ES2909389T3 - Formulaciones de ácido 1-amino-1-ciclopropanocaboxílico - Google Patents
Formulaciones de ácido 1-amino-1-ciclopropanocaboxílico Download PDFInfo
- Publication number
- ES2909389T3 ES2909389T3 ES18774530T ES18774530T ES2909389T3 ES 2909389 T3 ES2909389 T3 ES 2909389T3 ES 18774530 T ES18774530 T ES 18774530T ES 18774530 T ES18774530 T ES 18774530T ES 2909389 T3 ES2909389 T3 ES 2909389T3
- Authority
- ES
- Spain
- Prior art keywords
- formulation
- acc
- weight
- calcium chloride
- concentration
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 68
- 238000009472 formulation Methods 0.000 title claims abstract description 64
- PAJPWUMXBYXFCZ-UHFFFAOYSA-N 1-aminocyclopropanecarboxylic acid Chemical compound OC(=O)C1(N)CC1 PAJPWUMXBYXFCZ-UHFFFAOYSA-N 0.000 title abstract description 64
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 claims abstract description 29
- 239000001110 calcium chloride Substances 0.000 claims abstract description 29
- 229910001628 calcium chloride Inorganic materials 0.000 claims abstract description 29
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 16
- 238000000034 method Methods 0.000 claims description 21
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 claims description 18
- 235000013399 edible fruits Nutrition 0.000 claims description 15
- 241000196324 Embryophyta Species 0.000 claims description 14
- 239000004575 stone Substances 0.000 claims description 9
- 235000014787 Vitis vinifera Nutrition 0.000 claims description 8
- 239000003755 preservative agent Substances 0.000 claims description 8
- 244000141359 Malus pumila Species 0.000 claims description 6
- 235000011430 Malus pumila Nutrition 0.000 claims description 6
- 235000015103 Malus silvestris Nutrition 0.000 claims description 6
- 235000006040 Prunus persica var persica Nutrition 0.000 claims description 6
- 235000009754 Vitis X bourquina Nutrition 0.000 claims description 6
- 235000012333 Vitis X labruscana Nutrition 0.000 claims description 6
- 244000144730 Amygdalus persica Species 0.000 claims description 5
- 240000006365 Vitis vinifera Species 0.000 claims description 5
- 239000002738 chelating agent Substances 0.000 claims description 5
- 235000006029 Prunus persica var nucipersica Nutrition 0.000 claims description 4
- 244000017714 Prunus persica var. nucipersica Species 0.000 claims description 4
- 235000002532 grape seed extract Nutrition 0.000 claims description 2
- BEGLCMHJXHIJLR-UHFFFAOYSA-N methylisothiazolinone Chemical compound CN1SC=CC1=O BEGLCMHJXHIJLR-UHFFFAOYSA-N 0.000 claims description 2
- 230000002335 preservative effect Effects 0.000 claims description 2
- 239000000243 solution Substances 0.000 description 16
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 15
- 239000005977 Ethylene Substances 0.000 description 15
- 230000000694 effects Effects 0.000 description 11
- 239000007921 spray Substances 0.000 description 9
- JPMIIZHYYWMHDT-UHFFFAOYSA-N octhilinone Chemical compound CCCCCCCCN1SC=CC1=O JPMIIZHYYWMHDT-UHFFFAOYSA-N 0.000 description 8
- 241000219095 Vitis Species 0.000 description 7
- 238000004519 manufacturing process Methods 0.000 description 7
- 229920000742 Cotton Polymers 0.000 description 6
- 231100000674 Phytotoxicity Toxicity 0.000 description 6
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 6
- 238000001556 precipitation Methods 0.000 description 6
- 150000003839 salts Chemical class 0.000 description 6
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 4
- 230000015572 biosynthetic process Effects 0.000 description 4
- 239000007788 liquid Substances 0.000 description 4
- LXCFILQKKLGQFO-UHFFFAOYSA-N methylparaben Chemical compound COC(=O)C1=CC=C(O)C=C1 LXCFILQKKLGQFO-UHFFFAOYSA-N 0.000 description 4
- 239000002244 precipitate Substances 0.000 description 4
