FI63764C - Foerfarande foer polymerisation av alfa-olefiner och foer framstaellning i detsamma anvaendbart fast katalytiskt komplex - Google Patents

Foerfarande foer polymerisation av alfa-olefiner och foer framstaellning i detsamma anvaendbart fast katalytiskt komplex Download PDF

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Publication number
FI63764C
FI63764C FI781798A FI781798A FI63764C FI 63764 C FI63764 C FI 63764C FI 781798 A FI781798 A FI 781798A FI 781798 A FI781798 A FI 781798A FI 63764 C FI63764 C FI 63764C
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FI
Finland
Prior art keywords
compound
polymerization
organic
titanium
catalytic
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Application number
FI781798A
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English (en)
Finnish (fi)
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FI781798A (fi
FI63764B (fi
Inventor
Charles Bienfait
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Solvay
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Publication of FI63764B publication Critical patent/FI63764B/fi
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2410/00—Features related to the catalyst preparation, the catalyst use or to the deactivation of the catalyst
    • C08F2410/06—Catalyst characterized by its size
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/908—Containing catalyst of specified particle size

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Claims (10)

1. Förfarande för polymerisation av öC-olefiner, varvid polymerisationen utförs i närvaro av en aluminiumorganisk förening och ett sädant fast katalytiskt komplex, vilket framställs genom att omsätta med varandra: 1. minst en förening (M), vilken utgörs av en organisk syre-förening av magnesium innehällande endast bindningar magnesium-syre-organisk radikal, 2. minst en förening (T) , vilken utgörs av en organisk syre-förening av titan innehällande endastbindningar titan-syre-orga-nisk radikal och 3. minst en aluminiumhalogenid (A), kännetecknat därav, att (A) är en organoaluminiumklorid med den allmänna for-meln AlR^l^ , väri R är en förgrenad alkylradikal med 4-8 kol-atomer och n är ett sädant tai, a;tt 1 ^ n 4 1,5.
2. Förfarande enligt patentkravet 1, känne tecknat därav, att den förgrenade alkylradikalen utgörs av en isoradikal och n är 1.
3. Förfarande enligt patentkravet 1, 'känne tecknat därav, att organoaluminiumkloriden utgörs av isobutylaluminium-klorid.
4. Förfarande enligt nägot av patentkraven 1-3, kännetecknat därav, att föreningen (M) utgörs av en magnesium-dialkoxid och föreningen (T) utgörs av en titantetra-alkoxid
5. Förfarande enligt nägot av patentkraven 1-4, kännetecknat därav, att det fasta katalytiska komplexet fram-ställts genom att omsätta med varandra, förutom föreningen (M) , föreningen (T) och aluminiumhalogeniden (A), ytterligare en förening (Z) , vilken utgörs av en organisk syreförening av zirkonium eller en halogenförening av zirkonium.
6. Förfarande enligt nägot av patentkraven 1-5, kännetecknat därav, att det fasta katalytiska komplexet fram-ställts genom att tillsätta aluminiumhalogeniden (A) i slutskedet av framställningen.
7. Förfarande enligt nägot av patentkraven 1-6, kännetecknat därav, att reaktionmediet vid tillsats av organoaluminiumklorid har en temperatur av 30-65°C.
FI781798A 1977-06-06 1978-06-06 Foerfarande foer polymerisation av alfa-olefiner och foer framstaellning i detsamma anvaendbart fast katalytiskt komplex FI63764C (fi)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
LU77489 1977-06-06
LU77489A LU77489A1 (sv) 1977-06-06 1977-06-06

Publications (3)

Publication Number Publication Date
FI781798A FI781798A (fi) 1978-12-07
FI63764B FI63764B (fi) 1983-04-29
FI63764C true FI63764C (fi) 1983-08-10

Family

ID=19728598

Family Applications (1)

Application Number Title Priority Date Filing Date
FI781798A FI63764C (fi) 1977-06-06 1978-06-06 Foerfarande foer polymerisation av alfa-olefiner och foer framstaellning i detsamma anvaendbart fast katalytiskt komplex

Country Status (22)

Country Link
US (1) US4617360A (sv)
EP (1) EP0000007B2 (sv)
JP (2) JPS5825361B2 (sv)
AT (1) AT368173B (sv)
AU (1) AU518713B2 (sv)
BR (1) BR7803604A (sv)
CA (1) CA1120021A (sv)
DE (1) DE2860707D1 (sv)
DK (1) DK152738C (sv)
ES (1) ES470502A1 (sv)
FI (1) FI63764C (sv)
GR (1) GR63739B (sv)
IE (1) IE47195B1 (sv)
IT (1) IT1096378B (sv)
LU (1) LU77489A1 (sv)
MX (1) MX149219A (sv)
NO (1) NO151415C (sv)
NZ (1) NZ187308A (sv)
PH (1) PH16748A (sv)
PT (1) PT68131A (sv)
TR (1) TR21240A (sv)
ZA (1) ZA782810B (sv)

