FI68845C - Foerfarande foer framstaellning av polymerlatex - Google Patents
Foerfarande foer framstaellning av polymerlatex Download PDFInfo
- Publication number
- FI68845C FI68845C FI793467A FI793467A FI68845C FI 68845 C FI68845 C FI 68845C FI 793467 A FI793467 A FI 793467A FI 793467 A FI793467 A FI 793467A FI 68845 C FI68845 C FI 68845C
- Authority
- FI
- Finland
- Prior art keywords
- water
- initiator
- emulsion
- amount
- monomer
- Prior art date
Links
- 239000003999 initiator Substances 0.000 claims description 77
- 239000000839 emulsion Substances 0.000 claims description 68
- 239000000178 monomer Substances 0.000 claims description 51
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 42
- 229920000126 latex Polymers 0.000 claims description 32
- 239000004816 latex Substances 0.000 claims description 31
- 239000002245 particle Substances 0.000 claims description 29
- 239000002904 solvent Substances 0.000 claims description 22
- 239000003995 emulsifying agent Substances 0.000 claims description 21
- 238000000034 method Methods 0.000 claims description 21
- 238000006116 polymerization reaction Methods 0.000 claims description 21
- 239000000203 mixture Substances 0.000 claims description 16
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical group ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 claims description 14
- 229920000642 polymer Polymers 0.000 claims description 12
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 6
- 230000009969 flowable effect Effects 0.000 claims description 6
- 238000002844 melting Methods 0.000 claims description 5
- 230000008018 melting Effects 0.000 claims description 5
- 238000000354 decomposition reaction Methods 0.000 claims description 4
- 230000000977 initiatory effect Effects 0.000 claims description 4
- 239000012875 nonionic emulsifier Substances 0.000 claims description 4
- 230000001804 emulsifying effect Effects 0.000 claims description 3
- 238000004519 manufacturing process Methods 0.000 claims description 3
- 125000000129 anionic group Chemical group 0.000 claims description 2
- 125000002091 cationic group Chemical group 0.000 claims description 2
- 239000000126 substance Substances 0.000 description 40
- WSLDOOZREJYCGB-UHFFFAOYSA-N 1,2-Dichloroethane Chemical compound ClCCCl WSLDOOZREJYCGB-UHFFFAOYSA-N 0.000 description 24
- 229940043264 dodecyl sulfate Drugs 0.000 description 15
- MVPPADPHJFYWMZ-UHFFFAOYSA-N chlorobenzene Chemical compound ClC1=CC=CC=C1 MVPPADPHJFYWMZ-UHFFFAOYSA-N 0.000 description 12
- 238000000265 homogenisation Methods 0.000 description 12
- SRSFOMHQIATOFV-UHFFFAOYSA-N octanoyl octaneperoxoate Chemical compound CCCCCCCC(=O)OOC(=O)CCCCCCC SRSFOMHQIATOFV-UHFFFAOYSA-N 0.000 description 10
- 239000007787 solid Substances 0.000 description 10
- 238000003756 stirring Methods 0.000 description 10
- 238000004945 emulsification Methods 0.000 description 9
- 238000002474 experimental method Methods 0.000 description 9
- 238000006243 chemical reaction Methods 0.000 description 8
- 238000002360 preparation method Methods 0.000 description 8
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 7
- 229920002554 vinyl polymer Polymers 0.000 description 7
- DCAYPVUWAIABOU-UHFFFAOYSA-N hexadecane Chemical compound CCCCCCCCCCCCCCCC DCAYPVUWAIABOU-UHFFFAOYSA-N 0.000 description 6
- 239000000693 micelle Substances 0.000 description 6
- 230000008961 swelling Effects 0.000 description 5
- URYAFVKLYSEINW-UHFFFAOYSA-N Chlorfenethol Chemical compound C=1C=C(Cl)C=CC=1C(O)(C)C1=CC=C(Cl)C=C1 URYAFVKLYSEINW-UHFFFAOYSA-N 0.000 description 4
- 239000008346 aqueous phase Substances 0.000 description 4
- 238000005119 centrifugation Methods 0.000 description 4
- 239000007788 liquid Substances 0.000 description 4
- 239000000654 additive Substances 0.000 description 3
- 238000009826 distribution Methods 0.000 description 3
