FI57766C - Foerfarande foer homopolymerisering och sampolymerisering av etylen samt vid foerfarande anvaend katalysator - Google Patents
Foerfarande foer homopolymerisering och sampolymerisering av etylen samt vid foerfarande anvaend katalysator Download PDFInfo
- Publication number
- FI57766C FI57766C FI346/72A FI34672A FI57766C FI 57766 C FI57766 C FI 57766C FI 346/72 A FI346/72 A FI 346/72A FI 34672 A FI34672 A FI 34672A FI 57766 C FI57766 C FI 57766C
- Authority
- FI
- Finland
- Prior art keywords
- oxygen
- foerfarande
- solid support
- compound
- nitrogen
- Prior art date
Links
- 101100148710 Clarkia breweri SAMT gene Proteins 0.000 title 1
- -1 halogen derivative of titanium Chemical class 0.000 claims description 37
- 239000003054 catalyst Substances 0.000 claims description 33
- 239000010936 titanium Substances 0.000 claims description 23
- 229910052736 halogen Inorganic materials 0.000 claims description 22
- 239000007787 solid Substances 0.000 claims description 19
- 238000000034 method Methods 0.000 claims description 18
- 229910052719 titanium Inorganic materials 0.000 claims description 14
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 11
- 239000005977 Ethylene Substances 0.000 claims description 11
- 150000001875 compounds Chemical class 0.000 claims description 9
- 229910052751 metal Inorganic materials 0.000 claims description 8
- 239000002184 metal Substances 0.000 claims description 8
- OLBVUFHMDRJKTK-UHFFFAOYSA-N [N].[O] Chemical compound [N].[O] OLBVUFHMDRJKTK-UHFFFAOYSA-N 0.000 claims description 7
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 7
- 229910017464 nitrogen compound Inorganic materials 0.000 claims description 5
- 230000003213 activating effect Effects 0.000 claims description 4
- 239000007795 chemical reaction product Substances 0.000 claims description 4
- 125000002734 organomagnesium group Chemical group 0.000 claims description 4
- 150000002927 oxygen compounds Chemical class 0.000 claims description 3
- 150000003839 salts Chemical group 0.000 claims description 3
- NEAQRZUHTPSBBM-UHFFFAOYSA-N 2-hydroxy-3,3-dimethyl-7-nitro-4h-isoquinolin-1-one Chemical compound C1=C([N+]([O-])=O)C=C2C(=O)N(O)C(C)(C)CC2=C1 NEAQRZUHTPSBBM-UHFFFAOYSA-N 0.000 claims description 2
- 239000002253 acid Substances 0.000 claims 1
- 239000004698 Polyethylene Substances 0.000 description 21
- 229920000573 polyethylene Polymers 0.000 description 21
- 150000002367 halogens Chemical class 0.000 description 18
- 239000011777 magnesium Substances 0.000 description 14
- 238000006116 polymerization reaction Methods 0.000 description 14
- 229910052782 aluminium Inorganic materials 0.000 description 13
- 239000000460 chlorine Substances 0.000 description 13
- 238000006243 chemical reaction Methods 0.000 description 12
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 12
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 11
- 125000004432 carbon atom Chemical group C* 0.000 description 11
- 229910052749 magnesium Inorganic materials 0.000 description 11
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical group [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 10
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 8
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 6
- 239000002904 solvent Substances 0.000 description 6
- 239000003085 diluting agent Substances 0.000 description 5
- 239000007788 liquid Substances 0.000 description 5
- 229920000642 polymer Polymers 0.000 description 5
- 239000000243 solution Substances 0.000 description 5
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 4
- 229910052801 chlorine Inorganic materials 0.000 description 4
- 238000007334 copolymerization reaction Methods 0.000 description 4
- 238000000921 elemental analysis Methods 0.000 description 4
- 239000000725 suspension Substances 0.000 description 4
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 3
