FI87351B - Vinylcyklopropankarboxyl-syraestrar. - Google Patents
Vinylcyklopropankarboxyl-syraestrar. Download PDFInfo
- Publication number
- FI87351B FI87351B FI861606A FI861606A FI87351B FI 87351 B FI87351 B FI 87351B FI 861606 A FI861606 A FI 861606A FI 861606 A FI861606 A FI 861606A FI 87351 B FI87351 B FI 87351B
- Authority
- FI
- Finland
- Prior art keywords
- formula
- spp
- trans
- vinylcyclopropanecarboxylic acid
- active substance
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
- C07C69/74—Esters of carboxylic acids having an esterified carboxyl group bound to a carbon atom of a ring other than a six-membered aromatic ring
- C07C69/743—Esters of carboxylic acids having an esterified carboxyl group bound to a carbon atom of a ring other than a six-membered aromatic ring of acids with a three-membered ring and with unsaturation outside the ring
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N53/00—Biocides, pest repellants or attractants, or plant growth regulators containing cyclopropane carboxylic acids or derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C321/00—Thiols, sulfides, hydropolysulfides or polysulfides
- C07C321/24—Thiols, sulfides, hydropolysulfides, or polysulfides having thio groups bound to carbon atoms of six-membered aromatic rings
- C07C321/28—Sulfides, hydropolysulfides, or polysulfides having thio groups bound to carbon atoms of six-membered aromatic rings
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Plant Pathology (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Pest Control & Pesticides (AREA)
- Agronomy & Crop Science (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Claims (12)
1. Vinylcyklopropankarboxylsyraester, kännetecknad därav, att den har formeln 5 H 3C CH3 X X U Y>=^ ' coo-ch2/Vr
10. F i vilken R är en C1.4-alkyltio-, di(C1.4-alkyl)amino- eller C1.4-alkylsulfinylgrupp och X och Y vardera är halogenatomer eller 15. och Y vardera är metylgrupper.
2. Vinylcyklopropankarboxylsyraester enligt patent-kravet 1 med formeln I, kännetecknad därav, att R är en C^-alkyltiogrupp och 20. och Y vardera är antingen kloratomer eller varde ra metylgrupper.
3. Förfarande för framställning av vinylcyklopro-pankarboxylsyraestrar med formeln
25 H3C CH3 x Ä M ^ C00-CH2-^V-r F F 30. vilken R är en C^-alkyltio-, di(C^-alkyl )amino- eller C1.4-alkylsulfinylgrupp och X och Y vardera är halogenatomer eller X och Y vardera är metylgrupper, 35 kännetecknat därav, att en syra eller dess reaktiva derivat med formeln t 37 87351 H C CH. X \=/ ' coz, / 1 (II) 5 i vilken X och Y är ovan definierade och Z1 är halogen, företrädesvis klor, eller OH, bringas att reagera med en alkohol eller dess reaktiva derivat med formeln F f
10 V/ 22-c„2_<fJ_8 (III) J F 15. vilken R Sr ovan definierad och Z2 är OH, Cl eller Br, eventuellt i närvaro av lösningsmedel, syraacceptorer och/eller fastransferkatalysatorer.
4. Förfarande för framställning av vinylcyklopro-pankarboxylsyraestrar med formeln 20 H3c ,CH3 F f * X W )=A coo-c»rO- R‘ <Ia) 25 γ' t i vilken R1 är en C1.4-alkyltiogrupp och X och Y vardera är halogenatomer eller - X och Y vardera är metylgrupper, k ä n n e - 30 tecknat därav, att en ester med formeln H C CH, V 3 F F 1 Λ3'' COOCHj—^C-F (IIa) 38 87351 i vilken X och Y är ovan definierade, bringas att reagera med en alkalimerkaptid med formeln [R1]^ (lib) 5 i vilken R1 är en C1.4-alkylmerkaptidgrupp och Me* är en aikaiimetallkatjon, i ett organiskt lösningsmesdel eller i ett tväfassystem 10 som omfattar vatten och ett organiskt lösningsmedel.
5. Skadedjursbekämpningsmedel, känneteck-n a t därav, att det innehäller ätminstone en vinylcyklo-propankarboxylsyraester enligt patentkravet 1.
6. Förfarande för bekämpning av skadedjur, k ä n-15 netecknat därav, att en vinylcyklopropankarboxyl- syraester enligt patentkravet 1 tilläts päverka skadedjur och/eller deras levnadsmiljö.
