ES8603511A1 - Un procedimiento para preparar catalizadores soportados adecuados para polimerizar olefinas - Google Patents
Un procedimiento para preparar catalizadores soportados adecuados para polimerizar olefinasInfo
- Publication number
- ES8603511A1 ES8603511A1 ES537870A ES537870A ES8603511A1 ES 8603511 A1 ES8603511 A1 ES 8603511A1 ES 537870 A ES537870 A ES 537870A ES 537870 A ES537870 A ES 537870A ES 8603511 A1 ES8603511 A1 ES 8603511A1
- Authority
- ES
- Spain
- Prior art keywords
- pref
- cpd
- atom
- redn
- stage
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2410/00—Features related to the catalyst preparation, the catalyst use or to the deactivation of the catalyst
- C08F2410/06—Catalyst characterized by its size
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/901—Monomer polymerized in vapor state in presence of transition metal containing catalyst
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Catalysts (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
METODO DE PREPARACION DE CATALIZADORES SOPORTADOS EN LOS QUE EL SOPORTE ESTA CONSTITUIDO BASICAMENTE POR CLORURO DE MAGNESIO Y CLORURO DE ALUMINIO, EN FORMA DE PARTICULAS ESFEROIDALES CUYO DIAMETRO MEDIO ESTA COMPRENDIDO ENTRE 10 Y 100 MICRAS; QUE TIENEN APLICACIONES PARA LA COPOLIMERIZACION DE ETILENO Y OTRAS A-OLEFINAS. COMPRENDE LA PRECIPITACION, SOBRE EL SOPORTE, DE UN METAL DE TRANSICION CORRESPONDIENTE A UNO DE LOS GRUPOS IV, V O VI DE LA TABLA PERIODICA, A PARTIR DE UNO DE SUS COMPUESTOS, MEDIANTE REDUCCION DEL MISMO EN DOS ETAPAS. LA PRIMERA REDUCCION SE LLEVA A CABO CON UN AGENTE REDUCTOR DIHALURO DE DIALQUILALUMINIO, DE FORMULA AL(R8)X2, EN LA QUE R8 ES UN ALQUILO DE 2 A 12 ATOMOS DE CARBONO Y X ES CLORO O BROMO; Y LA SEGUNDA REDUCCION SE EFECTUA CON OTRO AGENTE REDUCTOR, COMPUESTO ORGANOMETALICO DE METAL PERTENECIENTE A UNO DE LOS GRUPOS II O III DE LA TABLA PERIODICA.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR8318624A FR2555182B1 (fr) | 1983-11-23 | 1983-11-23 | Procede de preparation de catalyseur supporte pour la copolymerisation de l'ethylene avec des alpha-olefines superieures |
Publications (2)
Publication Number | Publication Date |
---|---|
ES537870A0 ES537870A0 (es) | 1985-12-16 |
ES8603511A1 true ES8603511A1 (es) | 1985-12-16 |
Family
ID=9294418
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES537870A Expired ES8603511A1 (es) | 1983-11-23 | 1984-11-22 | Un procedimiento para preparar catalizadores soportados adecuados para polimerizar olefinas |
Country Status (14)
Country | Link |
---|---|
US (1) | US4564605A (es) |
EP (1) | EP0143002B1 (es) |
JP (1) | JPS60133011A (es) |
AT (1) | ATE36863T1 (es) |
AU (1) | AU580974B2 (es) |
CA (1) | CA1222999A (es) |
DE (1) | DE3473765D1 (es) |
ES (1) | ES8603511A1 (es) |
FI (1) | FI79331C (es) |
FR (1) | FR2555182B1 (es) |
IN (1) | IN166822B (es) |
NO (1) | NO163960C (es) |
NZ (1) | NZ210270A (es) |
PT (1) | PT79539B (es) |
Families Citing this family (74)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5208109A (en) * | 1982-06-24 | 1993-05-04 | Bp Chemicals Limited | Process for the polymerization and copolymerization of alpha-olefins in a fluidized bed |
IT1173452B (it) * | 1984-03-20 | 1987-06-24 | Montedison Spa | Componenti e catalizzatori per la polimerizzazione delle olefine |
