FR2358924A1 - Catalyseur pour reformage a la vapeur d'eau et son procede de preparation - Google Patents

Catalyseur pour reformage a la vapeur d'eau et son procede de preparation

Info

Publication number
FR2358924A1
FR2358924A1 FR7722288A FR7722288A FR2358924A1 FR 2358924 A1 FR2358924 A1 FR 2358924A1 FR 7722288 A FR7722288 A FR 7722288A FR 7722288 A FR7722288 A FR 7722288A FR 2358924 A1 FR2358924 A1 FR 2358924A1
Authority
FR
France
Prior art keywords
degrees
calcium
catalyst
nickel
oxide
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
FR7722288A
Other languages
English (en)
Other versions
FR2358924B1 (fr
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Fujimi Kenmazai Kogyo Co Ltd
Original Assignee
Fujimi Kenmazai Kogyo Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Fujimi Kenmazai Kogyo Co Ltd filed Critical Fujimi Kenmazai Kogyo Co Ltd
Publication of FR2358924A1 publication Critical patent/FR2358924A1/fr
Application granted granted Critical
Publication of FR2358924B1 publication Critical patent/FR2358924B1/fr
Granted legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/04—Mixing
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/78—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with alkali- or alkaline earth metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
    • C01B3/38—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
    • C01B3/40—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts characterised by the catalyst
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10—Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041—Composition of the catalyst
    • C01B2203/1047—Group VIII metal catalysts
    • C01B2203/1052—Nickel or cobalt catalysts
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Inorganic Chemistry (AREA)
  • Catalysts (AREA)
  • Hydrogen, Water And Hydrids (AREA)

Abstract

Catalyseur contenant de 10 à 30 % en poids de nickel sous forme d'oxyde de nickel, de 20 à 60 % en poids de calcium sous forme d'oxyde de calcium, 10 à 70 % en poids d'aluminium sous forme d'oxyde d'aluminium et contenant moins de 1 % en poids de bioxyde de silicium. Le catalyseur est préparé en utilisant, comme matière de départ pour le composant nickel, de fines particules d'oxyde de nickel obtenues en chauffant un composé de nickel qui est décomposé en oxyde de nickel par chauffage à une température comprise entre 400 degrés et 800 degrés C en présence d'oxygène; comme matière de départ pour le composant calcium, l'ozyde de calcium lui-même ou un composé de calcium qui est décomposé en oxyde de calcium par chauffage, et comme matière de départ sur le composant aluminium, du ciment à l'alumine de grande pureté. Le catalyseur est préparé en mélangeant et malaxant les matières de départ avec de l'eau, en les moulant puis en maintenant la composition du catalyseur en atmosphère de forte humidité, à une température comprise entre 5 degrés et 35 degrés C, pendant plus d'un jour pour hydrater et durcir le ciment, puis en la frittant à une température comprise entre 550 degrés et 1200 degrés C.
FR7722288A 1976-07-20 1977-07-20 Catalyseur pour reformage a la vapeur d'eau et son procede de preparation Granted FR2358924A1 (fr)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP8627276A JPS5311893A (en) 1976-07-20 1976-07-20 Catalysts

Publications (2)

Publication Number Publication Date
FR2358924A1 true FR2358924A1 (fr) 1978-02-17
FR2358924B1 FR2358924B1 (fr) 1983-12-23

Family

ID=13882174

Family Applications (1)

Application Number Title Priority Date Filing Date
FR7722288A Granted FR2358924A1 (fr) 1976-07-20 1977-07-20 Catalyseur pour reformage a la vapeur d'eau et son procede de preparation

Country Status (10)

Country Link
US (1) US4101449A (fr)
JP (1) JPS5311893A (fr)
AR (1) AR225591A1 (fr)
AU (1) AU505781B2 (fr)
CA (1) CA1090319A (fr)
DD (1) DD132052A5 (fr)
DE (1) DE2722333A1 (fr)
FR (1) FR2358924A1 (fr)
GB (1) GB1571865A (fr)
NL (1) NL7706186A (fr)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0009068A1 (fr) * 1978-04-13 1980-04-02 Süd-Chemie Ag Catalyseurs à lit fluidisé pour préparer synthétiquement du gaz naturel par méthanisation du monoxyde de carbone
EP0538912A1 (fr) * 1990-04-17 1993-04-28 Nkk Corporation Utilisation d'un catalyseur pour la production de phénol
US5268512A (en) * 1990-04-17 1993-12-07 Nkk Corporation Catalyst and process for producing phenol

