FR2405272A1 - Procede de reaction d'un compose de polyepoxyde avec un phenol dans un milieu aqueux - Google Patents

Procede de reaction d'un compose de polyepoxyde avec un phenol dans un milieu aqueux

Info

Publication number
FR2405272A1
FR2405272A1 FR7828502A FR7828502A FR2405272A1 FR 2405272 A1 FR2405272 A1 FR 2405272A1 FR 7828502 A FR7828502 A FR 7828502A FR 7828502 A FR7828502 A FR 7828502A FR 2405272 A1 FR2405272 A1 FR 2405272A1
Authority
FR
France
Prior art keywords
reacting
phenol
aqueous medium
solid granules
polyepoxide compound
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
FR7828502A
Other languages
English (en)
Other versions
FR2405272B1 (fr
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Celanese Polymer Specialties Co
Original Assignee
Celanese Polymer Specialties Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Celanese Polymer Specialties Co filed Critical Celanese Polymer Specialties Co
Publication of FR2405272A1 publication Critical patent/FR2405272A1/fr
Application granted granted Critical
Publication of FR2405272B1 publication Critical patent/FR2405272B1/fr
Granted legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/02—Polycondensates containing more than one epoxy group per molecule
    • C08G59/04—Polycondensates containing more than one epoxy group per molecule of polyhydroxy compounds with epihalohydrins or precursors thereof
    • C08G59/06—Polycondensates containing more than one epoxy group per molecule of polyhydroxy compounds with epihalohydrins or precursors thereof of polyhydric phenols
    • C08G59/066—Polycondensates containing more than one epoxy group per molecule of polyhydroxy compounds with epihalohydrins or precursors thereof of polyhydric phenols with chain extension or advancing agents
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/40—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
    • C08G59/62—Alcohols or phenols
    • C08G59/621—Phenols
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/68—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the catalysts used

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Epoxy Resins (AREA)
  • Polyethers (AREA)

Abstract

L'invention concerne un procédé de préparation de résines de polyhydroxypolyéthers d'un poids moléculaire supérieur par réaction d'un composé époxyde contenant plus de un groupement 1,2-époxy par molécule avec un phénol dihydrique au rapport molaire de 2 : 1 à 1 : 2, en utilisant, comme catalyseur, une phosphine organique, une amine tertiaire ou un ammonium quaternaire ou un phosphonium. Selon l'invention, on entreprend la réaction dans l'eau à une température de l'ordre de 80 à 100 degrés C et en présence d'un agent dispersant non ionique, on récupère la résine de polyhydroxypolyéther sous forme de granules solides ou sous forme d'une dispersion stable. L'invention s'applique notamment à l'industrie chimique.
FR7828502A 1977-10-07 1978-10-05 Procede de reaction d'un compose de polyepoxyde avec un phenol dans un milieu aqueux Granted FR2405272A1 (fr)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US05/840,360 US4122067A (en) 1977-10-07 1977-10-07 Process of reacting a polyepoxide compound with a phenol in aqueous medium

Publications (2)

Publication Number Publication Date
FR2405272A1 true FR2405272A1 (fr) 1979-05-04
FR2405272B1 FR2405272B1 (fr) 1982-04-02

Family

ID=25282156

Family Applications (1)

Application Number Title Priority Date Filing Date
FR7828502A Granted FR2405272A1 (fr) 1977-10-07 1978-10-05 Procede de reaction d'un compose de polyepoxyde avec un phenol dans un milieu aqueux

Country Status (12)

Country Link
US (1) US4122067A (fr)
JP (1) JPS5462298A (fr)
AU (1) AU538790B2 (fr)
BE (1) BE871032A (fr)
CA (1) CA1137694A (fr)
CH (1) CH635354A5 (fr)
DE (1) DE2841751A1 (fr)
FR (1) FR2405272A1 (fr)
GB (1) GB2005686B (fr)
IT (1) IT1099776B (fr)
NL (1) NL7810102A (fr)
ZA (1) ZA785655B (fr)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2496675A1 (fr) * 1980-12-18 1982-06-25 Sumitomo Chemical Co Poly (hydroxy ethers) et leur utilisation, notamment dans les peintures

