FI124773B - Menetelmä ja järjestely kasvannaisten poistamiseksi suspensiosulatusuunissa - Google Patents

Menetelmä ja järjestely kasvannaisten poistamiseksi suspensiosulatusuunissa Download PDF

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Publication number
FI124773B
FI124773B FI20125499A FI20125499A FI124773B FI 124773 B FI124773 B FI 124773B FI 20125499 A FI20125499 A FI 20125499A FI 20125499 A FI20125499 A FI 20125499A FI 124773 B FI124773 B FI 124773B
Authority
FI
Finland
Prior art keywords
reaction shaft
growth
outgrowth
reaction
cooling block
Prior art date
Application number
FI20125499A
Other languages
English (en)
Swedish (sv)
Other versions
FI20125499A (fi
Inventor
Peter Björklund
Aki Laaninen
Kaarle Peltoniemi
Lauri Pesonen
Original Assignee
Outotec Oyj
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to FI20125499A priority Critical patent/FI124773B/fi
Application filed by Outotec Oyj filed Critical Outotec Oyj
Priority to EA201491903A priority patent/EA026558B1/ru
Priority to BR112014027932A priority patent/BR112014027932A2/pt
Priority to US14/398,590 priority patent/US9845993B2/en
Priority to RS20190628A priority patent/RS58805B1/sr
Priority to PCT/FI2013/050509 priority patent/WO2013167810A1/en
Priority to CA2870834A priority patent/CA2870834C/en
Priority to KR1020147034463A priority patent/KR101672115B1/ko
Priority to TR2019/08221T priority patent/TR201908221T4/tr
Priority to PL13787240T priority patent/PL2847532T3/pl
Priority to MX2014013531A priority patent/MX2014013531A/es
Priority to CN201380024062.XA priority patent/CN104321606B/zh
Priority to ES13787240T priority patent/ES2728717T3/es
Priority to EP13787240.4A priority patent/EP2847532B1/en
Publication of FI20125499A publication Critical patent/FI20125499A/fi
Priority to PH12014502395A priority patent/PH12014502395A1/en
Priority to CL2014003022A priority patent/CL2014003022A1/es
Application granted granted Critical
Publication of FI124773B publication Critical patent/FI124773B/fi

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Classifications

    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F27—FURNACES; KILNS; OVENS; RETORTS
    • F27D—DETAILS OR ACCESSORIES OF FURNACES, KILNS, OVENS, OR RETORTS, IN SO FAR AS THEY ARE OF KINDS OCCURRING IN MORE THAN ONE KIND OF FURNACE
    • F27D25/00—Devices or methods for removing incrustations, e.g. slag, metal deposits, dust; Devices or methods for preventing the adherence of slag
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B15/00—Obtaining copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B08—CLEANING
    • B08B—CLEANING IN GENERAL; PREVENTION OF FOULING IN GENERAL
    • B08B7/00—Cleaning by methods not provided for in a single other subclass or a single group in this subclass
    • B08B7/02—Cleaning by methods not provided for in a single other subclass or a single group in this subclass by distortion, beating, or vibration of the surface to be cleaned
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B15/00—Obtaining copper
    • C22B15/0026—Pyrometallurgy
    • C22B15/0028—Smelting or converting
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B15/00—Obtaining copper
    • C22B15/0026—Pyrometallurgy
    • C22B15/0028—Smelting or converting
    • C22B15/0047—Smelting or converting flash smelting or converting
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F27—FURNACES; KILNS; OVENS; RETORTS
    • F27B—FURNACES, KILNS, OVENS, OR RETORTS IN GENERAL; OPEN SINTERING OR LIKE APPARATUS
    • F27B1/00—Shaft or like vertical or substantially vertical furnaces
    • F27B1/10—Details, accessories, or equipment peculiar to furnaces of these types
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F27—FURNACES; KILNS; OVENS; RETORTS
    • F27B—FURNACES, KILNS, OVENS, OR RETORTS IN GENERAL; OPEN SINTERING OR LIKE APPARATUS
    • F27B1/00—Shaft or like vertical or substantially vertical furnaces
    • F27B1/10—Details, accessories, or equipment peculiar to furnaces of these types
    • F27B1/24—Cooling arrangements
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F27—FURNACES; KILNS; OVENS; RETORTS
    • F27B—FURNACES, KILNS, OVENS, OR RETORTS IN GENERAL; OPEN SINTERING OR LIKE APPARATUS
    • F27B1/00—Shaft or like vertical or substantially vertical furnaces
    • F27B1/10—Details, accessories, or equipment peculiar to furnaces of these types
    • F27B1/26—Arrangements of controlling devices
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F27—FURNACES; KILNS; OVENS; RETORTS
    • F27D—DETAILS OR ACCESSORIES OF FURNACES, KILNS, OVENS, OR RETORTS, IN SO FAR AS THEY ARE OF KINDS OCCURRING IN MORE THAN ONE KIND OF FURNACE
    • F27D3/00—Charging; Discharging; Manipulation of charge
    • F27D3/18—Charging particulate material using a fluid carrier
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P10/00—Technologies related to metal processing
    • Y02P10/10—Reduction of greenhouse gas [GHG] emissions
    • Y02P10/134—Reduction of greenhouse gas [GHG] emissions by avoiding CO2, e.g. using hydrogen