7. Användning av vinylcyklopropankarboxylsyraest-rar enligt patentkravet 1 för bekämpning av skadedjur. 20 8. Förfarande för framställning av skadedjursbe kämpningsmedel, kännetecknat därav, att vi-nylcyklopropankarboxylsyraestrar enligt patentkravet 1 blandas med fyllmedel och/eller ytaktiva ämnen.
9. Vinylcyklopropankarboxylsyraester enligt patent-25 kravet 1, kännetecknad därav, att den har formeln H.C CH. Y F F
30 C1\ H 'N H C1/C-C“ coo-ch2_<^V)_ sch3 F
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE3513978 | 1985-04-18 | ||
| DE19853513978 DE3513978A1 (de) | 1985-04-18 | 1985-04-18 | Vinylcyclopropancarbonsaeureester |
Publications (4)
| Publication Number | Publication Date |
|---|---|
| FI861606A0 FI861606A0 (fi) | 1986-04-16 |
| FI861606A FI861606A (fi) | 1986-10-19 |
| FI87351B true FI87351B (fi) | 1992-09-15 |
| FI87351C FI87351C (sv) | 1992-12-28 |
Family
ID=6268442
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| FI861606A FI87351C (sv) | 1985-04-18 | 1986-04-16 | Vinylcyklopropankarboxylsyraestrar |
Country Status (29)
| Country | Link |
|---|---|
| US (1) | US4820735A (sv) |
| EP (1) | EP0200943B1 (sv) |
| JP (2) | JPH0768189B2 (sv) |
| KR (1) | KR940010766B1 (sv) |
| CN (1) | CN1013861B (sv) |
| AR (1) | AR242782A1 (sv) |
| AT (1) | ATE39111T1 (sv) |
| AU (1) | AU592082B2 (sv) |
| BR (1) | BR8601715A (sv) |
| CA (1) | CA1280762C (sv) |
| CS (1) | CS258478B2 (sv) |
| DD (1) | DD244490A5 (sv) |
| DE (2) | DE3513978A1 (sv) |
| DK (1) | DK168287B1 (sv) |
| ES (1) | ES8704454A1 (sv) |
| FI (1) | FI87351C (sv) |
| GR (1) | GR861006B (sv) |
| HU (1) | HU203866B (sv) |
| IE (1) | IE58670B1 (sv) |
| IL (1) | IL78500A (sv) |
| MA (1) | MA20666A1 (sv) |
| NO (1) | NO163326C (sv) |
| NZ (1) | NZ215826A (sv) |
| PH (1) | PH22037A (sv) |
| PL (1) | PL148195B1 (sv) |
| PT (1) | PT82352B (sv) |
| TR (1) | TR24983A (sv) |
| ZA (1) | ZA862879B (sv) |
| ZW (1) | ZW6786A1 (sv) |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2587589B1 (fr) * | 1985-09-23 | 1990-05-11 | Roussel Uclaf | Nouvelles compositions pesticides renfermant du (1r cis,e) 2,2-dimethyl 3/2-fluoro 3-oxo 3-methoxy 1-propenyl/cyclopropane carboxylate de pentafluoro phenyl methyl |
| GB8607920D0 (en) * | 1986-04-01 | 1986-05-08 | Cpc International Inc | Dry food composition |
| DE3705224A1 (de) * | 1987-02-19 | 1988-09-01 | Bayer Ag | (+)1r-trans-2,2-dimethyl-3-(2,2-dichlorvinyl) -cyclopropancarbonsaeure-2,3,5,6- tetrafluorbenzylester |
| IT1226546B (it) * | 1988-07-07 | 1991-01-24 | Mini Ricerca Scient Tecnolog | Esteri dell'acido 2,2-dimetil- ciclopropancarbossilico |
| FR2678609B1 (fr) * | 1991-07-04 | 1994-08-26 | Roussel Uclaf | Nouveaux esters pyrethrinouides de l'alcool 4-amino 2,3,5,6-tetrafluorophenyl methylique, leur procede de preparation et leur application comme pesticides. |
| CN102070439B (zh) * | 2011-01-13 | 2013-01-02 | 浙江大学 | (±)-2,2-二甲基-3-乙烯基环丙烷羧酸的制备方法 |
| CN108218696B (zh) * | 2016-12-21 | 2021-03-26 | 江苏优嘉植物保护有限公司 | 一种联苯菊酯的生产工艺 |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2819788A1 (de) * | 1978-05-05 | 1979-11-08 | Bayer Ag | Benzylester mit fluorsubstituierten aether- und/oder thioaethergruppen und ihre verwendung als insektizide |
