FR2404651A1 - Polyurethanne acrylique durcissable par irradiation - Google Patents
Polyurethanne acrylique durcissable par irradiationInfo
- Publication number
- FR2404651A1 FR2404651A1 FR7827785A FR7827785A FR2404651A1 FR 2404651 A1 FR2404651 A1 FR 2404651A1 FR 7827785 A FR7827785 A FR 7827785A FR 7827785 A FR7827785 A FR 7827785A FR 2404651 A1 FR2404651 A1 FR 2404651A1
- Authority
- FR
- France
- Prior art keywords
- tetraol
- tri
- organic
- acrylic polyurethane
- polyether
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/67—Unsaturated compounds having active hydrogen
- C08G18/671—Unsaturated compounds having only one group containing active hydrogen
- C08G18/672—Esters of acrylic or alkyl acrylic acid having only one group containing active hydrogen
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/4009—Two or more macromolecular compounds not provided for in one single group of groups C08G18/42 - C08G18/64
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Macromonomer-Based Addition Polymer (AREA)
- Polyurethanes Or Polyureas (AREA)
- Paints Or Removers (AREA)
- Polymerisation Methods In General (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
L'invention concerne un polyuréthanne acrylique durcissable par irradiation. On obtient ce produit a. en formant un composé intermédiaire à terminaison isocyanate par coréaction d'un diisocyanate organique avec un tri/tétraol organique associé à un diol organique, l'association étant choisie entre un mélange polyester-tri/tétraol-polyéther-diol; et un mélange polyéther-tri/tétraol-polyester-diol; et b. en faisant réagir le composé intermédiaire à terminaison isocyanate avec un hydroxyacrylate tel que l'acrylate de 2-hydroxyéthyle. L'oligomère a une faible viscosité très avantageuse, et il durcit cependant par exposition à une irradiation en donnant un revêtement doué de bonnes propriétés physiques.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US05/837,974 US4131602A (en) | 1977-09-29 | 1977-09-29 | Radiation curable acrylated polyurethane |
Publications (2)
Publication Number | Publication Date |
---|---|
FR2404651A1 true FR2404651A1 (fr) | 1979-04-27 |
FR2404651B1 FR2404651B1 (fr) | 1984-05-11 |
Family
ID=25275935
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
FR7827785A Granted FR2404651A1 (fr) | 1977-09-29 | 1978-09-28 | Polyurethanne acrylique durcissable par irradiation |
Country Status (10)
Country | Link |
---|---|
US (1) | US4131602A (fr) |
JP (1) | JPS5840973B2 (fr) |
BE (1) | BE870844A (fr) |
CA (1) | CA1123548A (fr) |
DE (1) | DE2842274B2 (fr) |
FR (1) | FR2404651A1 (fr) |
GB (1) | GB2006241B (fr) |
IT (1) | IT1099186B (fr) |
NL (1) | NL7809842A (fr) |
SE (1) | SE438315B (fr) |
Families Citing this family (76)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4216267A (en) * | 1977-12-29 | 1980-08-05 | Gaf Corporation | Flexible substrates containing a radiation curable coating composition |
US4188455A (en) * | 1978-01-03 | 1980-02-12 | Lord Corporation | Actinic radiation-curable formulations containing at least one unsaturated polyether-esterurethane oligomer |