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2439040A1 (fr) * 1978-10-16 1980-05-16 Matsushita Electric Ind Co Ltd Surfaces revetues comprenant un liant renfermant un ou plusieurs oxydes, capables de decomposer des huiles
JPS55154303A (en) * 1979-05-18 1980-12-01 Toyo Eng Corp Method and apparatus for steam-reforming hydrocarbon
US4331451A (en) * 1980-02-04 1982-05-25 Mitsui Toatsu Chemicals, Inc. Catalytic gasification
US4415484A (en) * 1982-04-26 1983-11-15 United Technologies Corporation Autothermal reforming catalyst
US4451578A (en) * 1982-04-26 1984-05-29 United Technologies Corporation Iron oxide catalyst for steam reforming
AU4695985A (en) * 1984-09-04 1986-03-13 Mitsubishi Jukogyo Kabushiki Kaisha Process for reforming methanol
US5149893A (en) * 1989-05-09 1992-09-22 Imperial Chemical Industries Plc Catalytic hydrogenation process
GB8910623D0 (en) * 1989-05-09 1989-06-21 Ici Plc Catalyst
US5756421A (en) * 1992-09-10 1998-05-26 Council Of Scientific & Industrial Research Composite catalysts containing transitional and alkaline earth metal oxides useful for oxidative conversion of methane (or natural gas) to carbon monoxide and hydrogen (or synthesis gas)
JP3389412B2 (ja) * 1996-05-16 2003-03-24 東洋エンジニアリング株式会社 改良された低級炭化水素用水蒸気改質触媒
GB9619724D0 (en) * 1996-09-20 1996-11-06 Ici Plc Catalyst
US6261991B1 (en) * 1999-03-25 2001-07-17 Toyo Engineering Corporation Steam-reforming catalyst for hydrocarbons
US7335346B2 (en) * 1999-08-17 2008-02-26 Battelle Memorial Institute Catalyst and method of steam reforming
US7378369B2 (en) * 2002-07-26 2008-05-27 Sud-Chemie Inc. Nickel supported on titanium stabilized promoted calcium aluminate carrier
US20040077496A1 (en) * 2002-07-26 2004-04-22 Shizhong Zhao Catalyst
US7449167B2 (en) * 2004-07-08 2008-11-11 Air Products And Chemicals, Inc. Catalyst and process for improving the adiabatic steam-reforming of natural gas
US8114176B2 (en) * 2005-10-12 2012-02-14 Great Point Energy, Inc. Catalytic steam gasification of petroleum coke to methane
US7922782B2 (en) * 2006-06-01 2011-04-12 Greatpoint Energy, Inc. Catalytic steam gasification process with recovery and recycle of alkali metal compounds
JP5371181B2 (ja) * 2006-06-26 2013-12-18 独立行政法人国立環境研究所 水素含有ガス製造方法および水素含有ガス製造装置
AU2008282518B2 (en) * 2007-08-02 2012-03-01 Greatpoint Energy, Inc. Catalyst-loaded coal compositions, methods of making and use
WO2009048723A2 (fr) * 2007-10-09 2009-04-16 Greatpoint Energy, Inc. Compositions pour la gazéification catalytique d'un coke de pétrole
JP4436424B2 (ja) * 2007-12-27 2010-03-24 新日本製鐵株式会社 タール含有ガスの改質方法
US20090165383A1 (en) * 2007-12-28 2009-07-02 Greatpoint Energy, Inc. Catalytic Gasification Process with Recovery of Alkali Metal from Char
WO2009086407A2 (fr) * 2007-12-28 2009-07-09 Greatpoint Energy, Inc. Gazéificateur de boues à génération de vapeur pour la gazéification catalytique d'une charge carbonée
WO2009086383A2 (fr) * 2007-12-28 2009-07-09 Greatpoint Energy, Inc. Procédé de gazéification catalytique avec récupération de métal alcalin à partir du résidu carboné
WO2009086366A1 (fr) * 2007-12-28 2009-07-09 Greatpoint Energy, Inc. Procédés pour fabriquer du gaz de synthèse et produits dérivés de gaz de synthèse
WO2009086363A1 (fr) * 2007-12-28 2009-07-09 Greatpoint Energy, Inc. Compositions de charbon pour gazéification catalytique et leur procédé de préparation
WO2009086370A2 (fr) * 2007-12-28 2009-07-09 Greatpoint Energy, Inc. Procédés de fabrication de produits dérivés de gaz synthétique
WO2009086377A2 (fr) * 2007-12-28 2009-07-09 Greatpoint Energy, Inc. Procédé de gazéification catalytique avec récupération de métal alcalin à partir du résidu carboné
US20090165384A1 (en) * 2007-12-28 2009-07-02 Greatpoint Energy, Inc. Continuous Process for Converting Carbonaceous Feedstock into Gaseous Products
US20090165382A1 (en) * 2007-12-28 2009-07-02 Greatpoint Energy, Inc. Catalytic Gasification Process with Recovery of Alkali Metal from Char
US20090220406A1 (en) * 2008-02-29 2009-09-03 Greatpoint Energy, Inc. Selective Removal and Recovery of Acid Gases from Gasification Products
US8286901B2 (en) 2008-02-29 2012-10-16 Greatpoint Energy, Inc. Coal compositions for catalytic gasification
WO2009111342A2 (fr) 2008-02-29 2009-09-11 Greatpoint Energy, Inc Recyclage de fines carbonées
US8361428B2 (en) * 2008-02-29 2013-01-29 Greatpoint Energy, Inc. Reduced carbon footprint steam generation processes
