FR2356679A1 - Preparation du polychlorure de vinyle par le procede de polymerisation en suspension - Google Patents
Preparation du polychlorure de vinyle par le procede de polymerisation en suspensionInfo
- Publication number
- FR2356679A1 FR2356679A1 FR7720094A FR7720094A FR2356679A1 FR 2356679 A1 FR2356679 A1 FR 2356679A1 FR 7720094 A FR7720094 A FR 7720094A FR 7720094 A FR7720094 A FR 7720094A FR 2356679 A1 FR2356679 A1 FR 2356679A1
- Authority
- FR
- France
- Prior art keywords
- suspension polymerization
- preparation
- polymerization process
- vinyl polychloride
- mole
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F14/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
- C08F14/02—Monomers containing chlorine
- C08F14/04—Monomers containing two carbon atoms
- C08F14/06—Vinyl chloride
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Polymerisation Methods In General (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Medicinal Preparation (AREA)
Abstract
Procédé de préparation de polychlorure de vinyle par polymérisation en suspension, en présence d'une association de deux colloides protecteurs. Le procédé est caractérisé en ce que cette association comprend 20 à 65 % d'un polyacétate de vinyle ayant un degré d'hydrolyse de 40 à 55 moles% et une viscosité déterminée, et un alcool polyvinylique soluble dans l'eau ayant un degré d'hydrolyse de 70 à 80 moles% et une viscosité déterminée, ou bien une aminoéthyl-hydroxypropyle cellulose ou un copolymère acétate de vinyle/vinylpyrrolidone.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE2629880A DE2629880B2 (de) | 1976-07-02 | 1976-07-02 | Verfahren zur Herstellung von Polyvinylchlorid nach dem Suspensionsverfahren |
Publications (2)
Publication Number | Publication Date |
---|---|
FR2356679A1 true FR2356679A1 (fr) | 1978-01-27 |
FR2356679B1 FR2356679B1 (fr) | 1979-03-09 |
Family
ID=5982106
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
FR7720094A Granted FR2356679A1 (fr) | 1976-07-02 | 1977-06-30 | Preparation du polychlorure de vinyle par le procede de polymerisation en suspension |
Country Status (12)
Country | Link |
---|---|
US (1) | US4345056A (fr) |
JP (1) | JPS536392A (fr) |
AT (1) | AT353006B (fr) |
BE (1) | BE856372A (fr) |
CA (1) | CA1089597A (fr) |
CH (1) | CH630101A5 (fr) |
DE (1) | DE2629880B2 (fr) |
FR (1) | FR2356679A1 (fr) |
GB (1) | GB1541386A (fr) |
NL (1) | NL7704507A (fr) |
NO (1) | NO147486B (fr) |
SE (1) | SE7707688L (fr) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0033892A2 (fr) * | 1980-02-02 | 1981-08-19 | Hoechst Aktiengesellschaft | Procédé de polymérisation de chlorure de vinyle en phase aqueuse |
EP0033893A2 (fr) * | 1980-02-02 | 1981-08-19 | Hoechst Aktiengesellschaft | Procédé de polymérisation de chlorure de vinyle en phase aqueuse |
EP0258882A2 (fr) * | 1986-09-05 | 1988-03-09 | The B.F. Goodrich Company | Procédé de préparation de CPV pour feuilles |
Families Citing this family (29)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
IT1160355B (it) * | 1978-12-15 | 1987-03-11 | Sigma Italiana Prod Chimici | Procedimento perfezionato per la produzione di cloruro di polivinile |
SE431221B (sv) * | 1977-01-18 | 1984-01-23 | Kema Nord Ab | Sett vid suspensionspolymerisation av vinylklorid och eventuell sammonomer i nervaro av en suspensionsstabilisator innefattande en blandning av tva delvis hydrolyserade polyvinylacetat med olika hydrolysgrad |
JPS6044324B2 (ja) * | 1980-06-30 | 1985-10-03 | 三井東圧化学株式会社 | 塩化ビニルの懸濁重合法 |
DE3036127C2 (de) * | 1980-09-25 | 1983-01-27 | Chemische Werke Hüls AG, 4370 Marl | Verfahren zur Herstellung von Vinylchlorid-Polymeren |
DE3167717D1 (en) | 1980-09-25 | 1985-01-24 | Huels Chemische Werke Ag | Process for producing vinyl-chloride polymers |