| DE2831193A1 (de) * | 1978-07-15 | 1980-01-24 | Bayer Ag | Fluoralkenylsubstituierte cyclopropancarbonsaeureester und ihre verwendung als insektizide |
| BR8008346A (pt) * | 1979-12-21 | 1981-07-07 | Ici Ltd | Compostos e composicoes inseticidas a base dos mesmos,bem como processo de sua obtencao |
| DE3065914D1 (en) * | 1979-12-21 | 1984-01-19 | Ici Plc | Substituted benzyl esters of cyclopropane carboxylic acids and their preparation, compositions containing them and methods of combating insect pests therewith, and substituted benzyl alcohols |
| US4370346A (en) * | 1979-12-21 | 1983-01-25 | Imperial Chemical Industries Plc | Halogenated esters |
| DE3170890D1 (en) * | 1980-12-17 | 1985-07-11 | Ici Plc | Fluorobenzyl cyclopropane carboxylates, their preparation, compositions comprising them and their use as insecticides |
| EP0060617A1 (en) * | 1981-03-18 | 1982-09-22 | Imperial Chemical Industries Plc | Fluorobenzyl cyclopropane carboxylates, their preparation, compositions and use as insecticides |
-
1985
- 1985-04-18 DE DE19853513978 patent/DE3513978A1/de not_active Withdrawn
-
1986
- 1986-03-21 ZW ZW67/86A patent/ZW6786A1/xx unknown
- 1986-04-02 AR AR86303549A patent/AR242782A1/es active
- 1986-04-07 PH PH33626A patent/PH22037A/en unknown
- 1986-04-08 NO NO861365A patent/NO163326C/no unknown
- 1986-04-09 AT AT86104876T patent/ATE39111T1/de not_active IP Right Cessation
- 1986-04-09 PT PT82352A patent/PT82352B/pt not_active IP Right Cessation
- 1986-04-09 EP EP86104876A patent/EP0200943B1/de not_active Expired
- 1986-04-09 DE DE8686104876T patent/DE3661357D1/de not_active Expired
- 1986-04-10 CN CN86102323A patent/CN1013861B/zh not_active Expired
- 1986-04-15 NZ NZ215826A patent/NZ215826A/xx unknown
- 1986-04-15 IL IL78500A patent/IL78500A/xx not_active IP Right Cessation
- 1986-04-15 TR TR86/0192A patent/TR24983A/xx unknown
- 1986-04-15 CS CS862758A patent/CS258478B2/cs unknown
- 1986-04-16 FI FI861606A patent/FI87351C/sv not_active IP Right Cessation
- 1986-04-16 GR GR861006A patent/GR861006B/el unknown
- 1986-04-16 CA CA000506773A patent/CA1280762C/en not_active Expired - Lifetime
- 1986-04-16 MA MA20891A patent/MA20666A1/fr unknown
- 1986-04-16 DD DD86289241A patent/DD244490A5/de not_active IP Right Cessation
- 1986-04-17 ES ES554092A patent/ES8704454A1/es not_active Expired
- 1986-04-17 JP JP61087231A patent/JPH0768189B2/ja not_active Expired - Lifetime
- 1986-04-17 PL PL1986259008A patent/PL148195B1/pl unknown
- 1986-04-17 DK DK176086A patent/DK168287B1/da active
- 1986-04-17 AU AU56341/86A patent/AU592082B2/en not_active Ceased
- 1986-04-17 ZA ZA862879A patent/ZA862879B/xx unknown
- 1986-04-17 BR BR8601715A patent/BR8601715A/pt not_active IP Right Cessation
- 1986-04-17 IE IE101786A patent/IE58670B1/en not_active IP Right Cessation
- 1986-04-17 HU HU861605A patent/HU203866B/hu not_active IP Right Cessation
- 1986-04-18 KR KR1019860003005A patent/KR940010766B1/ko active IP Right Grant
-
1987
- 1987-08-18 US US07/087,999 patent/US4820735A/en not_active Expired - Fee Related
-
1993
- 1993-03-17 JP JP5081154A patent/JPH0749415B2/ja not_active Expired - Lifetime
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MM | Patent lapsed | ||
| MM | Patent lapsed |
Owner name: BAYER AKTIENGESELLSCHAFT |