FR2381715A1 - Synthese de zeolites cristallines de type aluminosilicate - Google Patents
Synthese de zeolites cristallines de type aluminosilicateInfo
- Publication number
- FR2381715A1 FR2381715A1 FR7705392A FR7705392A FR2381715A1 FR 2381715 A1 FR2381715 A1 FR 2381715A1 FR 7705392 A FR7705392 A FR 7705392A FR 7705392 A FR7705392 A FR 7705392A FR 2381715 A1 FR2381715 A1 FR 2381715A1
- Authority
- FR
- France
- Prior art keywords
- contg
- atoms
- cations
- prepn
- prefd
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 150000001768 cations Chemical class 0.000 title abstract 4
- 239000010457 zeolite Substances 0.000 title abstract 4
- 150000004645 aluminates Chemical class 0.000 title abstract 2
- 239000003054 catalyst Substances 0.000 title abstract 2
- 150000004760 silicates Chemical class 0.000 title 1
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 abstract 3
- 125000004433 nitrogen atom Chemical group N* 0.000 abstract 3
- 229910021536 Zeolite Inorganic materials 0.000 abstract 2
- 229920000554 ionomer Polymers 0.000 abstract 2
- IMNIMPAHZVJRPE-UHFFFAOYSA-N triethylenediamine Chemical compound C1CN2CCN1CC2 IMNIMPAHZVJRPE-UHFFFAOYSA-N 0.000 abstract 2
- GETQZCLCWQTVFV-UHFFFAOYSA-N trimethylamine Chemical compound CN(C)C GETQZCLCWQTVFV-UHFFFAOYSA-N 0.000 abstract 2
- YTEIHWVCQJZNEN-UHFFFAOYSA-N 3-pyridin-4-ylpyridine Chemical group C1=CN=CC(C=2C=CN=CC=2)=C1 YTEIHWVCQJZNEN-UHFFFAOYSA-N 0.000 abstract 1
- MGFJDEHFNMWYBD-OWOJBTEDSA-N 4-[(e)-2-pyridin-4-ylethenyl]pyridine Chemical group C=1C=NC=CC=1/C=C/C1=CC=NC=C1 MGFJDEHFNMWYBD-OWOJBTEDSA-N 0.000 abstract 1
- YRNWIFYIFSBPAU-UHFFFAOYSA-N 4-[4-(dimethylamino)phenyl]-n,n-dimethylaniline Chemical compound C1=CC(N(C)C)=CC=C1C1=CC=C(N(C)C)C=C1 YRNWIFYIFSBPAU-UHFFFAOYSA-N 0.000 abstract 1
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 abstract 1
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 abstract 1
- 238000010521 absorption reaction Methods 0.000 abstract 1
- 125000005263 alkylenediamine group Chemical group 0.000 abstract 1
- 229910000323 aluminium silicate Inorganic materials 0.000 abstract 1
- 238000004517 catalytic hydrocracking Methods 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 abstract 1
- 238000005336 cracking Methods 0.000 abstract 1
- 229910001683 gmelinite Inorganic materials 0.000 abstract 1
- 229910001387 inorganic aluminate Inorganic materials 0.000 abstract 1
- 238000006317 isomerization reaction Methods 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- 229910052680 mordenite Inorganic materials 0.000 abstract 1
- -1 poly(epichlorohydrin) Polymers 0.000 abstract 1
- 229920002755 poly(epichlorohydrin) Polymers 0.000 abstract 1
- 229920000642 polymer Polymers 0.000 abstract 1
- 150000003839 salts Chemical class 0.000 abstract 1
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
- B01J29/084—Y-type faujasite
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/18—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the mordenite type
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/0234—Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds
- B01J31/0235—Nitrogen containing compounds
- B01J31/0254—Nitrogen containing compounds on mineral substrates
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B33/00—Silicon; Compounds thereof
- C01B33/20—Silicates
- C01B33/26—Aluminium-containing silicates, i.e. silico-aluminates
- C01B33/28—Base exchange silicates, e.g. zeolites
- C01B33/2807—Zeolitic silicoaluminates with a tridimensional crystalline structure possessing molecular sieve properties; Isomorphous compounds wherein a part of the aluminium ore of the silicon present may be replaced by other elements such as gallium, germanium, phosphorus; Preparation of zeolitic molecular sieves from molecular sieves of another type or from preformed reacting mixtures
- C01B33/2838—Zeolitic silicoaluminates with a tridimensional crystalline structure possessing molecular sieve properties; Isomorphous compounds wherein a part of the aluminium ore of the silicon present may be replaced by other elements such as gallium, germanium, phosphorus; Preparation of zeolitic molecular sieves from molecular sieves of another type or from preformed reacting mixtures of faujasite type, or type X or Y (UNION CARBIDE trade names; correspond to GRACE's types Z-14 and Z-14HS, respectively)
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B33/00—Silicon; Compounds thereof
- C01B33/20—Silicates
- C01B33/26—Aluminium-containing silicates, i.e. silico-aluminates
- C01B33/28—Base exchange silicates, e.g. zeolites
