FR2333794A1 - Derives d'acides hydroxy-benzyl-maloniques utilisables comme stabilisants de matieres plastiques - Google Patents

Derives d'acides hydroxy-benzyl-maloniques utilisables comme stabilisants de matieres plastiques

Info

Publication number
FR2333794A1
FR2333794A1 FR7633593A FR7633593A FR2333794A1 FR 2333794 A1 FR2333794 A1 FR 2333794A1 FR 7633593 A FR7633593 A FR 7633593A FR 7633593 A FR7633593 A FR 7633593A FR 2333794 A1 FR2333794 A1 FR 2333794A1
Authority
FR
France
Prior art keywords
benzyl
hydroxy
acid derivatives
malonic acid
derivatives used
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
FR7633593A
Other languages
English (en)
Other versions
FR2333794B1 (fr
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Novartis AG
Original Assignee
Ciba Geigy AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from CH1443375A external-priority patent/CH597298A5/de
Priority claimed from CH1443275A external-priority patent/CH597297A5/de
Application filed by Ciba Geigy AG filed Critical Ciba Geigy AG
Publication of FR2333794A1 publication Critical patent/FR2333794A1/fr
Application granted granted Critical
Publication of FR2333794B1 publication Critical patent/FR2333794B1/fr
Granted legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/16Nitrogen-containing compounds
    • C08K5/34Heterocyclic compounds having nitrogen in the ring
    • C08K5/3412Heterocyclic compounds having nitrogen in the ring having one nitrogen atom in the ring
    • C08K5/3432Six-membered rings
    • C08K5/3435Piperidines
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D211/00Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings
    • C07D211/04Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D211/06Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having no double bonds between ring members or between ring members and non-ring members
    • C07D211/36Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having no double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D211/40Oxygen atoms
    • C07D211/44Oxygen atoms attached in position 4
    • C07D211/46Oxygen atoms attached in position 4 having a hydrogen atom as the second substituent in position 4
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D211/00Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings
    • C07D211/04Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D211/06Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having no double bonds between ring members or between ring members and non-ring members
    • C07D211/36Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having no double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D211/56Nitrogen atoms
    • C07D211/58Nitrogen atoms attached in position 4
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D211/00Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings
    • C07D211/92Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with a hetero atom directly attached to the ring nitrogen atom
    • C07D211/94Oxygen atom, e.g. piperidine N-oxide
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02Phosphorus compounds
    • C07F9/28Phosphorus compounds with one or more P—C bonds
    • C07F9/38Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)]
    • C07F9/40Esters thereof
    • C07F9/4003Esters thereof the acid moiety containing a substituent or a structure which is considered as characteristic
    • C07F9/4006Esters of acyclic acids which can have further substituents on alkyl
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02Phosphorus compounds
    • C07F9/547Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
    • C07F9/553Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having one nitrogen atom as the only ring hetero atom
    • C07F9/576Six-membered rings
    • C07F9/58Pyridine rings
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02Phosphorus compounds
    • C07F9/547Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
    • C07F9/553Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having one nitrogen atom as the only ring hetero atom
    • C07F9/576Six-membered rings
    • C07F9/59Hydrogenated pyridine rings
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/0008Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
    • C08K5/005Stabilisers against oxidation, heat, light, ozone

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Biochemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Molecular Biology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Hydrogenated Pyridines (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
FR7633593A 1975-11-07 1976-11-08 Derives d'acides hydroxy-benzyl-maloniques utilisables comme stabilisants de matieres plastiques Granted FR2333794A1 (fr)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
CH1443375A CH597298A5 (en) 1975-11-07 1975-11-07 (4)-Piperidyl hydroxybenzyl-malonates and -malonamides
CH1443275A CH597297A5 (en) 1975-11-07 1975-11-07 (4)-Piperidyl hydroxybenzyl-malonates and -malonamides
CH414776 1976-04-02
CH414676 1976-04-02
CH1121476 1976-09-03

Publications (2)

Publication Number Publication Date
FR2333794A1 true FR2333794A1 (fr) 1977-07-01
FR2333794B1 FR2333794B1 (fr) 1982-01-08

Family

ID=27509185

Family Applications (2)

Application Number Title Priority Date Filing Date
FR7633593A Granted FR2333794A1 (fr) 1975-11-07 1976-11-08 Derives d'acides hydroxy-benzyl-maloniques utilisables comme stabilisants de matieres plastiques
FR7713689A Granted FR2366278A1 (fr) 1975-11-07 1977-05-05 Esters et amides maloniques de piperidyle-4 utilisables comme stabilisants de matieres plastiques