- 150000001993 dienes Chemical class 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 239000007789 gas Substances 0.000 description 3
- 230000005484 gravity Effects 0.000 description 3
- 230000026030 halogenation Effects 0.000 description 3
- 238000005658 halogenation reaction Methods 0.000 description 3
- 229930195733 hydrocarbon Natural products 0.000 description 3
- 150000002430 hydrocarbons Chemical class 0.000 description 3
- 239000000155 melt Substances 0.000 description 3
- OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 3
- 229910052757 nitrogen Inorganic materials 0.000 description 3
- 150000002902 organometallic compounds Chemical class 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- 150000003254 radicals Chemical class 0.000 description 3
- 229910052723 transition metal Inorganic materials 0.000 description 3
- 150000003624 transition metals Chemical class 0.000 description 3
- PTPLXVHPKMTVIW-FPLPWBNLSA-N (Z)-hydroxyimino-oxido-phenylazanium Chemical class O\N=[N+](/[O-])c1ccccc1 PTPLXVHPKMTVIW-FPLPWBNLSA-N 0.000 description 2
- UWNADWZGEHDQAB-UHFFFAOYSA-N 2,5-dimethylhexane Chemical group CC(C)CCC(C)C UWNADWZGEHDQAB-UHFFFAOYSA-N 0.000 description 2
- 239000004215 Carbon black (E152) Substances 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 2
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 2
- 150000001336 alkenes Chemical class 0.000 description 2
- 150000004703 alkoxides Chemical class 0.000 description 2
- 125000000217 alkyl group Chemical group 0.000 description 2
- 125000004429 atom Chemical group 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical group [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 239000006227 byproduct Substances 0.000 description 2
- 150000001723 carbon free-radicals Chemical class 0.000 description 2
- 229920001519 homopolymer Polymers 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- UAEPNZWRGJTJPN-UHFFFAOYSA-N methylcyclohexane Chemical compound CC1CCCCC1 UAEPNZWRGJTJPN-UHFFFAOYSA-N 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 229920000098 polyolefin Polymers 0.000 description 2
- 238000000746 purification Methods 0.000 description 2
- 239000007858 starting material Substances 0.000 description 2
- 150000003608 titanium Chemical class 0.000 description 2
- 229920002554 vinyl polymer Polymers 0.000 description 2
- XTBYRVXNZACGQT-UHFFFAOYSA-N 1-bromo-2-ethynyl-4,5-dimethoxybenzene Chemical group COC1=CC(Br)=C(C#C)C=C1OC XTBYRVXNZACGQT-UHFFFAOYSA-N 0.000 description 1
- HECLRDQVFMWTQS-RGOKHQFPSA-N 1755-01-7 Chemical compound C1[C@H]2[C@@H]3CC=C[C@@H]3[C@@H]1C=C2 HECLRDQVFMWTQS-RGOKHQFPSA-N 0.000 description 1
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 1
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- AVXURJPOCDRRFD-UHFFFAOYSA-N Hydroxylamine Chemical class ON AVXURJPOCDRRFD-UHFFFAOYSA-N 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- RUWYNYYXYMKWPZ-UHFFFAOYSA-N [N].[O].[Mg] Chemical class [N].[O].[Mg] RUWYNYYXYMKWPZ-UHFFFAOYSA-N 0.000 description 1
- 239000012190 activator Substances 0.000 description 1
- 125000002252 acyl group Chemical group 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 125000003342 alkenyl group Chemical group 0.000 description 1
- 125000002877 alkyl aryl group Chemical group 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 125000003710 aryl alkyl group Chemical group 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- GXCSNALCLRPEAS-CFYXSCKTSA-N azane (Z)-hydroxyimino-oxido-phenylazanium Chemical compound N.O\N=[N+](/[O-])c1ccccc1 GXCSNALCLRPEAS-CFYXSCKTSA-N 0.000 description 1
- 238000000071 blow moulding Methods 0.000 description 1
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 1
- 229910052794 bromium Inorganic materials 0.000 description 1
- 239000001273 butane Substances 0.000 description 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 150000001804 chlorine Chemical class 0.000 description 1