DE3147672A1 (de) * | 1981-12-02 | 1983-06-09 | Chemische Werke Hüls AG, 4370 Marl | Verfahren zur herstellung von polymeren und copolymeren des vinylchlorids und deren verwendung |
DE3218173A1 (de) * | 1982-05-14 | 1983-11-17 | Chemische Werke Hüls AG, 4370 Marl | Verfahren zur herstellung von polymeren und copolymeren des vinylchlorids durch suspensionspolymerisation und verwendung fuer den einsatz als viskositaetserniedriger in der plastisolverarbeitung |
US4532314A (en) * | 1983-02-28 | 1985-07-30 | Henkel Corporation | Method of suspension polymerization of vinyl chloride utilizing hydroxypropyl guar |
US4526946A (en) * | 1983-06-23 | 1985-07-02 | Occidental Chemical Corporation | Polyvinyl chloride suspension polymerization process and product having improved plasticizer absorption |
US4732953A (en) * | 1983-06-23 | 1988-03-22 | Occidental Chemical Corporation | Novel polyvinyl chloride suspension polymerization process and product having improved plasticizer absorption |
US4732954A (en) * | 1983-06-23 | 1988-03-22 | Occidental Chemical Corporation | Novel polyvinyl chloride suspension polymerization process and product having improved plasticizer absorption |
JPS62101609A (ja) * | 1985-10-29 | 1987-05-12 | Mitsubishi Kasei Vinyl Co | 塩化ビニル系重合体の製造方法 |
JPH0778083B2 (ja) * | 1986-04-03 | 1995-08-23 | 信越化学工業株式会社 | 塩化ビニル系懸濁重合方法における懸濁安定剤の仕込み方法 |
US4940759A (en) * | 1986-09-05 | 1990-07-10 | The B.F. Goodrich Company | Process for making film grade PVC |
JPH0696616B2 (ja) * | 1987-03-19 | 1994-11-30 | チッソ株式会社 | 塩化ビニル重合体の製造方法 |
DE3835244A1 (de) * | 1988-10-15 | 1990-04-19 | Hoechst Ag | Verfahren zur polymerisation von vinylchlorid in waessriger phase |
US5166028A (en) * | 1989-01-31 | 1992-11-24 | Xerox Corporation | Processes for the preparation of styrene butadiene resins |
US4957983A (en) * | 1989-06-07 | 1990-09-18 | The B. F. Goodrich Company | Method for providing improved colloidal stability and polyvinyl chloride using a hot charge polymerization procedure with emulsifier package |
WO1991015518A1 (fr) * | 1990-04-05 | 1991-10-17 | Kuraray Co., Ltd. | Polymerisation en suspension d'un compose vinylique |
US5609993A (en) * | 1991-04-17 | 1997-03-11 | Nippon Paint Co., Ltd. | Process for producing lithographic printing plate, photosensitive plate and aqueous ink composition therefor |
EP0633273A1 (fr) * | 1993-07-05 | 1995-01-11 | Shin-Etsu Chemical Co., Ltd. | Procédé pour la préparation de chlorure de polyvinyle |
EP0847405B1 (fr) * | 1995-08-31 | 2002-10-09 | LG Chemical Limited | Emulsifiants polymeres destines a une polymerisation de chlorure de vinyle |
JPH10251339A (ja) * | 1997-03-17 | 1998-09-22 | Kanegafuchi Chem Ind Co Ltd | ペーストブレンド用塩化ビニル系樹脂の製造方法 |
TW426707B (en) * | 1997-07-24 | 2001-03-21 | Akzo Nobel Nv | Emulsions of peroxyesters |
RU2295540C2 (ru) * | 2002-04-12 | 2007-03-20 | Акцо Нобель Н.В. | Совместное введение органических инициаторов и защитных коллоидов в ходе проведения реакций полимеризации |
DE10309857A1 (de) * | 2003-03-06 | 2004-09-23 | Wacker Polymer Systems Gmbh & Co. Kg | Epoxy-modifizierte Vinylchlorid-Vinylester-Copolymer-Festharze |
GB0427390D0 (en) * | 2004-12-14 | 2005-01-19 | Evc Europ Vinyls Corp Switzerl | Polymerisation of vinyl chloride monomer |
EP2154161B1 (fr) | 2007-04-16 | 2012-01-04 | Kuraray Co., Ltd. | Stabilisateur de dispersion pour polymérisation en suspension |
KR102024141B1 (ko) * | 2016-06-21 | 2019-09-23 | 주식회사 엘지화학 | 염화비닐계 중합체의 제조방법 |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2207149A1 (fr) * | 1972-11-21 | 1974-06-14 | Sumitomo Chemical Co | |
BE849753A (fr) * | 1976-02-17 | 1977-04-15 | Procede de fabrication du chlorure de polyvinyle |
Family Cites Families (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3172877A (en) * | 1965-03-09 | Copolymerization of vinyl chloride and vinyl acetate | ||