Family Applications After (1)

Application Number Title Priority Date Filing Date
FR7713689A Granted FR2366278A1 (fr) 1975-11-07 1977-05-05 Esters et amides maloniques de piperidyle-4 utilisables comme stabilisants de matieres plastiques

Country Status (11)

Country Link
US (1) US4198334A (fr)
JP (1) JPS6029387B2 (fr)
AU (1) AU1934876A (fr)
BE (1) BE848017A (fr)
CA (1) CA1077940A (fr)
DD (1) DD127176A5 (fr)
DE (2) DE2647452A1 (fr)
FR (2) FR2333794A1 (fr)
GB (2) GB1516780A (fr)
NL (1) NL7612248A (fr)
SE (1) SE7612366L (fr)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0031304B1 (fr) * 1979-12-21 1984-06-13 CIBA-GEIGY S.p.A. Dérivés de pipéridine comme stabilisants de polymères synthétiques

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DE2861955D1 (en) * 1977-12-02 1982-09-02 Ciba Geigy Ag Malonic acid derivatives of sterically hindered piperidines, process for their preparation and stabilised organic matter
US4185003A (en) * 1978-02-16 1980-01-22 E. I. Du Pont De Nemours And Company Stabilized copolyetheresters
EP0006564B1 (fr) * 1978-06-26 1981-12-30 Ciba-Geigy Ag 2-(Hydroxyphényle 3.5-disubstitué)-2H-benzotriazoles et compositions stabilisées les contenant
ATE4992T1 (de) * 1978-07-25 1983-10-15 Imperial Chemical Industries Plc Durch gamma-strahlen sterilisierbare polyolefin- artikel.
IT1110826B (it) * 1979-02-01 1986-01-06 Montedison Spa N-alchil-piperidin derivati dell'acido idrossi-benzil malonico e loro impiego come stabilizzanti per polimeri
US4315848A (en) * 1979-05-10 1982-02-16 Ciba-Geigy Corporation 2-[2-Hydroxy-3,5-di-(α,α-dimethylbenzyl)-phenyl]-2H-benzotriazole and stabilized compositions
IT1165130B (it) * 1979-06-28 1987-04-22 Montedison Spa Policondensati di piperidine sostituite e loro impiego come stabilizzanti per polimeri
US4377651A (en) * 1979-10-05 1983-03-22 Phillips Petroleum Company Polyolefin stabilization
US4302383A (en) * 1980-05-19 1981-11-24 Borg-Warner Chemicals, Inc. Stabilized olefin polymers
EP0104146B1 (fr) * 1982-09-21 1986-07-30 Ciba-Geigy Ag Matériau d'enregistrement photographique couleur
DE3375231D1 (en) * 1982-12-16 1988-02-11 Ciba Geigy Ag Colour-photographic recording material
CA1266272A (fr) * 1983-05-27 1990-02-27 Masakatsu Yoshimura Derive de 2,2,6,6-tetramethylpiperidine; methode de preparation; stabilisateur a base de ce derive pour les resines synthetiques
EP0146879A3 (fr) * 1983-12-22 1986-01-02 General Electric Company Compositions de résines de polyéther de phénylène ayant une stabilité améliorée à la lumière ultraviolette
US4691015A (en) * 1984-07-23 1987-09-01 Ciba-Geigy Corporation Hydroxylamines derived from hindered amines
US4785076A (en) * 1985-09-03 1988-11-15 General Electric Company Polyphenylene ether resin blends having improved ultraviolet light stability
US4762872A (en) * 1985-11-01 1988-08-09 The B. F. Goodrich Company Oligomeric light stabilizers with substituted piperidine ends
US5026751A (en) * 1986-03-17 1991-06-25 General Electric Company UV light stabilizer composition comprising cyclic aliphatic epoxy UV screener, and polyalkyldipiperidine (HALS) compounds
US4843116A (en) * 1986-03-17 1989-06-27 General Electric Company UV light stabilizer composition comprising cyclic aliphatic epoxy, UV screener, and polyalkyldipiperidine (HALS) compounds
EP0253010B1 (fr) * 1986-07-16 1992-12-02 The B.F. GOODRICH Company Alpha-(3,5-dialkyl-4-hydroxyphényl)-alpha, alpha-dialkylacétamides N-substitués par une alkylèneimine cyclique substituée
