ES8302618A1 - Procedimiento para convertir los hidroperoxidos presentes en alilalquileteres. - Google Patents
Procedimiento para convertir los hidroperoxidos presentes en alilalquileteres.Info
- Publication number
- ES8302618A1 ES8302618A1 ES510331A ES510331A ES8302618A1 ES 8302618 A1 ES8302618 A1 ES 8302618A1 ES 510331 A ES510331 A ES 510331A ES 510331 A ES510331 A ES 510331A ES 8302618 A1 ES8302618 A1 ES 8302618A1
- Authority
- ES
- Spain
- Prior art keywords
- beta
- alpha
- hydroperoxides
- aldehydes
- ether
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 150000002432 hydroperoxides Chemical class 0.000 title abstract 3
- 238000000034 method Methods 0.000 title abstract 3
- 150000001299 aldehydes Chemical class 0.000 title 1
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 abstract 5
- 125000002485 formyl group Chemical class [H]C(*)=O 0.000 abstract 4
- 238000007037 hydroformylation reaction Methods 0.000 abstract 2
- NWUYHJFMYQTDRP-UHFFFAOYSA-N 1,2-bis(ethenyl)benzene;1-ethenyl-2-ethylbenzene;styrene Chemical compound C=CC1=CC=CC=C1.CCC1=CC=CC=C1C=C.C=CC1=CC=CC=C1C=C NWUYHJFMYQTDRP-UHFFFAOYSA-N 0.000 abstract 1
- 150000001298 alcohols Chemical class 0.000 abstract 1
- 239000007864 aqueous solution Substances 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 abstract 1
- 238000000354 decomposition reaction Methods 0.000 abstract 1
- -1 ether aldehyde Chemical class 0.000 abstract 1
- 239000012535 impurity Substances 0.000 abstract 1
- 230000005764 inhibitory process Effects 0.000 abstract 1
- 239000003456 ion exchange resin Substances 0.000 abstract 1
- 229920003303 ion-exchange polymer Polymers 0.000 abstract 1
- 229910052987 metal hydride Inorganic materials 0.000 abstract 1
- 150000004681 metal hydrides Chemical class 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C43/00—Ethers; Compounds having groups, groups or groups
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/17—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by hydrogenation of carbon-to-carbon double or triple bonds
- C07C29/175—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by hydrogenation of carbon-to-carbon double or triple bonds with simultaneous reduction of an oxo group
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C31/00—Saturated compounds having hydroxy or O-metal groups bound to acyclic carbon atoms
- C07C31/02—Monohydroxylic acyclic alcohols
- C07C31/10—Monohydroxylic acyclic alcohols containing three carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C41/00—Preparation of ethers; Preparation of compounds having groups, groups or groups
- C07C41/01—Preparation of ethers
- C07C41/34—Separation; Purification; Stabilisation; Use of additives
- C07C41/36—Separation; Purification; Stabilisation; Use of additives by solid-liquid treatment; by chemisorption
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C41/00—Preparation of ethers; Preparation of compounds having groups, groups or groups
- C07C41/01—Preparation of ethers
- C07C41/34—Separation; Purification; Stabilisation; Use of additives
- C07C41/44—Separation; Purification; Stabilisation; Use of additives by treatments giving rise to a chemical modification
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/51—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition
- C07C45/53—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition of hydroperoxides
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/61—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups
- C07C45/62—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by hydrogenation of carbon-to-carbon double or triple bonds
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Steroid Compounds (AREA)
