WO1991018851A3 - Procede de conversion catalytique d'olefines - Google Patents

Procede de conversion catalytique d'olefines Download PDF

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Publication number
WO1991018851A3
WO1991018851A3 PCT/EP1991/001053 EP9101053W WO9118851A3 WO 1991018851 A3 WO1991018851 A3 WO 1991018851A3 EP 9101053 W EP9101053 W EP 9101053W WO 9118851 A3 WO9118851 A3 WO 9118851A3
Authority
WO
WIPO (PCT)
Prior art keywords
olefins
catalytic conversion
conversion
dimerization
butene
Prior art date
Application number
PCT/EP1991/001053
Other languages
English (en)
Other versions
WO1991018851A2 (fr
Inventor
Mechilium Johannes Ger Janssen
Wilfried Jozef Mortier
Oorschot Cornelius Wilhelm Van
Michiel Makkee
Original Assignee
Exxon Chemical Patents Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=10677235&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=WO1991018851(A3) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Exxon Chemical Patents Inc filed Critical Exxon Chemical Patents Inc
Priority to EP91911457A priority Critical patent/EP0532646B1/fr
Priority to DE69116364T priority patent/DE69116364T2/de
Publication of WO1991018851A2 publication Critical patent/WO1991018851A2/fr
Publication of WO1991018851A3 publication Critical patent/WO1991018851A3/fr

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C6/00—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions
    • C07C6/02—Metathesis reactions at an unsaturated carbon-to-carbon bond
    • C07C6/04—Metathesis reactions at an unsaturated carbon-to-carbon bond at a carbon-to-carbon double bond
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
    • B01J29/084—Y-type faujasite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/7007—Zeolite Beta
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/82—Phosphates
    • B01J29/84—Aluminophosphates containing other elements, e.g. metals, boron
    • B01J29/85—Silicoaluminophosphates [SAPO compounds]
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
    • C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
    • C07C2/06—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
    • C07C2/08—Catalytic processes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
    • C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
    • C07C2/06—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
    • C07C2/08—Catalytic processes
    • C07C2/12—Catalytic processes with crystalline alumino-silicates or with catalysts comprising molecular sieves
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/22—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by isomerisation
    • C07C5/27—Rearrangement of carbon atoms in the hydrocarbon skeleton
    • C07C5/2767—Changing the number of side-chains
    • C07C5/277—Catalytic processes
    • C07C5/2775—Catalytic processes with crystalline alumino-silicates, e.g. molecular sieves
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups C07C2529/08 - C07C2529/65
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/82—Phosphates
    • C07C2529/84—Aluminophosphates containing other elements, e.g. metals, boron
    • C07C2529/85—Silicoaluminophosphates (SAPO compounds)

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)

Abstract

La conversion de n-oléfines, particulièrement de n-butène, par isomérisation schématique, ou par dimérisation éventuellement avec craquage, peut s'effectuer sélectivement en utilisant comme catalyseur un tamis moléculaire, tel qu'une zéolite ou un phosphate de silice/alumine, qui a subi un échange ionique avec un cation pour produire un site acide de Lewis.
PCT/EP1991/001053 1990-06-07 1991-06-06 Procede de conversion catalytique d'olefines WO1991018851A2 (fr)

Priority Applications (2)

Application Number Priority Date Filing Date Title
EP91911457A EP0532646B1 (fr) 1990-06-07 1991-06-06 Procede de conversion catalytique d'olefines
DE69116364T DE69116364T2 (de) 1990-06-07 1991-06-06 Verfahren zur katalytischen umsetzung von olefinen

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GB909012725A GB9012725D0 (en) 1990-06-07 1990-06-07 Process for catalytic conversion of olefins
GB9012725.9 1990-06-07

Publications (2)

Publication Number Publication Date
WO1991018851A2 WO1991018851A2 (fr) 1991-12-12
WO1991018851A3 true WO1991018851A3 (fr) 1992-01-09

Family

ID=10677235

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP1991/001053 WO1991018851A2 (fr) 1990-06-07 1991-06-06 Procede de conversion catalytique d'olefines

Country Status (8)

Country Link
EP (1) EP0532646B1 (fr)
JP (1) JP3152242B2 (fr)
AT (1) ATE132843T1 (fr)
CA (1) CA2084672A1 (fr)
DE (1) DE69116364T2 (fr)
ES (1) ES2082211T3 (fr)
GB (1) GB9012725D0 (fr)
WO (1) WO1991018851A2 (fr)