- C01B33/2807—Zeolitic silicoaluminates with a tridimensional crystalline structure possessing molecular sieve properties; Isomorphous compounds wherein a part of the aluminium ore of the silicon present may be replaced by other elements such as gallium, germanium, phosphorus; Preparation of zeolitic molecular sieves from molecular sieves of another type or from preformed reacting mixtures
- C01B33/2838—Zeolitic silicoaluminates with a tridimensional crystalline structure possessing molecular sieve properties; Isomorphous compounds wherein a part of the aluminium ore of the silicon present may be replaced by other elements such as gallium, germanium, phosphorus; Preparation of zeolitic molecular sieves from molecular sieves of another type or from preformed reacting mixtures of faujasite type, or type X or Y (UNION CARBIDE trade names; correspond to GRACE's types Z-14 and Z-14HS, respectively)
- C01B33/2853—Zeolitic silicoaluminates with a tridimensional crystalline structure possessing molecular sieve properties; Isomorphous compounds wherein a part of the aluminium ore of the silicon present may be replaced by other elements such as gallium, germanium, phosphorus; Preparation of zeolitic molecular sieves from molecular sieves of another type or from preformed reacting mixtures of faujasite type, or type X or Y (UNION CARBIDE trade names; correspond to GRACE's types Z-14 and Z-14HS, respectively) of type Y
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B33/00—Silicon; Compounds thereof
- C01B33/20—Silicates
- C01B33/26—Aluminium-containing silicates, i.e. silico-aluminates
- C01B33/28—Base exchange silicates, e.g. zeolites
- C01B33/2807—Zeolitic silicoaluminates with a tridimensional crystalline structure possessing molecular sieve properties; Isomorphous compounds wherein a part of the aluminium ore of the silicon present may be replaced by other elements such as gallium, germanium, phosphorus; Preparation of zeolitic molecular sieves from molecular sieves of another type or from preformed reacting mixtures
- C01B33/2876—Zeolitic silicoaluminates with a tridimensional crystalline structure possessing molecular sieve properties; Isomorphous compounds wherein a part of the aluminium ore of the silicon present may be replaced by other elements such as gallium, germanium, phosphorus; Preparation of zeolitic molecular sieves from molecular sieves of another type or from preformed reacting mixtures from a reacting mixture containing an amine or an organic cation, e.g. a quaternary onium cation-ammonium, phosphonium, stibonium
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G73/00—Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups C08G12/00 - C08G71/00
- C08G73/02—Polyamines
- C08G73/0206—Polyalkylene(poly)amines
- C08G73/0213—Preparatory process
- C08G73/022—Preparatory process from polyamines and epihalohydrins
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
- C10G45/58—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins
- C10G45/60—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins characterised by the catalyst used
- C10G45/64—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins characterised by the catalyst used containing crystalline alumino-silicates, e.g. molecular sieves
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
- C10G2400/02—Gasoline
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S423/00—Chemistry of inorganic compounds
- Y10S423/25—Mordenite, e.g. NA-D, pttilolite, zeolon
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S423/00—Chemistry of inorganic compounds
- Y10S423/33—MTW, e.g. ZSM-12, NU-13, CZH-5, TPZ-3
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S502/00—Catalyst, solid sorbent, or support therefor: product or process of making
- Y10S502/506—Method of making inorganic composition utilizing organic compound, except formic, acetic, or oxalic acid or salt thereof
- Y10S502/507—Synthetic resin, natural resin, polysaccaride, or polypeptide
Abstract
La présente invention a pour objet la synthèse de zéolites cristallines de type aluminosilicate à partir d'un mélange réactionnel aqueux contenant des sources de silicate, d'aluminate et de cations en quantité au moins équivalente à l'aluminium dans le mélange. Elle est caractérisée en ce que la source de cations comprend, en particulier, un polymere choisi parmi les ionènes et les ionomères de poids équivalent tel et en quantité telle que la charge négative sur 1 à 100 % des tétraedres contenant de l'aluminium de la zéolite résultante est équilibrée par des atomes d'azote du polymère chargés positivement. Elle se rapporte à la production de zéolites telles que la mordénite, la zéolite Y ou la zéolyte ZSM-5 et, en particulier, de la gmélinite dépourvue de chabazite.