- QELSKZZBTMNZEB-UHFFFAOYSA-N propylparaben Chemical compound CCCOC(=O)C1=CC=C(O)C=C1 QELSKZZBTMNZEB-UHFFFAOYSA-N 0.000 description 4
- 238000011282 treatment Methods 0.000 description 4
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 3
- 241000219977 Vigna Species 0.000 description 3
- 239000007864 aqueous solution Substances 0.000 description 3
- 238000003860 storage Methods 0.000 description 3
- CHHHXKFHOYLYRE-UHFFFAOYSA-M 2,4-Hexadienoic acid, potassium salt (1:1), (2E,4E)- Chemical compound [K+].CC=CC=CC([O-])=O CHHHXKFHOYLYRE-UHFFFAOYSA-M 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- 235000010726 Vigna sinensis Nutrition 0.000 description 2
- 241000219094 Vitaceae Species 0.000 description 2
- 235000010323 ascorbic acid Nutrition 0.000 description 2
- 239000011668 ascorbic acid Substances 0.000 description 2
- 229960005070 ascorbic acid Drugs 0.000 description 2
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 2
- 235000021028 berry Nutrition 0.000 description 2
- 231100000673 dose–response relationship Toxicity 0.000 description 2
- 235000021021 grapes Nutrition 0.000 description 2
- -1 known stabilizers Chemical class 0.000 description 2
- 230000028514 leaf abscission Effects 0.000 description 2
- 239000004292 methyl p-hydroxybenzoate Substances 0.000 description 2
- 235000010270 methyl p-hydroxybenzoate Nutrition 0.000 description 2
- 229960002216 methylparaben Drugs 0.000 description 2
- 235000010241 potassium sorbate Nutrition 0.000 description 2
- 239000004302 potassium sorbate Substances 0.000 description 2
- 229940069338 potassium sorbate Drugs 0.000 description 2
- 239000002243 precursor Substances 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 235000010232 propyl p-hydroxybenzoate Nutrition 0.000 description 2
- 239000004405 propyl p-hydroxybenzoate Substances 0.000 description 2
- 229960003415 propylparaben Drugs 0.000 description 2
- 230000004044 response Effects 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 239000003381 stabilizer Substances 0.000 description 2
- 230000002195 synergetic effect Effects 0.000 description 2
- 238000004383 yellowing Methods 0.000 description 2
- 101710194665 1-aminocyclopropane-1-carboxylate synthase Proteins 0.000 description 1
- QYYMDNHUJFIDDQ-UHFFFAOYSA-N 5-chloro-2-methyl-1,2-thiazol-3-one;2-methyl-1,2-thiazol-3-one Chemical compound CN1SC=CC1=O.CN1SC(Cl)=CC1=O QYYMDNHUJFIDDQ-UHFFFAOYSA-N 0.000 description 1
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 1
- 241000167854 Bourreria succulenta Species 0.000 description 1
- OCUCCJIRFHNWBP-IYEMJOQQSA-L Copper gluconate Chemical class [Cu+2].OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C([O-])=O.OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C([O-])=O OCUCCJIRFHNWBP-IYEMJOQQSA-L 0.000 description 1
- 244000018633 Prunus armeniaca Species 0.000 description 1
- 235000009827 Prunus armeniaca Nutrition 0.000 description 1
- 240000005809 Prunus persica Species 0.000 description 1
- 244000042314 Vigna unguiculata Species 0.000 description 1
- 235000010722 Vigna unguiculata Nutrition 0.000 description 1
- 230000006578 abscission Effects 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000002518 antifoaming agent Substances 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 235000006708 antioxidants Nutrition 0.000 description 1
- 239000013011 aqueous formulation Substances 0.000 description 1
- DMSMPAJRVJJAGA-UHFFFAOYSA-N benzo[d]isothiazol-3-one Chemical compound C1=CC=C2C(=O)NSC2=C1 DMSMPAJRVJJAGA-UHFFFAOYSA-N 0.000 description 1
- 150000001558 benzoic acid derivatives Chemical class 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 235000019693 cherries Nutrition 0.000 description 1