US5349033A (en) * | 1986-06-14 | 1994-09-20 | Hoechst Aktiengesellschaft | Process for the preparation of polyolefin |
FI85498C (fi) * | 1988-11-08 | 1992-04-27 | Neste Oy | Foerfarande foer polymerisering och kopolymerisering av alfa-olefiner och ett i foerfarandet anvaent katalysatorsystem. |
FR2639351B1 (es) * | 1988-11-23 | 1992-12-31 | Atochem | |
FR2647454B1 (fr) * | 1989-05-29 | 1993-01-22 | Solvay | Suspensions de particules contenant des composes de metaux de transition dans des huiles et procedes de polymerisation d'alpha-olefines effectues en presence de ces suspensions |
ZA974798B (en) * | 1996-05-31 | 1998-11-30 | Sastech Pty Ltd | Termpolymerization |
US6281306B1 (en) | 1999-12-16 | 2001-08-28 | Univation Technologies, Llc | Method of polymerization |
EP1620479B1 (en) | 2002-10-15 | 2013-07-24 | ExxonMobil Chemical Patents Inc. | Polyolefin adhesive compositions and articles made therefrom |
US7223822B2 (en) | 2002-10-15 | 2007-05-29 | Exxonmobil Chemical Patents Inc. | Multiple catalyst and reactor system for olefin polymerization and polymers produced therefrom |
EP1611169B1 (en) * | 2003-03-21 | 2010-06-02 | Dow Global Technologies Inc. | Morphology controlled olefin polymerization process |
US6953764B2 (en) | 2003-05-02 | 2005-10-11 | Dow Global Technologies Inc. | High activity olefin polymerization catalyst and process |
US7985811B2 (en) * | 2004-01-02 | 2011-07-26 | Univation Technologies, Llc | Method for controlling sheeting in gas phase reactors |
US20050148742A1 (en) * | 2004-01-02 | 2005-07-07 | Hagerty Robert O. | Method for controlling sheeting in gas phase reactors |
US20070073012A1 (en) * | 2005-09-28 | 2007-03-29 | Pannell Richard B | Method for seed bed treatment before a polymerization reaction |
US7193017B2 (en) * | 2004-08-13 | 2007-03-20 | Univation Technologies, Llc | High strength biomodal polyethylene compositions |
US7629422B2 (en) | 2004-12-21 | 2009-12-08 | Univation Technologies, Llc | Process for transitioning between Ziegler-Natta-based and chromium-based catalysts |
US6987152B1 (en) | 2005-01-11 | 2006-01-17 | Univation Technologies, Llc | Feed purification at ambient temperature |
US7312279B2 (en) * | 2005-02-07 | 2007-12-25 | Univation Technologies, Llc | Polyethylene blend compositions |
US7947797B2 (en) | 2005-09-14 | 2011-05-24 | Univation Technologies, Llc | Method for operating a gas-phase reactor at or near maximum production rates while controlling polymer stickiness |
US20070109911A1 (en) * | 2005-11-16 | 2007-05-17 | Neubauer Anthony C | High speed and direct driven rotating equipment for polyolefin manufacturing |
EP1803747A1 (en) | 2005-12-30 | 2007-07-04 | Borealis Technology Oy | Surface-modified polymerization catalysts for the preparation of low-gel polyolefin films |
EP3467077A1 (en) | 2006-10-03 | 2019-04-10 | Univation Technologies, LLC | System for olefin polymerization |
TW200936564A (en) * | 2007-11-15 | 2009-09-01 | Univation Tech Llc | Methods for the removal of impurities from polymerization feed streams |
US20100125124A1 (en) * | 2008-11-17 | 2010-05-20 | Fina Technology, Inc. | Methods of catalyst activation |
