FR2378790A1 - Procede de preparation en continu de phosphines organiques - Google Patents

Procede de preparation en continu de phosphines organiques

Info

Publication number
FR2378790A1
FR2378790A1 FR7802415A FR7802415A FR2378790A1 FR 2378790 A1 FR2378790 A1 FR 2378790A1 FR 7802415 A FR7802415 A FR 7802415A FR 7802415 A FR7802415 A FR 7802415A FR 2378790 A1 FR2378790 A1 FR 2378790A1
Authority
FR
France
Prior art keywords
reactor
catalyst
zone
organic phosphines
phosphines
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
FR7802415A
Other languages
English (en)
Other versions
FR2378790B1 (fr
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hoechst AG
Original Assignee
Hoechst AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hoechst AG filed Critical Hoechst AG
Publication of FR2378790A1 publication Critical patent/FR2378790A1/fr
Application granted granted Critical
Publication of FR2378790B1 publication Critical patent/FR2378790B1/fr
Granted legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/28—Phosphorus compounds with one or more P—C bonds
    • C07F9/50—Organo-phosphines
    • C07F9/505—Preparation; Separation; Purification; Stabilisation
    • C07F9/5059—Preparation; Separation; Purification; Stabilisation by addition of phosphorus compounds to alkenes or alkynes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
    • C07F9/6564—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms
    • C07F9/6568—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms having phosphorus atoms as the only ring hetero atoms
    • C07F9/65683—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms having phosphorus atoms as the only ring hetero atoms the ring phosphorus atom being part of a phosphine

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Biochemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Molecular Biology (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

L'invention concerne un procédé de préparation de phosphines organiques par réaction d'un alkylène, cycloalkylène ou aralkylène avec l'hydrogène phosphoré en présence d'une solution d'un catalyseur radicalaire dans un solvant inerte. Dans un réacteur résistant à la pression, muni intérieurement de dispositifs mélangeurs, exempt d'oxygène et subdivisé de manière à comporter une zone de refroidissement supérieure et une zone de reaction inférieure, on introduit en continu d'en haut conjointement mais séparément : a une solution de l'alkylène, du cycloalkylène, de l'aralkylène et du catalyseur dans un solvant inerte et, b. un excès d'hydrogène phosphoré. On mélange les réactifs a et b dans la zone de refroidissement à environ 0-35 degrés C. et sous une pression de PH3 d'environ 80 à 300 bars, on fait réagir le mélange qui s'écoule vers le bas dans la zone de réaction a environ 90-190 degrés C, la durée de séjour des réactifs dans le réacteur étant 13-15 fois plus longue que la période du catalyseur, on évacue le mélange de réaction par le fond du réacteur et on sépare les phosphines organiques par distillation. Les phosphines sont des produits de départ de la préparation de catalyseurs d'hydroformylation.
FR7802415A 1977-01-29 1978-01-27 Procede de preparation en continu de phosphines organiques Granted FR2378790A1 (fr)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE2703802A DE2703802C3 (de) 1977-01-29 1977-01-29 Verfahren zur kontinuierlichen Herstellung von organischen Phosphinen

Publications (2)

Publication Number Publication Date
FR2378790A1 true FR2378790A1 (fr) 1978-08-25
FR2378790B1 FR2378790B1 (fr) 1984-03-09

Family

ID=5999929

Family Applications (1)

Application Number Title Priority Date Filing Date
FR7802415A Granted FR2378790A1 (fr) 1977-01-29 1978-01-27 Procede de preparation en continu de phosphines organiques

Country Status (12)

Country Link
US (1) US4163760A (fr)
JP (1) JPS6035353B2 (fr)
BE (1) BE863423A (fr)
CA (1) CA1071653A (fr)
CH (1) CH632518A5 (fr)
DD (1) DD134768A5 (fr)
DE (1) DE2703802C3 (fr)
DK (1) DK145743C (fr)
FR (1) FR2378790A1 (fr)
GB (1) GB1561874A (fr)
IT (1) IT1104153B (fr)
NL (1) NL177407C (fr)