US20090217582A1 (en) * 2008-02-29 2009-09-03 Greatpoint Energy, Inc. Processes for Making Adsorbents and Processes for Removing Contaminants from Fluids Using Them
WO2009111331A2 (fr) * 2008-02-29 2009-09-11 Greatpoint Energy, Inc. Procédé de génération de vapeur utilisant des charges de biomasse
WO2009111345A2 (fr) * 2008-02-29 2009-09-11 Greatpoint Energy, Inc. Compositions particulaires de gazéification catalytique
US8297542B2 (en) 2008-02-29 2012-10-30 Greatpoint Energy, Inc. Coal compositions for catalytic gasification
US8114177B2 (en) * 2008-02-29 2012-02-14 Greatpoint Energy, Inc. Co-feed of biomass as source of makeup catalysts for catalytic coal gasification
US7926750B2 (en) * 2008-02-29 2011-04-19 Greatpoint Energy, Inc. Compactor feeder
US8652222B2 (en) 2008-02-29 2014-02-18 Greatpoint Energy, Inc. Biomass compositions for catalytic gasification
WO2009124019A2 (fr) * 2008-04-01 2009-10-08 Greatpoint Energy, Inc. Procédé de déplacement acide pour l’élimination de monoxyde de carbone dans un flux de gaz
CA2718295C (fr) 2008-04-01 2013-06-18 Greatpoint Energy, Inc. Procedes pour la separation de methane a partir d'un flux de gaz
WO2009158579A2 (fr) * 2008-06-27 2009-12-30 Greatpoint Energy, Inc. Systèmes de gazéification catalytique à trois lignes
US8647402B2 (en) 2008-09-19 2014-02-11 Greatpoint Energy, Inc. Processes for gasification of a carbonaceous feedstock
CN102159687B (zh) 2008-09-19 2016-06-08 格雷特波因特能源公司 使用炭甲烷化催化剂的气化方法
AU2009293087B2 (en) 2008-09-19 2012-11-15 Sure Champion Investment Limited Processes for gasification of a carbonaceous feedstock
WO2010048493A2 (fr) 2008-10-23 2010-04-29 Greatpoint Energy, Inc. Procédés de gazéification d’une charge carbonée
EP2370549A1 (fr) 2008-12-30 2011-10-05 Greatpoint Energy, Inc. Procédés de préparation de particules carbonées chargées d'un catalyseur
KR101290453B1 (ko) 2008-12-30 2013-07-29 그레이트포인트 에너지, 인크. 촉매된 탄소질 미립자의 제조 방법
CN104119956B (zh) 2009-05-13 2016-05-11 格雷特波因特能源公司 含碳原料的加氢甲烷化方法
US8268899B2 (en) * 2009-05-13 2012-09-18 Greatpoint Energy, Inc. Processes for hydromethanation of a carbonaceous feedstock
CN102459525B (zh) 2009-05-13 2016-09-21 格雷特波因特能源公司 进行含碳原料的加氢甲烷化的方法
WO2011017630A1 (fr) * 2009-08-06 2011-02-10 Greatpoint Energy, Inc. Procédés d'hydrométhanation d'une charge d'alimentation carbonée
WO2011034890A2 (fr) * 2009-09-16 2011-03-24 Greatpoint Energy, Inc. Processus intégré à cycle combiné d'hydrométhanation
CN102597417B (zh) 2009-10-19 2014-10-01 格雷特波因特能源公司 整合的强化采油方法
AU2010310846B2 (en) 2009-10-19 2013-05-30 Greatpoint Energy, Inc. Integrated enhanced oil recovery process
AU2010339952B8 (en) 2009-12-17 2013-12-19 Greatpoint Energy, Inc. Integrated enhanced oil recovery process
WO2011106285A1 (fr) 2010-02-23 2011-09-01 Greatpoint Energy, Inc. Génération d'électricité avec pile à combustible à hydro-méthanisation intégrée
US8652696B2 (en) 2010-03-08 2014-02-18 Greatpoint Energy, Inc. Integrated hydromethanation fuel cell power generation
US8557878B2 (en) 2010-04-26 2013-10-15 Greatpoint Energy, Inc. Hydromethanation of a carbonaceous feedstock with vanadium recovery
KR101506381B1 (ko) 2010-05-28 2015-03-26 그레이트포인트 에너지, 인크. 액체 중질 탄화수소 공급원료의 가스상 생성물로의 전환
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US8648121B2 (en) 2011-02-23 2014-02-11 Greatpoint Energy, Inc. Hydromethanation of a carbonaceous feedstock with nickel recovery
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US9012524B2 (en) 2011-10-06 2015-04-21 Greatpoint Energy, Inc. Hydromethanation of a carbonaceous feedstock
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CN104704204B (zh) 2012-10-01 2017-03-08 格雷特波因特能源公司 用于从原始的低煤阶煤原料产生蒸汽的方法
US9034058B2 (en) 2012-10-01 2015-05-19 Greatpoint Energy, Inc. Agglomerated particulate low-rank coal feedstock and uses thereof
WO2014055349A1 (fr) 2012-10-01 2014-04-10 Greatpoint Energy, Inc. Charge d'alimentation de charbon de rang bas à particules agglomérées et ses utilisations
CN103157477B (zh) * 2013-03-26 2014-12-24 北京化工大学 氧化镍掺杂钛酸钠-二氧化钛复合光催化剂及其制备方法
US10464872B1 (en) 2018-07-31 2019-11-05 Greatpoint Energy, Inc. Catalytic gasification to produce methanol
US10344231B1 (en) 2018-10-26 2019-07-09 Greatpoint Energy, Inc. Hydromethanation of a carbonaceous feedstock with improved carbon utilization
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Citations (5)