BRPI0922454A2 (pt) | 2008-12-18 | 2018-05-22 | Univation Tech Llc | método para tratamento de leito de semente para uma reação de polimerização |
WO2010080871A1 (en) | 2009-01-08 | 2010-07-15 | Univation Technologies, Llc | Additive for gas phase polymerization processes |
JP5661645B2 (ja) | 2009-01-08 | 2015-01-28 | ユニベーション・テクノロジーズ・エルエルシー | ポリオレフィン重合プロセス用の添加剤 |
US8598283B2 (en) | 2010-02-18 | 2013-12-03 | Univation Technologies, Llc | Methods for operating a polymerization reactor |
JP5727523B2 (ja) | 2010-02-22 | 2015-06-03 | ユニベーション・テクノロジーズ・エルエルシー | 触媒系及びポリオレフィン製品を製造するための該触媒系の使用方法 |
EP2558531B1 (en) | 2010-04-13 | 2017-02-15 | Univation Technologies, LLC | Polymer blends and films made therefrom |
WO2012009215A1 (en) | 2010-07-16 | 2012-01-19 | Univation Technologies, Llc | Systems and methods for measuring static charge on particulates |
BR112013000679A2 (pt) | 2010-07-16 | 2016-05-31 | Univation Tech Llc | sistemas e métodos para medir acúmulo de partícula em superfícies de reator |
WO2012015898A1 (en) | 2010-07-28 | 2012-02-02 | Univation Technologies, Llc | Systems and methods for measuring velocity of a particle/fluid mixture |
EP2651982B1 (en) | 2010-12-17 | 2018-04-11 | Univation Technologies, LLC | Systems and methods for recovering hydrocarbons from a polyolefin purge gas product |
CN103347905B (zh) | 2010-12-22 | 2015-12-16 | 尤尼威蒂恩技术有限责任公司 | 用于聚烯烃聚合方法的添加剂 |
US9382347B2 (en) * | 2011-02-16 | 2016-07-05 | Fina Technology Inc | Ziegler-Natta catalysts doped with non-group IV metal chlorides |
WO2013028283A1 (en) | 2011-08-19 | 2013-02-28 | Univation Technologies, Llc | Catalyst systems and methods for using same to produce polyolefin products |
WO2013070602A1 (en) | 2011-11-08 | 2013-05-16 | Univation Technologies, Llc | Methods for producing polyolefins with catalyst systems |
EP2750797B1 (en) | 2011-11-08 | 2020-04-01 | Univation Technologies, LLC | Methods of preparing a catalyst system |
CA2800056A1 (en) | 2012-12-24 | 2014-06-24 | Nova Chemicals Corporation | Polyethylene blend compositions |
WO2014106143A1 (en) | 2012-12-28 | 2014-07-03 | Univation Technologies, Llc | Supported catalyst with improved flowability |
ES2823768T3 (es) | 2012-12-28 | 2021-05-10 | Univation Tech Llc | Métodos para integrar la producción de aluminoxano en la producción de catalizador |
EP3747913B1 (en) | 2014-04-02 | 2024-04-17 | Univation Technologies, LLC | Continuity compositions and olefin polymerisation method using the same |
EP3189085B1 (en) * | 2014-09-04 | 2019-08-07 | PTT Global Chemical Public Company Limited | A method for preparing high activity ethylene polymerization catalyst |
CA2974122C (en) | 2015-01-21 | 2023-09-19 | Univation Technologies, Llc | Methods for gel reduction in polyolefins |
EP3247548B1 (en) | 2015-01-21 | 2021-09-01 | Univation Technologies, LLC | Methods for controlling polymer chain scission |
EP3268399B1 (en) | 2015-03-10 | 2021-01-20 | Univation Technologies, LLC | Spray dried catalyst compositions, methods for preparation and use in olefin polymerization processes |
CA2983736C (en) | 2015-04-27 | 2023-09-12 | Univation Technologies, Llc | Supported catalyst compositions having improved flow properties and preparation thereof |
CN107660216B (zh) | 2015-05-08 | 2021-05-14 | 埃克森美孚化学专利公司 | 聚合方法 |