US4317895A (en) * | 1979-01-02 | 1982-03-02 | Inmont Corporation | Coating compositions of thermoplastic acrylic-urethane copolymers |
DE3071406D1 (en) * | 1979-08-29 | 1986-03-20 | Minnesota Mining & Mfg | Ophthalmic lens blank with protective coating |
US4369300A (en) * | 1979-11-26 | 1983-01-18 | Union Carbide Corporation | Acrylated urethane silicone compositions |
US4424333A (en) * | 1980-11-03 | 1984-01-03 | Olin Corporation | Modified polyurethane liquid polymer compositions |
DE3045788A1 (de) * | 1980-12-04 | 1982-07-08 | Bayer Ag, 5090 Leverkusen | Strahlenhaertbare urethangruppenhaltige acrylsaeureester und ihre verwendung |
US4914223A (en) * | 1981-10-29 | 1990-04-03 | Minnesota Mining And Manufacturing Company | Acrylamidoacylated oligomers |
US4996243A (en) * | 1981-10-29 | 1991-02-26 | Minnesota Mining And Manufacturing Company | Curable acrylamido oligomer compositions with initiator, and cured products |
US4777276A (en) * | 1981-10-29 | 1988-10-11 | Minnesota Mining And Manufacturing Company | Acrylamidoacylated oligomers |
US4837290A (en) * | 1981-10-29 | 1989-06-06 | Minnesota Mining And Manufacturing Company | Acrylamidoacylated oligomers |
US4535024A (en) * | 1982-11-01 | 1985-08-13 | Transfer Print Foils, Inc. | Gloss black metalized product and method of preparation |
AU1982283A (en) * | 1982-11-12 | 1984-05-17 | Loctite Corporation | Conformal coating and potting system |
US4932750A (en) * | 1982-12-09 | 1990-06-12 | Desoto, Inc. | Single-coated optical fiber |
US5223553A (en) * | 1983-03-09 | 1993-06-29 | Metallized Products, Inc. | Antistatic resin composition |
EP0125710A3 (fr) * | 1983-04-11 | 1985-07-10 | International Standard Electric Corporation | Revêtement durcissable par rayonnement U.V. pour des fibres optiques |
JPS59211028A (ja) * | 1983-05-17 | 1984-11-29 | Canon Inc | 画像読み取り装置 |
JPS59232110A (ja) * | 1983-06-16 | 1984-12-26 | Sanyo Chem Ind Ltd | ウレタン−ビニル系樹脂の製造法 |
CA1287322C (fr) * | 1984-03-12 | 1991-08-06 | Metallized Products, Inc. | Produit de revetement obtenu par irradiation, a base de prepolymere et de sel quaternaire d'ammonium |
DE3508399C2 (de) * | 1984-04-04 | 1995-08-10 | Hoechst Ag | 2-Komponentenlacke und deren Verwendung |
US4607084A (en) * | 1984-06-11 | 1986-08-19 | Celanese Specialty Resins, Inc. | Radiation curable acrylated polyurethane oligomer compositions |
EP0168173B1 (fr) * | 1984-06-11 | 1989-01-18 | INTEREZ, Inc.(a Delaware corporation) | Compositions de polyuréthanes oligomères acrylés durcissables par rayonnement |
DE3421826A1 (de) * | 1984-06-13 | 1985-12-19 | Hüls AG, 4370 Marl | Lagerstabile, nco-freie urethanharnstoffacrylate |
US4650845A (en) * | 1984-07-10 | 1987-03-17 | Minnesota Mining And Manufacturing Company | Ultra-violet light curable compositions for abrasion resistant articles |
US4606870A (en) * | 1984-07-25 | 1986-08-19 | Essex Group, Inc. | Preparing magnet wire having electron beam curable wire enamels |
US5177120A (en) * | 1984-07-31 | 1993-01-05 | Dentsply Research & Development Corp. | Chain extended urethane diacrylate and dental impression formation |