- 150000001860 citric acid derivatives Chemical class 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 235000009508 confectionery Nutrition 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 229910001873 dinitrogen Inorganic materials 0.000 description 1
- SZXQTJUDPRGNJN-UHFFFAOYSA-N dipropylene glycol Chemical compound OCCCOCCCO SZXQTJUDPRGNJN-UHFFFAOYSA-N 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- DEFVIWRASFVYLL-UHFFFAOYSA-N ethylene glycol bis(2-aminoethyl)tetraacetic acid Chemical compound OC(=O)CN(CC(O)=O)CCOCCOCCN(CC(O)=O)CC(O)=O DEFVIWRASFVYLL-UHFFFAOYSA-N 0.000 description 1
- 230000005089 fruit drop Effects 0.000 description 1
- 230000005094 fruit set Effects 0.000 description 1
- 238000004817 gas chromatography Methods 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000003966 growth inhibitor Substances 0.000 description 1
- 239000003906 humectant Substances 0.000 description 1
- 238000005470 impregnation Methods 0.000 description 1
- 239000000411 inducer Substances 0.000 description 1
- 230000005764 inhibitory process Effects 0.000 description 1
- 230000036244 malformation Effects 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 230000001376 precipitating effect Effects 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 238000010561 standard procedure Methods 0.000 description 1
- 230000035882 stress Effects 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 230000021918 systemic acquired resistance Effects 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N53/00—Biocides, pest repellants or attractants, or plant growth regulators containing cyclopropane carboxylic acids or derivatives thereof
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/02—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing liquids as carriers, diluents or solvents
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/22—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing ingredients stabilising the active ingredients
Landscapes
- Life Sciences & Earth Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Health & Medical Sciences (AREA)
- Dentistry (AREA)
- Zoology (AREA)
- Plant Pathology (AREA)
- Environmental Sciences (AREA)
- Engineering & Computer Science (AREA)
- Agronomy & Crop Science (AREA)
- Wood Science & Technology (AREA)
- Pest Control & Pesticides (AREA)
- Toxicology (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Cultivation Of Plants (AREA)
- Medicinal Preparation (AREA)
- Acyclic And Carbocyclic Compounds In Medicinal Compositions (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201762479540P | 2017-03-31 | 2017-03-31 | |
| PCT/US2018/025148 WO2018183680A1 (en) | 2017-03-31 | 2018-03-29 | 1-amino-1-cyclopropanecaboxylic acid formulations |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2909389T3 true ES2909389T3 (es) | 2022-05-06 |
Family
ID=63672356
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES18774530T Active ES2909389T3 (es) | 2017-03-31 | 2018-03-29 | Formulaciones de ácido 1-amino-1-ciclopropanocaboxílico |
Country Status (15)
| Country | Link |
|---|---|
| US (1) | US10517299B2 (https=) |
| EP (1) | EP3600279B1 (https=) |
| JP (4) | JP7077337B2 (https=) |
| CN (2) | CN115777699B (https=) |
| AR (1) | AR111550A1 (https=) |
| AU (2) | AU2018243281B2 (https=) |
| CL (1) | CL2019002729A1 (https=) |
| ES (1) | ES2909389T3 (https=) |
| IL (1) | IL268678B (https=) |
| MX (1) | MX391757B (https=) |
| PE (1) | PE20200405A1 (https=) |
| PL (1) | PL3600279T3 (https=) |
| UA (1) | UA125528C2 (https=) |
| WO (1) | WO2018183680A1 (https=) |
| ZA (1) | ZA201905379B (https=) |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US11350630B2 (en) * | 2017-03-31 | 2022-06-07 | Valent Biosciences Llc | 1-amino-1-cyclopropanecarboxylic acid hydrochloride formulations |
| EP3600280B1 (en) * | 2017-03-31 | 2024-05-01 | Valent BioSciences LLC | 1-amino-1-cyclopropanecarboxylic acid hydrochloride formulations |