US10975183B2 (en) | 2016-09-09 | 2021-04-13 | Exxonmobil Chemical Patents Inc. | Pilot plant scale semi-condensing operation |
WO2018063764A1 (en) | 2016-09-27 | 2018-04-05 | Exxonmobil Chemical Patents Inc. | Polymerization process |
WO2018063765A1 (en) | 2016-09-27 | 2018-04-05 | Exxonmobil Chemical Patents Inc. | Polymerization process |
WO2018063767A1 (en) | 2016-09-27 | 2018-04-05 | Exxonmobil Chemical Patents Inc. | Polymerization process |
WO2018118258A1 (en) | 2016-12-20 | 2018-06-28 | Exxonmobil Chemical Patents Inc. | Methods for controlling start up conditions in polymerization processes |
WO2018118155A1 (en) | 2016-12-20 | 2018-06-28 | Exxonmobil Chemical Patents Inc. | Polymerization process |
CA3052770C (en) | 2017-02-07 | 2021-09-07 | Exxonmobil Chemical Patents Inc. | Processes for reducing the loss of catalyst activity of a ziegler-natta catalyst |
WO2019118073A1 (en) | 2017-12-13 | 2019-06-20 | Exxonmobil Chemical Patents Inc. | Deactivation methods for active components from gas phase polyolefin polymerization process |
WO2019173030A1 (en) | 2018-03-08 | 2019-09-12 | Exxonmobil Chemical Patents Inc. | Methods of preparing and monitoring a seed bed for polymerization reactor startup |
CN112055720B (zh) | 2018-05-02 | 2022-11-22 | 埃克森美孚化学专利公司 | 从中试装置放大到较大生产设施的方法 |
EP3788081A1 (en) | 2018-05-02 | 2021-03-10 | ExxonMobil Chemical Patents Inc. | Methods for scale-up from a pilot plant to a larger production facility |
WO2020109870A2 (en) | 2018-06-28 | 2020-06-04 | Exxonmobil Chemical Patents Inc. | Polyethylene compositions, wires and cables, and methods for making the same |
WO2020014138A1 (en) | 2018-07-09 | 2020-01-16 | Exxonmobil Chemical Patents Inc. | Polyethylene cast films and methods for making the same |
CN112469556B (zh) | 2018-07-26 | 2023-05-02 | 埃克森美孚化学专利公司 | 多层泡沫膜及其制造方法 |
CN113195603B (zh) | 2018-11-13 | 2023-05-26 | 埃克森美孚化学专利公司 | 聚乙烯膜 |
US11649331B2 (en) | 2018-11-13 | 2023-05-16 | Exxonmobil Chemical Patents Inc. | Polyethylene blends and films |
US11866522B2 (en) | 2018-12-28 | 2024-01-09 | Braskem S.A. | Process for introducing catalyst in a polymerization process |
WO2020163079A1 (en) | 2019-02-06 | 2020-08-13 | Exxonmobil Chemical Patents Inc. | Films and backsheets for hygiene articles |
US20230018505A1 (en) | 2019-12-17 | 2023-01-19 | Exxonmobil Chemical Patents Inc. | Films Made of Polyethylene Blends for Improved Sealing Performance and Mechanical Properties |
US20230097375A1 (en) | 2020-03-12 | 2023-03-30 | Exxonmobil Chemical Patents Inc. | Films made of polyethylene blends for improved bending stiffness and high md tear resistance |
WO2022020025A1 (en) | 2020-07-22 | 2022-01-27 | Exxonmobil Chemical Patents Inc. | Polyolefin compositions and articles thereof |
WO2022126068A1 (en) | 2020-12-08 | 2022-06-16 | Exxonmobil Chemical Patents Inc. | High density polyethylene compositions with long-chain branching |
WO2022232760A1 (en) | 2021-04-30 | 2022-11-03 | Exxonmobil Chemical Patents Inc. | Processes for transitioning between different polymerization catalysts in a polymerization reactor |
WO2023081577A1 (en) | 2021-11-02 | 2023-05-11 | Exxonmobil Chemical Patents Inc. | Polyethylene compositions, articles thereof, and methods thereof |