- 239000012530 fluid Substances 0.000 description 3
- NOBYOEQUFMGXBP-UHFFFAOYSA-N (4-tert-butylcyclohexyl) (4-tert-butylcyclohexyl)oxycarbonyloxy carbonate Chemical compound C1CC(C(C)(C)C)CCC1OC(=O)OOC(=O)OC1CCC(C(C)(C)C)CC1 NOBYOEQUFMGXBP-UHFFFAOYSA-N 0.000 description 2
- BEQKKZICTDFVMG-UHFFFAOYSA-N 1,2,3,4,6-pentaoxepane-5,7-dione Chemical compound O=C1OOOOC(=O)O1 BEQKKZICTDFVMG-UHFFFAOYSA-N 0.000 description 2
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 230000000996 additive effect Effects 0.000 description 2
- 150000001335 aliphatic alkanes Chemical class 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- ZFMQKOWCDKKBIF-UHFFFAOYSA-N bis(3,5-difluorophenyl)phosphane Chemical compound FC1=CC(F)=CC(PC=2C=C(F)C=C(F)C=2)=C1 ZFMQKOWCDKKBIF-UHFFFAOYSA-N 0.000 description 2
- XJOBOFWTZOKMOH-UHFFFAOYSA-N decanoyl decaneperoxoate Chemical compound CCCCCCCCCC(=O)OOC(=O)CCCCCCCCC XJOBOFWTZOKMOH-UHFFFAOYSA-N 0.000 description 2
- 229940071161 dodecylbenzenesulfonate Drugs 0.000 description 2
- 238000007720 emulsion polymerization reaction Methods 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- ZTFMJDHQENZIHJ-UHFFFAOYSA-N octanoyloxycarbonylperoxycarbonyl octanoate Chemical compound CCCCCCCC(=O)OC(=O)OOC(=O)OC(=O)CCCCCCC ZTFMJDHQENZIHJ-UHFFFAOYSA-N 0.000 description 2
- 239000003021 water soluble solvent Substances 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical group C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 1
- YIVJZNGAASQVEM-UHFFFAOYSA-N Lauroyl peroxide Chemical compound CCCCCCCCCCCC(=O)OOC(=O)CCCCCCCCCCC YIVJZNGAASQVEM-UHFFFAOYSA-N 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
- LSBBDCGAKMJKSJ-UHFFFAOYSA-N carboxy hydrogen carbonate;1-dodecylperoxydodecane Chemical compound OC(=O)OC(O)=O.CCCCCCCCCCCCOOCCCCCCCCCCCC LSBBDCGAKMJKSJ-UHFFFAOYSA-N 0.000 description 1
- 239000000084 colloidal system Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- GVGUFUZHNYFZLC-UHFFFAOYSA-N dodecyl benzenesulfonate;sodium Chemical compound [Na].CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 GVGUFUZHNYFZLC-UHFFFAOYSA-N 0.000 description 1
- MOTZDAYCYVMXPC-UHFFFAOYSA-N dodecyl hydrogen sulfate Chemical compound CCCCCCCCCCCCOS(O)(=O)=O MOTZDAYCYVMXPC-UHFFFAOYSA-N 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- -1 ester compounds Chemical class 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 238000011081 inoculation Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 125000001434 methanylylidene group Chemical group [H]C#[*] 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 230000006911 nucleation Effects 0.000 description 1
- 238000010899 nucleation Methods 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 239000011368 organic material Substances 0.000 description 1
- 238000005192 partition Methods 0.000 description 1
- 150000002978 peroxides Chemical class 0.000 description 1
- 239000012071 phase Substances 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229940080264 sodium dodecylbenzenesulfonate Drugs 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 238000009987 spinning Methods 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/12—Polymerisation in non-solvents
- C08F2/16—Aqueous medium
- C08F2/22—Emulsion polymerisation
- C08F2/24—Emulsion polymerisation with the aid of emulsifying agents
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Polymerisation Methods In General (AREA)
- Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| NO783717 | 1978-11-06 | ||
| NO783717A NO145164C (no) | 1978-11-06 | 1978-11-06 | Fremgangsmaate for fremstilling av polymerlateks. |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| FI793467A7 FI793467A7 (fi) | 1980-05-07 |
| FI68845B FI68845B (fi) | 1985-07-31 |
| FI68845C true FI68845C (fi) | 1985-11-11 |
Family
ID=19884523
