FI20155285A - Menetelmä furaanikarboksylaattien valmistamiseksi aldaarihapoista käyttämällä kiinteää heterogeenista katalyyttiä - Google Patents

Menetelmä furaanikarboksylaattien valmistamiseksi aldaarihapoista käyttämällä kiinteää heterogeenista katalyyttiä Download PDF

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Publication number
FI20155285A
FI20155285A FI20155285A FI20155285A FI20155285A FI 20155285 A FI20155285 A FI 20155285A FI 20155285 A FI20155285 A FI 20155285A FI 20155285 A FI20155285 A FI 20155285A FI 20155285 A FI20155285 A FI 20155285A
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FI
Finland
Prior art keywords
age
acids
preparation
heterogeneous catalyst
solid heterogeneous
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FI20155285A
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English (en)
Swedish (sv)
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FI126387B (fi
Inventor
Martta Asikainen
David Thomas
Ali Harlin
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Teknologian Tutkimuskeskus Vtt Oy
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Application filed by Teknologian Tutkimuskeskus Vtt Oy filed Critical Teknologian Tutkimuskeskus Vtt Oy
Priority to FI20155285A priority Critical patent/FI126387B/fi
Priority to US15/566,759 priority patent/US10301276B2/en
Priority to PCT/FI2016/050254 priority patent/WO2016166421A1/en
Priority to EP16779667.1A priority patent/EP3283471B1/en
Publication of FI20155285A publication Critical patent/FI20155285A/fi
Application granted granted Critical
Publication of FI126387B publication Critical patent/FI126387B/fi

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    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D307/00Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
    • C07D307/02Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings
    • C07D307/34Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
    • C07D307/56Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D307/68Carbon atoms having three bonds to hetero atoms with at the most one bond to halogen
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/02Boron or aluminium; Oxides or hydroxides thereof
    • B01J21/04Alumina
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/066Zirconium or hafnium; Oxides or hydroxides thereof
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/08Silica
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00Catalysts comprising molecular sieves
    • B01J29/03Catalysts comprising molecular sieves not having base-exchange properties
    • B01J29/0308Mesoporous materials not having base exchange properties, e.g. Si-MCM-41
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0215Sulfur-containing compounds
    • B01J31/0225Sulfur-containing compounds comprising sulfonic acid groups or the corresponding salts
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/06Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing polymers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02Impregnation, coating or precipitation
    • B01J37/0201Impregnation
    • B01J37/0203Impregnation the impregnation liquid containing organic compounds
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07HSUGARS; DERIVATIVES THEREOF; NUCLEOSIDES; NUCLEOTIDES; NUCLEIC ACIDS
    • C07H3/00Compounds containing only hydrogen atoms and saccharide radicals having only carbon, hydrogen, and oxygen atoms
    • C07H3/02Monosaccharides
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/02Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
    • C08G63/12Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from polycarboxylic acids and polyhydroxy compounds
    • C08G63/16Dicarboxylic acids and dihydroxy compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/02Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
    • C08G63/12Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from polycarboxylic acids and polyhydroxy compounds
    • C08G63/16Dicarboxylic acids and dihydroxy compounds
    • C08G63/18Dicarboxylic acids and dihydroxy compounds the acids or hydroxy compounds containing carbocyclic rings
    • C08G63/181Acids containing aromatic rings
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/66Polyesters containing oxygen in the form of ether groups
    • C08G63/668Polyesters containing oxygen in the form of ether groups derived from polycarboxylic acids and polyhydroxy compounds
    • C08G63/672Dicarboxylic acids and dihydroxy compounds
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30After treatment, characterised by the means used
    • B01J2229/32Reaction with silicon compounds, e.g. TEOS, siliconfluoride

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Dispersion Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Biotechnology (AREA)
  • General Health & Medical Sciences (AREA)
  • Genetics & Genomics (AREA)
  • Molecular Biology (AREA)
  • Biochemistry (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Furan Compounds (AREA)
FI20155285A 2015-04-17 2015-04-17 Menetelmä furaanikarboksylaattien valmistamiseksi aldaarihapoista käyttämällä kiinteää heterogeenista katalyyttiä FI126387B (fi)

Priority Applications (4)

Application Number Priority Date Filing Date Title
FI20155285A FI126387B (fi) 2015-04-17 2015-04-17 Menetelmä furaanikarboksylaattien valmistamiseksi aldaarihapoista käyttämällä kiinteää heterogeenista katalyyttiä
US15/566,759 US10301276B2 (en) 2015-04-17 2016-04-18 Method of producing furan carboxylates from aldaric acids by using solid heterogeneous catalyst
PCT/FI2016/050254 WO2016166421A1 (en) 2015-04-17 2016-04-18 Method of producing furan carboxylates from aldaric acids by using solid heterogeneous catalysts
EP16779667.1A EP3283471B1 (en) 2015-04-17 2016-04-18 Method of producing furan carboxylates from aldaric acids by using solid heterogeneous catalysts