US4798836A (en) * 1987-10-26 1989-01-17 Adeka Argus Chemical Co., Ltd. Bis-(2,2,6,6-tetramethyl-piperidyl) diimides as light stabilizers for synthetic polymers
DE69012619T2 (de) * 1989-03-21 1995-01-26 Ciba Geigy Ag Bis(1-Hydrocarbyloxy-2,2,6,6-tetramethylpiperidin-4-yl)-amin-derivate und stabilisierte Zusammensetzungen.
US5015683A (en) * 1989-03-21 1991-05-14 Ciba-Geigy Corporation Bis(1-hydrocarbyloxy-2,2,6,6-tetramethylpiperidin-4-yl)-amine derivatives and stabilized compositions
US5041545A (en) * 1989-04-06 1991-08-20 Atochem North America, Inc. 2-hydroxybenzophenone hydrazides and derivatives thereof
US5096948A (en) * 1989-07-03 1992-03-17 Sankyo Company, Limited Resistant resin compositions
US5380774A (en) * 1989-11-28 1995-01-10 Hoechst Celanese Corporation Nylon molding compositions exhibiting improved protection against UV-light degradation
US5025048A (en) * 1990-04-12 1991-06-18 Hercules Incorporated Organosilicon composition comprising stabilizer
FR2664275B1 (fr) * 1990-07-03 1994-04-29 Rhone Poulenc Chimie Nouveaux composes a fonction piperidinyle et leur utilisation dans les polymeres.
US5118735A (en) * 1990-10-05 1992-06-02 Hercules Incorporated Organosilicon composition comprising stabilizers
US5189172A (en) * 1991-06-03 1993-02-23 Mitsubishi Petrochemical Company Limited Piperdine derivatives
IT1247977B (it) * 1991-06-04 1995-01-05 Ciba Geigy Spa Stabilizzazione di materiali organici polimerici mediante l`impiego dimiscele sinergiche costituite da ammine cicliche stericamente impeditee derivati del 3-pirazolidinone o del 1,2,4,-triazolidin-3,5,-dione
IT1264817B1 (it) * 1993-07-28 1996-10-10 Ciba Geigy Spa Derivati di polialchil-4-piperidinoli atti all'impderivati di polialchil-4-piperidinoli atti all'impiego come stabilizzanti per materiali organici iego come stabilizzanti per materiali organici
US6946517B2 (en) * 1999-08-17 2005-09-20 Ciba Specialty Chemicals Corporation Stabilizer mixtures
JP5498638B2 (ja) * 2000-05-31 2014-05-21 チバ ホールディング インコーポレーテッド 安定剤混合物
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ITMI20012085A1 (it) 2000-10-17 2003-04-09 Ciba Sc Holding Ag Polpropilene metallocene stabilizzato
US6465645B1 (en) 2001-04-17 2002-10-15 Ciba Specialty Chemicals Corporation Long chain hindered amines and compositions stabilized therewith
US20030225191A1 (en) 2002-04-12 2003-12-04 Francois Gugumus Stabilizer mixtures
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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0031304B1 (fr) * 1979-12-21 1984-06-13 CIBA-GEIGY S.p.A. Dérivés de pipéridine comme stabilisants de polymères synthétiques
US4501837A (en) * 1979-12-21 1985-02-26 Ciba-Geigy S.P.A. Piperidine derivatives which are stabilisers for synthetic polymers
US4525503A (en) * 1979-12-21 1985-06-25 Ciba-Geigy S.P.A. Piperidine derivatives which are stabilizers for synthetic polymers

Also Published As

Publication number Publication date
FR2366278A1 (fr) 1978-04-28
DE2647452A1 (de) 1977-05-18
FR2333794B1 (fr) 1982-01-08
JPS5271476A (en) 1977-06-14
US4198334A (en) 1980-04-15
DE2661090C2 (fr) 1990-02-08
BE848017A (fr) 1977-05-05
CA1077940A (fr) 1980-05-20
NL7612248A (nl) 1977-05-10
DE2647452C2 (fr) 1991-08-08
JPS6029387B2 (ja) 1985-07-10
SE7612366L (sv) 1977-05-08
DD127176A5 (fr) 1977-09-07
FR2366278B1 (fr) 1979-04-06
GB1516779A (en) 1978-07-05
AU1934876A (en) 1978-05-11
GB1516780A (en) 1978-07-05

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