FI111711B - Polyol- och komplexa estrar i synnerhet för användning med fluorerade köldmedel - Google Patents
Polyol- och komplexa estrar i synnerhet för användning med fluorerade köldmedel Download PDFInfo
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- FI111711B FI111711B FI971549A FI971549A FI111711B FI 111711 B FI111711 B FI 111711B FI 971549 A FI971549 A FI 971549A FI 971549 A FI971549 A FI 971549A FI 111711 B FI111711 B FI 111711B
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- C10M171/00—Lubricating compositions characterised by purely physical criteria, e.g. containing as base-material, thickener or additive, ingredients which are characterised exclusively by their numerically specified physical properties, i.e. containing ingredients which are physically well-defined but for which the chemical nature is either unspecified or only very vaguely indicated
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- C09K5/044—Materials undergoing a change of physical state when used the change of state being from liquid to vapour or vice versa for compression-type refrigeration systems comprising halogenated compounds
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- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
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- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
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- C10M2207/28—Esters
- C10M2207/30—Complex esters, i.e. compounds containing at leasst three esterified carboxyl groups and derived from the combination of at least three different types of the following five types of compounds: monohydroxyl compounds, polyhydroxy xompounds, monocarboxylic acids, polycarboxylic acids or hydroxy carboxylic acids
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- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/28—Esters
- C10M2207/30—Complex esters, i.e. compounds containing at leasst three esterified carboxyl groups and derived from the combination of at least three different types of the following five types of compounds: monohydroxyl compounds, polyhydroxy xompounds, monocarboxylic acids, polycarboxylic acids or hydroxy carboxylic acids
- C10M2207/304—Complex esters, i.e. compounds containing at leasst three esterified carboxyl groups and derived from the combination of at least three different types of the following five types of compounds: monohydroxyl compounds, polyhydroxy xompounds, monocarboxylic acids, polycarboxylic acids or hydroxy carboxylic acids derived from the combination of monohydroxy compounds, dihydroxy compounds and dicarboxylic acids only and having no free hydroxy or carboxyl groups
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Claims (16)
1. Kylmedelsblandning, som omfattar ett klorfritt, fluorkolvätebaserat kylmedel samt ett därmedblandatsmöijmedelsominnehällerenpolyolester, kännetecknad avatt 5 smörjmedlet innehäller en ester av 2-butyl-2-etyl-l ,3-propandiol samt en ester av minst en andra polyol, varvid andelen av 2-butyl-2-etyl-l,3-propandiolens ester av smörjmedlets polyolrest uppgär tili minst 50 mol-%.
2. Kylmedelsblandning enligt krav 1, kännetecknad avatt polyolresten av 10 smöqmedlets andra polyolester är härledd frän neopentylglykol, hydroxipivalylhydroxi-pivalat, 2-etyl-l,3-hexandiol, trimetylolpropan, trimetyloletan, pentaerytritol eller 2,2,4-trimetylpentandiol.
3. Kylmedelsblandning enligt nägot av de föregäende kraven, kännetecknad avatt 15 molförhällandet mellan 2-butyl-2-etyl-1,3-propandiol och den andra polyolen i smöqmedlet uppgär tili 50 : 50...99,9 : 0,1.
4. Kylmedelsblandning enligt nägot av de föregäende kraven, kännetecknad avatt karboxylsyraresten av polyolestem är härledd frän en lineär eller förgrenad C4...Cjg- . . 20 karboxylsyra eller dess anhydrid, eller är härledd frän en blandning av en lineär eller > · ’ förgrenad C^.-Cig-karboxylsyra eller dess anhydrid. ; - j
5. Kylmedelsblandning enligt krav 4, kännetecknad avatt karboxylsyraresten är • ‘ ·.. härledd frän 2-etylhexansyra, oktansyra och/eller laurinsyra. 25
6. Kylmedelsblandning enligt krav 1, kännetecknad avatt karboxylsyraresten av j ’, estem är härledd frän en blandning av en- och tväbasiska karboxylsyror. » I I ;1;
7. Kylmedelsblandning enligt krav 6, kännetecknad avatt den envärdiga • I I I 30 karboxylsyraresten är härledd frän lineära eller förgrenade C4...C1 g-karboxylsyror, deras :'\': anhydrider eller blandningar. » · i6 111711
8. Kylmedelsblandning enligt kraven 6 eller 7, k ä n n e t e c k n a d av att den tvävärdiga karboxylsyraresten är härledd frän oxalsyra, malonsyra, dimetyl-malonsyra, bämstenssyra, glutarsyra, adipinsyra, sebacinsyra, pimelinsyra, suberinsyra eller azelainsyra, eller frän en cyklisk anhydrid, säsom bämstensyraanhydrid eller dess alkylderivat, eller 5 trimellitanhydrid.