Description

METHOD AND ARRANGEMENT FOR REMOVING OUTGROWTH IN A SUSPENSION SMELTING FURNACE
Field of the invention
The invention relates to a method for removing outgrowth in a suspension smelting furnace as defined in the preamble of independent claim 1.
The invention also relates to an arrangement for removing outgrowth in a suspension smelting furnace as defined in the preamble of independent claim 5.
Outgrowth comprising for example partially melted fine solids fed by the concentrate burner of a suspension smelting furnace may be built-up in the interior of a reaction shaft of a suspension smelting furnace reaction shaft, especially in the uppermost part of the interior of the reaction shaft in the vicinity of the concentrate burner. Such outgrowth has a negative effect on the suspension smelting process.
It is known in the art to manually remove such outgrowth manually. For this purpose, the reaction shaft can be provided with openings. This manual work is however both dirty and physically exhausting.
Publication WO 2012/001238 presents a suspension smelting furnace comprising a reaction shaft having a reaction shaft structure, a lower furnace, an uptake, and a concentrate burner for feeding at least reaction gas and fine solids such as copper or nickel concentrate into the reaction shaft of the suspension smelting furnace as well as at least one opening for an outgrowth removal means in a cooling block between the a reaction shaft structure and the concentrate burner.
Publication JP 58009945 presents a water-cooled breaker and removing method for oil-can from flash smelting furnace.
Objective of the invention
The object of the invention is to provide a method and an arrangement for removing outgrowth in a suspension smelting furnace.
Short description of the invention
The method for removing outgrowth in a suspension smelting furnace is characterized by the definitions of independent claim 1.
Preferred embodiments of the method are defined in the dependent claims 2 to 4.
The method for removing outgrowth in a suspension smelting furnace of the invention is correspondingly characterized by the definitions of independent claim 5.
Preferred embodiments of the arrangement are defined in the dependent claims 6 to 8.
The method for removing outgrowth in a suspension smelting furnace comprises providing the reaction shaft with at least one opening for an outgrowth removal means. The method comprises additionally providing at least one outgrowth removal means having a movable piston, and arranging a movable piston of at least one outgrowth removal means such that the movable piston of at least one outgrowth removal means can move in the opening in the reaction shaft and into the reaction shaft, and moving the movable piston of at least one outgrowth removal means into the reaction shaft to push possible outgrowth in the reaction shaft by means of the movable piston of said at least one outgrowth removal means to detach possible outgrowth in the reaction shaft and to cause possible outgrowth to fall in the reaction shaft.
In the arrangement for removing outgrowth in a suspension smelting furnace, the reaction shaft comprises at least one opening for an outgrowth removal means. The arrangement comprises additionally at least one outgrowth removal means having a movable piston that is arranges such that the movable piston of said at least one outgrowth removal means can move in the opening in the reaction shaft and into the reaction shaft to push possible outgrowth in the reaction shaft by means of the movable piston of said at least one outgrowth removal means to detach possible outgrowth in the reaction shaft and to cause possible outgrowth to fall in the reaction shaft.
List of figures
In the following the invention will be described in more detail by referring to the figures, in which
Figure 1 shows a suspension smelting furnace,
Figure 2 is a detail view of an embodiment of an arrangement for removing outgrowth in a suspension smelting furnace, and
Figure 3 shows a cooling block that is provided with eight openings for a maximum of eight outgrowth removal means.
