FI112075B - N-bis- eller N-tris[(1,2-dikarboxyl-etoxi)-etyl]aminderivat, framställning och användning av dem - Google Patents

N-bis- eller N-tris[(1,2-dikarboxyl-etoxi)-etyl]aminderivat, framställning och användning av dem Download PDF

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Publication number
FI112075B
FI112075B FI962261A FI962261A FI112075B FI 112075 B FI112075 B FI 112075B FI 962261 A FI962261 A FI 962261A FI 962261 A FI962261 A FI 962261A FI 112075 B FI112075 B FI 112075B
Authority
FI
Finland
Prior art keywords
compounds
formula
ethyl
acid
alkaline earth
Prior art date
Application number
FI962261A
Other languages
English (en)
Finnish (fi)
Other versions
FI962261A (sv
FI962261A0 (sv
Inventor
Aarto Paren
Ilkka Renvall
Reijo Aksela
Original Assignee
Kemira Chemicals Oy
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Kemira Chemicals Oy filed Critical Kemira Chemicals Oy
Publication of FI962261A0 publication Critical patent/FI962261A0/sv
Priority to FI962261A priority Critical patent/FI112075B/sv
Priority to FI970304A priority patent/FI105932B/sv
Priority to FI970303A priority patent/FI104572B/sv
Priority to CA002256579A priority patent/CA2256579C/en
Priority to EP97924047A priority patent/EP0904263B1/en
Priority to JP54169397A priority patent/JP3901735B2/ja
Priority to BR9709393A priority patent/BR9709393A/pt
Priority to AT97924047T priority patent/ATE198316T1/de
Priority to PCT/FI1997/000332 priority patent/WO1997045396A1/en
Priority to CNB971951357A priority patent/CN1158243C/zh
Priority to PCT/FI1997/000334 priority patent/WO1997045585A1/en
Priority to CA002256559A priority patent/CA2256559C/en
Priority to PT97924047T priority patent/PT904263E/pt
Priority to DE69703796T priority patent/DE69703796T2/de
Priority to AU29643/97A priority patent/AU2964397A/en
Priority to ES97924047T priority patent/ES2154902T3/es
Priority to AU29644/97A priority patent/AU2964497A/en
Priority to US09/194,349 priority patent/US6264790B1/en
Priority to AT97924048T priority patent/ATE252178T1/de
Priority to EP97924048A priority patent/EP0907788B1/en
Priority to PCT/FI1997/000333 priority patent/WO1997045586A1/en
Priority to US09/194,310 priority patent/US6093849A/en
Priority to AU29645/97A priority patent/AU2964597A/en
Priority to DE69725573T priority patent/DE69725573T2/de
Publication of FI962261A publication Critical patent/FI962261A/sv
Application granted granted Critical
Publication of FI112075B publication Critical patent/FI112075B/sv

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/26—Organic compounds containing nitrogen
    • C11D3/33—Amino carboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B15/00—Peroxides; Peroxyhydrates; Peroxyacids or salts thereof; Superoxides; Ozonides
    • C01B15/01—Hydrogen peroxide
    • C01B15/037—Stabilisation by additives
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C217/00—Compounds containing amino and etherified hydroxy groups bound to the same carbon skeleton
    • C07C217/02—Compounds containing amino and etherified hydroxy groups bound to the same carbon skeleton having etherified hydroxy groups and amino groups bound to acyclic carbon atoms of the same carbon skeleton
    • C07C217/04—Compounds containing amino and etherified hydroxy groups bound to the same carbon skeleton having etherified hydroxy groups and amino groups bound to acyclic carbon atoms of the same carbon skeleton the carbon skeleton being acyclic and saturated
    • C07C217/06—Compounds containing amino and etherified hydroxy groups bound to the same carbon skeleton having etherified hydroxy groups and amino groups bound to acyclic carbon atoms of the same carbon skeleton the carbon skeleton being acyclic and saturated having only one etherified hydroxy group and one amino group bound to the carbon skeleton, which is not further substituted
    • C07C217/08—Compounds containing amino and etherified hydroxy groups bound to the same carbon skeleton having etherified hydroxy groups and amino groups bound to acyclic carbon atoms of the same carbon skeleton the carbon skeleton being acyclic and saturated having only one etherified hydroxy group and one amino group bound to the carbon skeleton, which is not further substituted the oxygen atom of the etherified hydroxy group being further bound to an acyclic carbon atom
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C229/00—Compounds containing amino and carboxyl groups bound to the same carbon skeleton
    • C07C229/02—Compounds containing amino and carboxyl groups bound to the same carbon skeleton having amino and carboxyl groups bound to acyclic carbon atoms of the same carbon skeleton
    • C07C229/04—Compounds containing amino and carboxyl groups bound to the same carbon skeleton having amino and carboxyl groups bound to acyclic carbon atoms of the same carbon skeleton the carbon skeleton being acyclic and saturated
    • C07C229/24—Compounds containing amino and carboxyl groups bound to the same carbon skeleton having amino and carboxyl groups bound to acyclic carbon atoms of the same carbon skeleton the carbon skeleton being acyclic and saturated having more than one carboxyl group bound to the carbon skeleton, e.g. aspartic acid
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21C—PRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
    • D21C9/00—After-treatment of cellulose pulp, e.g. of wood pulp, or cotton linters ; Treatment of dilute or dewatered pulp or process improvement taking place after obtaining the raw cellulosic material and not provided for elsewhere
    • D21C9/10—Bleaching ; Apparatus therefor
    • D21C9/1026—Other features in bleaching processes
    • D21C9/1042—Use of chelating agents

