FI58337C - Foerfarande foer avbrytande av vattenemulsionspolymerisationen av vinylklorid i en vattenemulsion - Google Patents
Foerfarande foer avbrytande av vattenemulsionspolymerisationen av vinylklorid i en vattenemulsion Download PDFInfo
- Publication number
- FI58337C FI58337C FI752484A FI752484A FI58337C FI 58337 C FI58337 C FI 58337C FI 752484 A FI752484 A FI 752484A FI 752484 A FI752484 A FI 752484A FI 58337 C FI58337 C FI 58337C
- Authority
- FI
- Finland
- Prior art keywords
- polymerization
- vinyl chloride
- hydroxyquinoline
- vinylklorid
- vattenemulsionspolymerisationen
- Prior art date
Links
- 238000006116 polymerization reaction Methods 0.000 description 30
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 23
- 239000005725 8-Hydroxyquinoline Substances 0.000 description 16
- 229960003540 oxyquinoline Drugs 0.000 description 16
- MCJGNVYPOGVAJF-UHFFFAOYSA-N quinolin-8-ol Chemical compound C1=CN=C2C(O)=CC=CC2=C1 MCJGNVYPOGVAJF-UHFFFAOYSA-N 0.000 description 16
- 238000006243 chemical reaction Methods 0.000 description 14
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 6
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 6
- 239000000839 emulsion Substances 0.000 description 6
- 238000000034 method Methods 0.000 description 6
- 239000000178 monomer Substances 0.000 description 6
- 229920000642 polymer Polymers 0.000 description 6
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 5
- 239000006185 dispersion Substances 0.000 description 5
- 150000002989 phenols Chemical class 0.000 description 4
- 238000003756 stirring Methods 0.000 description 4
- 229960001701 chloroform Drugs 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- 238000007720 emulsion polymerization reaction Methods 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- PLIKAWJENQZMHA-UHFFFAOYSA-N 4-aminophenol Chemical compound NC1=CC=C(O)C=C1 PLIKAWJENQZMHA-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 description 2
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 2
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 description 2
- 239000012736 aqueous medium Substances 0.000 description 2
- YCIMNLLNPGFGHC-UHFFFAOYSA-N catechol Chemical compound OC1=CC=CC=C1O YCIMNLLNPGFGHC-UHFFFAOYSA-N 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 238000011109 contamination Methods 0.000 description 2
- 238000004880 explosion Methods 0.000 description 2
- 239000003960 organic solvent Substances 0.000 description 2
- XESZUVZBAMCAEJ-UHFFFAOYSA-N 4-tert-butylcatechol Chemical compound CC(C)(C)C1=CC=C(O)C(O)=C1 XESZUVZBAMCAEJ-UHFFFAOYSA-N 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
- LUTSRLYCMSCGCS-BWOMAWGNSA-N [(3s,8r,9s,10r,13s)-10,13-dimethyl-17-oxo-1,2,3,4,7,8,9,11,12,16-decahydrocyclopenta[a]phenanthren-3-yl] acetate Chemical compound C([C@@H]12)C[C@]3(C)C(=O)CC=C3[C@@H]1CC=C1[C@]2(C)CC[C@H](OC(=O)C)C1 LUTSRLYCMSCGCS-BWOMAWGNSA-N 0.000 description 1
- 230000001133 acceleration Effects 0.000 description 1
- 229910001870 ammonium persulfate Inorganic materials 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000007334 copolymerization reaction Methods 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 238000002845 discoloration Methods 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 239000012153 distilled water Substances 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 239000012744 reinforcing agent Substances 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- RYYKJJJTJZKILX-UHFFFAOYSA-M sodium octadecanoate Chemical compound [Na+].CCCCCCCCCCCCCCCCCC([O-])=O RYYKJJJTJZKILX-UHFFFAOYSA-M 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F14/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
- C08F14/02—Monomers containing chlorine
- C08F14/04—Monomers containing two carbon atoms
- C08F14/06—Vinyl chloride
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Polymerisation Methods In General (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR7435507A FR2288109A1 (fr) | 1974-10-18 | 1974-10-18 | Procede pour arreter la polymerisation du chlorure de vinyle en dispersion aqueuse |