Family Cites Families (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2943063A (en) * | 1955-11-30 | 1960-06-28 | Exxon Research Engineering Co | Catalysts for polymerization of olefins |
US3118865A (en) * | 1960-02-03 | 1964-01-21 | Du Pont | Olefin polymerization catalyst |
US2971925A (en) * | 1959-02-16 | 1961-02-14 | Shell Oil Co | Polymerization catalysts |
US3135809A (en) * | 1960-07-21 | 1964-06-02 | Southern Res Inst | Isomerization process |
US3278510A (en) * | 1963-01-28 | 1966-10-11 | Union Carbide Corp | Stable catalyst systems for highly crystalline alpha olefin polymers |
US3293229A (en) * | 1963-01-28 | 1966-12-20 | Union Carbide Corp | Stable, promoted catalyst systems for highly crystalline alpha olefin polymers |
NO750225L (es) * | 1974-02-12 | 1975-08-13 | Ici Ltd | |
JPS591723B2 (ja) * | 1980-01-17 | 1984-01-13 | チッソ株式会社 | α−オレフイン重合体を製造する方法 |
FR2529207A1 (fr) * | 1982-06-24 | 1983-12-30 | Bp Chimie Sa | Procede pour la preparation de supports de catalyseurs pour la polymerisation des alpha-olefines et supports obtenus |
DE3366573D1 (en) * | 1982-06-24 | 1986-11-06 | Bp Chimie Sa | Process for the polymerization and copolymerization of alpha-olefins in a fluidized bed |
DE3362530D1 (en) * | 1982-06-24 | 1986-04-17 | Bp Chimie Sa | Catalysts for the polymerization and copolymerization of ethylene, and polymerization processes using such catalysts |
-
1983
- 1983-11-23 FR FR8318624A patent/FR2555182B1/fr not_active Expired
-
1984
- 1984-11-19 CA CA000468123A patent/CA1222999A/en not_active Expired
- 1984-11-20 NZ NZ210270A patent/NZ210270A/en unknown
- 1984-11-21 US US06/673,889 patent/US4564605A/en not_active Expired - Fee Related
- 1984-11-21 AU AU35757/84A patent/AU580974B2/en not_active Ceased
- 1984-11-22 EP EP84308119A patent/EP0143002B1/en not_active Expired
- 1984-11-22 DE DE8484308119T patent/DE3473765D1/de not_active Expired
- 1984-11-22 AT AT84308119T patent/ATE36863T1/de not_active IP Right Cessation
- 1984-11-22 NO NO844653A patent/NO163960C/no unknown
- 1984-11-22 ES ES537870A patent/ES8603511A1/es not_active Expired
- 1984-11-23 FI FI844614A patent/FI79331C/fi not_active IP Right Cessation
- 1984-11-23 PT PT79539A patent/PT79539B/pt not_active IP Right Cessation
- 1984-11-24 JP JP59248575A patent/JPS60133011A/ja active Pending
-
1985
- 1985-11-18 IN IN960/DEL/85A patent/IN166822B/en unknown
Also Published As
Publication number | Publication date |
---|---|
EP0143002A1 (en) | 1985-05-29 |
NO163960B (no) | 1990-05-07 |
NO163960C (no) | 1990-08-15 |
AU3575784A (en) | 1985-05-30 |
EP0143002B1 (en) | 1988-08-31 |
ES537870A0 (es) | 1985-12-16 |
CA1222999A (en) | 1987-06-16 |
FR2555182A1 (fr) | 1985-05-24 |
FI844614L (fi) | 1985-05-24 |
JPS60133011A (ja) | 1985-07-16 |
PT79539B (en) | 1986-10-20 |
DE3473765D1 (en) | 1988-10-06 |
ATE36863T1 (de) | 1988-09-15 |
IN166822B (es) | 1990-07-21 |
FI844614A0 (fi) | 1984-11-23 |
PT79539A (en) | 1984-12-01 |
AU580974B2 (en) | 1989-02-09 |
FI79331B (fi) | 1989-08-31 |
NZ210270A (en) | 1987-10-30 |
US4564605A (en) | 1986-01-14 |
FI79331C (fi) | 1989-12-11 |
NO844653L (no) | 1985-05-24 |
FR2555182B1 (fr) | 1986-11-07 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
FD1A | Patent lapsed |
Effective date: 19970303 |