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Publication number Priority date Publication date Assignee Title
FR1379478A (fr) * 1964-01-14 1964-11-20 Perfectionnements aux traltements catalytiques d'hydrocarbures et nouveaux catalyseurs destinés à ces traitements
US3391089A (en) * 1964-09-08 1968-07-02 Girdler Corp Catalyst for the stream reforming of naphtha and related hydrocarbons
FR1570343A (fr) * 1967-06-02 1969-06-06
FR2103522A1 (fr) * 1970-08-26 1972-04-14 Ici Ltd
US3947381A (en) * 1970-10-08 1976-03-30 Imperial Chemical Industries Limited Method of making a catalyst

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FR2094210A5 (fr) * 1970-05-05 1972-02-04 Pechiney Saint Gobain
US3759678A (en) * 1971-04-08 1973-09-18 Du Pont Reformer catalyst
JPS515356A (ja) * 1974-07-03 1976-01-17 Tokyo Shibaura Electric Co Tainetsuseifuenoorukeiseikeizairyo

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FR1379478A (fr) * 1964-01-14 1964-11-20 Perfectionnements aux traltements catalytiques d'hydrocarbures et nouveaux catalyseurs destinés à ces traitements
US3391089A (en) * 1964-09-08 1968-07-02 Girdler Corp Catalyst for the stream reforming of naphtha and related hydrocarbons
FR1570343A (fr) * 1967-06-02 1969-06-06
FR2103522A1 (fr) * 1970-08-26 1972-04-14 Ici Ltd
US3947381A (en) * 1970-10-08 1976-03-30 Imperial Chemical Industries Limited Method of making a catalyst

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0009068A1 (fr) * 1978-04-13 1980-04-02 Süd-Chemie Ag Catalyseurs à lit fluidisé pour préparer synthétiquement du gaz naturel par méthanisation du monoxyde de carbone
EP0538912A1 (fr) * 1990-04-17 1993-04-28 Nkk Corporation Utilisation d'un catalyseur pour la production de phénol
US5268512A (en) * 1990-04-17 1993-12-07 Nkk Corporation Catalyst and process for producing phenol

Also Published As

Publication number Publication date
NL7706186A (nl) 1978-01-24
AU505781B2 (en) 1979-11-29
FR2358924B1 (fr) 1983-12-23
JPS5311893A (en) 1978-02-02
JPS5624576B2 (fr) 1981-06-06
GB1571865A (en) 1980-07-23
AU2488177A (en) 1978-11-09
AR225591A1 (es) 1982-04-15
DD132052A5 (de) 1978-08-23
US4101449A (en) 1978-07-18
CA1090319A (fr) 1980-11-25
DE2722333A1 (de) 1978-01-26

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