Families Citing this family (38)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4302574A (en) * 1979-05-23 1981-11-24 The Dow Chemical Company Phosphonium phenoxide catalysts for promoting reacting of epoxides with phenols and/or carboxylic acids
DE2947469A1 (de) * 1979-11-24 1981-06-04 Hoechst Ag, 6000 Frankfurt Verfahren zur herstellung von glycidylaethern ein- oder mehrwertiger phenole
US4267301A (en) * 1979-12-31 1981-05-12 Eastman Kodak Company Linear hydroquinone phenoxy polymers and process
US4572853A (en) * 1980-06-05 1986-02-25 Tokyo Shibaura Denki Kabushiki Kaisha Resin encapsulation type semiconductor device
DE3163054D1 (en) * 1980-06-05 1984-05-17 Toshiba Kk Resin encapsulation type semiconductor device
US4315044A (en) * 1980-11-05 1982-02-09 Celanese Corporation Stable aqueous epoxy dispersions
JPS5943485B2 (ja) * 1980-11-26 1984-10-22 ザ・ダウ・ケミカル・カンパニ− 加水分解されたグリシジル基を含有する高分子量エポキシ樹脂を製造する方法
US4340713A (en) * 1980-11-26 1982-07-20 The Dow Chemical Company Method for preparing high molecular weight epoxy resins containing hydrolyzed epoxy groups
US4358577A (en) * 1980-11-26 1982-11-09 The Dow Chemical Company Method for preparing high molecular weight epoxy resins containing hydrolyzed epoxy groups
US4480058A (en) * 1980-12-04 1984-10-30 Scm Corporation Aqueous epoxy ester emulsions
US4339369A (en) * 1981-04-23 1982-07-13 Celanese Corporation Cationic epoxide-amine reaction products
AU567882B2 (en) * 1982-06-10 1987-12-10 Dow Chemical Company, The Advanced epoxy resins and coating compositions containing the advanced epoxy resins.
US4758638A (en) * 1982-06-10 1988-07-19 The Dow Chemical Company Advanced epoxy resins
US4608313A (en) * 1982-06-10 1986-08-26 The Dow Chemical Company Advanced epoxy resins crosslinked with polyisocyanates
US4532274A (en) * 1982-09-30 1985-07-30 Union Carbide Corporation Curable epoxy resin containing molding compositions
EP0105488A3 (fr) * 1982-09-30 1987-07-22 Union Carbide Corporation Matières à mouler contenant une résine époxy durcissable
US4423201A (en) * 1982-10-29 1983-12-27 Celanese Corporation Co-reactive urethane surfactants and stable aqueous epoxy dispersions
US4438254A (en) * 1983-02-28 1984-03-20 The Dow Chemical Company Process for producing epoxy resins
US4737553A (en) * 1986-09-29 1988-04-12 Ciba-Geigy Corporation Advanced resins from diglycidyl ethers of di-secondary alcohols and dihydric phenols
DE3643751A1 (de) * 1986-12-20 1988-06-23 Hoechst Ag Stabile waessrige epoxidharz-dispersionen, verfahren zu deren herstellung und deren verwendung
US4845172A (en) * 1987-08-19 1989-07-04 Ciba-Geigy Corporation Co-advanced resins from copolymers of polyethers of polyhydric phenols and diglycidyl ethers of di-secondary alcohols
EP0321088B1 (fr) * 1987-12-04 1994-01-26 Imperial Chemical Industries Plc Procédé pour préparer des dispersions de résines époxyde allongées
US4808692A (en) * 1988-02-18 1989-02-28 The Dow Chemical Company Preparation of advanced epoxy resins from epoxy resins and dihydric phenols in the presence of phosphonium compounds
US5252637A (en) * 1992-06-12 1993-10-12 The Glidden Company Low VOC, high molecular weight epoxy emulsion coatings
DE4225999A1 (de) 1992-08-06 1994-02-10 Hoechst Ag Vernetzte Polymermikroteilchen auf Epoxidharz-Basis, deren Herstellung und deren Verwendung
WO1994009068A1 (fr) * 1992-10-21 1994-04-28 Adhesive Coatings Co. Nouveaux polymeres en emulsion ionique, et leur preparation
US5401814A (en) * 1993-10-13 1995-03-28 The Dow Chemical Company Process for the preparation of thermoplastic poly(hydroxy ethers)
US6011111A (en) * 1993-10-18 2000-01-04 The Dow Chemical Company Hydroxy-phenoxyether polymer thermoplastic composites
US5500461A (en) * 1995-04-19 1996-03-19 Shell Oil Company Stable waterborne epoxy resin dispersion containing micronized DICY
DE19536608A1 (de) * 1995-09-30 1997-04-03 Hoechst Ag Emulgatorsystem für wasserverdünnbare Epoxidharzsysteme mit Topfzeit-Anzeige
US5684080A (en) * 1995-11-15 1997-11-04 Shell Oil Company Aqueous polymer emulsion
TW513456B (en) 1997-08-14 2002-12-11 Shell Int Research Aqueous dispersions of epoxy resins
US6143809A (en) * 1998-07-17 2000-11-07 Shell Oil Company Process to prepare aqueous dispersions of epoxy resins
US6515045B1 (en) * 1999-11-29 2003-02-04 Vantico, Inc. Removable adhesive of epoxy resin, amine and non-ionic surfactant
US6534621B2 (en) * 2000-05-18 2003-03-18 Dow Global Technologies Inc. Process for manufacturing a hydroxyester derivative intermediate and epoxy resins prepared therefrom
US6653436B2 (en) 2000-12-08 2003-11-25 Resolution Performance Products Llc Water dispersible epoxy resins
MX2012002315A (es) 2009-08-24 2012-04-11 Dow Global Technologies Llc Metodo para elaborar una resina epoxica particulada.
IT1402349B1 (it) * 2010-09-15 2013-08-30 Lamberti Spa Composizioni per la patinatura della carta

