publication date
DE2913552A1 (de) 1979-10-18
IT1112972B (it) 1986-01-20
IT7921594A0 (it) 1979-04-04
NL7803662A (nl) 1979-10-09
FR2421846B1 (fr) 1980-10-24
CA1135679A (fr) 1982-11-16
JPS54151600A (en) 1979-11-28
GB2018232A (en) 1979-10-17
GB2018232B (en) 1982-07-21

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