Priority Applications (6)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US05/697,646 US4061717A (en) | 1974-10-03 | 1976-06-18 | Directed crystallization of synthetic aluminosilicates |
DE19772705436 DE2705436A1 (de) | 1974-10-03 | 1977-02-09 | Verfahren zur herstellung kristalliner aluminosilicatzeolithe und danach erhaltene synthetische produkte |
NL7701382A NL7701382A (en) | 1974-10-03 | 1977-02-09 | Prepn. of zeolites for use as catalysts - from silicates, aluminates and polymeric cations |
GB5721/77A GB1572135A (en) | 1974-10-03 | 1977-02-11 | Directed crystallisation of synthetic aluminosilicates |
FR7705392A FR2381715A1 (fr) | 1974-10-03 | 1977-02-24 | Synthese de zeolites cristallines de type aluminosilicate |
BE175295A BE851865A (fr) | 1974-10-03 | 1977-02-25 | Synthese de zeolites cristallines de type aluminosilicate |
Applications Claiming Priority (7)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US51190274A | 1974-10-03 | 1974-10-03 | |
US05/697,646 US4061717A (en) | 1974-10-03 | 1976-06-18 | Directed crystallization of synthetic aluminosilicates |
DE19772705436 DE2705436A1 (de) | 1974-10-03 | 1977-02-09 | Verfahren zur herstellung kristalliner aluminosilicatzeolithe und danach erhaltene synthetische produkte |
NL7701382A NL7701382A (en) | 1974-10-03 | 1977-02-09 | Prepn. of zeolites for use as catalysts - from silicates, aluminates and polymeric cations |
GB5721/77A GB1572135A (en) | 1974-10-03 | 1977-02-11 | Directed crystallisation of synthetic aluminosilicates |
FR7705392A FR2381715A1 (fr) | 1974-10-03 | 1977-02-24 | Synthese de zeolites cristallines de type aluminosilicate |
BE175295A BE851865A (fr) | 1974-10-03 | 1977-02-25 | Synthese de zeolites cristallines de type aluminosilicate |
Publications (2)
Publication Number | Publication Date |
---|---|
FR2381715A1 true FR2381715A1 (fr) | 1978-09-22 |
FR2381715B1 FR2381715B1 (fr) | 1981-10-23 |
Family
ID=43927619
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
FR7705392A Granted FR2381715A1 (fr) | 1974-10-03 | 1977-02-24 | Synthese de zeolites cristallines de type aluminosilicate |
Country Status (6)
Country | Link |
---|---|
US (1) | US4061717A (fr) |
BE (1) | BE851865A (fr) |
DE (1) | DE2705436A1 (fr) |
FR (1) | FR2381715A1 (fr) |
GB (1) | GB1572135A (fr) |
NL (1) | NL7701382A (fr) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0055046A1 (fr) * | 1980-12-19 | 1982-06-30 | Imperial Chemical Industries Plc | Zéolites |
EP0532993A1 (fr) * | 1991-09-20 | 1993-03-24 | BASF Aktiengesellschaft | Procédé de préparation d'alumino- et de silicoaluminophosphates de structure AEL par utilisation de 1,2-bis(4-pyridyl)éthane |
Families Citing this family (54)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4100262A (en) * | 1977-08-15 | 1978-07-11 | Mobil Oil Corporation | Synthesis of zeolite ZSM-5 |
US4205052A (en) * | 1979-02-01 | 1980-05-27 | Mobil Oil Corporation | Manufacture of synthetic mordenite |
US4205053A (en) * | 1979-02-01 | 1980-05-27 | Mobil Oil Corporation | Manufacture of nitrogenous zeolites |
US4215015A (en) * | 1979-02-02 | 1980-07-29 | Uop Inc. | High octane FCC catalyst |