Family Cites Families (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2615008A (en) * 1945-09-18 1952-10-21 Devoe & Raynolds Co Epoxide resin compositions
US2506486A (en) * 1948-04-21 1950-05-02 Union Carbide & Carbon Corp Thermosetting resin from a diphenol and a diglycidyl ether of a diphenol
GB652024A (en) * 1948-11-26 1951-04-11 Courtaulds Ltd Improvements in and relating to the production of thermoplastic resins and of threads, fibres, filaments and like products therefrom
US3020250A (en) * 1959-08-04 1962-02-06 Union Carbide Corp Aqueous epoxy resin emulsions and coatings therefrom
NL277243A (fr) * 1961-04-13
US3350353A (en) * 1965-03-25 1967-10-31 Celanese Coatings Co Epoxide resin process
US3336257A (en) * 1965-06-29 1967-08-15 Celanese Coatings Co High molecular weight thermoplastic resin from the polymerization of diphenols and diepoxides
NL137295C (fr) * 1965-11-03
US3477990A (en) * 1967-12-07 1969-11-11 Shell Oil Co Process for reacting a phenol with an epoxy compound and resulting products
US3879324A (en) * 1968-04-29 1975-04-22 Robert D Timmons Solvent-free, aqueous resin dispersion
US3945964A (en) * 1971-03-19 1976-03-23 Garth Winton Hastings Aqueous epoxy emulsions
US3948855A (en) * 1971-09-16 1976-04-06 The Dow Chemical Company Process for reacting a phenol with a vicinal epoxy compound in the presence of phosphorus or carbon containing acid, ester or acid ester
BE794087A (nl) * 1972-01-21 1973-07-16 Shell Int Research Polyepoxyden
US3931109A (en) * 1972-03-13 1976-01-06 The Dow Chemical Company Process for coating substrates with high molecular weight epoxy resins
US3842037A (en) * 1972-06-08 1974-10-15 Shell Oil Co Process for preparing higher molecular weight polyepoxide products by condensing lower molecular weight polyepoxide with polyhydric phenols
US3919169A (en) * 1974-02-20 1975-11-11 Dow Chemical Co Continuous process for the production of solid epoxy resins
US3978027A (en) * 1975-05-07 1976-08-31 Shell Oil Company Process for reacting a phenol with an epoxy compound

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2496675A1 (fr) * 1980-12-18 1982-06-25 Sumitomo Chemical Co Poly (hydroxy ethers) et leur utilisation, notamment dans les peintures

Also Published As

Publication number Publication date
CA1137694A (fr) 1982-12-14
DE2841751A1 (de) 1979-04-12
AU538790B2 (en) 1984-08-30
GB2005686A (en) 1979-04-25
US4122067A (en) 1978-10-24
AU4031378A (en) 1980-04-03
IT1099776B (it) 1985-09-28
JPS5462298A (en) 1979-05-19
IT7828522A0 (it) 1978-10-06
ZA785655B (en) 1979-09-26
NL7810102A (nl) 1979-04-10
BE871032A (fr) 1979-04-05
FR2405272B1 (fr) 1982-04-02
GB2005686B (en) 1982-03-17
JPS625174B2 (fr) 1987-02-03
CH635354A5 (fr) 1983-03-31

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Legal Events

Date Code Title Description
TP Transmission of property
ST Notification of lapse