| AU2022214462B2 (en) * | 2021-02-01 | 2024-09-12 | Valent Biosciences Llc | 1-amino-1-cyclopropanecarboaylic acid solid compositions |
| MX2023009032A (es) * | 2021-02-01 | 2023-08-09 | Valent Biosciences Llc | Proceso para la preparacion de granulos de acido 1-amino-1-ciclopropanocarboxilico. |
| UY39924A (es) * | 2021-09-03 | 2023-03-31 | Valent Biosciences Llc | Ácido 1-amino-1-ciclopropancarboxílico para el raleo de frutos |
| EP4599071A2 (en) * | 2022-10-03 | 2025-08-13 | Valent BioSciences LLC | 1-amino-1-cyclopropanecarboxylic acid and prohydrojasmon mixtures and uses thereof |
| WO2025117570A1 (en) * | 2023-11-30 | 2025-06-05 | Virginia Tech Intellectual Properties, Inc. | Use of ethylene inhibitors and 1-aminocyclopropane-l- carboxylic acid for improved fruit maturation |
Family Cites Families (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2824517A1 (de) * | 1978-06-03 | 1979-12-06 | Bayer Ag | Mittel zur regulierung des pflanzenwachstums |
| DE2936038A1 (de) * | 1979-09-06 | 1981-03-26 | Bayer Ag, 51373 Leverkusen | Verfahren zur herstellung von 1-aminocyclopropan-carbonsaeure und deren derivaten |
| US8247352B2 (en) * | 2005-03-11 | 2012-08-21 | The Regents Of The University Of California | Method of inhibiting ethylene production in plants |
| BRPI0819106A2 (pt) * | 2007-11-08 | 2014-10-07 | Valent Biosciences Corp | Métodos para melhorar a cor de uva vermelho e alterar as características sensoriais do vinho, e para melhorar as características sensoriais de vinho branco |
| CN101475790B (zh) * | 2008-01-04 | 2012-10-10 | 杨光 | 新型木材胶粘剂及其制备方法 |
| MX2008013788A (es) * | 2008-10-16 | 2010-04-16 | Miguel Angel Martinez Tellez | Metodo para el control de la coloracion en uva de mesa, a partir de los oligogalacturonidos. |
| WO2010123872A1 (en) * | 2009-04-20 | 2010-10-28 | Valent Biosciences Corporation | Plant growth enhancement with combinations of pesa and plant growth regulators |
| EP2440516B1 (en) * | 2009-06-12 | 2014-03-05 | Valent Biosciences Corporation | 1-aminocyclopropane carboxylic acid as a fruit thinner |
| CN101715760A (zh) * | 2009-12-01 | 2010-06-02 | 山东营养源食品科技有限公司 | 1-甲基环丙烯液体制剂 |
| MX2013005529A (es) | 2010-11-19 | 2013-07-03 | Isp Investments Inc | Composicion conservadora concentrada acuosa y estable de acido deshidroacetico (dha) y metilisotiazolinona. |
| US8993484B1 (en) | 2013-10-04 | 2015-03-31 | Fmc Corporation | Methods for improving plant growth |
-
2018
- 2018-03-27 AR ARP180100746A patent/AR111550A1/es active IP Right Grant
- 2018-03-29 CN CN202310047759.4A patent/CN115777699B/zh active Active
- 2018-03-29 AU AU2018243281A patent/AU2018243281B2/en active Active
- 2018-03-29 ES ES18774530T patent/ES2909389T3/es active Active
- 2018-03-29 PE PE2019001903A patent/PE20200405A1/es unknown
- 2018-03-29 US US15/940,345 patent/US10517299B2/en active Active
- 2018-03-29 JP JP2019552599A patent/JP7077337B2/ja active Active
- 2018-03-29 EP EP18774530.2A patent/EP3600279B1/en active Active
- 2018-03-29 WO PCT/US2018/025148 patent/WO2018183680A1/en not_active Ceased
- 2018-03-29 CN CN201880013031.7A patent/CN110461320B/zh active Active
- 2018-03-29 MX MX2019011613A patent/MX391757B/es unknown
- 2018-03-29 PL PL18774530T patent/PL3600279T3/pl unknown
- 2018-03-29 UA UAA201910035A patent/UA125528C2/uk unknown
-
2019
- 2019-08-13 IL IL268678A patent/IL268678B/en unknown
- 2019-08-14 ZA ZA2019/05379A patent/ZA201905379B/en unknown
- 2019-09-25 CL CL2019002729A patent/CL2019002729A1/es unknown
-
2021
- 2021-12-23 JP JP2021209249A patent/JP7291774B2/ja active Active
-
2023
- 2023-04-20 JP JP2023069460A patent/JP7633303B2/ja active Active
- 2023-07-19 AU AU2023206127A patent/AU2023206127B2/en active Active
-
2024
- 2024-12-17 JP JP2024220699A patent/JP7763321B2/ja active Active
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