FI116071B - Förfarande för tillvaratagande av zink med motströmsupplösning - Google Patents
Förfarande för tillvaratagande av zink med motströmsupplösning Download PDFInfo
- Publication number
- FI116071B FI116071B FI20030285A FI20030285A FI116071B FI 116071 B FI116071 B FI 116071B FI 20030285 A FI20030285 A FI 20030285A FI 20030285 A FI20030285 A FI 20030285A FI 116071 B FI116071 B FI 116071B
- Authority
- FI
- Finland
- Prior art keywords
- leaching
- och
- zinc
- jarosite
- concentrate
- Prior art date
Links
- 238000002386 leaching Methods 0.000 title claims abstract description 119
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 title claims abstract description 62
- 238000000034 method Methods 0.000 title claims abstract description 61
- 229910052725 zinc Inorganic materials 0.000 title claims abstract description 57
- 239000011701 zinc Substances 0.000 title claims abstract description 56
- 239000007787 solid Substances 0.000 claims abstract description 29
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims abstract description 19
- 239000000463 material Substances 0.000 claims abstract description 6
- 235000011149 sulphuric acid Nutrition 0.000 claims abstract description 5
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 169
- 229910052742 iron Inorganic materials 0.000 claims description 80
- 239000012141 concentrate Substances 0.000 claims description 63
- 229910052935 jarosite Inorganic materials 0.000 claims description 50
- 239000002253 acid Substances 0.000 claims description 45
- 230000007935 neutral effect Effects 0.000 claims description 44
- 238000001556 precipitation Methods 0.000 claims description 37
- 238000006243 chemical reaction Methods 0.000 claims description 29
- NWONKYPBYAMBJT-UHFFFAOYSA-L zinc sulfate Chemical compound [Zn+2].[O-]S([O-])(=O)=O NWONKYPBYAMBJT-UHFFFAOYSA-L 0.000 claims description 25
- 239000002244 precipitate Substances 0.000 claims description 23
- 229910000859 α-Fe Inorganic materials 0.000 claims description 23
- 235000009529 zinc sulphate Nutrition 0.000 claims description 21
- 239000011686 zinc sulphate Substances 0.000 claims description 21
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 15
- 239000001301 oxygen Substances 0.000 claims description 15
- 229910052760 oxygen Inorganic materials 0.000 claims description 15
- 238000005868 electrolysis reaction Methods 0.000 claims description 12
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims description 6
- 239000003513 alkali Substances 0.000 claims description 4
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 claims description 4
- 229910052732 germanium Inorganic materials 0.000 claims description 4
- GNPVGFCGXDBREM-UHFFFAOYSA-N germanium atom Chemical compound [Ge] GNPVGFCGXDBREM-UHFFFAOYSA-N 0.000 claims description 4
- 230000001376 precipitating effect Effects 0.000 claims description 4
- 238000011144 upstream manufacturing Methods 0.000 claims description 4
- 229910052787 antimony Inorganic materials 0.000 claims description 3
- 238000009835 boiling Methods 0.000 claims description 3
- BAUYGSIQEAFULO-UHFFFAOYSA-L iron(2+) sulfate (anhydrous) Chemical class [Fe+2].[O-]S([O-])(=O)=O BAUYGSIQEAFULO-UHFFFAOYSA-L 0.000 claims description 3