- 238000000748 compression moulding Methods 0.000 description 1
- 238000010924 continuous production Methods 0.000 description 1
- 125000004122 cyclic group Chemical group 0.000 description 1
- 125000000753 cycloalkyl group Chemical group 0.000 description 1
- 125000004177 diethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 150000004820 halides Chemical class 0.000 description 1
- 125000005843 halogen group Chemical group 0.000 description 1
- 150000004678 hydrides Chemical class 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 229910000039 hydrogen halide Inorganic materials 0.000 description 1
- 239000012433 hydrogen halide Substances 0.000 description 1
- 230000008676 import Effects 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 238000001746 injection moulding Methods 0.000 description 1
- 159000000003 magnesium salts Chemical class 0.000 description 1
- 150000002736 metal compounds Chemical class 0.000 description 1
- GYNNXHKOJHMOHS-UHFFFAOYSA-N methyl-cycloheptane Natural products CC1CCCCCC1 GYNNXHKOJHMOHS-UHFFFAOYSA-N 0.000 description 1
- 239000003607 modifier Substances 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 1
- SJYNFBVQFBRSIB-UHFFFAOYSA-N norbornadiene Chemical compound C1=CC2C=CC1C2 SJYNFBVQFBRSIB-UHFFFAOYSA-N 0.000 description 1
- 150000002899 organoaluminium compounds Chemical class 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 230000000737 periodic effect Effects 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- 230000000379 polymerizing effect Effects 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- JLTRXTDYQLMHGR-UHFFFAOYSA-N trimethylaluminium Chemical group C[Al](C)C JLTRXTDYQLMHGR-UHFFFAOYSA-N 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2410/00—Features related to the catalyst preparation, the catalyst use or to the deactivation of the catalyst
- C08F2410/04—Dual catalyst, i.e. use of two different catalysts, where none of the catalysts is a metallocene
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR7105656A FR2125740A6 (fr) | 1966-10-21 | 1971-02-18 | Procede de polymerisation et copolymerisation d'olefines |
| FR7105656 | 1971-02-18 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| FI57766B FI57766B (fi) | 1980-06-30 |
| FI57766C true FI57766C (fi) | 1980-10-10 |
Family
ID=9072145
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| FI346/72A FI57766C (fi) | 1971-02-18 | 1972-02-08 | Foerfarande foer homopolymerisering och sampolymerisering av etylen samt vid foerfarande anvaend katalysator |
Country Status (16)
| Country | Link |
|---|---|
| JP (1) | JPS5835601B2 (enExample) |
| AU (1) | AU454535B2 (enExample) |
| BE (1) | BE778966R (enExample) |
| BG (1) | BG20612A3 (enExample) |
| BR (1) | BR7200908D0 (enExample) |
| CA (1) | CA1006648A (enExample) |
| CH (1) | CH549410A (enExample) |
| DD (1) | DD96487A6 (enExample) |
| DE (1) | DE2205102A1 (enExample) |
| ES (1) | ES399622A2 (enExample) |
| FI (1) | FI57766C (enExample) |
| GB (1) | GB1328067A (enExample) |
| HU (1) | HU165743B (enExample) |
| IT (1) | IT998050B (enExample) |
| NL (1) | NL168849C (enExample) |
| ZA (1) | ZA72392B (enExample) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BE786467R (fr) * | 1971-07-21 | 1973-01-19 | Solvay | Procede pour la polymerisation et la copolymerisation des |
| US4587220A (en) * | 1983-03-28 | 1986-05-06 | Miles Laboratories, Inc. | Ascorbate interference-resistant composition, device and method for the determination of peroxidatively active substances |
-
1972
- 1972-01-17 CH CH64372A patent/CH549410A/fr not_active IP Right Cessation
- 1972-01-20 ZA ZA720392A patent/ZA72392B/xx unknown
- 1972-01-25 IT IT19798/72A patent/IT998050B/it active
- 1972-02-03 DE DE19722205102 patent/DE2205102A1/de not_active Ceased
- 1972-02-03 NL NLAANVRAGE7201421,A patent/NL168849C/xx active Search and Examination