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Wood Science & Technology (AREA)
  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Inorganic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Silver Salt Photography Or Processing Solution Therefor (AREA)
  • Detergent Compositions (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Paper (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Hydrogenated Pyridines (AREA)

Claims (13)

1. N-bis- eller N-tris-[(1,2-dikarboxi-etoxi)-etyl]-amin- derivat med formeln 5 R-.OOC--- R‘ ^-COORj R2OOC ° COOR2 10 (I) cHrCOOR2 cHrCOOR^ I där R,är H, I eller CH2-CH2 /CH\ CH_ / COOR2 / ^~COOR2 / ° 15 och R2 är väte, en alkalimetall eller en alkalisk jordartsmetall.
2. Förening enligt krav 1, kännetecknad av att 20 den är N-bis-[(1,2-dikarboxi-etoxi)-etyl]-amin eller ett Na+, K+, Ca2+ eller Mg2+ -salt därav. • ·
3. Förening enligt krav 1, kännetecknad av att • · den är N-bis-[(1,2-dikarboxi-etoxi)-etyl]-asparagin-syra : :*: 25 eller ett Na+, K+, Ca2+ eller Mg2+ -salt därav.
4. Förening enligt krav 1, kännetecknad av att den är N-tris-[ (1,2-dikarboxi-etoxi) -etyl] -amin eller ett Na+,K+, Ca2+ eller Mg2+ -salt därav. 30
5. Förfarande för framställning av föreningar med formel I I ! enligt krav 1, vilket förfarande är i och för sig kännat, kännetecknat av att di- eller trietanolamin , bringas att reagera med ett alkalimetall- eller ’ ' 35 jordalkalimetallsalt av maleinsyra för bildning av en förening med formel I, varvid man säsom katalysator använder 112075 lantanidföreningar, blandningar av lantanid-föreningar eller föreningar av alkaliska jordartsmetaller.
6. Förfarande enligt krav 5, kännetecknat av att 5 di- eller trietanolamin bringas att reagera med ett alka-limetall- eller jordalkalimetallsalt av malein-syra i närvaro av en La3+-katalysator tili bildning av en förening med formel I. 10
7. Förfarande enligt krav 5, kännetecknat av att alkalimetall- eller jordalkalimetallsaltet av malein-syra framställes genom en reaktion mellan maleinsyraan-hydrid och en hydroxid eller ett karbonat av en alkalimetall eller en alkalisk jordartsmetall. 15
8. Förfarande enligt krav 5, kännetecknat av att reaktionen genomföres vid en temperatur av 75-95°C.
9. Användning av föreningar med formel I enligt krav 1 säsom 20 kelatbildare för metaller. i » ·
10. Användning av föreningar med formel I enligt krav 1 säsom kelatbildare för metaller i samband med massablekning.
11. Användning av föreningar med formel I enligt krav 1 ;.· i alkaliska vattenlösningar som innehäller väteperoxid eller ,· · peroxiföreningar.
12. Användning av föreningar med formel I enligt krav 1 30 säsom kelatbildare i detergenter, rengöringsmedel och desinfektionsmedel. * * * * • »
13. Användning av föreningar med formel I enligt krav 1 säsom kelatbildare i fotokemikalier. • I < · > * > » » ·
FI962261A 1996-05-30 1996-05-30 N-bis- eller N-tris[(1,2-dikarboxyl-etoxi)-etyl]aminderivat, framställning och användning av dem FI112075B (sv)

Priority Applications (24)