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| FI793467A FI68845C (fi) | 1978-11-06 | 1979-11-05 | Foerfarande foer framstaellning av polymerlatex |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US4563510A (OSRAM) |
| EP (1) | EP0010986B2 (OSRAM) |
| JP (2) | JPS5573701A (OSRAM) |
| DE (1) | DE2966375D1 (OSRAM) |
| DK (1) | DK160206C (OSRAM) |
| FI (1) | FI68845C (OSRAM) |
| NO (1) | NO145164C (OSRAM) |
Families Citing this family (39)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4524199A (en) * | 1983-11-09 | 1985-06-18 | Xerox Corporation | Stable polymeric dispersion and methods for making |
| US4613559A (en) * | 1985-04-01 | 1986-09-23 | Xerox Corporation | Process for colored toner compositions with controlled charges thereon |
| US4652508A (en) * | 1985-04-11 | 1987-03-24 | Xerox Corporation | Toner compositions with stabilizer irreversibly anchored thereto |
| US6013531A (en) * | 1987-10-26 | 2000-01-11 | Dade International Inc. | Method to use fluorescent magnetic polymer particles as markers in an immunoassay |
| US5162280A (en) * | 1988-01-27 | 1992-11-10 | Witco Corporation | Aqueous dispersions of aromatic diacyl peroxides |
| US5057479A (en) * | 1990-05-09 | 1991-10-15 | Witco Corporation | Aqueous dispersions of aromatic diacyl peroxides |
| JPH04146U (OSRAM) * | 1990-04-11 | 1992-01-06 | ||
| GB9019650D0 (en) | 1990-09-07 | 1990-10-24 | Nycomed As | Chemical compounds |
| AT398973B (de) * | 1992-11-18 | 1995-02-27 | Bonn Guenther Dr | Verfahren zur trennung von nukleinsäuren |
| US6066258A (en) * | 1997-12-05 | 2000-05-23 | Transgenomic, Inc. | Polynucleotide separations on polymeric separation media |
| US6355791B1 (en) | 1995-11-13 | 2002-03-12 | Transgenomic, Inc. | Polynucleotide separations on polymeric separation media |
| US5772889A (en) * | 1995-11-13 | 1998-06-30 | Transgenomic, Inc. | System and method for performing nucleic acid separations using liquid chromatography |
| NO302370B1 (no) * | 1996-07-18 | 1998-02-23 | Nyfotek As | Fremgangsmåte for fremstilling av en vandig emulsjon med snever dråpestörrelsesfordeling, og anvendelse av en slik emulsjon for fremstilling av en polymerdispersjon |
| US6030527A (en) * | 1996-11-13 | 2000-02-29 | Transgenomic, Inc. | Apparatus for performing polynucleotide separations using liquid chromatography |
| US7138518B1 (en) | 1996-11-13 | 2006-11-21 | Transgenomic, Inc. | Liquid chromatographic separation of polynucleotides |
| US6174441B1 (en) | 1996-11-13 | 2001-01-16 | Transgenomic, Inc. | Method for performing polynucleotide separations using liquid chromatography |
| US6482317B2 (en) | 1996-11-13 | 2002-11-19 | Transgenomic, Inc. | Polynucleotide separations on polymeric separation media |
| US5997742A (en) * | 1996-11-13 | 1999-12-07 | Transgenomic, Inc. | Method for performing polynucleotide separations using liquid chromatography |
| US6576133B2 (en) | 1996-11-13 | 2003-06-10 | Transgenomic, Inc | Method and system for RNA analysis by matched ion polynucleotide chromatography |
| US6372142B1 (en) | 1996-11-13 | 2002-04-16 | Transgenomic, Inc. | Column for DNA separation by matched ion polynucleotide chromatography |
| US6017457A (en) * | 1996-11-13 | 2000-01-25 | Transgenomic, Inc. | Method for performing polynucleotide separations using liquid chromatography |
| US6471866B1 (en) | 1996-11-13 | 2002-10-29 | Transgenomic, Inc. | Process for performing polynucleotide separations |
| US5972222A (en) * | 1996-11-13 | 1999-10-26 | Transgenomic, Inc. | Process for performing polynucleotide separations |
| US6475388B1 (en) | 1996-11-13 | 2002-11-05 | Transgenomic, Inc. | Method and system for RNA analysis by matched ion polynucleotide chromatography |
| US6056877A (en) * | 1997-12-05 | 2000-05-02 | Transgenomic, Inc. | Non-polar media for polynucleotide separations |