- 239000011573 trace mineral Substances 0.000 claims description 3
- 235000013619 trace mineral Nutrition 0.000 claims description 3
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims description 2
- -1 ammonium ions Chemical class 0.000 claims description 2
- RNWHGQJWIACOKP-UHFFFAOYSA-N zinc;oxygen(2-) Chemical compound [O-2].[Zn+2] RNWHGQJWIACOKP-UHFFFAOYSA-N 0.000 claims description 2
- RYXPMWYHEBGTRV-UHFFFAOYSA-N Omeprazole sodium Chemical compound [Na+].N=1C2=CC(OC)=CC=C2[N-]C=1S(=O)CC1=NC=C(C)C(OC)=C1C RYXPMWYHEBGTRV-UHFFFAOYSA-N 0.000 claims 2
- 239000003086 colorant Substances 0.000 claims 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 claims 1
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N iron oxide Inorganic materials [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 claims 1
- 239000004922 lacquer Substances 0.000 claims 1
- NDLPOXTZKUMGOV-UHFFFAOYSA-N oxo(oxoferriooxy)iron hydrate Chemical compound O.O=[Fe]O[Fe]=O NDLPOXTZKUMGOV-UHFFFAOYSA-N 0.000 claims 1
- 229910021653 sulphate ion Inorganic materials 0.000 claims 1
- 239000005083 Zinc sulfide Substances 0.000 abstract description 7
- 238000011084 recovery Methods 0.000 abstract description 7
- DRDVZXDWVBGGMH-UHFFFAOYSA-N zinc;sulfide Chemical compound [S-2].[Zn+2] DRDVZXDWVBGGMH-UHFFFAOYSA-N 0.000 abstract description 7
- 239000001117 sulphuric acid Substances 0.000 abstract 1
- 239000000243 solution Substances 0.000 description 81
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical group [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 14
- 230000003647 oxidation Effects 0.000 description 9
- 238000007254 oxidation reaction Methods 0.000 description 9
- 229910052598 goethite Inorganic materials 0.000 description 8
- AEIXRCIKZIZYPM-UHFFFAOYSA-M hydroxy(oxo)iron Chemical compound [O][Fe]O AEIXRCIKZIZYPM-UHFFFAOYSA-M 0.000 description 8
- 238000000746 purification Methods 0.000 description 8
- 239000011787 zinc oxide Substances 0.000 description 7
- 238000006386 neutralization reaction Methods 0.000 description 6
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 5
- 239000003795 chemical substances by application Substances 0.000 description 5
- 239000011019 hematite Substances 0.000 description 5
- 229910052595 hematite Inorganic materials 0.000 description 5
- LIKBJVNGSGBSGK-UHFFFAOYSA-N iron(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[Fe+3].[Fe+3] LIKBJVNGSGBSGK-UHFFFAOYSA-N 0.000 description 5
- 230000003472 neutralizing effect Effects 0.000 description 5
- 229910052717 sulfur Inorganic materials 0.000 description 5
- 239000011593 sulfur Substances 0.000 description 5
- 229960001763 zinc sulfate Drugs 0.000 description 5
- 229910000368 zinc sulfate Inorganic materials 0.000 description 5
- 229910052984 zinc sulfide Inorganic materials 0.000 description 5
- 230000002378 acidificating effect Effects 0.000 description 4
- 239000002562 thickening agent Substances 0.000 description 4
- 238000010586 diagram Methods 0.000 description 3
- 238000004090 dissolution Methods 0.000 description 3
- 238000005188 flotation Methods 0.000 description 3
- NIFIFKQPDTWWGU-UHFFFAOYSA-N pyrite Chemical group [Fe+2].[S-][S-] NIFIFKQPDTWWGU-UHFFFAOYSA-N 0.000 description 3
- 229910052683 pyrite Inorganic materials 0.000 description 3