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LU77489A1 (sv) * 1977-06-06 1979-01-19
JPS5424966A (en) * 1977-07-26 1979-02-24 Kuwayama Shigeharu Fiber clay
JPS5478718A (en) * 1977-12-06 1979-06-23 Shigeharu Kuwayama Clay
FR2529208A1 (fr) * 1982-06-24 1983-12-30 Bp Chimie Sa Catalyseurs pour la polymerisation et la copolymerisation de l'ethylene et procedes de polymerisation utilisant ces catalyseurs
DE3366573D1 (en) * 1982-06-24 1986-11-06 Bp Chimie Sa Process for the polymerization and copolymerization of alpha-olefins in a fluidized bed
FR2529211B1 (fr) * 1982-06-24 1986-09-26 Bp Chimie Sa Procede pour la polymerisation et la copolymerisation des alpha-olefines en lit fluidise
EP0099772B2 (fr) * 1982-06-24 1991-11-13 BP Chimie Société Anonyme Catalyseurs pour la polymérisation et la copolymérisation de l'éthylène et procédés de polymérisation utilisant ces catalyseurs
US4526943A (en) * 1982-07-29 1985-07-02 The Dow Chemical Company Process for polymerizing olefins in the presence of a catalyst prepared from organomagnesium compound, organic hydroxyl-containing compound, reducing halide source and transition metal compound
US4529715A (en) * 1983-10-17 1985-07-16 The Dow Chemical Company Catalyst prepared from organomagnesium compound, carbon dioxide, reducing aluminum source, transition metal compound and zinc compound
US4544647A (en) * 1982-07-29 1985-10-01 The Dow Chemical Company Catalyst prepared from organomagnesium compound, organic hydroxyl-containing compound, reducing halide source and transition metal compound
CA1201705A (en) * 1982-08-05 1986-03-11 M. Bruce Welch Olefin polymerization
US4426316A (en) 1982-09-10 1984-01-17 The Dow Chemical Company Catalyst prepared from organomagnesium compound, organic hydroxyl-containing compound, reducing halide source and transition metal compound
US4604374A (en) * 1982-09-20 1986-08-05 The Dow Chemical Company Catalyst prepared from organomagnesium compound, epihalohydrin reducing halide source and transition metal compound
US4605715A (en) * 1982-09-20 1986-08-12 The Dow Chemical Company Process for polymerizing olefins in the presence of a catalyst prepared from organomagnesium compound, epihalohydrin reducing halide source and transition metal compound
US4456547A (en) * 1982-10-21 1984-06-26 Fuentes Jr Ricardo Catalyst prepared from organomagnesium compound, organic hydroxyl-containing compound, reducing halide source and complex formed from admixture of a transition metal compound and an organozinc compound
US4569975A (en) * 1984-03-19 1986-02-11 The Dow Chemical Company Polymerization of olefins in presence of a catalyst prepared from organomagnesium compound, carbon dioxide compound, reducing halide source and transition metal compound
US4783512A (en) * 1985-05-20 1988-11-08 The Dow Chemical Company Process for polymerizing olefins in the presence of a catalyst prepared from organomagnesium compound, organic hydroxyl-containing compound, reducing halide source and transition metal compound
US4661465A (en) * 1985-10-31 1987-04-28 The Dow Chemical Company Method for preparing transition metal component of Ziegler-Natta catalysts
JPH0721024B2 (ja) * 1986-03-04 1995-03-08 出光石油化学株式会社 エチレン重合体または共重合体の製造方法
JPH0717714B2 (ja) * 1986-06-25 1995-03-01 出光石油化学株式会社 直鎖状低密度ポリエチレンの製造方法
US5045612A (en) * 1990-04-18 1991-09-03 The Dow Chemical Company Catalyst and process for polymerizing olefins
US5114897A (en) * 1990-04-18 1992-05-19 The Dow Chemical Company Catalyst and process for polymerizing olefins
US6730627B1 (en) * 1991-07-12 2004-05-04 Ecp Enichem Polimeri S.R.L. Solid component of catalyst for the (co) polymerization of ethylene and α-olefins
IT1251462B (it) * 1991-07-12 1995-05-15 Enichem Polimeri Componente solido di catalizzatore per la (co)polimerizzazione dell'etilene e delle alfa olefine.
BE1005795A3 (fr) * 1992-05-13 1994-02-01 Solvay Procede de polymerisation d'olefines et (co)polymeres a blocs derives d'au moins une olefine.
BE1007040A3 (fr) 1993-05-25 1995-02-28 Solvay Support de catalyseur et catalyseur de polymerisation des alpha-olefines; procedes pour leur obtention et polymerisation des alpha-olefines en presence du catalyseur.
JP3319051B2 (ja) * 1993-07-28 2002-08-26 東ソー株式会社 ポリオレフィンの製造方法
US6001939A (en) * 1994-09-22 1999-12-14 Solvay Polyolefins Europe-Belgium Process for the polymerization of olefins
BE1011333A3 (fr) 1997-08-20 1999-07-06 Solvay Procede de fabrication d'une composition de polymeres d'ethylene.
EP1630178A1 (en) 2004-08-10 2006-03-01 Innovene Manufacturing Belgium NV Polymerisation process
AU2004323687B2 (en) * 2004-09-27 2011-08-18 Prysmian Cavi E Sistemi Energia S.R.L. Water-resistant optical cable and manufacturing method
EP1803011B1 (en) * 2004-09-27 2019-06-12 Prysmian S.p.A. Optical cable for communication
EP1820820A1 (en) 2006-02-15 2007-08-22 INEOS Manufacturing Belgium NV Polyethylene composition
US20090048402A1 (en) * 2007-08-17 2009-02-19 Lynch Michael W Preparing multimodal polyethylene having controlled long chain branching distribution
ES2434738T3 (es) 2009-01-23 2013-12-17 Evonik Degussa Gmbh Polimerización en fase gaseosa de una olefina con alqueno de C4-10 sustituido en 3
ES2401763T3 (es) 2009-01-23 2013-04-24 Evonik Oxeno Gmbh Película de PE-MIB preparada con ayuda de Zn/Cr
EP2410011A1 (en) 2010-07-23 2012-01-25 INEOS Manufacturing Belgium NV Polyethylene composition
WO2013156491A1 (en) 2012-04-19 2013-10-24 Ineos Europe Ag Catalyst for the polymerisation of olefins, process for its production and use
EP2855577B1 (en) 2012-05-30 2016-03-16 Ineos Europe AG Polymer composition for blow moulding
BR112014032628B1 (pt) 2012-06-26 2021-06-22 Ineos Europe Ag Película formada por uma composição de polietileno
CN103665207B (zh) * 2012-09-10 2016-03-30 中国石油化工股份有限公司 一种用于乙烯聚合反应的催化剂组分及其催化剂
CN110036043B (zh) * 2016-10-28 2021-09-28 Sabic环球技术有限责任公司 超高分子量聚乙烯的生产方法
WO2022136121A1 (en) 2020-12-22 2022-06-30 Ineos Europe Ag Polymer composition for caps and closures
CA3227522A1 (en) 2021-08-03 2023-02-09 Ineos Europe Ag Polyethylene film