Detailed description of the invention
The invention relates to a method for removing outgrowth in a suspension smelting furnace and to an arrangement for removing outgrowth in a suspension smelting furnace.
Fig. 1 shows a suspension smelting furnace which comprises a reaction shaft 1, an uptake 2, and a lower furnace 3, as well as a concentrate burner 4 for feeding reaction gas (not shown in the figures) and fine solids (not shown) such as concentrate, preferable copper or nickel concentrate, matte and/or flux into the reaction shaft 1. The operation of such a suspension smelting furnace is for example described in the Finnish patent publication FI22694.
First the method for removing outgrowth in a suspension smelting furnace and preferred embodiments and variants thereof will be describer in greater detail.
The suspension smelting furnace in the method comprises a reaction shaft 1 having a reaction shaft structure 9, and a concentrate burner 4 for feeding at least reaction gas and fine solids such as copper or nickel concentrate into the reaction shaft 1 of the suspension smelting furnace.
The method comprises providing the reaction shaft 1 with at least one opening 5 for an outgrowth removal means 6.
The method comprises providing at least one outgrowth removal means 6 having a movable piston 7.
The method comprises arranging the movable piston 7 of at least one outgrowth removal means 6 such that the movable piston 7 of said at least one outgrowth removal means 6 can move in the opening 5 in the reaction shaft 1 and into the reaction shaft 1 i.e. into the interior (not marked with a reference numeral) of the reaction shaft 1.
The method comprises moving the movable piston 7 into the reaction shaft 1 to push possible outgrowth in the reaction shaft 1 by means of the movable piston 7 of said at least one outgrowth removal means 6, preferably to push outgrowth present in the reaction shaft 1 by means of the movable piston 7 of said at least one outgrowth removal means 6.
In an embodiment of the method, the method comprises providing a cooling block 8 having an aperture 13 for the concentrate burner 4 and first fastening means 10 for fastening the concentrate burner 4 to the cooling block 8 and second fastening means 11 for fastening the cooling block 8 at the top of the reaction shaft 1 of the suspension smelting furnace. This embodiment of the method comprises additionally providing the cooling block 8 with at least one opening 5 for the movable piston 7 of at least one outgrowth removal means 6. This embodiment of the method comprises additionally fastening the cooling block 8 at the top of the reaction shaft 1 of the reaction shaft 1 of the suspension smelting furnace so that the cooling block 8 is fastened to the reaction shaft structure 9 of the reaction shaft 1 of the suspension smelting furnace by using the second fastening means 11 and so that the cooling block 8 is fastened to the concentrate burner 4 by using the first fastening means 10 and so that the concentrate burner 4 extends into the reaction shaft 1. The cooling block can for example be made of copper or comprise copper. Figure 3 shows a cooling block 8 having in total eight openings 5 for eight movable pistons 7 of eight outgrowth removal means 6.
The method comprises preferably providing at least one opening 5 for a movable piston 7 of at least one outgrowth removal means 6 adjacent to the concentrate burner 4 at the top of the interior of the reaction shaft 1 of the suspension smelting furnace.
The method may comprise an attachment step for attaching the outgrowth removal means 6 to the concentrate burner 4 as is shown in figure 2.
The method may comprise using a pneumatic cylinder-piston-arrangement in at least one outgrowth removal means 6 for moving the movable piston 7 of said at least one outgrowth removal means 6.
The method may comprise using a linear actuator such as a mechanical actuator, a hydraulic actuator, or a pneumatic actuator in at least one outgrowth removal means 6 for moving the movable piston 7 of at least one outgrowth removal means.