- 239000002002 slurry Substances 0.000 description 3
- 239000007858 starting material Substances 0.000 description 3
- VTLYFUHAOXGGBS-UHFFFAOYSA-N Fe3+ Chemical compound [Fe+3] VTLYFUHAOXGGBS-UHFFFAOYSA-N 0.000 description 2
- 229910001308 Zinc ferrite Inorganic materials 0.000 description 2
- 239000003929 acidic solution Substances 0.000 description 2
- 229960004887 ferric hydroxide Drugs 0.000 description 2
- 235000003891 ferrous sulphate Nutrition 0.000 description 2
- 239000011790 ferrous sulphate Substances 0.000 description 2
- 238000001914 filtration Methods 0.000 description 2
- IEECXTSVVFWGSE-UHFFFAOYSA-M iron(3+);oxygen(2-);hydroxide Chemical compound [OH-].[O-2].[Fe+3] IEECXTSVVFWGSE-UHFFFAOYSA-M 0.000 description 2
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000008188 pellet Substances 0.000 description 2
- 239000011028 pyrite Substances 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- 150000004763 sulfides Chemical class 0.000 description 2
- 230000008719 thickening Effects 0.000 description 2
- WGEATSXPYVGFCC-UHFFFAOYSA-N zinc ferrite Chemical compound O=[Zn].O=[Fe]O[Fe]=O WGEATSXPYVGFCC-UHFFFAOYSA-N 0.000 description 2
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical group [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 1
- 229910002588 FeOOH Inorganic materials 0.000 description 1
- 206010018498 Goitre Diseases 0.000 description 1
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 238000000855 fermentation Methods 0.000 description 1
- 230000004151 fermentation Effects 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 201000003872 goiter Diseases 0.000 description 1
- 235000014413 iron hydroxide Nutrition 0.000 description 1
- RUTXIHLAWFEWGM-UHFFFAOYSA-H iron(3+) sulfate Chemical compound [Fe+3].[Fe+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O RUTXIHLAWFEWGM-UHFFFAOYSA-H 0.000 description 1
- 229910000359 iron(II) sulfate Inorganic materials 0.000 description 1
- 229910000360 iron(III) sulfate Inorganic materials 0.000 description 1
- NCNCGGDMXMBVIA-UHFFFAOYSA-L iron(ii) hydroxide Chemical compound [OH-].[OH-].[Fe+2] NCNCGGDMXMBVIA-UHFFFAOYSA-L 0.000 description 1
- 230000002934 lysing effect Effects 0.000 description 1
- 229910052960 marcasite Inorganic materials 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- BITYAPCSNKJESK-UHFFFAOYSA-N potassiosodium Chemical compound [Na].[K] BITYAPCSNKJESK-UHFFFAOYSA-N 0.000 description 1
- 239000010970 precious metal Substances 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052950 sphalerite Inorganic materials 0.000 description 1
- 150000003752 zinc compounds Chemical class 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
- C22B3/04—Extraction of metal compounds from ores or concentrates by wet processes by leaching
- C22B3/06—Extraction of metal compounds from ores or concentrates by wet processes by leaching in inorganic acid solutions, e.g. with acids generated in situ; in inorganic salt solutions other than ammonium salt solutions
- C22B3/08—Sulfuric acid, other sulfurated acids or salts thereof
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B19/00—Obtaining zinc or zinc oxide
- C22B19/04—Obtaining zinc by distilling