US4518703A (en) * | 1979-02-16 | 1985-05-21 | Union Oil Company Of California | Crystalline silica catalysts |
US4303791A (en) * | 1979-09-10 | 1981-12-01 | Mobil Oil Corporation | 1-Methyl or propyl organic nitrogen compounds and method of preparation |
US4285922A (en) * | 1979-09-10 | 1981-08-25 | Mobil Oil Corporation | Method of preparing crystalline zeolite |
US4239615A (en) * | 1979-12-19 | 1980-12-16 | Uop Inc. | High octane FCC process |
AU542052B2 (en) * | 1980-06-12 | 1985-02-07 | Imperial Chemical Industries Ltd. | Zeoliteeuz and its use as a catalyst |
DE3165380D1 (en) * | 1980-06-12 | 1984-09-13 | Ici Plc | Zeolite eu-1 |
DE3170192D1 (en) * | 1980-12-11 | 1985-05-30 | Ici Plc | Zeolites |
US4790927A (en) * | 1981-05-26 | 1988-12-13 | Union Oil Company Of California | Process for simultaneous hydrotreating and hydrodewaxing of hydrocarbons |
US4877762A (en) * | 1981-05-26 | 1989-10-31 | Union Oil Company Of California | Catalyst for simultaneous hydrotreating and hydrodewaxing of hydrocarbons |
IT1139860B (it) * | 1981-11-27 | 1986-09-24 | Montedison Spa | Processo per la sintesi di zeoliti a struttura nordenitica ad elevata attivita' catalitica |
US4391785A (en) * | 1981-12-21 | 1983-07-05 | Mobil Oil Corporation | Preparation of ZSM-12 type zeolites |
US4544538A (en) * | 1982-07-09 | 1985-10-01 | Chevron Research Company | Zeolite SSZ-13 and its method of preparation |
US4508837A (en) * | 1982-09-28 | 1985-04-02 | Chevron Research Company | Zeolite SSZ-16 |
US4481177A (en) * | 1982-12-09 | 1984-11-06 | Mobil Oil Corporation | Synthesis of zeolite ZSM-22 with a heterocyclic organic compound |
US4557919A (en) * | 1983-04-12 | 1985-12-10 | Teijin Petrochemical Industries Ltd. | Production of crystalline zeolites |
US4559213A (en) * | 1983-04-29 | 1985-12-17 | Mobil Oil Corporation | Synthesis of ZSM-12 zeolite |
US4482531A (en) * | 1983-04-29 | 1984-11-13 | Mobil Oil Corporation | Synthesis of ZSM-12 zeolite |
US4483835A (en) * | 1983-11-14 | 1984-11-20 | Chevron Research Company | Process for preparing molecular sieves using imidazole template |
US4585639A (en) * | 1984-04-16 | 1986-04-29 | Mobil Oil Corporation | Preparation of crystalline silicate ZSM-12 |
US4554145A (en) * | 1984-04-16 | 1985-11-19 | Mobil Oil Corporation | Preparation of crystalline silicate zeolite Beta |
EP0159846B1 (fr) * | 1984-04-16 | 1989-07-19 | Mobil Oil Corporation | Préparation de zéolite bêta |
US5171556A (en) * | 1989-09-22 | 1992-12-15 | Institut Francais Du Petrole | Beta type zeolite and its preparation process |
FR2652347B1 (fr) * | 1989-09-22 | 1992-01-10 | Inst Francais Du Petrole | Zeolithe de type beta et son procede de preparation invention de philippe caullet, jean-louis guth, anne-catherine faust, francis raatz, jean-francois joly et jean-marie deves. |
FR2670772B1 (fr) * | 1990-12-21 | 1993-04-09 | Inst Francais Du Petrole | Zeolithe de type mtw et son procede de preparation. |
DE4126461C2 (de) * | 1991-08-09 | 1994-09-29 | Rainer Hoppe | Farbstoffbeladenes anorganisches Molekularsieb, Verfahren zu seiner Herstellung und seine Verwendung |