The method may comprise providing the outgrowth removal means 6 with a control arrangement 12 for actuating at least one outgrowth removal means 6 to move the movable piston 7 of at least one outgrowth removal means 6 into the reaction shaft 1 for example with regular time-intervals.
Next the arrangement for removing outgrowth in a suspension smelting furnace and preferred embodiments and variants thereof will be describer in greater detail.
The suspension smelting furnace in the arrangement comprises a reaction shaft 1 having a reaction shaft structure 9, and a concentrate burner 4 for feeding at least reaction gas and fine solids such as copper or nickel concentrate into the reaction shaft 1 of the suspension smelting furnace.
The reaction shaft 1 comprises at least one opening 5 for an outgrowth removal means 6.
The arrangement comprises at least one outgrowth removal means 6 having a movable piston 7. The movable piston 7 of at least one outgrowth removal means 6 is arranged such that the movable piston 7 of said at least one outgrowth removal means 6 can move in the opening 5 in the reaction shaft 1 and into the reaction shaft 1 to push possible outgrowth in the reaction shaft 1 by means of the movable piston 7 of said at least one outgrowth removal means 6, preferably to push outgrowth present in the reaction shaft 1 by means of the movable piston 7 of said at least one outgrowth removal means 6.
In a preferred embodiment of the arrangement, the arrangement comprises a cooling block 8 having an aperture 13 for the concentrate burner 4 and first fastening means 10 for fastening the concentrate burner 4 to the cooling block 8 and second fastening means 11 for fastening the cooling block 8 at the top of the reaction shaft 1 of the suspension smelting furnace. The cooling block 8 is provided with at least one opening 5 for at least one movable piston 7 of at least one outgrowth removal means 6. The cooling block 8 is arranged at the top of the interior of the reaction shaft 1 of the reaction shaft 1 of the suspension smelting furnace so that the cooling block 8 is fastened to the reaction shaft structure 9 of the reaction shaft 1 of the suspension smelting furnace by using the second fastening means 11 and to the concentrate burner 4 by using the first fastening means 10 and so that the concentrate burner 4 extends into the reaction shaft 1. The cooling block can for example be made of copper or comprise copper. Figure 3 shows a cooling block 8 having in total eight openings 5 for eight movable pistons 7 of eight outgrowth removal means 6.
In the arrangement at least one opening 5 for a movable piston 7 of an outgrowth removal means 6 is preferably, but not necessarily, provided adjacent to the concentrate burner 4 at the top of the interior of the reaction shaft 1 of the suspension smelting furnace.
In the arrangement the outgrowth removal means 6 is preferably, but not necessarily, attached to the concentrate burner 4.
In the arrangement the outgrowth removal means 6 comprises preferably, but not necessarily, a pneumatic cylinder-piston-arrangement in the outgrowth removal means 6 for moving the movable piston 7.
In the arrangement the outgrowth removal means 6 comprises preferably, but not necessarily, a linear actuator such as a mechanical actuator, a hydraulic actuator, or a pneumatic actuator in the outgrowth removal means 6 for moving the movable piston 7.
In the arrangement the outgrowth removal means 6 comprises preferably, but not necessarily, a control arrangement 12 for actuating the outgrowth removal means 6 to moving the movable piston 7 into the reaction shaft 1 for example with regular time-intervals.
It is apparent to a person skilled in the art that as technology advances, the basic idea of the invention can be implemented in various ways. The invention and its embodiments are therefore not restricted to the above examples, but they may vary within the scope of the claims.
FI20125499A 2012-05-09 2012-05-09 Menetelmä ja järjestely kasvannaisten poistamiseksi suspensiosulatusuunissa FI124773B (fi)

