FR2357555A1 - Procede de preparation de cis-hexahydrodibenzopyranones - Google Patents

Procede de preparation de cis-hexahydrodibenzopyranones

Info

Publication number
FR2357555A1
FR2357555A1 FR7720642A FR7720642A FR2357555A1 FR 2357555 A1 FR2357555 A1 FR 2357555A1 FR 7720642 A FR7720642 A FR 7720642A FR 7720642 A FR7720642 A FR 7720642A FR 2357555 A1 FR2357555 A1 FR 2357555A1
Authority
FR
France
Prior art keywords
cis
hexahydrodibenzopyranones
hydroxy
substituted
preparing cis
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
FR7720642A
Other languages
English (en)
Other versions
FR2357555B1 (fr
Inventor
Charles Wilbur Ryan
William Allen Day
Edward Ralph Lavagnino
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Eli Lilly and Co
Original Assignee
Eli Lilly and Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Eli Lilly and Co filed Critical Eli Lilly and Co
Publication of FR2357555A1 publication Critical patent/FR2357555A1/fr
Application granted granted Critical
Publication of FR2357555B1 publication Critical patent/FR2357555B1/fr
Granted legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D311/00—Heterocyclic compounds containing six-membered rings having one oxygen atom as the only hetero atom, condensed with other rings
    • C07D311/02—Heterocyclic compounds containing six-membered rings having one oxygen atom as the only hetero atom, condensed with other rings ortho- or peri-condensed with carbocyclic rings or ring systems
    • C07D311/78—Ring systems having three or more relevant rings
    • C07D311/80—Dibenzopyrans; Hydrogenated dibenzopyrans

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
  • Pyrane Compounds (AREA)
  • Saccharide Compounds (AREA)
  • Heterocyclic Carbon Compounds Containing A Hetero Ring Having Oxygen Or Sulfur (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

L'invention concerne un procédé de préparation de cis-hexa-hydrodibenzopyranones. La réaction d'un résocinol substitué en position 5 et d'un 1-alcoxy-4-(1-hydroxy-1-méthyléthyl)-1,4-cyclohexadiène en présence de tribromure de bore, de trifluorure de bore et de chlorure stannique, et éventuellement en présence d'une quantité environ équimolaire d'eau, fournit essentiellement la dl -6a, 10a - cis - 1 - hydroxy - 6,6 - diméthyl -6a, 7, 8, 10, 10a -hexahydro - 9H - dibenzo - Øb,dõpyran - 9 one substituée en position 3 de formule :
FR7720642A 1976-07-06 1977-07-05 Procede de preparation de cis-hexahydrodibenzopyranones Granted FR2357555A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US70280676A 1976-07-06 1976-07-06
US70280976A 1976-07-06 1976-07-06

Publications (2)

Publication Number Publication Date
FR2357555A1 true FR2357555A1 (fr) 1978-02-03
FR2357555B1 FR2357555B1 (fr) 1980-02-01

Family

ID=27107024

Family Applications (1)

Application Number Title Priority Date Filing Date
FR7720642A Granted FR2357555A1 (fr) 1976-07-06 1977-07-05 Procede de preparation de cis-hexahydrodibenzopyranones

Country Status (22)

Country Link
JP (1) JPS5943466B2 (fr)
AR (1) AR213440A1 (fr)
AT (1) AT351531B (fr)
AU (1) AU511627B2 (fr)
BG (1) BG28063A3 (fr)
CH (1) CH633786A5 (fr)
CS (1) CS193580B2 (fr)
DD (1) DD131469A5 (fr)
DE (1) DE2729817C2 (fr)
DK (1) DK145100C (fr)
FR (1) FR2357555A1 (fr)
GB (1) GB1582564A (fr)
GR (1) GR66415B (fr)
HU (1) HU176954B (fr)
IE (1) IE45244B1 (fr)
IL (1) IL52425A (fr)
NL (1) NL7707464A (fr)
NZ (1) NZ184528A (fr)
PL (1) PL108319B1 (fr)
SE (1) SE428018B (fr)
SU (1) SU772483A3 (fr)
YU (1) YU163477A (fr)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4171315A (en) * 1978-03-31 1979-10-16 Eli Lilly And Company Preparation of cis-hexahydrodibenzopyranones
US4395560A (en) * 1982-05-24 1983-07-26 Eli Lilly And Company Preparation of 6a,10a-trans-hexahydrodibenzopyranones
CA2638940C (fr) 2008-08-28 2009-09-15 Dalton Chemical Laboratories Inc. Synthese amelioree d'hexahydrodibenzopyranones

Also Published As

Publication number Publication date
PL108319B1 (en) 1980-04-30
GR66415B (fr) 1981-03-20
SE7707631L (sv) 1978-01-07
JPS5943466B2 (ja) 1984-10-22
ATA483477A (de) 1979-01-15
AT351531B (de) 1979-07-25
DK301377A (da) 1978-01-07
CS193580B2 (en) 1979-10-31
FR2357555B1 (fr) 1980-02-01
PL199361A1 (pl) 1978-04-10
AU2668277A (en) 1979-01-04
SU772483A3 (ru) 1980-10-15
NZ184528A (en) 1978-09-20
NL7707464A (nl) 1978-01-10
IL52425A0 (en) 1977-08-31
AR213440A1 (es) 1979-01-31
DK145100B (da) 1982-08-30
SE428018B (sv) 1983-05-30
DD131469A5 (de) 1978-06-28
BG28063A3 (en) 1980-02-25
IE45244L (en) 1978-01-06
GB1582564A (en) 1981-01-14
DE2729817A1 (de) 1978-01-12
DK145100C (da) 1983-01-31
AU511627B2 (en) 1980-08-28
IE45244B1 (en) 1982-07-14
HU176954B (hu) 1981-06-28
CH633786A5 (en) 1982-12-31
IL52425A (en) 1980-09-16
YU163477A (en) 1982-06-30
JPS537678A (en) 1978-01-24
DE2729817C2 (de) 1982-05-27

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Legal Events

Date Code Title Description
ST Notification of lapse