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US3644318A (en) * 1968-08-21 1972-02-22 Hoechst Ag Process for the polymerization of olefins
NL136668C (sv) * 1969-01-24
FR2093306A6 (fr) * 1970-06-09 1972-01-28 Solvay Catalyseurs et procede perfectionnes pour la polymerisation et la copolymerisation des olefines
DE1929863A1 (de) * 1969-06-12 1970-12-17 Hoechst Ag Verfahren zur Polymerisation von Olefinen
BE791676A (fr) * 1971-12-08 1973-05-21 Solvay Procédé pour la polymérisation des oléfines
LU65587A1 (sv) * 1972-06-22 1973-12-27
US4071674A (en) * 1972-09-14 1978-01-31 Mitsui Petrochemical Industries Ltd. Process for polymerization or copolymerization of olefin and catalyst compositions used therefor
JPS5439876B2 (sv) * 1973-08-24 1979-11-30
IT1020055B (it) * 1973-09-08 1977-12-20 Solvay Polimerizzazione a bassa pressio ne di olefine
FR2252355B1 (sv) * 1973-11-22 1976-10-01 Solvay
JPS5719122B2 (sv) * 1973-12-26 1982-04-21
JPS5128189A (ja) * 1974-09-03 1976-03-09 Mitsui Petrochemical Ind Koketsushoseihoriorefuin no kokatsuseijugohoho
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LU77489A1 (sv) * 1977-06-06 1979-01-19

Also Published As

Publication number Publication date
ATA407378A (de) 1982-01-15
DK247178A (da) 1979-02-09
NZ187308A (en) 1979-10-25
NO151415C (no) 1985-04-10
DE2860707D1 (en) 1981-08-27
DK152738C (da) 1988-10-03
NO151415B (no) 1984-12-27
EP0000007A1 (fr) 1978-12-20
LU77489A1 (sv) 1979-01-19
ES470502A1 (es) 1979-01-01
MX149219A (es) 1983-09-27
FI781798A (fi) 1978-12-07
JPS5896613A (ja) 1983-06-08
AU3621978A (en) 1979-11-22
IE781124L (en) 1978-12-06
NO781953L (no) 1978-12-07
FI63764B (fi) 1983-04-29
PH16748A (en) 1984-02-10
PT68131A (fr) 1978-07-01
EP0000007B1 (fr) 1981-05-20
IE47195B1 (en) 1984-01-11
AT368173B (de) 1982-09-27
JPS543184A (en) 1979-01-11
JPS6351442B2 (sv) 1988-10-14
JPS5825361B2 (ja) 1983-05-27
IT7824261A0 (it) 1978-06-06
TR21240A (tr) 1984-02-07
GR63739B (en) 1979-12-04
IT1096378B (it) 1985-08-26
BR7803604A (pt) 1979-02-20
AU518713B2 (en) 1981-10-15
EP0000007B2 (fr) 1984-11-21
CA1120021A (fr) 1982-03-16
ZA782810B (en) 1979-05-30
US4617360A (en) 1986-10-14
DK152738B (da) 1988-05-02

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