Families Citing this family (21)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2939588A1 (de) * 1979-09-29 1981-04-09 Hoechst Ag, 6000 Frankfurt Verfahren zur herstellung eines isomerengemisches sekundaerer phosphine sowie die verwendung dieses gemisches
JPS6074145A (ja) * 1983-09-28 1985-04-26 Matsushita Electric Ind Co Ltd カセットロ−ディング装置
US4503178A (en) * 1984-04-26 1985-03-05 Fmc Corporation Cyclic phosphine oxides and their use as flame retardants in styrene modified polyphenylene ether resins
JPH0356912Y2 (fr) * 1984-12-11 1991-12-24
US4623687A (en) 1985-03-01 1986-11-18 Fmc Corporation Bicyclic phosphine oxides and their use as flame retardants in styrene modified polyphenylene ether resins
US4613699A (en) * 1985-03-01 1986-09-23 Fmc Corporation Phosphine oxides and their use as flame retardants in styrene modified polyphenylene ether resins
JPS6295763A (ja) * 1985-10-19 1987-05-02 Alps Electric Co Ltd デイスク駆動装置
JPH0445154Y2 (fr) * 1986-05-26 1992-10-23
DE3629189A1 (de) * 1986-08-28 1988-03-17 Hoechst Ag Verfahren zur herstellung von tertiaeren alkylphosphanen
JPH0445161Y2 (fr) * 1986-12-23 1992-10-23
JPH0441489Y2 (fr) * 1987-08-03 1992-09-29
US5260485A (en) * 1991-07-11 1993-11-09 American Cyanamid Company Process of making alkyl phosphine compounds by reacting an olefin and a phosphine in the vapor phase over a mineral acid catalyst
JP2000109491A (ja) * 1998-10-02 2000-04-18 Kankyo Kagaku Center:Kk 第二級ホスフィンの製造法
CA2291503A1 (fr) * 1999-12-03 2001-06-03 Allan James Robertson Synthese de phospines organiques
BR0113209B1 (pt) * 2000-08-14 2012-05-15 processo para produzir produtos oxigenados de uma carga de alimentação olefìnica, e, catalisador de hidroformilação.
US6794553B2 (en) 2001-11-09 2004-09-21 Shell Oil Company Process for the telomerization of a conjugated diene, catalyst and bidentate ligand useful therein
US7084089B2 (en) 2002-07-31 2006-08-01 Shell Oil Company Process for the carbonylation of ethylenically unsaturated compounds, bidentate diphosphine composition used in this process and a process for preparation of this bidentate diphosphine composition
US6806391B2 (en) 2002-07-31 2004-10-19 Shell Oil Company Process for the carbonylation of ethylenically unsaturated compounds and bidentate diphosphine composition used in this process
US7013601B2 (en) * 2004-07-22 2006-03-21 Coastal Planters, Llc Plant container with hanger
EP2851370B1 (fr) 2013-09-19 2016-03-09 Magpie Polymers Procédé de préparation de tris(hydroxyméthyl) phosphine
EP3539924A1 (fr) 2018-03-14 2019-09-18 ETH Zurich Nouvelles phosphines vinyliques et photo-initiateurs obtenus à partir de celles-ci

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR1018432A (fr) * 1949-04-30 1953-01-07 Bataafsche Petroleum Procédé de préparation des phosphines organiques
US3400163A (en) * 1965-06-30 1968-09-03 Shell Oil Co Bicyclic heterocyclic sec- and tert-phosphines
FR2002763A6 (fr) * 1968-02-28 1969-10-31 Shell Int Research

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2803597A (en) * 1949-04-30 1957-08-20 Shell Dev Process for producing organic phosphines
US2957931A (en) * 1949-07-28 1960-10-25 Socony Mobil Oil Co Inc Synthesis of compounds having a carbonphosphorus linkage
US2584112A (en) * 1950-08-30 1952-02-05 Standard Oil Co Organic phosphines
US2822376A (en) * 1957-02-27 1958-02-04 American Cyanamid Co Reaction of phosphine with alpha, beta-unsatu-rated compounds
US3401204A (en) * 1965-11-26 1968-09-10 Shell Oil Co Hydrocarbylene-bis (monophosphobicyclononanes) and the preparation thereof
US3435076A (en) * 1966-07-19 1969-03-25 Shell Oil Co Tricyclic phosphines and the preparation thereof

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR1018432A (fr) * 1949-04-30 1953-01-07 Bataafsche Petroleum Procédé de préparation des phosphines organiques
US3400163A (en) * 1965-06-30 1968-09-03 Shell Oil Co Bicyclic heterocyclic sec- and tert-phosphines
FR2002763A6 (fr) * 1968-02-28 1969-10-31 Shell Int Research

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
EXBK/61 *

Also Published As

Publication number Publication date
CA1071653A (fr) 1980-02-12
BE863423A (fr) 1978-07-27
IT1104153B (it) 1985-10-21
DK145743B (da) 1983-02-14
DK145743C (da) 1983-08-01
US4163760A (en) 1979-08-07
DE2703802A1 (de) 1978-08-03
DE2703802B2 (de) 1978-11-16
FR2378790B1 (fr) 1984-03-09
JPS6035353B2 (ja) 1985-08-14
NL177407C (nl) 1985-09-16
NL177407B (nl) 1985-04-16
IT7847816A0 (it) 1978-01-27
NL7800955A (nl) 1978-08-01
DE2703802C3 (de) 1979-07-12
DK41078A (da) 1978-07-30
JPS5395920A (en) 1978-08-22
DD134768A5 (de) 1979-03-21
CH632518A5 (de) 1982-10-15
GB1561874A (en) 1980-03-05

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