FR2408573A1 - Procede de preparation de l'acide terephtalique - Google Patents

Procede de preparation de l'acide terephtalique

Info

Publication number
FR2408573A1
FR2408573A1 FR7832034A FR7832034A FR2408573A1 FR 2408573 A1 FR2408573 A1 FR 2408573A1 FR 7832034 A FR7832034 A FR 7832034A FR 7832034 A FR7832034 A FR 7832034A FR 2408573 A1 FR2408573 A1 FR 2408573A1
Authority
FR
France
Prior art keywords
terephthalic acid
manganese
cobalt
compound
bromide
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
FR7832034A
Other languages
English (en)
Other versions
FR2408573B1 (fr
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mitsubishi Kasei Corp
Original Assignee
Mitsubishi Kasei Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mitsubishi Kasei Corp filed Critical Mitsubishi Kasei Corp
Publication of FR2408573A1 publication Critical patent/FR2408573A1/fr
Application granted granted Critical
Publication of FR2408573B1 publication Critical patent/FR2408573B1/fr
Granted legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/06Halogens; Compounds thereof
    • B01J27/08Halides
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/255Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of compounds containing six-membered aromatic rings without ring-splitting
    • C07C51/265Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of compounds containing six-membered aromatic rings without ring-splitting having alkyl side chains which are oxidised to carboxyl groups
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/50Improvements relating to the production of bulk chemicals
    • Y02P20/52Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

L'INVENTION CONCERNE UN PROCEDE DE PREPARATION D'ACIDE TEREPHTALIQUE DE PURETE ELEVEE, PAR OXYDATION DU P-OXYLENE AVEC L'OXYGENE MOLECULAIRE EN PRESENCE D'UN CATALYSEUR D'OXYDATION. LE CATALYSEUR EST CONSTITUE PAR: A.UN COMPOSE DU COBALT A RAISON DE 120PPM AU MOINS ET MOINS DE 200PPM; B.UN COMPOSE DU MANGANESE EN QUANTITE SUFFISANTE POUR ASSURER UN RAPPORT PONDERAL ENTRE LE MANGANESE ET LE COBALT DE 0,5 A 1,5; ET C.UN COMPOSE DU BROME CHOISI PARMI LE BROMURE D'HYDROGENE, LE BROMURE DE COBALT ET LE BROMURE DE MANGANESE, A RAISON DE 200 A 1000PPM, TOUTES LES PROPORTIONS ETANT CALCULEES EN TANT QU'ELEMENTS PAR RAPPORT AU POIDS DU SOLVANT ET LA TENEUR EN EAU DE LA PHASE LIQUIDE DU SYSTEME REACTIONNEL ETANT MAINTENUE ENTRE 4 ET 14 EN POIDS. ON OBTIENT UN ACIDE TEREPHTALIQUE DE PURETE ELEVEE, AVEC UNE MOINDRE CONSOMMATION DE SOLVANT ET EN FAISANT L'ECONOMIE DE L'ETAPE DE PURIFICATION.
FR7832034A 1977-11-14 1978-11-13 Procede de preparation de l'acide terephtalique Granted FR2408573A1 (fr)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP13644977A JPS5470235A (en) 1977-11-14 1977-11-14 Preparation of terephthalic acid

Publications (2)

Publication Number Publication Date
FR2408573A1 true FR2408573A1 (fr) 1979-06-08
FR2408573B1 FR2408573B1 (fr) 1983-09-09

Family

ID=15175360

Family Applications (1)

Application Number Title Priority Date Filing Date
FR7832034A Granted FR2408573A1 (fr) 1977-11-14 1978-11-13 Procede de preparation de l'acide terephtalique

Country Status (10)

Country Link
US (1) US4197412A (fr)
JP (1) JPS5470235A (fr)
BE (1) BE872009A (fr)
CA (1) CA1114835A (fr)
DE (1) DE2847170C2 (fr)
ES (1) ES475036A1 (fr)
FR (1) FR2408573A1 (fr)
GB (1) GB2008105B (fr)
IT (1) IT1100211B (fr)
NL (1) NL7811251A (fr)