- C22B19/08—Obtaining zinc by distilling in blast furnaces
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B19/00—Obtaining zinc or zinc oxide
- C22B19/20—Obtaining zinc otherwise than by distilling
- C22B19/22—Obtaining zinc otherwise than by distilling with leaching with acids
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B19/00—Obtaining zinc or zinc oxide
- C22B19/20—Obtaining zinc otherwise than by distilling
- C22B19/26—Refining solutions containing zinc values, e.g. obtained by leaching zinc ores
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/20—Recycling
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Manufacturing & Machinery (AREA)
- Life Sciences & Earth Sciences (AREA)
- Environmental & Geological Engineering (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Geology (AREA)
- Inorganic Chemistry (AREA)
- Geochemistry & Mineralogy (AREA)
- Manufacture And Refinement Of Metals (AREA)
- Electrolytic Production Of Metals (AREA)
Priority Applications (18)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FI20030285A FI116071B (sv) | 2003-02-26 | 2003-02-26 | Förfarande för tillvaratagande av zink med motströmsupplösning |
BRPI0407700A BRPI0407700B1 (pt) | 2003-02-26 | 2004-02-24 | método para a recuperação de zinco por lixiviação em contra-corrente |
KR1020057016072A KR101084522B1 (ko) | 2003-02-26 | 2004-02-24 | 대향류 방식 침출에 의한 아연 회수 방법 |
CNB2004800027969A CN100572569C (zh) | 2003-02-26 | 2004-02-24 | 通过逆流浸提回收锌的方法 |
US10/544,272 US7517383B2 (en) | 2003-02-26 | 2004-02-24 | Method for recovery of zinc by countercurrent leaching |
AT04713920T ATE389038T1 (de) | 2003-02-26 | 2004-02-24 | Verfahren zur rückgewinnung von zink durch gegenstromauslaugung |
DE602004012394T DE602004012394T2 (de) | 2003-02-26 | 2004-02-24 | Verfahren zur rückgewinnung von zink durch gegenstromauslaugung |
JP2006502070A JP4511519B2 (ja) | 2003-02-26 | 2004-02-24 | 向流リーチングによる亜鉛回収方法 |
PCT/FI2004/000085 WO2004076698A1 (en) | 2003-02-26 | 2004-02-24 | Method for recovery of zinc by countercurrent leaching |
ES04713920T ES2301973T3 (es) | 2003-02-26 | 2004-02-24 | Metodo para recuperar zinc por lixiviacion contracorriente. |
EA200500980A EA008362B1 (ru) | 2003-02-26 | 2004-02-24 | Способ извлечения цинка противоточным выщелачиванием |
CA2516411A CA2516411C (en) | 2003-02-26 | 2004-02-24 | Method for recovery of zinc by countercurrent leaching |
MXPA05008897A MXPA05008897A (es) | 2003-02-26 | 2004-02-24 | Metodo para la recuperacion de cinc mediante lixiviacion a contracorriente. |
EP04713920A EP1597403B1 (en) | 2003-02-26 | 2004-02-24 | Method for recovery of zinc by countercurrent leaching |
AU2004215197A AU2004215197B2 (en) | 2003-02-26 | 2004-02-24 | Method for recovery of zinc by countercurrent leaching |
PE2004000192A PE20041037A1 (es) | 2003-02-26 | 2004-02-25 | Metodo para recuperar zinc por medio de lixiviacion en contracorriente |
ZA200505981A ZA200505981B (en) | 2003-02-26 | 2005-07-26 | Method for recovery of zinc by countercurrent leaching |
NO20054254A NO20054254L (no) | 2003-02-26 | 2005-09-14 | Fremgangsmate for utvinning av sink ved motstromsutlutning |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FI20030285A FI116071B (sv) | 2003-02-26 | 2003-02-26 | Förfarande för tillvaratagande av zink med motströmsupplösning |