US4813875A (en) * | 1984-07-31 | 1989-03-21 | Dentsply Research & Development Corp. | Chain extended urethane diacrylate and dental impression formation |
US4598009A (en) * | 1984-09-13 | 1986-07-01 | Armstrong World Industries, Inc. | Embossed material and method for producing the same from a photocrosslinkable polyurethane |
US5128385A (en) * | 1984-09-13 | 1992-07-07 | Armstrong World Industries, Inc. | Photocrosslinkable thermoplastic urethane coating system |
JPS61203108A (ja) * | 1985-03-04 | 1986-09-09 | Toyobo Co Ltd | 光硬化型可撓性組成物 |
US4564666A (en) * | 1985-03-11 | 1986-01-14 | Desoto, Inc. | Urethane acrylates based on polyepichlorohydrin polyether diols and optical fiber coatings based thereon |
CA1292752C (fr) * | 1985-10-29 | 1991-12-03 | John M. Zimmerman | Enrobage durcissable aux ultraviolets pour fibres de verre d'optique |
DE3540464A1 (de) * | 1985-11-14 | 1987-05-21 | Polychemie Gmbh | Reaktive bindemittel |
JPS639360A (ja) * | 1986-06-30 | 1988-01-16 | Canon Inc | 画像読取装置 |
JPS6315659U (fr) * | 1986-07-16 | 1988-02-02 | ||
GB8621835D0 (en) * | 1986-09-10 | 1986-10-15 | Courtaulds Plc | Urethane polymer films |
US5019636A (en) * | 1989-05-10 | 1991-05-28 | Allied-Signal Inc. | Polyester chain-extended vinyl ether urethane oligomers |
US5536529A (en) * | 1989-05-11 | 1996-07-16 | Borden, Inc. | Ultraviolet radiation-curable coatings for optical fibers and optical fibers coated therewith |
US5352712A (en) * | 1989-05-11 | 1994-10-04 | Borden, Inc. | Ultraviolet radiation-curable coatings for optical fibers |
CA1321671C (fr) * | 1989-05-11 | 1993-08-24 | Paul J. Shustack | Revetements reticulables sans rayonnement ultraviolet pour fibres optiques; les fibres ainsi obtenues |
DE3916340A1 (de) * | 1989-05-19 | 1990-11-22 | Huels Chemische Werke Ag | Verfahren zur herstellung waessriger, strahlenhaertbarer urethanacrylatdispersionen |
CA1341128C (fr) | 1989-06-27 | 2000-10-24 | Borden Chemical, Inc. | Matrice de fibres optiques |
US5095069A (en) * | 1990-08-30 | 1992-03-10 | Ppg Industries, Inc. | Internally-curable water-based polyurethanes |
DE4027770A1 (de) * | 1990-09-01 | 1992-03-05 | Basf Lacke & Farben | Fluessige, strahlenhaertbare ueberzugsmasse fuer die beschichtung von glasoberflaechen |
DE4027971A1 (de) * | 1990-09-04 | 1992-03-05 | Bayer Ag | Acryloylgruppen enthaltende, aliphatische polyurethane, ein verfahren zu ihrer herstellung und ihre verwendung |
CA2082614A1 (fr) * | 1992-04-24 | 1993-10-25 | Paul J. Shustack | Revetements resistants aux solvants organiques et a l'eau, thermiquement, oxydativement et hydrolytiquement stables pour fibres optiques, fibres optiques ainsi revetues et procedede fabrication de celles-ci |
DE4404616A1 (de) * | 1994-02-14 | 1995-08-17 | Bayer Ag | Verwendung von UV-härtbaren Beschichtungsmitteln zur Beschichtung von Polycarbonatformkörpern |
US5843622A (en) * | 1994-03-04 | 1998-12-01 | Ashai Kasei Kogyo Kabushiki Kaisha | Liquid photosensitive resin composition for use in forming a relief structure |
JPH08218295A (ja) * | 1995-02-13 | 1996-08-27 | New Oji Paper Co Ltd | 強光沢シート |