GB991134A (en) * | 1961-03-23 | 1965-05-05 | Wacker Chemie Gmbh | Process for the manufacture of vinyl chloride polymers |
GB1237735A (en) * | 1967-09-21 | 1971-06-30 | Hoechst Ag | Process for the manufacture of a polyvinyl ester dispersion |
US3592800A (en) * | 1967-11-29 | 1971-07-13 | Werner Oschmann | Polymerization of vinyl chloride in aqueous suspension in the presence of low viscosity polyvinyl alcohol and a protective colloid |
DE2225236C3 (de) * | 1972-05-24 | 1979-12-20 | Wacker-Chemie Gmbh, 8000 Muenchen | Verfahren zur Polymerisation von Vinylchlorid |
DE2234038C3 (de) * | 1972-07-11 | 1978-05-18 | Wacker-Chemie Gmbh, 8000 Muenchen | Verfahren zur Polymerisation von Vinylchlorid |
TR18667A (tr) * | 1974-12-10 | 1977-06-23 | Anic Spa | Vinil - kloridin suespansiyon polimerizasyonu icin usul |
DE2528950B2 (de) * | 1975-06-28 | 1979-02-15 | Sigma Italiana Prodotti Chimici S.P.A., Bergamo (Italien) | Verfahren zur Herstellung von Polyvinylchlorid |
HU172617B (hu) * | 1976-01-28 | 1978-11-28 | Borsodi Vegyi Komb | Sposob poluchenija polivinilacetata v chastnosti gidrolizirovannojj sostojanii v gele |
-
1976
- 1976-07-02 DE DE2629880A patent/DE2629880B2/de not_active Withdrawn
-
1977
- 1977-04-25 NL NL7704507A patent/NL7704507A/xx not_active Application Discontinuation
- 1977-05-05 AT AT319177A patent/AT353006B/de not_active IP Right Cessation
- 1977-06-06 CA CA279,915A patent/CA1089597A/fr not_active Expired
- 1977-06-30 FR FR7720094A patent/FR2356679A1/fr active Granted
- 1977-07-01 CH CH814677A patent/CH630101A5/de not_active IP Right Cessation
- 1977-07-01 GB GB27681/77A patent/GB1541386A/en not_active Expired
- 1977-07-01 NO NO772348A patent/NO147486B/no unknown
- 1977-07-01 BE BE178999A patent/BE856372A/fr not_active IP Right Cessation
- 1977-07-01 SE SE7707688A patent/SE7707688L/xx not_active Application Discontinuation
- 1977-07-01 JP JP7897877A patent/JPS536392A/ja active Granted
-
1978
- 1978-11-13 US US05/959,796 patent/US4345056A/en not_active Expired - Lifetime
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2207149A1 (fr) * | 1972-11-21 | 1974-06-14 | Sumitomo Chemical Co | |
BE849753A (fr) * | 1976-02-17 | 1977-04-15 | Procede de fabrication du chlorure de polyvinyle |
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0033892A2 (fr) * | 1980-02-02 | 1981-08-19 | Hoechst Aktiengesellschaft | Procédé de polymérisation de chlorure de vinyle en phase aqueuse |
EP0033893A2 (fr) * | 1980-02-02 | 1981-08-19 | Hoechst Aktiengesellschaft | Procédé de polymérisation de chlorure de vinyle en phase aqueuse |
EP0033892A3 (fr) * | 1980-02-02 | 1981-12-23 | Hoechst Aktiengesellschaft | Procédé de polymérisation de chlorure de vinyle en phase aqueuse |
EP0033893A3 (en) * | 1980-02-02 | 1981-12-30 | Hoechst Aktiengesellschaft | Process for the polymerisation of vinyl chloride in the aqueous phase |
EP0258882A2 (fr) * | 1986-09-05 | 1988-03-09 | The B.F. Goodrich Company | Procédé de préparation de CPV pour feuilles |
EP0258882A3 (fr) * | 1986-09-05 | 1988-10-12 | The B.F. Goodrich Company | Procédé de préparation de CPV pour feuilles |
Also Published As
Publication number | Publication date |
---|---|
ATA319177A (de) | 1979-03-15 |
SE7707688L (sv) | 1978-01-03 |
CA1089597A (fr) | 1980-11-11 |
DE2629880B2 (de) | 1980-10-16 |
JPS5512444B2 (fr) | 1980-04-02 |
JPS536392A (en) | 1978-01-20 |
US4345056A (en) | 1982-08-17 |
AT353006B (de) | 1979-10-25 |
CH630101A5 (de) | 1982-05-28 |
NO772348L (no) | 1978-01-03 |
GB1541386A (en) | 1979-02-28 |
DE2629880A1 (de) | 1978-01-05 |
FR2356679B1 (fr) | 1979-03-09 |
NO147486B (no) | 1983-01-10 |
BE856372A (fr) | 1978-01-02 |
NL7704507A (nl) | 1978-01-04 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
ST | Notification of lapse |