Families Citing this family (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6323384B1 (en) 1991-06-05 2001-11-27 Equistar Chemicals, Lp Process for isomerizing linear olefins to isoolefins
CN1032059C (zh) * 1991-06-05 1996-06-19 莱昂德尔石油化学公司 将直链烯烃异构成异烯烃的方法
US5302567A (en) * 1991-11-04 1994-04-12 W. R. Grace & Co.-Conn. Zeolite octane additive
US5157194A (en) * 1991-12-20 1992-10-20 Mobil Oil Corporation Highly selective n-olefin isomerization process using microcrystalline ZSM-22
US5321194A (en) * 1992-05-11 1994-06-14 Mobil Oil Corporation N-olefin skeletal isomerization process using dicarboxylic acid treated zeolites
CN1036320C (zh) * 1993-11-23 1997-11-05 中国石油化工总公司石油化工科学研究院 一种制备异丁烯和异戊烯的裂化催化剂
US5763726A (en) * 1996-07-03 1998-06-09 Chevron U.S.A. Inc. C4 /C5 olefin skeletal isomerization process
EP0968160B1 (fr) * 1996-10-16 2001-08-16 Mobil Oil Corporation Procede d'isomerisation de type a squelette carbone de n-olefines
US6429348B1 (en) 1998-05-05 2002-08-06 Exxonmobil Chemical Patents, Inc. Method for selectively producing propylene by catalytically cracking an olefinic hydrocarbon feedstock
US6339181B1 (en) 1999-11-09 2002-01-15 Exxonmobil Chemical Patents, Inc. Multiple feed process for the production of propylene
GB9930402D0 (en) * 1999-12-23 2000-02-16 Exxon Chemical Patents Inc Selective removal of isobutene from C4 olefinic feedstocks
GB0010433D0 (en) * 2000-04-28 2000-06-14 Exxon Chemical Patents Inc Alkene oligomerization process
ES2204409T5 (es) 2000-06-26 2008-04-16 Saudi Basic Industries Corporation Dimerizacion de isobuteno.
US6914166B2 (en) 2000-12-20 2005-07-05 Exxonmobil Chemical Patents Inc. Process for the selective dimerization of isobutene
KR101470623B1 (ko) * 2006-11-17 2014-12-12 에스케이이노베이션 주식회사 자일렌 이성화 촉매 및 그 제조방법
EP2098498A1 (fr) 2008-03-04 2009-09-09 ExxonMobil Chemical Patents Inc. Oligomérisation sélective d'isobutylène
CN102177110A (zh) 2008-10-10 2011-09-07 埃克森美孚化学专利公司 用于生产仲丁基苯的方法
CN102481555B (zh) 2009-06-12 2015-10-07 阿尔比马尔欧洲有限公司 Sapo分子筛催化剂及其制备和用途
CN114570420B (zh) * 2022-03-30 2023-09-08 江南大学 一种用于催化长链烯烃裂解制备丙烯的催化体系及其应用

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2217252A (en) * 1937-08-14 1940-10-08 Shell Dev Process for isomerization of olefin hydrocarbons
EP0034444A2 (fr) * 1980-02-14 1981-08-26 Mobil Oil Corporation Augmentation de l'activité catalytique d'une zéolite
EP0111808A2 (fr) * 1982-12-16 1984-06-27 Bayer Ag Catalyseur, procédé pour le préparer et un procédé d'isomérisation en présence dudit catalyseur

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2217252A (en) * 1937-08-14 1940-10-08 Shell Dev Process for isomerization of olefin hydrocarbons
EP0034444A2 (fr) * 1980-02-14 1981-08-26 Mobil Oil Corporation Augmentation de l'activité catalytique d'une zéolite
EP0111808A2 (fr) * 1982-12-16 1984-06-27 Bayer Ag Catalyseur, procédé pour le préparer et un procédé d'isomérisation en présence dudit catalyseur

Also Published As

Publication number Publication date
CA2084672A1 (fr) 1991-12-08
ES2082211T3 (es) 1996-03-16
DE69116364T2 (de) 1996-07-11
JPH05507691A (ja) 1993-11-04
EP0532646A1 (fr) 1993-03-24
EP0532646B1 (fr) 1996-01-10
ATE132843T1 (de) 1996-01-15
DE69116364D1 (de) 1996-02-22
JP3152242B2 (ja) 2001-04-03
WO1991018851A2 (fr) 1991-12-12
GB9012725D0 (en) 1990-08-01

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