US5578693A (en) * | 1995-09-05 | 1996-11-26 | Bomar Specialties Company | Multifunctional terminally unsaturated urethane oligomers |
US5965460A (en) * | 1997-01-29 | 1999-10-12 | Mac Dermid, Incorporated | Polyurethane composition with (meth)acrylate end groups useful in the manufacture of polishing pads |
DE19902685B4 (de) * | 1999-01-23 | 2006-08-10 | Röhm GmbH & Co. KG | Neuartige Urethan(meth)acrylate, Verfahren zu deren Herstellung und deren Verwendung |
CN1247478C (zh) | 2000-12-29 | 2006-03-29 | Dsmip财产有限公司 | 用于可辐射固化的纤维透镜涂料的不形成结晶的低聚物 |
TW200307733A (en) * | 2002-02-01 | 2003-12-16 | Natoco Co Ltd | Composition curable with actinic energy ray and use thereof |
JP4436688B2 (ja) * | 2002-04-11 | 2010-03-24 | インフェイズ テクノロジーズ インコーポレイテッド | ホログラフィー記憶媒体 |
US20060079624A1 (en) * | 2004-10-08 | 2006-04-13 | Hildeberto Nava | Crosslinkable polymer systems |
US20060173142A1 (en) * | 2005-02-01 | 2006-08-03 | Hildeberto Nava | Functionalized thermosetting resin systems |
US20070179250A1 (en) * | 2006-01-30 | 2007-08-02 | Reichhold, Inc. | Laminating resin with reduced styrene monomer |
JP2007254529A (ja) * | 2006-03-22 | 2007-10-04 | Dainippon Ink & Chem Inc | 光ラジカル反応性塗料組成物及び塗装木質基材 |
WO2009041964A1 (fr) | 2007-09-25 | 2009-04-02 | Entrotech, Inc. | Films de remplacement de peinture, composites de ceux-ci, et procédés associés |
US10981371B2 (en) | 2008-01-19 | 2021-04-20 | Entrotech, Inc. | Protected graphics and related methods |
WO2010036981A1 (fr) * | 2008-09-26 | 2010-04-01 | Entrotech, Inc. | Procédés de polymérisation de films in situ |
EP2473333A4 (fr) * | 2009-09-04 | 2017-09-13 | Covestro LLC | Processus automatisés de production de pales d'éoliennes en polyuréthane |
US8828303B2 (en) * | 2010-03-31 | 2014-09-09 | Entrotech, Inc. | Methods for polymerizing films in-situ using a radiation source |
JP5382277B2 (ja) * | 2011-10-19 | 2014-01-08 | Dic株式会社 | 活性エネルギー線硬化型樹脂組成物、接着剤及び積層フィルム |
KR101716543B1 (ko) * | 2014-04-30 | 2017-03-15 | 제일모직주식회사 | 점착필름 및 이를 포함하는 광학표시장치 |
US10822811B2 (en) | 2015-04-03 | 2020-11-03 | Armstrong World Industries, Inc. | Scratch resistant coating |
EP3448949B8 (fr) | 2016-09-20 | 2024-01-24 | PPG Advanced Surface Technologies, LLC | Appliques de film de peinture ayant des défauts réduits, articles et procédés |
RU2645509C1 (ru) * | 2017-03-14 | 2018-02-21 | Федеральное государственное бюджетное образовательное учреждение высшего образования "Чувашский государственный университет имени И.Н. Ульянова" | Лаковая композиция на основе олигоуретанакрилата |
WO2019116181A1 (fr) | 2017-12-12 | 2019-06-20 | 3M Innovative Properties Company | Compositions comprenant des particules d'alumine-alpha et leurs procédés d'utilisation |
JP2020047797A (ja) | 2018-09-19 | 2020-03-26 | キオクシア株式会社 | 記憶装置及びその製造方法 |
US11518834B2 (en) | 2019-01-02 | 2022-12-06 | Polynt Composites USA, Inc. | Radically polymerizable compositions |
US20220169888A1 (en) | 2019-04-11 | 2022-06-02 | 3M Innovative Properties Company | Curable compositions, abrasion-resistant articles, and method of thermoforming the same |