Priority Applications (16)

Application Number Priority Date Filing Date Title
FI20125499A FI124773B (fi) 2012-05-09 2012-05-09 Menetelmä ja järjestely kasvannaisten poistamiseksi suspensiosulatusuunissa
MX2014013531A MX2014013531A (es) 2012-05-09 2013-05-08 Metodo y configuracion para eliminar el sobrecrecimiento en un horno de fusion por suspension.
US14/398,590 US9845993B2 (en) 2012-05-09 2013-05-08 Method and arrangement for removing outgrowth in a suspension smelting furnace
RS20190628A RS58805B1 (sr) 2012-05-09 2013-05-08 Metoda i sklop za uklanjanje nakupine u peći za topljenje suspenzije
PCT/FI2013/050509 WO2013167810A1 (en) 2012-05-09 2013-05-08 Method and arrangement for removing outgrowth in a suspension smelting furnace
CA2870834A CA2870834C (en) 2012-05-09 2013-05-08 Method and arrangement for removing outgrowth in a suspension smelting furnace
KR1020147034463A KR101672115B1 (ko) 2012-05-09 2013-05-08 현탁물 용융로에서 부산물을 제거하는 방법과 장치
TR2019/08221T TR201908221T4 (tr) 2012-05-09 2013-05-08 Bir süspansiyon izabe fırınında fazlalığın çıkarılmasına yönelik yöntem ve düzenleme.
EA201491903A EA026558B1 (ru) 2012-05-09 2013-05-08 Способ и устройство для удаления нароста в печи взвешенной плавки
BR112014027932A BR112014027932A2 (pt) 2012-05-09 2013-05-08 método e disposição para remoção de formações salientes em um forno de fusão em suspensão
CN201380024062.XA CN104321606B (zh) 2012-05-09 2013-05-08 用于移除悬浮熔炼炉中的副产物的方法和装置
ES13787240T ES2728717T3 (es) 2012-05-09 2013-05-08 Procedimiento y montaje para retirar las deposiciones en un horno de fundición en suspensión
EP13787240.4A EP2847532B1 (en) 2012-05-09 2013-05-08 Method and arrangement for removing outgrowth in a suspension smelting furnace
PL13787240T PL2847532T3 (pl) 2012-05-09 2013-05-08 Sposób i układ do usuwania osadu w zawiesinowym piecu wytopowym
PH12014502395A PH12014502395A1 (en) 2012-05-09 2014-10-24 Method and arrangement for removing outgrowth in a suspension smelting furnace
CL2014003022A CL2014003022A1 (es) 2012-05-09 2014-11-07 Método para la remoción de sobrecalentamiento en un horno de fusión por suspensión, comprende un árbol de reacción con una estructura de árbol de reacción y un quemador para alimentar al menos un gas de reacción y sólidos finos como concentrado de níquel o cobre en el árbol de reacción, donde es proporcionado un medio de remoción de sobrecalentamiento que tiene un pistón móvil; configuración para remoción de sobrecalentamiento.

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FI20125499A FI124773B (fi) 2012-05-09 2012-05-09 Menetelmä ja järjestely kasvannaisten poistamiseksi suspensiosulatusuunissa
FI20125499 2012-05-09

Publications (2)

Publication Number Publication Date
FI20125499A FI20125499A (fi) 2013-11-10
FI124773B true FI124773B (fi) 2015-01-30

Family

ID=49550202

Family Applications (1)

Application Number Title Priority Date Filing Date
FI20125499A FI124773B (fi) 2012-05-09 2012-05-09 Menetelmä ja järjestely kasvannaisten poistamiseksi suspensiosulatusuunissa

Country Status (16)