- Heterocyclic Carbon Compounds Containing A Hetero Ring Having Oxygen Or Sulfur (AREA)
Abstract
PROCEDIMIENTO PARA LA ELIMINACION DE LOS HIDROXIDOS PRESENTES EN ALILALQUILETERES DE FORMULA (I), EN LA QUE Z , Z , Z Y Z PUEDEN SER HIDROGENO O RADICAL ALQUILO, PUDIENDO Z Y Z FORMAR UN ANILLO DE 5 A 6 ATOMOS DE CARBONO. CONSISTE EN LA REACCION DE REDUCCION DE LOS HIDROPEROXIDOS CON UN HIDRURO METALICO EN DISOLUCION ACUOSA ALCALINA, PARA FORMAR UNA CAPA ORGANICA, QUE SE SEPARA BAJO UN MANTO DE GAS INERTE Y SE LAVA CON AGUA DESGASIFICADA, TRANSFORMANDO LOS HIDROPEROXIDOS EN LOS CORRESPONDIENTES ALCOHOLES. TIENE APLICACION EN LA FABRICACION DE ETERES-ALDEHIDO POR FORMILACION CATALIZADO POR RODIO DE LOS CORRESPONDIENTES ETERES.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US24308281A | 1981-03-12 | 1981-03-12 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| ES8302618A1 true ES8302618A1 (es) | 1983-02-01 |
| ES510331A0 ES510331A0 (es) | 1983-02-01 |
Family
ID=22917298
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES510331A Granted ES510331A0 (es) | 1981-03-12 | 1982-03-11 | Procedimiento para convertir los hidroperoxidos presentes en alilalquileteres. |
Country Status (11)
| Country | Link |
|---|---|
| EP (1) | EP0060523B1 (es) |
| JP (1) | JPS57159735A (es) |
| KR (1) | KR870000543B1 (es) |
| AT (1) | ATE8494T1 (es) |
| AU (1) | AU559430B2 (es) |
| BR (1) | BR8201245A (es) |
| CA (1) | CA1186342A (es) |
| DE (1) | DE3260390D1 (es) |
| ES (1) | ES510331A0 (es) |
| MX (1) | MX158566A (es) |
| ZA (1) | ZA821562B (es) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4599206A (en) * | 1984-02-17 | 1986-07-08 | Union Carbide Corporation | Transition metal complex catalyzed reactions |
| JPS60181859A (ja) * | 1984-02-28 | 1985-09-17 | Fujitsu Ltd | 集合チヤネルの制御方式 |
| BE1008017A3 (nl) * | 1994-01-06 | 1995-12-12 | Dsm Nv | Werkwijze voor de bereiding van 5-formylvaleriaanzure ester. |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3003002A (en) * | 1959-01-08 | 1961-10-03 | Robert N Feinstein | Purification of ether |
| GB981965A (en) * | 1961-03-20 | 1965-02-03 | Gulf Research Development Co | Process for producing oxo alcohol having a low aldehyde content |
| GB1032633A (en) * | 1961-12-07 | 1966-06-15 | Deputy Minister Of Ministerul | An improved process for the elimination of peroxide from ethers |
-
1982
- 1982-03-08 CA CA000397823A patent/CA1186342A/en not_active Expired
- 1982-03-09 ZA ZA821562A patent/ZA821562B/xx unknown
- 1982-03-09 BR BR8201245A patent/BR8201245A/pt not_active IP Right Cessation
- 1982-03-10 AU AU81256/82A patent/AU559430B2/en not_active Ceased
- 1982-03-11 KR KR8201051A patent/KR870000543B1/ko not_active Expired
- 1982-03-11 MX MX191755A patent/MX158566A/es unknown
- 1982-03-11 EP EP19820101961 patent/EP0060523B1/en not_active Expired
- 1982-03-11 AT AT82101961T patent/ATE8494T1/de not_active IP Right Cessation
- 1982-03-11 ES ES510331A patent/ES510331A0/es active Granted
- 1982-03-11 DE DE8282101961T patent/DE3260390D1/de not_active Expired
- 1982-03-11 JP JP3731882A patent/JPS57159735A/ja active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| EP0060523B1 (en) | 1984-07-18 |
| JPS57159735A (en) | 1982-10-01 |
| MX158566A (es) | 1989-02-15 |
| JPS632417B2 (es) | 1988-01-19 |
| AU8125682A (en) | 1982-09-16 |
| CA1186342A (en) | 1985-04-30 |
| KR870000543B1 (ko) | 1987-03-18 |
| AU559430B2 (en) | 1987-03-12 |
| ATE8494T1 (de) | 1984-08-15 |
| BR8201245A (pt) | 1983-01-18 |
| KR830008968A (ko) | 1983-12-16 |
| ES510331A0 (es) | 1983-02-01 |
| EP0060523A1 (en) | 1982-09-22 |
| DE3260390D1 (en) | 1984-08-23 |
| ZA821562B (en) | 1983-01-26 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FD1A | Patent lapsed |
Effective date: 19970401 |