EP3999569A1 (fr) * | 2019-07-17 | 2022-05-25 | Arkema France | Oligomères fonctionnalisés par méthacrylate et procédés de préparation et d'utilisation de tels oligomères |
CN112225868A (zh) * | 2020-09-30 | 2021-01-15 | 华南理工大学 | 一种二三官能度混合型聚氨酯丙烯酸酯树脂及其制备方法 |
WO2023281971A1 (fr) * | 2021-07-05 | 2023-01-12 | 東洋インキScホールディングス株式会社 | Composition de résine durcissable par rayonnement d'énergie active, dispersion de pigment durcissable par rayonnement d'énergie active, composition d'encre pour encre offset, et composition d'encre pour encre flexographique |
Family Cites Families (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3891523A (en) * | 1970-01-19 | 1975-06-24 | Dainippon Ink & Chemicals | Photopolymerizable, isocyanate-containing prepolymers |
US3700643A (en) * | 1970-09-02 | 1972-10-24 | Union Carbide Corp | Radiation-curable acrylate-capped polycaprolactone compositions |
JPS5034964B1 (fr) * | 1970-03-30 | 1975-11-12 | ||
US3642943A (en) * | 1970-07-08 | 1972-02-15 | Lord Corp | Acrylic urethane composition of acrylic polymer with pendant isocyanate groups and isocyanate containing urethane prepolymer |
US3741918A (en) * | 1971-08-02 | 1973-06-26 | Carbide Corp | Poly(oxycaproyl)-polyurethane products |
US3746665A (en) * | 1971-08-02 | 1973-07-17 | Union Carbide Corp | Polyurethane based on blends of poly (oxycaproyl) diols and poly(oxytetraurethylene) diols |
DE2259360C2 (de) * | 1972-12-04 | 1982-06-09 | Basf Ag, 6700 Ludwigshafen | Verfahren zur Herstellung von dünnen Schichten auf Basis von Polyurethan-Elastomeren |
US3954584A (en) * | 1973-06-20 | 1976-05-04 | Kansai Paint Company | Photopolymerizable vinylurethane liquid composition |
-
1977
- 1977-09-29 US US05/837,974 patent/US4131602A/en not_active Expired - Lifetime
-
1978
- 1978-09-18 CA CA311,488A patent/CA1123548A/fr not_active Expired
- 1978-09-28 IT IT28195/78A patent/IT1099186B/it active
- 1978-09-28 NL NL7809842A patent/NL7809842A/xx not_active Application Discontinuation
- 1978-09-28 JP JP53118697A patent/JPS5840973B2/ja not_active Expired
- 1978-09-28 FR FR7827785A patent/FR2404651A1/fr active Granted
- 1978-09-28 GB GB7838449A patent/GB2006241B/en not_active Expired
- 1978-09-28 DE DE2842274A patent/DE2842274B2/de not_active Ceased
- 1978-09-28 SE SE7810210A patent/SE438315B/sv not_active IP Right Cessation
- 1978-09-28 BE BE190776A patent/BE870844A/fr not_active IP Right Cessation
Also Published As
Publication number | Publication date |
---|---|
JPS5840973B2 (ja) | 1983-09-09 |
GB2006241A (en) | 1979-05-02 |
NL7809842A (nl) | 1979-04-02 |
FR2404651B1 (fr) | 1984-05-11 |
CA1123548A (fr) | 1982-05-11 |
DE2842274B2 (de) | 1980-11-06 |
GB2006241B (en) | 1982-04-28 |
DE2842274A1 (de) | 1979-04-05 |
US4131602A (en) | 1978-12-26 |
IT1099186B (it) | 1985-09-18 |
SE438315B (sv) | 1985-04-15 |
SE7810210L (sv) | 1979-03-30 |
BE870844A (fr) | 1979-03-28 |
IT7828195A0 (it) | 1978-09-28 |
JPS5493096A (en) | 1979-07-23 |
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Legal Events
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ST | Notification of lapse |