Country Link
US (1) US9845993B2 (fi)
EP (1) EP2847532B1 (fi)
KR (1) KR101672115B1 (fi)
CN (1) CN104321606B (fi)
BR (1) BR112014027932A2 (fi)
CA (1) CA2870834C (fi)
CL (1) CL2014003022A1 (fi)
EA (1) EA026558B1 (fi)
ES (1) ES2728717T3 (fi)
FI (1) FI124773B (fi)
MX (1) MX2014013531A (fi)
PH (1) PH12014502395A1 (fi)
PL (1) PL2847532T3 (fi)
RS (1) RS58805B1 (fi)
TR (1) TR201908221T4 (fi)
WO (1) WO2013167810A1 (fi)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP3631334A4 (en) * 2017-05-29 2020-08-26 Outotec (Finland) Oy PROCEDURE AND ARRANGEMENT FOR CONTROL OF A BURNER OF A SUSPENSION FUSION OVEN

Family Cites Families (14)

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Publication number Priority date Publication date Assignee Title
DE2147251B1 (fi) * 1971-09-22 1973-02-08 Steag Ag, 4300 Essen
JPS589945A (ja) * 1981-07-09 1983-01-20 古河鉱業株式会社 水冷式ブレ−カ−及び自溶炉ベコ除去方法
JPH05240588A (ja) * 1992-02-26 1993-09-17 Daido Steel Co Ltd スラグの除去方法および装置
JP2817595B2 (ja) * 1993-12-02 1998-10-30 日本鋼管株式会社 除滓装置の制御方法
MXPA02008281A (es) * 2000-02-23 2004-04-05 Denki Kagaku Kogyo Kk Aparato para eliminar masas grandes de revestimiento.
CN1136428C (zh) * 2000-03-16 2004-01-28 冶金工业部钢铁研究总院 悬浮熔炼水冷坩埚
FI109938B (fi) * 2000-06-29 2002-10-31 Outokumpu Oy Laite pölykasvannaisten poistamiseksi sulatusuunista
FI122703B (fi) * 2006-12-14 2012-05-31 Foster Wheeler Energia Oy Likaantuvan pinnan ravistuslaite
JP2008309461A (ja) * 2007-09-04 2008-12-25 Kawasaki Plant Systems Ltd プラズマ式灰溶融炉の制御方法及びプラズマ式灰溶融炉
JP4499772B2 (ja) * 2007-09-28 2010-07-07 パンパシフィック・カッパー株式会社 自溶炉の点検孔構造体
US7832367B2 (en) * 2007-12-05 2010-11-16 Berry Metal Company Furnace panel leak detection system
FI121852B (fi) * 2009-10-19 2011-05-13 Outotec Oyj Menetelmä polttoainekaasun syöttämiseksi suspensiosulatusuunin reaktiokuiluun ja rikastepoltin
FI122306B (fi) * 2009-12-11 2011-11-30 Outotec Oyj Järjestely suspensiosulatusuunin rikastepolttimen jauhemaisen kiintoaineen syötön tasaamiseksi
FI124223B (fi) * 2010-06-29 2014-05-15 Outotec Oyj Suspensiosulatusuuni ja rikastepoltin

Also Published As

Publication number Publication date
KR101672115B1 (ko) 2016-11-02
BR112014027932A2 (pt) 2018-04-10
KR20150006886A (ko) 2015-01-19
ES2728717T3 (es) 2019-10-28
PL2847532T3 (pl) 2019-09-30
EA201491903A1 (ru) 2015-06-30
FI20125499A (fi) 2013-11-10
PH12014502395A1 (en) 2014-12-22
US20150102537A1 (en) 2015-04-16
EP2847532B1 (en) 2019-03-13
TR201908221T4 (tr) 2019-07-22
EP2847532A1 (en) 2015-03-18
RS58805B1 (sr) 2019-07-31
CN104321606A (zh) 2015-01-28
EP2847532A4 (en) 2016-03-09
WO2013167810A1 (en) 2013-11-14
CA2870834C (en) 2017-01-17
CL2014003022A1 (es) 2015-02-20
EA026558B1 (ru) 2017-04-28
CN104321606B (zh) 2016-03-23
US9845993B2 (en) 2017-12-19
CA2870834A1 (en) 2013-11-14
MX2014013531A (es) 2015-01-19

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