FR2355919A1 - Procede de separation et de purification de ruthenium - Google Patents

Procede de separation et de purification de ruthenium

Info

Publication number
FR2355919A1
FR2355919A1 FR7718690A FR7718690A FR2355919A1 FR 2355919 A1 FR2355919 A1 FR 2355919A1 FR 7718690 A FR7718690 A FR 7718690A FR 7718690 A FR7718690 A FR 7718690A FR 2355919 A1 FR2355919 A1 FR 2355919A1
Authority
FR
France
Prior art keywords
ruthenium
separation
nitrosylruthenium
complex
purification process
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
FR7718690A
Other languages
English (en)
Other versions
FR2355919B3 (fr
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
NAT INST METALLURG
Original Assignee
NAT INST METALLURG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by NAT INST METALLURG filed Critical NAT INST METALLURG
Publication of FR2355919A1 publication Critical patent/FR2355919A1/fr
Application granted granted Critical
Publication of FR2355919B3 publication Critical patent/FR2355919B3/fr
Granted legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G55/00—Compounds of ruthenium, rhodium, palladium, osmium, iridium, or platinum
    • C01G55/001—Preparation involving a liquid-liquid extraction, an adsorption or an ion-exchange
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B11/00—Obtaining noble metals
    • C22B11/04—Obtaining noble metals by wet processes
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
    • C22B3/20—Treatment or purification of solutions, e.g. obtained by leaching
    • C22B3/26—Treatment or purification of solutions, e.g. obtained by leaching by liquid-liquid extraction using organic compounds
    • C22B3/262—Treatment or purification of solutions, e.g. obtained by leaching by liquid-liquid extraction using organic compounds using alcohols or phenols
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
    • C22B3/20—Treatment or purification of solutions, e.g. obtained by leaching
    • C22B3/26—Treatment or purification of solutions, e.g. obtained by leaching by liquid-liquid extraction using organic compounds
    • C22B3/28—Amines
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
    • C22B3/20—Treatment or purification of solutions, e.g. obtained by leaching
    • C22B3/26—Treatment or purification of solutions, e.g. obtained by leaching by liquid-liquid extraction using organic compounds
    • C22B3/28—Amines
    • C22B3/282—Aliphatic amines
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
    • C22B3/20—Treatment or purification of solutions, e.g. obtained by leaching
    • C22B3/26—Treatment or purification of solutions, e.g. obtained by leaching by liquid-liquid extraction using organic compounds
    • C22B3/306—Ketones or aldehydes
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
    • C22B3/20—Treatment or purification of solutions, e.g. obtained by leaching
    • C22B3/26—Treatment or purification of solutions, e.g. obtained by leaching by liquid-liquid extraction using organic compounds
    • C22B3/32—Carboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
    • C22B3/20—Treatment or purification of solutions, e.g. obtained by leaching
    • C22B3/26—Treatment or purification of solutions, e.g. obtained by leaching by liquid-liquid extraction using organic compounds
    • C22B3/38—Treatment or purification of solutions, e.g. obtained by leaching by liquid-liquid extraction using organic compounds containing phosphorus
    • C22B3/384—Pentavalent phosphorus oxyacids, esters thereof
    • C22B3/3846—Phosphoric acid, e.g. (O)P(OH)3
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
    • C22B3/20—Treatment or purification of solutions, e.g. obtained by leaching
    • C22B3/42—Treatment or purification of solutions, e.g. obtained by leaching by ion-exchange extraction
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P10/00—Technologies related to metal processing
    • Y02P10/20—Recycling

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Metallurgy (AREA)
  • Mechanical Engineering (AREA)
  • Materials Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Geology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Environmental & Geological Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Manufacture And Refinement Of Metals (AREA)
  • Extraction Or Liquid Replacement (AREA)
  • Catalysts (AREA)
  • Treatment Of Water By Oxidation Or Reduction (AREA)
  • Inorganic Compounds Of Heavy Metals (AREA)

Abstract

La présente invention concerne un procédé pour la séparation ou la purification de ruthénium à partir de ses solutions. Ce procédé comprend la transformation du ruthénium en complexe de nitrosylruthénium avec le ruthénium au degré d'oxydation Ru** +2; la transformation du complexe de nitrosyl-ruthénium en un chlorocomplexe de nitrosylruthénium et de tous autres métaux du groupe du platine en chlorocomplexes; et la séparation du chloro-complexe de nitrosylruthénium de la solution en utilisant un échangeur d'anions liquide ou en résine approprié. Application à la séparation du ruthénium.
FR7718690A 1976-06-21 1977-06-17 Procede de separation et de purification de ruthenium Granted FR2355919A1 (fr)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
ZA00763680A ZA763680B (en) 1976-06-21 1976-06-21 The separation and purification of ruthenium

Publications (2)

Publication Number Publication Date
FR2355919A1 true FR2355919A1 (fr) 1978-01-20
FR2355919B3 FR2355919B3 (fr) 1979-07-13

Family

ID=25570425

Family Applications (1)

Application Number Title Priority Date Filing Date
FR7718690A Granted FR2355919A1 (fr) 1976-06-21 1977-06-17 Procede de separation et de purification de ruthenium

Country Status (9)

Country Link
US (1) US4105442A (fr)
JP (1) JPS5928615B2 (fr)
BE (1) BE855934A (fr)
CA (1) CA1101678A (fr)
DE (1) DE2726556C2 (fr)
FR (1) FR2355919A1 (fr)
GB (1) GB1533541A (fr)
NO (1) NO149820C (fr)
ZA (1) ZA763680B (fr)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0498743A1 (fr) * 1991-02-08 1992-08-12 COMURHEX Société pour la Conversion de l'Uranium en Métal et Hexafluorure Procédé d'élimination du ruthenium contenu dans des solutions uranifères