US5283047A (en) * | 1992-09-25 | 1994-02-01 | Exxon Research And Engineering Company | Synthesis of ECR-26 (C-2646) |
EP0746529B1 (fr) * | 1994-02-18 | 2000-01-05 | Chevron Chemical Company LLC | Zeolite ssz-42 |
DE19818167A1 (de) | 1998-04-23 | 1999-10-28 | Alcatel Sa | Flexibles Leitungsrohr |
US6114484A (en) | 1998-11-16 | 2000-09-05 | Nalco Chemical Company | Polymers for chemical treatment and precipitation of soluble metal cyanide and oxoanion compounds from waste water |
US6423295B1 (en) | 2000-12-19 | 2002-07-23 | Praxair Technology, Inc. | Synthesis of aluminum rich AFI zeolite |
US6632767B2 (en) | 2000-12-19 | 2003-10-14 | Praxair Technology, Inc. | Stabilization of molecular sieves by salt addition |
US6451169B1 (en) | 2000-12-20 | 2002-09-17 | Nalco Chemical Company | Structurally rigid polymer coagulants as retention and drainage aids in papermaking |
AU2002356941A1 (en) * | 2001-11-15 | 2003-06-10 | Pq Holding, Inc. | Method for controlling synthesis conditions during molecular sieve synthesis using combinations of quaternary ammonium hydroxides and halides |
US7211239B2 (en) * | 2005-04-22 | 2007-05-01 | Basf Aktiengesellschaft | Process for preparing a nanosized zeolitic material |
EP2376888B1 (fr) * | 2009-01-09 | 2015-08-12 | Troxler Electronic Laboratories, Inc. | Appareils à compacteur giratoire et procedes associes |
US9522896B2 (en) | 2014-12-04 | 2016-12-20 | Uop Llc | Organo-1-oxa-4-azonium cyclohexane compounds |
US9815706B2 (en) | 2014-12-04 | 2017-11-14 | Uop Llc | Zeolites using an organo-1-oxa-4-azoniumcyclohexane compound |
US9751772B2 (en) | 2014-12-04 | 2017-09-05 | Uop Llc | Aluminophosphate molecular sieves using an organo-1-oxa-4-azoniumcyclohexane compound |
US9901911B2 (en) | 2014-12-18 | 2018-02-27 | Uop Llc | Coherently grown composite aluminophosphate and silicoaluminophosphate molecular sieves |
US9643853B2 (en) | 2015-01-26 | 2017-05-09 | Chevron U.S.A. Inc | Synthesis of GME framework type zeolites |
US9364782B1 (en) | 2015-01-26 | 2016-06-14 | Chevron U.S.A. Inc. | Separation of gases using GME framework type zeolites |
US9901909B2 (en) | 2015-02-24 | 2018-02-27 | California Institute Of Technology | Processes for preparing zincoaluminosilicates with AEI, CHA, and GME topologies and compositions derived therefrom |
US10828625B2 (en) | 2015-06-01 | 2020-11-10 | California Institute Of Technology | Crystalline germanosilicate materials of new CIT-13 topology and methods of preparing the same |
WO2016196533A1 (fr) | 2015-06-01 | 2016-12-08 | Schmidt Joel E | Matériaux à base de germanosilicate cristallin d'une nouvelle topologie cit-13 et leurs procédés de préparation |
US9642360B2 (en) * | 2015-06-25 | 2017-05-09 | International Business Machines Corporation | Antimicrobial polymers formed by bulk polyaddition |
US9708193B2 (en) * | 2015-08-20 | 2017-07-18 | Chevron U.S.A. Inc. | Synthesis of aluminosilicate LEV framework type zeolites |
EP3950591A1 (fr) | 2016-03-04 | 2022-02-09 | California Institute of Technology | Nouvelles compositions de germanosilicate et leurs procédés de préparation |