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FI20155285A FI126387B (fi) 2015-04-17 2015-04-17 Menetelmä furaanikarboksylaattien valmistamiseksi aldaarihapoista käyttämällä kiinteää heterogeenista katalyyttiä

Publications (2)

Publication Number Publication Date
FI20155285A true FI20155285A (fi) 2016-10-18
FI126387B FI126387B (fi) 2016-11-15

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FI20155285A FI126387B (fi) 2015-04-17 2015-04-17 Menetelmä furaanikarboksylaattien valmistamiseksi aldaarihapoista käyttämällä kiinteää heterogeenista katalyyttiä

Country Status (4)

Country Link
US (1) US10301276B2 (fi)
EP (1) EP3283471B1 (fi)
FI (1) FI126387B (fi)
WO (1) WO2016166421A1 (fi)

Families Citing this family (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2017083297A1 (en) * 2015-11-11 2017-05-18 Bp Corporation North America Inc. Acids-catalyzed dehydration of glucaric acid to 2,5-furandicarboxylic acid (fdca)
SG11201805514VA (en) 2016-01-13 2018-07-30 Stora Enso Oyj Processes for the preparation of 2,5-furandicarboxylic acid and intermediates and derivatives thereof
JP6970909B2 (ja) * 2017-05-26 2021-11-24 大日本印刷株式会社 多層容器およびその製造方法
US11078174B2 (en) 2017-06-22 2021-08-03 Archer Daniels Midland Company Process for making esters of 2,5-furandicarboxylic acid
SG11201913469PA (en) 2017-07-12 2020-01-30 Stora Enso Oyj Purified 2,5-furandicarboxylic acid pathway products
FI127644B (fi) 2017-09-01 2018-11-15 Teknologian Tutkimuskeskus Vtt Oy Furaanihapon synteesi ksylonihaposta
FI128780B (fi) 2018-02-09 2020-12-15 Teknologian Tutkimuskeskus Vtt Oy Furaanikarboksylaattien erotus ja puhdistaminen
KR102041210B1 (ko) * 2018-03-22 2019-11-27 한국생산기술연구원 갈락타릭산을 이용한 퓨란 디알킬카르복실레이트의 제조방법
CN109365004B (zh) * 2018-11-28 2022-03-18 武汉工程大学 一种磁性固体酸催化剂及其提取皂素的应用
FI128987B (fi) 2018-12-10 2021-04-30 Teknologian Tutkimuskeskus Vtt Oy Furaanidikarboksyylihapon ja sen esterin synteesi
KR102278268B1 (ko) * 2019-11-22 2021-07-16 한국화학연구원 5-알콕시메틸퍼퓨랄로부터 2,5-퓨란디카르복실산 제조방법
EP4157826A1 (en) * 2020-05-29 2023-04-05 Braskem S.A. Production and use of plasticizers based on 2,4-isomer of furandicarboxylic acid diesters
FI130511B (fi) 2021-01-15 2023-10-18 Teknologian Tutkimuskeskus Vtt Oy Furaanidikarboksyylihapon synteesi aldaarihaposta
CN116768832A (zh) * 2022-03-10 2023-09-19 江苏赛瑞克新材料科技有限公司 2,5-呋喃二甲酸类化合物的制备方法

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2723945B1 (fr) 1994-08-24 1996-10-18 Ard Sa Procede de fabrication de l'acide 2,5-furane dicarboxylique
FR2723946B1 (fr) * 1994-08-24 1996-10-18 Ard Sa Procede de fabrication d'un diester de l'acide 2,5-furane dicarboxylique
JP5051509B2 (ja) 2006-11-16 2012-10-17 独立行政法人産業技術総合研究所 2,5−フランジカルボン酸ジエステルの製造方法
WO2011063500A1 (en) 2009-11-24 2011-06-03 National Research Council Of Canada Process for preparing furfural from xylose
WO2013049711A1 (en) 2011-09-29 2013-04-04 Bio Architecture Lab, Inc. Methods for preparing 2,5-furandicarboxylic acid
JP2014019827A (ja) * 2012-07-20 2014-02-03 Hitachi Ltd ポリエステル製造方法及び装置

Also Published As

Publication number Publication date
EP3283471A4 (en) 2018-10-10
WO2016166421A1 (en) 2016-10-20
EP3283471A1 (en) 2018-02-21
FI126387B (fi) 2016-11-15
EP3283471B1 (en) 2021-06-09
US20180086728A1 (en) 2018-03-29
US10301276B2 (en) 2019-05-28

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