- 1972-02-03 AU AU38609/72A patent/AU454535B2/en not_active Expired
- 1972-02-04 BE BE778966A patent/BE778966R/xx active
- 1972-02-08 FI FI346/72A patent/FI57766C/fi active
- 1972-02-10 ES ES399622A patent/ES399622A2/es not_active Expired
- 1972-02-11 BG BG019700A patent/BG20612A3/xx unknown
- 1972-02-17 CA CA134,984A patent/CA1006648A/en not_active Expired
- 1972-02-17 DD DD160931A patent/DD96487A6/xx unknown
- 1972-02-18 BR BR908/72A patent/BR7200908D0/pt unknown
- 1972-02-18 GB GB760672A patent/GB1328067A/en not_active Expired
- 1972-02-18 HU HUSO1037A patent/HU165743B/hu unknown
-
1979
- 1979-02-15 JP JP54015551A patent/JPS5835601B2/ja not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| GB1328067A (en) | 1973-08-30 |
| JPS55757A (en) | 1980-01-07 |
| DD96487A6 (enExample) | 1973-03-20 |
| ZA72392B (en) | 1972-09-27 |
| ES399622A2 (es) | 1974-11-16 |
| HU165743B (enExample) | 1974-10-28 |
| NL168849B (nl) | 1981-12-16 |
| CH549410A (fr) | 1974-05-31 |
| BE778966R (fr) | 1972-08-04 |
| FI57766B (fi) | 1980-06-30 |
| AU3860972A (en) | 1973-08-09 |
| CA1006648A (en) | 1977-03-08 |
| BG20612A3 (bg) | 1975-12-05 |
| NL168849C (nl) | 1982-05-17 |
| BR7200908D0 (pt) | 1973-05-31 |
| JPS5835601B2 (ja) | 1983-08-03 |
| IT998050B (it) | 1976-01-20 |
| AU454535B2 (en) | 1974-10-16 |
| DE2205102A1 (de) | 1972-08-31 |
| NL7201421A (enExample) | 1972-08-22 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| FI58928C (fi) | Foerfarande och katalysatorsystem foer laogtryckspolymerisering av eten enbart eller tillsammans med en alfa-olefin med 3-6 kolatomer | |
| US4542199A (en) | Process for the preparation of polyolefins | |
| RU2143440C1 (ru) | Способ получения высокомолекулярного порошкообразного полиэтилена | |
| US4617360A (en) | Process for the polymerization of α-olefins | |
| US5122583A (en) | Efficiency of a pre-polymerized catalyst | |
| FI81815C (fi) | Foerfarande foer polymerisering eller kopolymerisering av alfa-olefiner i en fluidiserad baedd under naervaro av ett ziegler-natta-katalysatorsystem. | |
| US20150038647A1 (en) | Telechelic polyolefin and preparation thereof | |
| HU204291B (en) | Process for producing polymerizing catalyst component on carrier and polymerizing process | |
| US4021599A (en) | Olefin polymerization process and catalyst | |
| US4105585A (en) | Polymerization catalyst | |
| KR920003228B1 (ko) | 올레핀 중합시 촉매 생산성의 향상법 | |
| JP2001270909A (ja) | オレフィンのチーグラ−ナッタ重合触媒系 | |
| US4537870A (en) | Polyolefin polymerization process and catalyst | |
| RU2066240C1 (ru) | Сокаталитическая композиция для полимеризации альфа-олефинов, каталитическая система на ее основе и способ полимеризации альфа-олефинов | |
| US3847957A (en) | Chromyl bis-(triorganotitanates)and related compounds | |
| US3131171A (en) | Catalyst for the polymerization of olefins containing the product of a titanium halide and an organoaluminum compound mixed with a lower alkyl halide solution of aluminum chloride | |
| US5334568A (en) | Catalytic solid for use in the polymerization of alpha-olefines, process for preparing it and process for the polymerization of alpha-olefines in the presence of a catalyst system containing this solid | |
| FI57766C (fi) | Foerfarande foer homopolymerisering och sampolymerisering av etylen samt vid foerfarande anvaend katalysator | |
| CA1167829A (en) | Process for the preparation of supported catalysts for the polymerization of olefins | |
| JPH05502053A (ja) | 球形粒子を有するポリオレフィンの製法 | |
| US3984389A (en) | Process for the polymerization of olefins and catalytic products | |
| US4167493A (en) | High efficiency catalyst for high bulk density polyethylene | |
| US3989879A (en) | Process and catalysts for the polymerization and copolymerization of olefins | |
| AU658984B2 (en) | Process for the preparation of a spherical catalyst component | |
| KR20020091051A (ko) | 활성의 불균일 지지된 비덴테이트 또는 트리덴테이트계의올레핀 중합 촉매 |