Families Citing this family (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4438279A (en) 1981-09-30 1984-03-20 Standard Oil Company (Indiana) Fiber-grade terephthalic acid recovered from the effluent from paraxylene oxidation in acetic acid and the catalytic hydrogenation of the oxidation effluent in the presence of metallic platinum family metals
US4423245A (en) * 1982-01-18 1983-12-27 Union Carbide Corporation Process for preparing 2,5-dichloro-3-nitrobenzoic acid from 2,5-dichloro-3-nitro-p-xylene
US4835307A (en) * 1984-12-13 1989-05-30 Amoco Corporation Method and apparatus for controlling the manufacture of terephthalic acid to control the level and variability of the contaminant content and the optical density
US4719311A (en) * 1985-10-23 1988-01-12 Amoco Corporation Process for the production of aromatic polycarboxylic acids
US5041633A (en) * 1985-10-23 1991-08-20 Amoco Corporation Process for the production of an aromatic polycarboxylic acid
US4996353A (en) * 1989-05-16 1991-02-26 The Dow Chemical Company Process for the preparation of para,para'-polyphenyldicarboxylic acid
EP0465100B1 (fr) * 1990-06-25 1994-09-28 Mitsubishi Gas Chemical Company, Inc. Procédé pour la fabrication de l'acide isophtalique d'haute pureté
US5359134A (en) * 1992-08-14 1994-10-25 Eastman Chemical Company Process for preparing phenylterephthalic acid
US5929274A (en) * 1995-06-07 1999-07-27 Hfm International, Inc. Method to reduce carboxybenzaldehyde isomers in terephthalic acid or isophthalic acid
US5767311A (en) * 1995-06-07 1998-06-16 Glitsch International, Inc. Method and apparatus for preparing purified terephtalic acid
US6054610A (en) * 1995-06-07 2000-04-25 Hfm International, Inc. Method and apparatus for preparing purified terephthalic acid and isophthalic acid from mixed xylenes
US6013835A (en) * 1995-06-07 2000-01-11 Hfm International, Inc. Method and apparatus for preparing purified terephthalic acid
KR20030035412A (ko) * 2001-10-31 2003-05-09 주식회사 효성 복합전이금속촉매계를 이용한 테레프탈산의 제조방법
US20050256335A1 (en) * 2004-05-12 2005-11-17 Ovidiu Marin Providing gases to aromatic carboxylic acid manufacturing processes
US20060205974A1 (en) * 2005-03-08 2006-09-14 Lavoie Gino G Processes for producing aromatic dicarboxylic acids
US7550627B2 (en) * 2005-03-08 2009-06-23 Eastman Chemical Company Processes for producing aromatic dicarboxylic acids
KR100780751B1 (ko) 2006-12-28 2007-11-30 호남석유화학 주식회사 복합브롬 촉매계를 사용한 고효율 고순도 테레프탈산제조방법

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1249198A (en) * 1968-01-31 1971-10-06 Mitsui Petrochemical Ind Preparation of terephthalic acid
FR2245603A1 (fr) * 1973-07-28 1975-04-25 Matsuyama Petrochemicals Inc
FR2284585A1 (fr) * 1974-09-10 1976-04-09 Teijin Ltd Procede pour la preparation de l'acide terephtalique ou isophtalique par oxydation en phase liquide du p- ou m-xylene
FR2315497A1 (fr) * 1975-06-25 1977-01-21 Mitsubishi Chem Ind Procede de preparation d'un acide terephtalique presentant un degre eleve de purete
FR2328688A1 (fr) * 1975-10-24 1977-05-20 Standard Oil Co Procede pour l'oxydation secondaire d'un effluent liquide provenant de l'oxydation primaire de meta- ou para-xylene
FR2376114A1 (fr) * 1976-12-30 1978-07-28 Mitsubishi Chem Ind Procede perfectionne pour la preparation de l'acide terephtalique par oxydation du p-xylene

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1249198A (en) * 1968-01-31 1971-10-06 Mitsui Petrochemical Ind Preparation of terephthalic acid
FR2245603A1 (fr) * 1973-07-28 1975-04-25 Matsuyama Petrochemicals Inc
FR2284585A1 (fr) * 1974-09-10 1976-04-09 Teijin Ltd Procede pour la preparation de l'acide terephtalique ou isophtalique par oxydation en phase liquide du p- ou m-xylene
FR2315497A1 (fr) * 1975-06-25 1977-01-21 Mitsubishi Chem Ind Procede de preparation d'un acide terephtalique presentant un degre eleve de purete
US4051178A (en) * 1975-06-25 1977-09-27 Mitsubishi Chemical Industries Limited Process for producing terephthalic acid
FR2328688A1 (fr) * 1975-10-24 1977-05-20 Standard Oil Co Procede pour l'oxydation secondaire d'un effluent liquide provenant de l'oxydation primaire de meta- ou para-xylene
FR2376114A1 (fr) * 1976-12-30 1978-07-28 Mitsubishi Chem Ind Procede perfectionne pour la preparation de l'acide terephtalique par oxydation du p-xylene

Also Published As

Publication number Publication date
DE2847170A1 (de) 1979-05-17
GB2008105A (en) 1979-05-31
FR2408573B1 (fr) 1983-09-09
ES475036A1 (es) 1979-04-16
CA1114835A (fr) 1981-12-22
IT1100211B (it) 1985-09-28
GB2008105B (en) 1982-03-24
IT7829639A0 (it) 1978-11-09
BE872009A (fr) 1979-05-14
NL7811251A (nl) 1979-05-16
US4197412A (en) 1980-04-08
DE2847170C2 (de) 1983-12-29
JPS5470235A (en) 1979-06-05

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Legal Events

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