FR2354127A1 - Elimination de gaz dans des produits gazeux industriels a l'aide d'une membrane - Google Patents

Elimination de gaz dans des produits gazeux industriels a l'aide d'une membrane

Info

Publication number
FR2354127A1
FR2354127A1 FR7717888A FR7717888A FR2354127A1 FR 2354127 A1 FR2354127 A1 FR 2354127A1 FR 7717888 A FR7717888 A FR 7717888A FR 7717888 A FR7717888 A FR 7717888A FR 2354127 A1 FR2354127 A1 FR 2354127A1
Authority
FR
France
Prior art keywords
gas
membrane
catalyst
carbon dioxide
weight
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
FR7717888A
Other languages
English (en)
Other versions
FR2354127B1 (fr
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Exxon Res Engineering Cy
ExxonMobil Technology and Engineering Co
Original Assignee
Exxon Res Engineering Cy
Exxon Research and Engineering Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Exxon Res Engineering Cy, Exxon Research and Engineering Co filed Critical Exxon Res Engineering Cy
Publication of FR2354127A1 publication Critical patent/FR2354127A1/fr
Application granted granted Critical
Publication of FR2354127B1 publication Critical patent/FR2354127B1/fr
Granted legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/86—Catalytic processes
    • B01D53/864—Removing carbon monoxide or hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/50—Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification
    • C01B3/501—Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification by diffusion
    • C01B3/503—Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification by diffusion characterised by the membrane
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/0405—Purification by membrane separation
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/0465—Composition of the impurity
    • C01B2203/0475—Composition of the impurity the impurity being carbon dioxide
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02C—CAPTURE, STORAGE, SEQUESTRATION OR DISPOSAL OF GREENHOUSE GASES [GHG]
    • Y02C20/00—Capture or disposal of greenhouse gases
    • Y02C20/40—Capture or disposal of greenhouse gases of CO2

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Environmental & Geological Engineering (AREA)
  • Analytical Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Biomedical Technology (AREA)
  • Combustion & Propulsion (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Separation Using Semi-Permeable Membranes (AREA)
  • Hydrogen, Water And Hydrids (AREA)
  • Catalysts (AREA)
  • Treating Waste Gases (AREA)

Abstract

L'invention concerne une membrane et un procédé utilisables pour éliminer un constituant gazeux présent dans un gaz industrieL La membrane est caractérisée par une couche poreuse de matière hydrophile 2, dont les deux faces 1 et 3 sont couvertes d'une couche d'un mélange de 10 à 90 % en poids d'une substance hydrophobe et de 90 à 10 % en poids d'une substance hydrophile, les portions hydropiles des trois couches étant imprégnées d'un catalyseur qui favorise la conversion de l'anhydride carbonique en ions bicarbonate et la décomposition du bicarbonate en anhydride carbonique gazeux, la concentration du catalyseur étant comprise entre 0,1 M et 3 M, et d'une solution tampon 2 à 14 à base d'un métal alcalin. Le procédé consiste à faire circuler le gaz 4 au voisinage immédiat d'un gaz d'extraction 5 humidifié ayant une humidité relative de 0,4 à 0,95, le gaz 4 et le gaz d'extraction 5 étant séparés par la membrane. Application à l'élimination de CO2 de gaz destinés à des piles à combustibles alcalines.
FR7717888A 1976-06-11 1977-06-10 Elimination de gaz dans des produits gazeux industriels a l'aide d'une membrane Granted FR2354127A1 (fr)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB24299/76A GB1577723A (en) 1976-06-11 1976-06-11 Removal of a gas component present in a gaseous stream

Publications (2)

Publication Number Publication Date
FR2354127A1 true FR2354127A1 (fr) 1978-01-06
FR2354127B1 FR2354127B1 (fr) 1983-04-29

Family

ID=10209500

Family Applications (1)

Application Number Title Priority Date Filing Date
FR7717888A Granted FR2354127A1 (fr) 1976-06-11 1977-06-10 Elimination de gaz dans des produits gazeux industriels a l'aide d'une membrane

Country Status (6)

Country Link
US (1) US4117079A (fr)
JP (1) JPS52152888A (fr)
CA (1) CA1093536A (fr)
DE (1) DE2725995A1 (fr)
FR (1) FR2354127A1 (fr)
GB (1) GB1577723A (fr)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2482469A1 (fr) * 1980-05-14 1981-11-20 Gen Electric Procede de separation d'un gaz choisi d'un melange de gaz au moyen d'une membrane echangeuse d'ions

Families Citing this family (42)