9. Kylmedelsblandning enligt nägot av kraven 6-8, kännetecknad av att molforhällandet mellan de en- och tväbasiska karboxylsyroma är 50:50...99:1.
10. Kylmedelsblandning enligt nägot av de föregäende kraven, kännetecknad av att den fluorerade kolvätebaserade kylvätskan är fluorkolväte 134, fluorkolväte 134a, fluorkolväte 143, fluorkolväte 143a, fluorkolväte 152 eller fluorkolväte 152a eller en blandning av fluorkolväten.
11. Komplexestrar av 2-butyl-2-etyl-1,3-propanidiol, som innehäller karboxylsyrarester av bäde en- och tväbasiska karboxylsyror, varvid molforhällandet mellan de en- och tväbasiska karboxylsyraestrama i estem är 50 : 50...99 : 1.
12. Estrar enligt krav ll,kännetecknade av att karboxylsyrarestema av envärdiga ... 20 estrar är härledda frän lineära eller förgrenade C4... C j g -karboxylsyror, deras anhydrider t · · .:. eller blandningar. 1 1 · · • 1 • « · • » t
* · · · ·:··· 13. Estrar enligt krav 11 eller 12, k ä n n e t e c k n a d e av att de tvävärdiga i 1 ·,. karboxylsyrarestema av estrar är härledda frän oxalsyra, malonsyra, dimetyl-malonsyra, : .1 25 bämstenssyra, glutarsyra, adipinsyra, sebacinsyra, pimelinsyra, suberinsyra eller azelainsyra, eller frän en cyklisk anhydrid, som bämstensyraanhydrid eller dess I · 1 • '. alkylderivat, eller trimellitanhydrid. * 1 I * · • 1
» : 14. Estrar enligt nägot av krav 11 - 13, k ä n n e t e c k n a d e av att de finns i blandning t 1 1 ♦ :" ’: 30 med en annan polyolester och/eller komplexestrar. * · t
....: 15. Estrar enligt krav 14, kännetecknade av att de finns i blandning med estrar och/eller komplexestrar av NPG, ETHD eller PE. 111711
16. Användningen av en ester enligt nägot av kraven 11-15 säsom basolja ι smörjemedel. i * *
Priority Applications (15)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FI971549A FI111711B (sv) | 1997-04-11 | 1997-04-11 | Polyol- och komplexa estrar i synnerhet för användning med fluorerade köldmedel |
FI980730A FI980730A (sv) | 1997-04-11 | 1998-03-31 | Polyol- och komplexa estrar i synnerhet för användning med fluorerade köldmedel |
BR9809077-1A BR9809077A (pt) | 1997-04-11 | 1998-04-08 | ésteres de poliol e complexos para uso, em particular, com refrigerantes fluorados |
PCT/FI1998/000313 WO1998046704A1 (en) | 1997-04-11 | 1998-04-08 | Polyol and complex esters for use with, in particular, fluorinated refrigerants |
CN98805978A CN1108360C (zh) | 1997-04-11 | 1998-04-08 | 尤其适于与氟化制冷剂一起应用的多元醇和复合酯 |
EP98913780A EP0973851A1 (en) | 1997-04-11 | 1998-04-08 | Polyol and complex esters for use with, in particular, fluorinated refrigerants |
AU68348/98A AU6834898A (en) | 1997-04-11 | 1998-04-08 | Polyol and complex esters for use with, in particular, fluorinated refrigerants |
CA002285547A CA2285547A1 (en) | 1997-04-11 | 1998-04-08 | Polyol and complex esters for use with, in particular, fluorinated refrigerants |
KR19997009332A KR20010006249A (ko) | 1997-04-11 | 1998-04-08 | 플루오르화된 냉매와 함께 사용하기 위한 폴리올 및 복합 에스테르 |
US09/402,548 US6436309B1 (en) | 1997-04-11 | 1998-04-08 | Polyol and complex esters for use with, in particular, fluorinated refrigerants |
JP54352198A JP2001518971A (ja) | 1997-04-11 | 1998-04-08 | 特にフッ素化冷媒とともに使用するためのポリオールおよび複合エステル |
PCT/FI1998/000329 WO1998046706A1 (en) | 1997-04-11 | 1998-04-14 | Polyol and complex esters for use with, in particular, fluorinated refrigerants |
JP54352898A JP2001526712A (ja) | 1997-04-11 | 1998-04-14 | 特にフッ素化冷媒とともに使用するためのポリオールおよび複合エステル |
AU68361/98A AU6836198A (en) | 1997-04-11 | 1998-04-14 | Polyol and complex esters for use with, in particular, fluorinated refrigerants |