GB2551622A (en) | 2016-04-22 | 2017-12-27 | Johnson Matthey Plc | STA-19, A new member of the GME family of molecular sieve zeotypes, methods of preparation and use |
JP6975728B2 (ja) * | 2016-06-08 | 2021-12-01 | ビーエーエスエフ コーポレーション | NOxの選択的接触還元における銅で促進されたグメリン沸石およびその使用 |
WO2023044211A2 (fr) * | 2021-09-16 | 2023-03-23 | ExxonMobil Technology and Engineering Company | Synthèses de zéolite utilisant des agents directeurs de structure de bis-pyridinium |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
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FR1351708A (fr) * | 1962-02-21 | 1964-02-07 | Socony Mobil Oil Co | Nouvelle zéolite synthétique et procédé pour la préparer |
US3692470A (en) * | 1969-10-09 | 1972-09-19 | Mobil Oil Corp | Crystalline zeolite zsm-10 |
DE2511975A1 (de) * | 1974-03-20 | 1975-09-25 | Grace W R & Co | Verfahren zur herstellung von zeolighen mit offener gitterstruktur |
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Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3054657A (en) * | 1958-03-31 | 1962-09-18 | Union Carbide Corp | Crystalline zeolite s |
US3306922A (en) * | 1961-03-22 | 1967-02-28 | Union Carbide Corp | Molecular sieve adsorbents |
-
1976
- 1976-06-18 US US05/697,646 patent/US4061717A/en not_active Expired - Lifetime
-
1977
- 1977-02-09 NL NL7701382A patent/NL7701382A/xx not_active Application Discontinuation
- 1977-02-09 DE DE19772705436 patent/DE2705436A1/de active Granted
- 1977-02-11 GB GB5721/77A patent/GB1572135A/en not_active Expired
- 1977-02-24 FR FR7705392A patent/FR2381715A1/fr active Granted
- 1977-02-25 BE BE175295A patent/BE851865A/fr not_active IP Right Cessation
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR1351708A (fr) * | 1962-02-21 | 1964-02-07 | Socony Mobil Oil Co | Nouvelle zéolite synthétique et procédé pour la préparer |
US3692470A (en) * | 1969-10-09 | 1972-09-19 | Mobil Oil Corp | Crystalline zeolite zsm-10 |
DE2511975A1 (de) * | 1974-03-20 | 1975-09-25 | Grace W R & Co | Verfahren zur herstellung von zeolighen mit offener gitterstruktur |
Non-Patent Citations (1)
Title |
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NV6003/74 * |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0055046A1 (fr) * | 1980-12-19 | 1982-06-30 | Imperial Chemical Industries Plc | Zéolites |
EP0532993A1 (fr) * | 1991-09-20 | 1993-03-24 | BASF Aktiengesellschaft | Procédé de préparation d'alumino- et de silicoaluminophosphates de structure AEL par utilisation de 1,2-bis(4-pyridyl)éthane |
US5324493A (en) * | 1991-09-20 | 1994-06-28 | Basf Aktiengesellschaft | Preparation of aluminophosphates and silicoaluminophosphates having the AEL structure using 1,2-bis-(4-pyridyl)-ethane |
Also Published As
Publication number | Publication date |
---|---|
NL7701382A (en) | 1978-08-11 |
BE851865A (fr) | 1977-08-25 |
US4061717A (en) | 1977-12-06 |
DE2705436A1 (de) | 1978-08-17 |
GB1572135A (en) | 1980-07-23 |
FR2381715B1 (fr) | 1981-10-23 |
DE2705436C2 (fr) | 1987-10-01 |
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