FI20030285 | 2003-02-26 |
Publications (3)
Publication Number | Publication Date |
---|---|
FI20030285A0 FI20030285A0 (sv) | 2003-02-26 |
FI20030285A FI20030285A (sv) | 2004-08-27 |
FI116071B true FI116071B (sv) | 2005-09-15 |
Family
ID=8565718
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
FI20030285A FI116071B (sv) | 2003-02-26 | 2003-02-26 | Förfarande för tillvaratagande av zink med motströmsupplösning |
Country Status (18)
Country | Link |
---|---|
US (1) | US7517383B2 (sv) |
EP (1) | EP1597403B1 (sv) |
JP (1) | JP4511519B2 (sv) |
KR (1) | KR101084522B1 (sv) |
CN (1) | CN100572569C (sv) |
AT (1) | ATE389038T1 (sv) |
AU (1) | AU2004215197B2 (sv) |
BR (1) | BRPI0407700B1 (sv) |
CA (1) | CA2516411C (sv) |
DE (1) | DE602004012394T2 (sv) |
EA (1) | EA008362B1 (sv) |
ES (1) | ES2301973T3 (sv) |
FI (1) | FI116071B (sv) |
MX (1) | MXPA05008897A (sv) |
NO (1) | NO20054254L (sv) |
PE (1) | PE20041037A1 (sv) |
WO (1) | WO2004076698A1 (sv) |
ZA (1) | ZA200505981B (sv) |
Families Citing this family (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN100361750C (zh) * | 2005-12-07 | 2008-01-16 | 冯国臣 | 硫精矿除杂提纯浮选工艺 |
FI118226B (sv) | 2005-12-29 | 2007-08-31 | Outokumpu Technology Oyj | Förfarande för tillvaratagning av sällsynta metaller i en upplösningsprocess för zink |
FI122676B (sv) | 2010-10-12 | 2012-05-15 | Outotec Oyj | Förfarande för behandling av en zinksulfathaltig lösning |
KR101047986B1 (ko) | 2010-11-26 | 2011-07-13 | 한국지질자원연구원 | Ccd 공정을 이용한 리튬 이온의 흡착/탈착 장치 및 그 방법 |
JP2014510841A (ja) * | 2011-04-15 | 2014-05-01 | テアエメ5・ソシエダッド・リミターダ | 硫化亜鉛精鉱から出発して硫黄媒体内の亜鉛を回収する湿式製錬法 |
CN102191371B (zh) * | 2011-04-18 | 2013-02-06 | 中南大学 | 一种传统锌湿法冶炼过程中铁锌分离的方法 |
FI123884B (sv) | 2011-11-08 | 2013-11-29 | Outotec Oyj | Förfarande för lakning av sulfidiskt metallkoncentrat |
AU2014324082A1 (en) * | 2013-09-20 | 2016-04-14 | Metaleach Limited | Method for ammoniacal leaching of zinc from carbonate-hosted ores |
EP2902510A1 (en) | 2014-01-29 | 2015-08-05 | Canbekte, Hüsnü Sinan | A new method for leaching of electric arc furnace dust (EAFD) with sulphuric acid |
CN105734290A (zh) * | 2016-03-29 | 2016-07-06 | 湖北大江环保科技股份有限公司 | 一种锌湿法冶金的除砷工艺 |
CN106048217B (zh) * | 2016-07-29 | 2018-06-29 | 四环锌锗科技股份有限公司 | 氧化锌粉的综合回收利用方法 |
RU2767385C1 (ru) * | 2021-02-18 | 2022-03-17 | Федеральное государственное автономное образовательное учреждение высшего образования "Балтийский федеральный университет имени Иммануила Канта" (БФУ им. И. Канта) | Способ переработки окисленной цинковой руды |
Family Cites Families (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FI50097C (fi) * | 1973-02-12 | 1980-10-24 | Outokumpu Oy | Hydrometallurgiskt foerfarande foer aotervinning av zink koppar och kadmium fraon deras ferriter |
CA1090143A (en) * | 1976-01-26 | 1980-11-25 | Hans Reinhardt | Method of recovering zinc from a material containing zinc and iron |
CA1104837A (en) * | 1977-08-19 | 1981-07-14 | Donald R. Weir | Process for recovery of copper and zinc from complex sulfides |
LU78802A1 (fr) * | 1977-12-30 | 1979-07-20 | Prayon | Procede de traitement de residus de minerais de zinc ferriferes |
LU85385A1 (fr) * | 1984-05-28 | 1986-01-29 | Mines Fond Zinc Vieille | Procede de lixiviation de sulfures contenant du zinc et du fer |