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DE3107874A1 (de) * 1981-03-02 1982-09-16 Akzo Gmbh, 5600 Wuppertal Verfahren zur blasenfreien gaseinspeisung
JPS6090005A (ja) * 1983-10-22 1985-05-21 Agency Of Ind Science & Technol 気体分離膜
US4789468A (en) * 1984-08-28 1988-12-06 The Trustees Of The Stevens Institute Of Technology Immobilized-interface solute-transfer apparatus
US4761164A (en) * 1985-03-01 1988-08-02 Air Products And Chemicals, Inc. Method for gas separation
US4750918A (en) * 1985-05-28 1988-06-14 The Trustees Of The Stevens Institute Of Technology Selective-permeation gas-separation process and apparatus
US5110326A (en) * 1985-07-31 1992-05-05 Celanese Corporation Immobilized liquid membrane
ZA865173B (en) * 1985-07-31 1987-03-25 Celanese Corp Immobilized liquid membrane
US4921612A (en) * 1985-10-22 1990-05-01 The Trustees Of Stevens Institute Of Technology Asymmetrically-wettable porous membrane process
US4954145A (en) * 1986-11-03 1990-09-04 Kingston Technologies Filled membranes for separation of polar from non-polar gases
US4889541A (en) * 1988-07-05 1989-12-26 Texaco Inc. Separation of gases
US5141620A (en) * 1990-12-18 1992-08-25 United Technologies Corporation Device and method for separating and compressing carbon dioxide from a carbonate salt
US5281254A (en) * 1992-05-22 1994-01-25 United Technologies Corporation Continuous carbon dioxide and water removal system
US5445669A (en) * 1993-08-12 1995-08-29 Sumitomo Electric Industries, Ltd. Membrane for the separation of carbon dioxide
JP2683767B2 (ja) * 1993-08-12 1997-12-03 工業技術院長 多座配位子を含む二酸化炭素分離膜及び二酸化炭素キャリヤー
US5556449A (en) * 1993-10-25 1996-09-17 Membrane Technology And Research, Inc. Acid gas fractionation process for fossil fuel gasifiers
US5558698A (en) * 1993-10-25 1996-09-24 Membrane Technology And Research, Inc. Acid gas fractionation process
US6315968B1 (en) * 1995-01-18 2001-11-13 Air Products And Chemicals, Inc. Process for separating acid gases from gaseous mixtures utilizing composite membranes formed from salt-polymer blends
WO1999006138A1 (fr) 1997-08-01 1999-02-11 Exxon Research And Engineering Company Processus a membrane a selectivite co2 et systeme de reformage de combustible en hydrogene pour pile a combustible
US6875247B2 (en) * 2000-06-06 2005-04-05 Battelle Memorial Institute Conditions for fluid separations in microchannels, capillary-driven fluid separations, and laminated devices capable of separating fluids
AU2001280616A1 (en) * 2000-07-18 2002-01-30 Ohio University Photosynthetic carbon dioxide mitigation
SE523260C2 (sv) * 2002-02-27 2004-04-06 Volvo Teknisk Utveckling Ab System för generering av vätgasbränsle till en bränslecell
US6869462B2 (en) * 2002-03-11 2005-03-22 Battelle Memorial Institute Methods of contacting substances and microsystem contactors
CA2527486A1 (fr) * 2002-06-26 2004-01-08 Den Kongelige Veterinaer-Og Landbohojskole Filtre a double porosite
US7051540B2 (en) * 2003-01-27 2006-05-30 Battelle Memorial Institute Methods for fluid separations, and devices capable of separating fluids
US7318854B2 (en) * 2004-10-29 2008-01-15 New Jersey Institute Of Technology System and method for selective separation of gaseous mixtures using hollow fibers
WO2006049610A1 (fr) * 2004-10-29 2006-05-11 New Jersey Institute Of Technology Système et méthode de séparation sélective de mélanges gazeux employant des fibres creuses
JP4785920B2 (ja) * 2005-06-23 2011-10-05 シーオーピー エナジー テクノロジーズ エルエルシー 電気化学的な改質及び電解質の再生を使用する水素の生産
US7540475B2 (en) * 2005-09-16 2009-06-02 Battelle Memorial Institute Mixing in wicking structures and the use of enhanced mixing within wicks in microchannel devices
JP4621575B2 (ja) * 2005-10-17 2011-01-26 メタウォーター株式会社 ガス回収方法および装置
US8900435B2 (en) * 2007-12-19 2014-12-02 Palo Alto Research Center Incorporated Separating gas using ion exchange
US7938891B2 (en) * 2008-03-17 2011-05-10 Palo Alto Research Center Incorporated Using ionic liquids
US7938892B2 (en) * 2008-06-10 2011-05-10 Palo Alto Research Center Incorporated Producing articles that include ionic liquids
US7938890B2 (en) * 2008-07-08 2011-05-10 Palo Alto Research Center Incorporated Separating gas using immobilized buffers
MY164721A (en) * 2010-07-30 2018-01-30 Exxonmobil Upstream Res Co Cryogenic systems for removing acid gases from a hydrocarbon gas stream using co-current separation devices
US8877069B2 (en) * 2011-02-08 2014-11-04 Lawrence Livermore National Security, Llc. Tethered catalysts for the hydration of carbon dioxide
JP5743639B2 (ja) * 2011-03-29 2015-07-01 新日鉄住金エンジニアリング株式会社 二酸化炭素ガス分離システム
JP5945478B2 (ja) * 2012-09-04 2016-07-05 日東電工株式会社 分離膜、複合分離膜及び分離膜の製造方法
EP2913101B1 (fr) * 2012-10-02 2023-03-08 Renaissance Energy Research Corporation Membrane de transport de co2 simplifiée et son procédé de fabrication, et procédé et appareil permettant de séparer le co2
JP6235479B2 (ja) * 2012-11-12 2017-11-22 公益財団法人地球環境産業技術研究機構 Ｃｏ２ガス分離膜及びその製造方法
KR20150134315A (ko) * 2013-03-29 2015-12-01 가부시키가이샤 르네상스 에너지 리서치 Co2 촉진 수송막, 그 제조 방법 및 당해 제조 방법에 사용되는 수지 조성물, 그리고 co2 분리 모듈, co2 분리 방법 및 장치
EP3181214A4 (fr) * 2014-08-11 2018-03-21 Sumitomo Chemical Company Limited Composition pour membrane de separation de gaz co2, membrane de separation de gaz co2 et son procede de production, et module de membrane de separation de gaz co2
WO2018085377A1 (fr) 2016-11-02 2018-05-11 Ohio State Innovation Foundation Membranes de séparation de gaz contenant du borate

Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB982509A (en) * 1963-08-28 1965-02-03 Johnson Matthey Co Ltd Improvements in and relating to the production of ultra pure hydrogen
US3371468A (en) * 1966-07-08 1968-03-05 Exxon Research Engineering Co Barrier separator
GB1107114A (en) * 1964-07-29 1968-03-20 Gen Electric Electrolytic process and apparatus for gas purification
FR1573708A (fr) * 1967-08-02 1969-07-04
US3519488A (en) * 1969-03-21 1970-07-07 United Aircraft Corp Carbon dioxide absorber means and fuel cell to regenerate absorbent
DE2024353A1 (de) * 1969-03-10 1971-12-09 Hitachi Maxell Elektrische Zellen
US3847672A (en) * 1971-08-18 1974-11-12 United Aircraft Corp Fuel cell with gas separator
US3910780A (en) * 1973-06-14 1975-10-07 Hydro Membronics Inc Separative barrier for preferential transport of CO{HD 2 {B and apparatus employing same

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3396510A (en) * 1966-08-15 1968-08-13 Gen Electric Liquid membranes for use in the separation of gases
US3851041A (en) * 1966-02-01 1974-11-26 A Eickmeyer Method for removing acid gases from gaseous mixtures
US3676220A (en) * 1969-02-27 1972-07-11 Gen Electric Facilitated transport liquid membrane
US3911080A (en) * 1971-09-10 1975-10-07 Wright H Dudley Air pollution control

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB982509A (en) * 1963-08-28 1965-02-03 Johnson Matthey Co Ltd Improvements in and relating to the production of ultra pure hydrogen
GB1107114A (en) * 1964-07-29 1968-03-20 Gen Electric Electrolytic process and apparatus for gas purification
US3371468A (en) * 1966-07-08 1968-03-05 Exxon Research Engineering Co Barrier separator
FR1573708A (fr) * 1967-08-02 1969-07-04
DE2024353A1 (de) * 1969-03-10 1971-12-09 Hitachi Maxell Elektrische Zellen
US3519488A (en) * 1969-03-21 1970-07-07 United Aircraft Corp Carbon dioxide absorber means and fuel cell to regenerate absorbent
US3847672A (en) * 1971-08-18 1974-11-12 United Aircraft Corp Fuel cell with gas separator
US3910780A (en) * 1973-06-14 1975-10-07 Hydro Membronics Inc Separative barrier for preferential transport of CO{HD 2 {B and apparatus employing same

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2482469A1 (fr) * 1980-05-14 1981-11-20 Gen Electric Procede de separation d'un gaz choisi d'un melange de gaz au moyen d'une membrane echangeuse d'ions

Also Published As

Publication number Publication date
CA1093536A (fr) 1981-01-13
US4117079A (en) 1978-09-26
FR2354127B1 (fr) 1983-04-29
GB1577723A (en) 1980-10-29
DE2725995A1 (de) 1977-12-22
JPS52152888A (en) 1977-12-19

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