| JP2000516638A (ja) | 1997-06-10 | 2000-12-12 | トランスジエノミツク・インコーポレーテツド | 液体クロマトグラフィーを使用するポリヌクレオチド分離を実施するための系および方法 |
| AU752932B2 (en) * | 1997-10-09 | 2002-10-03 | Transgenomic, Inc. | Modifying double stranded DNA to enhance separations by matched ion polynucleotide chromatography |
| US6503397B2 (en) * | 1997-12-05 | 2003-01-07 | Transgenomic, Inc. | Non-polar media for polynucleotide separations |
| US6258264B1 (en) | 1998-04-10 | 2001-07-10 | Transgenomic, Inc. | Non-polar media for polynucleotide separations |
| US6372130B1 (en) | 1997-12-05 | 2002-04-16 | Transgenomic, Inc. | Non-polar media for polynucleotide separations |
| US6485648B1 (en) | 1998-05-18 | 2002-11-26 | Transgenomic, Inc. | MIPC column cleaning system and process |
| ATE317855T1 (de) | 1999-12-27 | 2006-03-15 | Arkema | Herstellungsverfahren von einem latex mit hohem feststoffgehalt, mit einer niedrigen viskosität und eine einer bimodalen verteilung |
| EP1235852B1 (en) | 2000-01-26 | 2011-06-15 | TRANSGENOMIC, Inc. | Method for separating polynucleotides using monolithic capillary columns |
| US6521411B2 (en) | 2000-09-28 | 2003-02-18 | Transgenomic, Inc. | Method and system for the preparation of cDNA |
| US20040146855A1 (en) * | 2003-01-27 | 2004-07-29 | Marchessault Robert H. | Formation of superparamagnetic particles |
| KR100727218B1 (ko) * | 2004-02-05 | 2007-06-13 | 주식회사 엘지화학 | 액체 미니이멀젼을 시드 입자로 사용하는 시드유화중합방법 |
| DE102007001370A1 (de) | 2007-01-09 | 2008-07-10 | Curevac Gmbh | RNA-kodierte Antikörper |
| EP2230515B1 (en) * | 2009-03-16 | 2014-12-17 | Agilent Technologies, Inc. | Passivation of surfaces after ligand coupling |
| CN117364527B (zh) * | 2023-09-21 | 2024-12-20 | 江苏博汇纸业有限公司 | 一种涂布纸用高稳定性胶乳及其制备方法 |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2475016A (en) * | 1945-05-02 | 1949-07-05 | Shell Dev | Emulsion polymerization of vinylidene compounds |
| GB1492028A (en) * | 1974-01-23 | 1977-11-16 | Ici Ltd | Vinyl chloride polymerisation process |
| SE405255C (sv) * | 1975-07-01 | 1985-09-09 | Norsk Hydro As | Forfarande for framstellning av vinylkloridpolymerer genom emulsionspolymerisation i nervaro av alifatisk alkohol innehallande 14-24 kolatomer |
| CA1065540A (en) * | 1975-07-01 | 1979-10-30 | Bela K. Mikofalvy | Process for producing dispersion resins by homo or copolymerization of vinyl or vinylidene halides |
| NO139410C (no) | 1976-02-19 | 1979-03-07 | Sintef | Fremgangsmaate for fremstilling av lateks |
| NO140932C (no) | 1977-08-10 | 1979-12-12 | Sintef | Fremgangsmaate for fremstilling av lateks |
-
1978
- 1978-11-06 NO NO783717A patent/NO145164C/no unknown
-
1979
- 1979-11-05 FI FI793467A patent/FI68845C/fi not_active IP Right Cessation
- 1979-11-05 DE DE7979302443T patent/DE2966375D1/de not_active Expired
- 1979-11-05 DK DK468179A patent/DK160206C/da not_active IP Right Cessation
- 1979-11-05 JP JP14318479A patent/JPS5573701A/ja active Granted
- 1979-11-05 EP EP79302443A patent/EP0010986B2/en not_active Expired - Lifetime
-
1984
- 1984-01-25 US US06/573,605 patent/US4563510A/en not_active Expired - Lifetime
-
1987
- 1987-12-02 JP JP62305521A patent/JPS63152602A/ja active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| NO145164B (no) | 1981-10-19 |
| FI793467A7 (fi) | 1980-05-07 |
| JPH0440362B2 (OSRAM) | 1992-07-02 |
| EP0010986B1 (en) | 1983-11-02 |
| JPH0244842B2 (OSRAM) | 1990-10-05 |
| FI68845B (fi) | 1985-07-31 |
| NO145164C (no) | 1982-01-27 |
| EP0010986A1 (en) | 1980-05-14 |
| NO783717L (no) | 1980-05-07 |
| JPS5573701A (en) | 1980-06-03 |
| JPS63152602A (ja) | 1988-06-25 |
| DK160206B (da) | 1991-02-11 |
| US4563510A (en) | 1986-01-07 |
| DK468179A (da) | 1980-05-07 |
| EP0010986B2 (en) | 1990-08-29 |
| DE2966375D1 (en) | 1983-12-08 |
| DK160206C (da) | 1991-07-15 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MA | Patent expired |
Owner name: SINTEF |