FI88516C (sv) * | 1990-02-16 | 1993-05-25 | Outokumpu Oy | Hydrometallurgiskt förfarande för behandling av zinksulfidhaltiga råäm nen |
CN1040133C (zh) * | 1993-08-27 | 1998-10-07 | 联合矿业有限公司 | 从硫化物精矿中提取锌的方法 |
FI100806B (sv) * | 1996-08-12 | 1998-02-27 | Outokumpu Base Metals Oy | Förfarande för upplösning av zinkslig under atmosfäriska för hållanden |
JP2001021224A (ja) * | 1999-07-06 | 2001-01-26 | Tadao Nakano | 浴槽の対流改善装置 |
JP3911536B2 (ja) * | 2000-01-31 | 2007-05-09 | Dowaメタルマイン株式会社 | 亜鉛精鉱の浸出法 |
FI20002699A0 (sv) * | 2000-12-08 | 2000-12-08 | Outokumpu Oy | Förfarande för hydrolytisk utfällning av järn |
-
2003
- 2003-02-26 FI FI20030285A patent/FI116071B/sv not_active IP Right Cessation
-
2004
- 2004-02-24 BR BRPI0407700A patent/BRPI0407700B1/pt not_active IP Right Cessation
- 2004-02-24 EP EP04713920A patent/EP1597403B1/en not_active Expired - Lifetime
- 2004-02-24 CA CA2516411A patent/CA2516411C/en not_active Expired - Fee Related
- 2004-02-24 CN CNB2004800027969A patent/CN100572569C/zh not_active Expired - Fee Related
- 2004-02-24 US US10/544,272 patent/US7517383B2/en not_active Expired - Fee Related
- 2004-02-24 WO PCT/FI2004/000085 patent/WO2004076698A1/en active IP Right Grant
- 2004-02-24 MX MXPA05008897A patent/MXPA05008897A/es active IP Right Grant
- 2004-02-24 EA EA200500980A patent/EA008362B1/ru not_active IP Right Cessation
- 2004-02-24 AU AU2004215197A patent/AU2004215197B2/en not_active Ceased
- 2004-02-24 KR KR1020057016072A patent/KR101084522B1/ko not_active IP Right Cessation
- 2004-02-24 ES ES04713920T patent/ES2301973T3/es not_active Expired - Lifetime
- 2004-02-24 DE DE602004012394T patent/DE602004012394T2/de not_active Expired - Lifetime
- 2004-02-24 JP JP2006502070A patent/JP4511519B2/ja not_active Expired - Fee Related
- 2004-02-24 AT AT04713920T patent/ATE389038T1/de not_active IP Right Cessation
- 2004-02-25 PE PE2004000192A patent/PE20041037A1/es not_active Application Discontinuation
-
2005
- 2005-07-26 ZA ZA200505981A patent/ZA200505981B/en unknown
- 2005-09-14 NO NO20054254A patent/NO20054254L/no not_active Application Discontinuation
Also Published As
Publication number | Publication date |
---|---|
ZA200505981B (en) | 2006-05-31 |
EP1597403B1 (en) | 2008-03-12 |
CA2516411C (en) | 2013-07-02 |
EA200500980A1 (ru) | 2006-04-28 |
CA2516411A1 (en) | 2004-09-10 |
CN100572569C (zh) | 2009-12-23 |
WO2004076698A1 (en) | 2004-09-10 |
JP4511519B2 (ja) | 2010-07-28 |
FI20030285A (sv) | 2004-08-27 |
US7517383B2 (en) | 2009-04-14 |
US20060213332A1 (en) | 2006-09-28 |
BRPI0407700A (pt) | 2006-04-11 |
ES2301973T3 (es) | 2008-07-01 |
DE602004012394T2 (de) | 2009-04-02 |
EA008362B1 (ru) | 2007-04-27 |
AU2004215197B2 (en) | 2009-08-27 |
ATE389038T1 (de) | 2008-03-15 |
PE20041037A1 (es) | 2005-01-18 |
MXPA05008897A (es) | 2006-02-17 |
CN1742104A (zh) | 2006-03-01 |
JP2006519309A (ja) | 2006-08-24 |
KR20050103512A (ko) | 2005-10-31 |
EP1597403A1 (en) | 2005-11-23 |
BRPI0407700B1 (pt) | 2015-12-22 |
DE602004012394D1 (de) | 2008-04-24 |
KR101084522B1 (ko) | 2011-11-18 |
AU2004215197A1 (en) | 2004-09-10 |
FI20030285A0 (sv) | 2003-02-26 |
NO20054254L (no) | 2005-09-14 |
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