Families Citing this family (25)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2448506A1 (fr) * 1979-02-08 1980-09-05 Commissariat Energie Atomique Procede de recuperation du ruthenium present dans une solution aqueuse acide
US4434240A (en) * 1981-11-16 1984-02-28 The Halcon Sd Group, Inc. Recovery of noble metal values from carbonylation residues
JPS6070707U (ja) * 1983-10-21 1985-05-18 スズキ株式会社 ４サイクルエンジンの動弁機構部潤滑装置
JPS61167146A (ja) * 1985-01-18 1986-07-28 Honda Motor Co Ltd 内燃機関
US4770788A (en) * 1985-04-25 1988-09-13 Kollmorgen Technologies Corp. Process for removing metal complexes from waste solutions
JPH0631840B2 (ja) * 1986-10-09 1994-04-27 健次 本島 放射性ルテニウムの除去方法
US5120443A (en) * 1991-06-03 1992-06-09 Brigham Young University Processes for removing, separating and concentrating rhodium, iridium, and ruthenium from solutions using macrocyclic and nonmacrocyclic polyalkylene-polyamine-containing ligands bonded to inorganic supports
GB2293372B (en) * 1994-09-21 1998-05-27 Matthey Rustenburg Refiners Improvements in refining
US5769922A (en) * 1996-04-12 1998-06-23 Reading Alloys, Inc. Method for producing vanadium-aluminum-ruthenium master alloys and master alloy compositions
DE19746136C1 (de) * 1997-10-18 1999-03-25 Degussa Verfahren zur Abtrennung von Ruthenium aus Scheidereilösungen
DE10000275C1 (de) * 2000-01-05 2001-05-03 Heraeus Gmbh W C Verfahren zur Abtrennung von Ruthenium aus Edelmetall-Lösungen
DE10000274C1 (de) * 2000-01-05 2001-05-03 Heraeus Gmbh W C Verfahren zur Gewinnung von Osmium und Ruthenium aus Edelmetallkonzentraten
US7253076B1 (en) * 2000-06-08 2007-08-07 Micron Technologies, Inc. Methods for forming and integrated circuit structures containing ruthenium and tungsten containing layers
GB0026809D0 (en) * 2000-11-02 2000-12-20 Anglo American Platinum Corp Separation of metals
US6551378B2 (en) 2001-02-20 2003-04-22 Green Mineral Products Llc Recovery of precious metals from low concentration sources
GB0210099D0 (en) * 2002-05-02 2002-06-12 Anglo Platinum Ltd Separation of metals
JP4144311B2 (ja) * 2002-10-08 2008-09-03 住友金属鉱山株式会社 白金族元素の分離回収方法
JP4268646B2 (ja) * 2007-03-30 2009-05-27 日鉱金属株式会社 ロジウムの回収方法
CN102959103B (zh) * 2010-09-03 2014-03-05 吉坤日矿日石金属株式会社 高纯度铂的回收方法
JP6222469B2 (ja) * 2014-03-28 2017-11-01 三菱マテリアル株式会社 白金族の回収方法
WO2016034301A1 (fr) * 2014-09-03 2016-03-10 Heraeus Deutschland GmbH & Co. KG Procédé pour la préparation et/ou la purification de chlorure de ruthénium (iii)
EP2998275B1 (fr) * 2014-09-19 2016-11-02 Heraeus Deutschland GmbH & Co. KG Procédé pour la préparation et/ou purification de chlorure de ruthénium (III)
JP6562351B2 (ja) * 2015-09-10 2019-08-21 学校法人上智学院 ポリマーの製造方法およびニトロシルルテニウム錯体の使用
WO2023099076A1 (fr) * 2021-12-02 2023-06-08 Heraeus Deutschland GmbH & Co. KG Procédé de séparation de rhodium
CN114921654A (zh) * 2022-05-27 2022-08-19 广东先导稀贵金属材料有限公司 一种含钌物料的富集回收方法

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2894816A (en) * 1950-09-27 1959-07-14 Herbert H Hyman Solvent extraction of ruthenium
ZA72308B (en) * 1972-01-18 1973-09-26 Nat Inst Metallurg Improved process for the separation and purification of platinum group metals and gold
GB1497534A (en) * 1973-12-13 1978-01-12 Matthey Rustenburg Refines Refining of metals
US4002470A (en) * 1974-12-10 1977-01-11 The Japan Carlit Co., Ltd. Process for recovering ruthenium

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0498743A1 (fr) * 1991-02-08 1992-08-12 COMURHEX Société pour la Conversion de l'Uranium en Métal et Hexafluorure Procédé d'élimination du ruthenium contenu dans des solutions uranifères
FR2672582A1 (fr) * 1991-02-08 1992-08-14 Comurhex Procede d'elimination du ruthenium contenu dans des solutions uraniferes.
US5219540A (en) * 1991-02-08 1993-06-15 Comurhex Societe Pour La Conversion De L'uranium En Metal Et Hexafluoroure Method of removing ruthenium contained in uranium-containing solutions

Also Published As

Publication number Publication date
CA1101678A (fr) 1981-05-26
US4105442A (en) 1978-08-08
DE2726556A1 (de) 1977-12-29
JPS5928615B2 (ja) 1984-07-14
NO772151L (no) 1977-12-22
ZA763680B (en) 1978-02-22
FR2355919B3 (fr) 1979-07-13
GB1533541A (en) 1978-11-29
NO149820B (no) 1984-03-19
NO149820C (no) 1984-06-27
DE2726556C2 (de) 1986-12-11
BE855934A (fr) 1977-12-21
JPS5322114A (en) 1978-03-01

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