EP98913796A EP0973853A1 (en) | 1997-04-11 | 1998-04-14 | Polyol and complex esters for use with, in particular, fluorinated refrigerants |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FI971549A FI111711B (sv) | 1997-04-11 | 1997-04-11 | Polyol- och komplexa estrar i synnerhet för användning med fluorerade köldmedel |
FI971549 | 1997-04-11 |
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Publication Number | Publication Date |
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FI971549A0 FI971549A0 (fi) | 1997-04-11 |
FI111711B true FI111711B (sv) | 2003-09-15 |
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FI971549A FI111711B (sv) | 1997-04-11 | 1997-04-11 | Polyol- och komplexa estrar i synnerhet för användning med fluorerade köldmedel |
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Country | Link |
---|---|
US (1) | US6436309B1 (sv) |
EP (1) | EP0973851A1 (sv) |
JP (1) | JP2001518971A (sv) |
KR (1) | KR20010006249A (sv) |
CN (1) | CN1108360C (sv) |
AU (1) | AU6834898A (sv) |
BR (1) | BR9809077A (sv) |
CA (1) | CA2285547A1 (sv) |
FI (1) | FI111711B (sv) |
WO (1) | WO1998046704A1 (sv) |
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JP4806967B2 (ja) | 2005-05-27 | 2011-11-02 | 日油株式会社 | 冷凍機用潤滑油組成物 |
US8402778B2 (en) * | 2008-03-31 | 2013-03-26 | National Refrigerants, Inc. | Method for enhancing mineral oil miscibility and oil return |
JP2015110698A (ja) * | 2013-12-06 | 2015-06-18 | コスモ石油ルブリカンツ株式会社 | 潤滑油用エステル基油及び潤滑油 |
TWI522456B (zh) | 2015-03-27 | 2016-02-21 | Novel refrigeration oil | |
CN107429953A (zh) | 2015-03-30 | 2017-12-01 | 开利公司 | 低油制冷剂和蒸汽压缩系统 |
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FR2649531B1 (fr) * | 1989-07-04 | 1995-11-10 | Alsthom Gec | Disjoncteur a haute ou moyenne tension |
JP2801703B2 (ja) * | 1989-09-01 | 1998-09-21 | 花王株式会社 | 冷凍機油 |
DK0435253T3 (da) * | 1989-12-28 | 1994-06-20 | Nippon Oil Co Ltd | Køleolier til brug sammen med hydrogenholdige halogencarbonkølemidler |
US5374366A (en) * | 1992-04-15 | 1994-12-20 | Sanken Chemical Co., Ltd. | Synthetic lubricating oil |
FR2734576B1 (fr) * | 1995-05-24 | 1997-07-18 | Elf Antar France | Composition lubrifiante pour compresseurs frigorifiques |
SE9602465D0 (sv) * | 1996-06-24 | 1996-06-24 | Perstorp Ab | A lubricant ester |
-
1997
- 1997-04-11 FI FI971549A patent/FI111711B/sv not_active IP Right Cessation
-
1998
- 1998-04-08 EP EP98913780A patent/EP0973851A1/en not_active Withdrawn
- 1998-04-08 WO PCT/FI1998/000313 patent/WO1998046704A1/en not_active Application Discontinuation
- 1998-04-08 JP JP54352198A patent/JP2001518971A/ja active Pending
- 1998-04-08 BR BR9809077-1A patent/BR9809077A/pt not_active IP Right Cessation
- 1998-04-08 US US09/402,548 patent/US6436309B1/en not_active Expired - Fee Related
- 1998-04-08 KR KR19997009332A patent/KR20010006249A/ko not_active Application Discontinuation
- 1998-04-08 CN CN98805978A patent/CN1108360C/zh not_active Expired - Fee Related
- 1998-04-08 AU AU68348/98A patent/AU6834898A/en not_active Abandoned
- 1998-04-08 CA CA002285547A patent/CA2285547A1/en not_active Abandoned
Also Published As
Publication number | Publication date |
---|---|
US6436309B1 (en) | 2002-08-20 |
EP0973851A1 (en) | 2000-01-26 |
BR9809077A (pt) | 2000-08-01 |
CA2285547A1 (en) | 1998-10-22 |
AU6834898A (en) | 1998-11-11 |
JP2001518971A (ja) | 2001-10-16 |
KR20010006249A (ko) | 2001-01-26 |
CN1108360C (zh) | 2003-05-14 |
FI971549A0 (fi) | 1997-04-11 |
WO1998046704A1 (en) | 1998-10-22 |
CN1259986A (zh) | 2000-07-12 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
MA | Patent expired |