| FR7435507 | 1974-10-18 |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| FI752484A7 FI752484A7 (en:Method) | 1976-04-19 |
| FI58337B FI58337B (fi) | 1980-09-30 |
| FI58337C true FI58337C (fi) | 1981-01-12 |
Family
ID=9144371
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| FI752484A FI58337C (fi) | 1974-10-18 | 1975-09-04 | Foerfarande foer avbrytande av vattenemulsionspolymerisationen av vinylklorid i en vattenemulsion |
Country Status (17)
| Country | Link |
|---|---|
| US (1) | US3985721A (en:Method) |
| JP (1) | JPS5161591A (en:Method) |
| AR (1) | AR205482A1 (en:Method) |
| AT (1) | AT342866B (en:Method) |
| BE (1) | BE834603A (en:Method) |
| BR (1) | BR7506341A (en:Method) |
| CH (1) | CH608506A5 (en:Method) |
| DE (1) | DE2539430C2 (en:Method) |
| ES (1) | ES441875A1 (en:Method) |
| FI (1) | FI58337C (en:Method) |
| FR (1) | FR2288109A1 (en:Method) |
| GB (1) | GB1496808A (en:Method) |
| IT (1) | IT1042102B (en:Method) |
| NL (1) | NL180938C (en:Method) |
| NO (1) | NO141263C (en:Method) |
| SE (1) | SE409720B (en:Method) |
| ZA (1) | ZA755316B (en:Method) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1583376A (en) * | 1977-04-19 | 1981-01-28 | Ici Ltd | Method of treating suspensions of vinyl chloride/vinyl acetate copolymers |
| US4283514A (en) * | 1978-12-14 | 1981-08-11 | Conoco, Inc. | Chemicals for termination of polyvinylchloride polymerizations |
| US4401798A (en) * | 1982-04-22 | 1983-08-30 | Tenneco Polymers, Inc. | Process for the production of vinyl halide polymers that uses an alkyl-substituted trisphenol as the chain-terminating agent |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2616882A (en) * | 1951-07-10 | 1952-11-04 | Us Rubber Co | Shortstopping vinyl chloride polymerizations with vinyl pyridines |
| NL131752C (en:Method) * | 1960-09-08 | |||
| US3766159A (en) * | 1970-06-11 | 1973-10-16 | Shinetsu Chemical Co | Method for controlling the reaction rate in the suspension polymerization of vinyl chloride |
-
1974
- 1974-10-18 FR FR7435507A patent/FR2288109A1/fr active Granted
-
1975
- 1975-01-01 AR AR260580A patent/AR205482A1/es active
- 1975-08-19 ZA ZA00755316A patent/ZA755316B/xx unknown
- 1975-08-26 US US05/607,958 patent/US3985721A/en not_active Expired - Lifetime
- 1975-08-27 IT IT26644/75A patent/IT1042102B/it active
- 1975-09-04 DE DE2539430A patent/DE2539430C2/de not_active Expired
- 1975-09-04 FI FI752484A patent/FI58337C/fi not_active IP Right Cessation
- 1975-09-23 NO NO753240A patent/NO141263C/no unknown
- 1975-09-29 JP JP50116537A patent/JPS5161591A/ja active Pending
- 1975-09-30 BR BR7506341*A patent/BR7506341A/pt unknown
- 1975-10-06 GB GB40864/75A patent/GB1496808A/en not_active Expired
- 1975-10-09 NL NLAANVRAGE7511884,A patent/NL180938C/xx not_active IP Right Cessation
- 1975-10-16 SE SE7511617A patent/SE409720B/xx not_active IP Right Cessation
- 1975-10-17 AT AT792675A patent/AT342866B/de not_active IP Right Cessation
- 1975-10-17 CH CH1352075A patent/CH608506A5/xx not_active IP Right Cessation
- 1975-10-17 ES ES441875A patent/ES441875A1/es not_active Expired
- 1975-10-17 BE BE161015A patent/BE834603A/xx not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| ZA755316B (en) | 1976-07-28 |
| SE409720B (sv) | 1979-09-03 |
| FI58337B (fi) | 1980-09-30 |
| DE2539430C2 (de) | 1985-05-23 |
| FR2288109A1 (fr) | 1976-05-14 |
| BE834603A (fr) | 1976-04-20 |
| FR2288109B1 (en:Method) | 1977-03-18 |
| DE2539430A1 (de) | 1976-04-29 |
| BR7506341A (pt) | 1976-08-17 |
| AR205482A1 (es) | 1976-05-07 |
| NL180938B (nl) | 1986-12-16 |
| NO753240L (en:Method) | 1976-04-21 |
| FI752484A7 (en:Method) | 1976-04-19 |
| NO141263B (no) | 1979-10-29 |
| AT342866B (de) | 1978-04-25 |
| NL7511884A (nl) | 1976-04-21 |
| GB1496808A (en) | 1978-01-05 |
| JPS5161591A (en:Method) | 1976-05-28 |
| CH608506A5 (en:Method) | 1979-01-15 |
| US3985721A (en) | 1976-10-12 |
| IT1042102B (it) | 1980-01-30 |
| ATA792675A (de) | 1977-08-15 |
| ES441875A1 (es) | 1977-04-01 |
| SE7511617L (sv) | 1976-04-20 |
| NO141263C (no) | 1980-02-06 |
| NL180938C (nl) | 1987-05-18 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MM | Patent lapsed |
Owner name: SOLVAY & CIE |