Application Number Priority Date Filing Date Title
FI962261A FI112075B (sv) 1996-05-30 1996-05-30 N-bis- eller N-tris[(1,2-dikarboxyl-etoxi)-etyl]aminderivat, framställning och användning av dem
FI970304A FI105932B (sv) 1996-05-30 1997-01-24 Förfarande för blekning av högbytes- eller returfibermassa
FI970303A FI104572B (sv) 1996-05-30 1997-01-24 Förfarande för blekning av kemisk massa
PT97924047T PT904263E (pt) 1996-05-30 1997-05-30 Derivados de n-bis- ou n-tris-¬(1,2-dicarboxi-etoxi)-etil|-amina e preparacao e utilizacao dos mesmos
AU29643/97A AU2964397A (en) 1996-05-30 1997-05-30 N-bis- or n-tris-{(1,2-dicarboxy-ethoxy)-ethyl}-amine derivatives and preparation and use of the same
JP54169397A JP3901735B2 (ja) 1996-05-30 1997-05-30 Ｎ―ビス―またはｎ―トリス〔（１，２―ジカルボキシエトキシ）エチル〕アミン誘導体およびそれらの製造および用途
BR9709393A BR9709393A (pt) 1996-05-30 1997-05-30 Derivados de n-bis ou n-tris-[(1,2-dicarbóxietóxi)etil] amina e preparação e uso dos mesmos
AT97924047T ATE198316T1 (de) 1996-05-30 1997-05-30 N-bis- oder n-tris-((1,2-dicarboxy-ethoxy)-ethyl)-amin-deri ate und herstellung und anwendung derselben
PCT/FI1997/000332 WO1997045396A1 (en) 1996-05-30 1997-05-30 N-bis- or n-tris-[(1,2-dicarboxy-ethoxy)-ethyl]-amine derivatives and preparation and use of the same
CNB971951357A CN1158243C (zh) 1996-05-30 1997-05-30 N-双-或n-三-[(1,2-二羟基-乙氧基)-乙基]胺衍生物以及它们的制备和用途
PCT/FI1997/000334 WO1997045585A1 (en) 1996-05-30 1997-05-30 Process for the bleaching of high yield pulp or recycled paper pulp
CA002256559A CA2256559C (en) 1996-05-30 1997-05-30 N-bis- or n-tris-[(1,2-dicarboxy-ethoxy)-ethyl]-amine derivatives and preparation and use of the same
CA002256579A CA2256579C (en) 1996-05-30 1997-05-30 Process for the bleaching of chemical pulp
DE69703796T DE69703796T2 (de) 1996-05-30 1997-05-30 N-bis- oder n-tris-[(1,2-dicarboxy-ethoxy)-ethyl]-amin-derivate und herstellung und anwendung derselben
EP97924047A EP0904263B1 (en) 1996-05-30 1997-05-30 N-bis- or n-tris-[(1,2-dicarboxy-ethoxy)-ethyl]-amine derivatives and preparation and use of the same
ES97924047T ES2154902T3 (es) 1996-05-30 1997-05-30 Derivados de la n-bis o n-tris-((1,2-dicarboxi-etoxi)-etil)-amina y a la preparacion y empleo de los mismos.
AU29644/97A AU2964497A (en) 1996-05-30 1997-05-30 Process for the bleaching of chemical pulp
US09/194,349 US6264790B1 (en) 1996-05-30 1997-05-30 Process for the peracid bleaching of chelated chemical pulp
AT97924048T ATE252178T1 (de) 1996-05-30 1997-05-30 Verfahren zum bleichen von zellstoff
EP97924048A EP0907788B1 (en) 1996-05-30 1997-05-30 Process for the bleaching of chemical pulp
PCT/FI1997/000333 WO1997045586A1 (en) 1996-05-30 1997-05-30 Process for the bleaching of chemical pulp
US09/194,310 US6093849A (en) 1996-05-30 1997-05-30 N-bis- or N-tris-[(1,2-dicarboxy-ethoxy)-ethyl]-amine derivatives and preparation and use of the same
AU29645/97A AU2964597A (en) 1996-05-30 1997-05-30 Process for the bleaching of high yield pulp or recycled paper pulp
DE69725573T DE69725573T2 (de) 1996-05-30 1997-05-30 Verfahren zum bleichen von zellstoff

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FI962261A FI112075B (sv) 1996-05-30 1996-05-30 N-bis- eller N-tris[(1,2-dikarboxyl-etoxi)-etyl]aminderivat, framställning och användning av dem
FI962261 1996-05-30

Publications (3)

Publication Number Publication Date
FI962261A0 FI962261A0 (sv) 1996-05-30
FI962261A FI962261A (sv) 1997-12-01
FI112075B true FI112075B (sv) 2003-10-31

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
FI962261A FI112075B (sv) 1996-05-30 1996-05-30 N-bis- eller N-tris[(1,2-dikarboxyl-etoxi)-etyl]aminderivat, framställning och användning av dem

Country Status (13)

Country Link
US (1) US6093849A (sv)
EP (1) EP0904263B1 (sv)
JP (1) JP3901735B2 (sv)
CN (1) CN1158243C (sv)
AT (1) ATE198316T1 (sv)
AU (1) AU2964397A (sv)
BR (1) BR9709393A (sv)
CA (1) CA2256559C (sv)
DE (1) DE69703796T2 (sv)
ES (1) ES2154902T3 (sv)
FI (1) FI112075B (sv)
PT (1) PT904263E (sv)
WO (1) WO1997045396A1 (sv)

Families Citing this family (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FI105214B (sv) * 1997-11-13 2000-06-30 Kemira Chemicals Oy Effektiverat förfarande för blekning av en kemisk massa
FI106258B (sv) 1998-03-09 2000-12-29 Kemira Chemicals Oy Förfaranden för framställning av ett N-bis-[2-(1,2-dikarboxi-etoxi)-etyl]aminderivat samt produkter som erhålls genom förfarandena och användningar därav
DE60020318T2 (de) 1999-09-03 2006-05-18 Nippon Shokubai Co., Ltd. Zusammensetzung von Aminosäure-Derivaten und Verfahren zur Herstellung von einem Aminosäure-Derivat
JP4632500B2 (ja) * 1999-09-03 2011-02-16 株式会社日本触媒 アミノ酸誘導体組成物及びアミノ酸誘導体の製造方法
FI122828B (sv) 2010-06-02 2012-07-31 Kemira Oyj Förfarande för återvinning av en katalysator
FI122829B (sv) 2010-06-02 2012-07-31 Kemira Oyj Förfarande för framställning av en blandning av kelaterande ämnen
US9745504B2 (en) 2013-03-21 2017-08-29 Halliburton Energy Services, Inc. Wellbore servicing compositions and methods of making and using same
US9512348B2 (en) 2013-03-28 2016-12-06 Halliburton Energy Services, Inc. Removal of inorganic deposition from high temperature formations with non-corrosive acidic pH fluids
SI2902544T1 (sl) * 2014-01-30 2017-09-29 Archroma France Sas Vodni sestavek, ki obsega polivalentno kovino, ki tvori komplekse s kabonatnimi ligandi in ligandi karboksilne kisline, ter njegova uporaba
CN106905171B (zh) * 2017-03-31 2018-12-11 浙江大学 2-[2-叔丁氧基乙氧基]-乙胺的制备方法
BR112019027294A2 (pt) * 2017-06-30 2020-07-21 Kemira Oyj processo para preparação de mistura de agentes quelantes, mistura de agentes quelantes e métodos de uso
CN110891931B (zh) 2017-06-30 2022-11-08 凯米拉公司 制备螯合剂混合物的方法、螯合剂混合物及其使用方法

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4044034A (en) * 1975-07-22 1977-08-23 The Miranol Chemical Company, Inc. Nitrogenous condensation products
JP2896541B2 (ja) * 1991-09-11 1999-05-31 コニカ株式会社 ハロゲン化銀写真感光材料用処理液
JPH06282044A (ja) * 1993-03-26 1994-10-07 Konica Corp ハロゲン化銀写真感光材料用固形処理剤包装体
JPH07120894A (ja) * 1993-10-21 1995-05-12 Fuji Photo Film Co Ltd 写真用処理組成物及び処理方法
JPH07120899A (ja) * 1993-10-27 1995-05-12 Fuji Photo Film Co Ltd 写真用処理組成物及び処理方法
JPH07261355A (ja) * 1994-03-17 1995-10-13 Fuji Photo Film Co Ltd カラー写真用処理装置および処理方法

Also Published As

Publication number Publication date
CN1158243C (zh) 2004-07-21
PT904263E (pt) 2001-04-30
AU2964397A (en) 1998-01-05
US6093849A (en) 2000-07-25
WO1997045396A1 (en) 1997-12-04
JP2000515121A (ja) 2000-11-14
DE69703796D1 (de) 2001-02-01
CN1220659A (zh) 1999-06-23
FI962261A (sv) 1997-12-01
BR9709393A (pt) 1999-08-10
CA2256559A1 (en) 1997-12-04
EP0904263B1 (en) 2000-12-27
FI962261A0 (sv) 1996-05-30
DE69703796T2 (de) 2001-04-19
CA2256559C (en) 2006-05-02
ATE198316T1 (de) 2001-01-15
EP0904263A1 (en) 1999-03-31
ES2154902T3 (es) 2001-04-16
JP3901735B2 (ja) 2007-04-04

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